36 Figure 14: (a) Image MET en champ clair du matériau vitrocéramique 55SiO 2 -5Na 2 O-17ZnO-23Ga 2 O 3

obtenu après une cristallisation à 1000° C sur une durée de 10 mn (b) Intensité d’émission en luminescence à 696 nm en fonction du temps pour la vitrocéramique 55SiO2-5Na2O-17ZnO-23Ga2O3

dopée au Cr3+. ... I-25

Figure 15: Images MEB des vitrocéramiques du système B2O3-BaO cristallisées en surface, obtenues avec différents traitements thermiques : (a) 550 ° C pendant 30 h; (b) 575 ° C pendant 5h (c) 600 ° C pendant 10 h, (d) 800 ° C pendant 1 h et (e) 900 ° C pendant 1 h [50]. ... I-30 Figure 16: images MEB de la surface des échantillons traités thermiquement à 620°C pendant 1h : (a) sans modification de surface, (b) surface exposée aux vibrations ultrasoniques dans une solution aqueuse de β-BBO avant le traitement thermique [58] ... I-31 Figure 17: Photo-précipitation de la Phase LaBGeO5 dans le verre 25La2O3-25B2O3-25GeO2 ... I-32 Figure 18: Images obtenues par microscopie optique de polarisation. La longueur d’onde du laser d’écriture est de λ=546 nm [67] ... I-33

I-37

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