Dickite

La dickite est une argile de la famille des kaolins qui possède la particularité de ne pas contenir d’ions dans la zone inter-feuillets. Ceci en fait une référence plus simple à étudier que les autres argiles car aucun processus d’échange d’ions n’a lieu entre les inter-feuillets et la solution extérieure.

Ce composé sera plus largement décrit et étudié au chapitre II de la seconde partie de ce manuscript.

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Chapitre II :

Ce chapitre présente des travaux préliminaires à l’étude des sorptions. En effet, étudier l’adsorption d’espèces contenues dans une solution aqueuse sur une surface requiert de connaître la surface de manière précise. La structure, la charge ainsi que l’état de cette surface sont autant de paramètres majeurs influençant la sorption d’espèces.

Cette partie s’intéresse donc à l’étude des surfaces monocristallines (110) et (001) par des techniques spectroscopiques complémentaires telles que les spectroscopies électroniques (AR-XPS), optiques (µ-Raman polarisé en champ lointain et en champ proche) et de forces (AFM liquide).

Dans le document Contribution à l'étude des interactions ions-surfaces : application aux systèmes Se(IV), Se(VI), U(VI) sur TiO2 rutile et Eu(III) sur dickite (Page 53-65)