3.
Par addition d’une quantité croissante de AgClO4 permettant la précipitation du ligand axial Cl- initialement coordiné à [FeIII(F20TPP)Cl] , l’espèce [FeIII
(F20TPP)DMF] est obtenue. Sa formation est suivie par CV sous argon.
-0.2 -0.1 0.0 0.1 0.2 0.3 -4 -3 -2 -1 0 1 2 3 I (µA) E (V vs SCE) +AgClO4
Figure A-4 : CV Fe(F20TPP) à 0.5 mM dans DMF + 0.1 M TBAPF6 à l’électrode de carbone vitreux ( d= 3 mm) à T = 293 K sous argon (en noir) et après ajout d’une quantité croissante, 0, 1, 2, 3, 4 et 5 mM de AgClO4 sous argon (en rouge) .vb =0.1 V.s1
134 -0.2 -0.1 0.0 0.1 0.2 0.3 -4 -3 -2 -1 0 1 2 3 I (µA) E (V vs SCE)
Figure A- 5 : CV Fe(F20TPP) à 0.5 mM dans DMF + 0.1 M TBAPF6 à l’électrode de carbone vitreux ( d= 3 mm) à T = 293 K sous argon (en noir),après ajout de 5 mM de TBACl (en bleu) et après ajout de 5 mM de AgClO4 sous argon (en rouge) .vb =0.1 V.s1
135
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