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Limitation of the Polarization by Radiation Trapping in
a Helium Afterglow Electron Source
I. Brissaud, C. Jacquemin
To cite this version:
J.
Phys.
II France 5(1995)
93-102 JANUARY 1995, PAGE 93Classification
Physics Abstracts 42.65J 32.80P
Limitation
of the
Polarization
by
Radiation
Trapping
in
aHelium
Afterglow
Electron
Source
1. Brissaud and C.
Jacquemin
Institut de
Physique
Nucldaire,
91406Orsay
Cedex, France(Received
7April
1994, revised 23September
1994,accepted
28September
1994)
Abstract. A
polarized
electron source using an opticallypumped
heliumafterglow
was built atOrsay.
Unfortunately
thespin
polarization
decreases athigh
metastable densities.Calculations of the radiation
trapping
effects in a weakmagnetic
field arepresented
using
theAnderson formalism.
Comparison
withexperimental
data leads to the conclusion that thesetrapping
effects are oneexplanation
of thispolarization
decrease. Effects of the main parametersare studied. Some deductions for a new
design
can be made.1. Introduction
A
polarized
electron source was built atOrsay
[1]using
anoptically
pumped
heliumafter-glow.
This source isadapted
from the RiceUniversity
modeldesigned by
Walters et al. [2].Metastable helium atoms in the
2~Si
state arepolarized
by
optical
pumping
to the2~Po
stateby
polarized
light.
Electrons are freedthrough
a chemi-ionization process such that thepolar-ization of the metastables and of the electrons should be the same. Therefore
100%
polarization
15
expected.
However in theOrsay
experiment
[3] the electronpolarization
values vary from80 ~
7%
for low helium pressureii-e-
low metastabledensity)
to 55 ~5%
forhigh
pressureii-e-high
metastabledensity).
A similar effect was also observed in aprevious
work[2].
Apos-sible
explanation
for thisdepolarization
phenomenon
could be resonance radiationtrapping,
I-e- the
reabsorption
ofunpolarized
deexcitationphotons
in the gas. This effect isstrongly
dependent
on the metastable densities in the media In this paper we present ouranalysis
of thisquestion.
However,
in order toexplain
thepolarization
loss at low helium pressure,where the radiation
trapping
isexpected
to benegligible,
one also has to take into accountintrinsic
depolarization
factors. Thesemight
be:I)
theimperfect efficiency
of theexperimental
apparatus:
incomplete
polarization
of the laserlight,
beamsslightly
out ofalignments,
andit) physical
difficulties: metastable atoms in thesinglet
state 2~So(estimated
to be less than 5Slo),polarization
degradation
in the chemi-ionization process, etc. Each of these factors may account for apolarization
loss of a fewpercent.
Thusperhaps
10%
metastabledepolarization
could be accounted for
by
all these mechanisms.2.
Experimental
Set-Up
A
high
purity
heliumjet
is ionized and excitedthrough
a Laval nozzle microwavedischarge
cavity
(Fig.
1).
Electrons and ions recombine at the wall of a 35 cmlong,
10 cm diameter pyrextube
forming
a mixture ofground
state and metastable2~Si
helium atoms.By
the action of apowerful
Roots blower the bulk gas flow has an averagespeed
of1.2 x10~
cm.s~~
in thepumping
chamber. For a helium pressure of 5 x10~~
to 2 x10~~
mb(approximately
10~~ atomscm~~
heliumdensity)
the metastabledensity
is several times10~° cm~~.
The destruction of metastables at the wallyields
anexponential
rate ofdecay,
down thetube,
of the metastabledensity.
The diffusiondecay length
is dd= o
R~
v
P/(DP)
where R is the tuberadius,
iJ the average gas
speed,
P the helium pressure and D the diffusion coefficient. In our case,between the molecular and the viscous flow case~ a is close to 0.27 and DP is 470
cm2torr
s~~
[4~
5].
The measured and calculated values of dd are between 10 and 15 cmThe horizontal earth
magnetic
field components are cancelledby
twopairs
of Helmholtz coilswhile a third
pair produces
a 2.5 gauss vertical fielddefining
thequantization
axis. Theoptical
pumping
is doneby
acircularly
polarized
alight
beamparallel
to themagnetic
field and alinearly
polarized
1rlight
beamperpendicular
to this field. These beams haveapproximately
equal
intensities and areprovided by
a multimode LNA laserthrough
a beamsplitter.
Figure
2shows the electric
dipole
transition at 1.083 pmwavelength
between the2~Si
and2~Po
states.The
pumping
occurs in a 10 cm cubic chamber attached to the end of the pyrex tube[3].
Thelight
beams have about the same diameter as the windows of thepumping
chamber. Themetastable densities are measured
by
theabsorption
of a ~= 1.083 ~tm
probe
beamprovided
Roots Laser c~ B Extraction RF
heating
Microwave oCavity
Laser 7t'He/
N°1 RADIATION TRAPPING 95
2P~
J=0 In°°1 6,~~
~@ ,~ ms=+i In+I ' rns =o no 2 S~ J= ms=-i In-1Fig.
2.Energy
levels of the helium metastable atoms. The a+ andx transitions used for
optical
pumping
are shown.Spontaneous
emissions from the2~Po
level reabsorbedby
the metastables arepresented.
by
a heliumlamp
orby
asingle mode,
low power, diodepumped,
LNA laser[6].
In this workthe
absorption
istypically
10 to20%.
The
Doppler
width,
A =2kTtn2/M(~~
k,T~
M are thepumping
wavelength,
theBoltz-mann
constant~
the absolutetemperature
and the helium massrespectively)
is very widecom-pared
to the Zeemansplitting
of the2~Si
levels in the very weakmagnetic
field(Landd
gfactor
=
2).
Therefore the radiation emittedby
the transitions from the2~Po
state to any oneof the
2~Si
substates can be reabsorbedby
any one of the threemagnetic
substates of the2~Si
metastable atoms. This considerationexplains
thelarge
probability
of thetrapping
effect.3. Radiation
lkapping
EvaluationThe densities of the metastable atoms in m
=
+1~o,-1
substates of the2~Si
triplet
aren+(f, t),n°(f~
t),n~(f~ t)
respectively
whilen°°(f,
t)
represents
thedensity
for the2~Po
state.At time t and
position
f the total excited statedensity
is thus n = n+ +n°
+ n~ +n°°
(the
n~(f, t) being
systematically
replaced
belowby
n~ forconvenience).
The four rateequations
describing
the densities in the various excited states are in the case ofa+
and 1rpumping,
without radiation
reabsorption:
dn~ n~ ~~
11
n~$
rp ~ ~ 3r ~ rp rr~~0
~0
~~~0
$
rp, ~ ~ 3r ~ rp> rr ~~~dn+
n°°
n+
$
3r rrdn°°
n~n°
~o 1I
rp ~ rp> ~ r ~ rp ~ rp>These
equations
describe what ishappening
as a function of time in the reference frame of the gas as it enters theoptical
pumping region
until itleaves,
and rr is the relaxation time.the form
1/rp
=
"
~'
and
1/rp,
='~ ~~
where
I,
andI~
are the intensities per unit areahu hu
for the
light
source and v is thefrequency
of this radiation. a, and a~ are theabsorption
cross sections for the
circularly
andlinearly
polarized
radiationdepending
on the normalizedDoppler
lineshape
Jf ~2 1/2 ~ ~~ 2
~~2
~~"
"°~~
21rkTu(
~~~ uo 2kT 'with uo "
c/~o,
~o
being
the resonance wavelength
1.083 ~tm.A correction due to the laser width
(2.5
x 10~s~~)
is deducedfollowing
theprocedure
suggested
by
Mitchell and Zemanski [7]. This correction reduces the cross sections a, and a~approximately
by
a factor 2 at~o.
These cross sections are the state-to-stateabsorption
crosssection for the
2~Si
(m~
=-1)
-2~Po
(m~
=o)
and2~Si
(m
=o)
-2~Po
(m
=o)
transitionsrespectively.
a, and a~ can be calculated from the classical level-to-level2~Si
-2~Po
absorption
cross section:all = ~~ ~
F(u
uo ,(2)
g~8~r
where gf and gi are the final and initial state statistical
weights
Thesequantities
arepro-vided
by
means of the matrix elements of the components of the electricdipole
operator p:(j'm'(p~(
jai)
with=
+1,o,-1
[8]. From these matrix elements one finds that all threetransitions
2~Po
-2~Si
have the sameprobability.
Note that the level-to-levelabsorption
cross sections
(2)
are forunpolarized
light.
The three state-to-stateabsorption
cross sections~2
are
equal
to-F(u
uo).
Inequations
(1)
then°°
/rp
andn°°/rp>
termscorrespond
to the 81rrstimulated transitions and are very weak and
negligible.
The relaxation time rr is
governed by
the metastable diffusion to the walls [9]. It can beevaluated from classical diffusion
theory
[10]
as rr = oR2P/(DP).
Acomplete
discussion ofthe measurements and calculations of rr has been achieved
by
Rice [4].To take the radiation
trapping
effects intoaccount,
we use theprocedure
proposed by
An-derson and coworkers
[10].
We summarise thisprocedure
as follows:At
point
f',
an atom in the2~Po
statedecays
to any of the three2~Si
substates and the emitted radiation is absorbed at apoint
fby
a metastable in any of the three2~Si
substates.Then the
trapping
contribution [10] to the rateequations
(1)
is,
for theexample
of then+
density:
dn+
(f,t)
dt
-n°°
/
£
d~fduPj(9)
exp
£
aj(9)(n~
n°°)(f
f)
aj(b)(n+
n°°)
,
(3)
~ ~
where
Pj (9)
is thedipolar
emissionprobability
between the level2~P
and the j Zeeman substateof the 2~S level.
aj
(9)
is theabsorption
cross section of the radiation emittedby
the deexcitationof
2~P
-
2~S
(in
the Zeeman substate m =j)
by
atoms in the Zeeman substate m = i.This radiation is
polarized
and itspolarization
is definedby
the Am selection rule. In thequantities
aj(9),
1 and jrepresent
the Am values of the radiation emissionii)
and of theradiation
absorption
j)
in thetrapping
process. The nine valuesaj
(9)
aregiven
inAppendix.
Here 9 is the
angle
between the direction T f' and thequantization
axis. Theexponential
N°I RADIATION TRAPPING 97
probability
at thepoint
f. Similarexpressions
for n~ andn°
can be obtained. Inaddition,
there is a fourth contribution to the rate
equations.
It is due to the2~P
state and can bedn°°
~
dn~ ~~~~~~~"dt
~
dt'
These
integro-differential
equations
are nonlinear and nonlocal. In order tosimplify
thenumerical calculations of these
equations
thefollowing
assumptions
are made:I)
the statepopulations n+,
n°,
n~,n°°
areindependent
off inside thepumping
chamber;
it)
theintensity
of the laserlight
is uniform on the window of the chamber.The first
assumption,
to be discussedlater,
allows ananalytical
integration
over f. Theinte-grations
overfrequency
andangle
areperformed by using
Hermitian-Gaussianapproximation
methods. We denote
by
x~ the nodes andby
uJ~ theweighting
factors of the Hermiteintegra-tion method
[11],
and denoteby
uj the nodesa~lj
by
uJ~j theweighting
factors of the Gaussintegration
method[iii.
Also ~~=
~~
~e~X~.
Thisyields
thefollowing
expression
81rr
21rkT~
in theexample
of n~:~t
2~r
~'~ '~~~l~
"~~j
"~~~
~~~ ~"~~'~~~
~ "~~~
~~~ withR7~i~i(uj)
j~
~2)2
I eXpl~l(llJ)
" ~j~
~~fi
~l J§~i(llJ)
"(~
ll~)(~
~~~)
+ll~
(
~~(~~
~~~)
+j~
~~2)~~~
~~~
' j j 1 exp~~~ ~~~~~~
F3(llJ)
"fi~
~~ §~3 llj with~J~(uj)
=(1
u))(n~
n°°)
+u)(n°
n°°)
+(1
u))(n+
n°°).
(4)
andR71§'5(uj)
exp i uj~
~~~~fi
§~5(llJ)
J with§'5(llJ)
j~
~~2)
~~ ~~~~ ~ ~~~
~~
~~~ ~~~~ ~ ~~~~~~~~
~~~~'
j jSimilar results can be written for
n+
andn°.
The detailed calculations areclearly
presented
The final necessary
parameters
are:I)
the initial values of the densitiesn+
= n~ =
n°
=n/3
andn°°
= 0
it)
the total laserintensity
I percm2
withI,
=I~
=1/2
iii)
the relaxation time rr; andiv)
the radius R of thepumping
chamber(in
ourexperiment
R = 5cm).
The total
density
ndepends
on the helium pressure and varies between10~
and 10~~cm~~.
4. Results and Discussion
With the inclusion of the
trapping
terms the rate equations are nolonger
linearand,
evenin their
steady-state
form,
they
cannot be solvedanalytically.
Therefore thesteady-state
limiting
values of the densities have been obtainedby
a numericalintegration
withrespect
to time. This numerical
integration
has beenperformed
by
two differentcodes,
run on twodifferent
computers.
These codes were writtenindependently,
using
two different numericalintegration
methods The results were identical within thecomputer's
accuracies.Therefore,
anydiscrepancy
between theoreticalpredictions
andexperimental
data must result from themodel,
notprogramming
errors.Figure
3displays
the time evolution of the calculatedpolarizations,
for various metastableinitial
densities,
taking
radiationtrapping
into account. For adensity
less than10~
cm~~
trapping
isnegligible
and the saturatedpolarization
value is of the order of80%,
while for aninitial
density
larger
than 2 x 10~~cm~~
thetrapping
effect is sostrong
that this saturatedvalue is reduced to a few
percent.
Precise values of the upper and lower bounds for the initialdensity
depend
on the parameter values used as well as on theapproximations
made in orderto
simplify
the numerical calculation. The same set of initial metastabledensity
values has been used in a calculation withouttrapping
effect;
for any of these densities anasymptotic
polarization
value close to85%
is obtained. These resultsclearly
showthat,
forhigh
metastableinitial
densities,
thetrapping
effectmight
account for the lowasymptotic
polarization
value ofmetastable atoms.
Figure
4 shows the calculatedpolarization
versus the laserintensity
with and withouttrap-ping:
ahigher
laserintensity
will result in ahigher
polarization
and saturation is reachedat
approximately
13mWcm~2.
This theoretical result agrees with theexperimental
one ofSchearer
[12].
In the Schearerexperiment
thepolarization
is saturated at a 17mWcm~2
in-tensity
while in the Waltersexperiment
thepolarization
is saturated at 2 mWcm~2.
If onetakes into account the
larger absorption
cross section in the Riceexperiment,
this lastintensity
value would
correspond
roughly
to a 12 mWcm~2
intensity
m our case. This means that weare interested in laser intensities
higher
than 15 mWcm~2,
ifpossible.
For a total
density
of 3 x10~°
cm~~,
the mean freepath
of the 1.083 ~tmphotons
is about15 cm.
Consequently,
if thepumping
chamber dimension isreduced,
theprobability
ofphotons
escaping
from the chamber increasessharply,
resulting
in lower radiationtrapping.
This isconfirmed
by
the calculations. Indeed if the radius of the chamber is varied from 7.5 cm to 2.5 cm thepolarization
increases from68%
to81%.
One concludes that a small dimension of thepumping
chamber is theright
choice.But,
such a reduction leads to shortened diffusiondecay
lengths'and
reduces the metastabledensity
and thus the electron currents that can beproduced
by
the source. Forinstance,
in a 1 cm diametertransport
tube the metastablesare
completely
destroyed.
So anoptimisation
procedure
must beapplied
insearching
for theN°1 RADIATION TRAPPING 99 p~ a 80 b 60 c ,o d e 20 f 0 0.5 5 2 2 5 , t (10~ s
Fig.
3. Polarization values calculatediJersus the time t for different metastable densities
la:
0.I,b 10, c. 5 0, d. 7 5, e- 100, f: 13-0, g: 20.0 m 10~° cm~~
unit).
The laser intensity is 7 mwcm~~-The radiationtrapping
is includedby
contributions(4)
to rate equations 11).no trapping
trapping 50
0 5 10 15
lmwcm-2)
Fig-
4 Polarization values calculated versus the laser intensity I with and without radiationtrapping. The metastable
density
is 3.0 x 10~° cm~~.One way to increase the electron current is to increase the metastable
density
by shortening
the
transport
tube. However this still increases thetrapping
effect and thus reduces thepolarization
achievable.Again
acompromise
must be found.Figure
5 showsexperimental
values of the metastablepolarization
versus thepumping
laserpower for two different
configurations: a)
helium pressure P = o.09 mb and metastabledensity
n < o.5 x
10~°
cm~~; b)
helium pressure P = o.16mb,
and metastabledensity
n ~J1.4 x
10~°
cm~~,
the otherparameters
remaining
equal
(the
curves areonly
aguide
for theeye).
The difference of
shape
is due to thetrapping
effect as isproved by
the curves ofFigure
4. This confirms theimportance
of this effect.Figure
6 shows the calculatedpolarizations
with the radiationtrapping
included for laserintensities of 7 and 5
mwcm~~
(these
values aretypical
of ourlaser),
as well asexperimental
metastable and electron
polarizations.
Theexperimental
values decrease athigher
metastable densitiesfollowing
thegeneral
trends of the calculatedpolarizations.
Notice however that theexperimental
polarizations
decreaseslightly
faster than the calculated ones Thisqualitative
agreement
confirms the effect of radiationtrapping.
The metastableexperimental
values aren
light
powerlmwcm-21
2 100 ~ Pl%I a ~ o 50 a = low P and n b= high P and n 0 2 5 5 ~ ~light
power mWcm-Fig-
5Experimental
metastablepolarization
data [6] versus the alight
intensity;a)
with lowhelium pressure and low metastable
density;
b)
withhigh
helium pressure andhigh
metastabledensity.
The curves are
only
aguide
for the eye Radiation trappingexplains
the lowestpolarization
m case b.P %J '°°
-j~j_j
~~~"~°bi~~~
mw ~rn-~ loo srnw ~rn-~~
=j~
j
~-~
50~
smw~m-~ Ele~trons 0 10~ 10~° 10~~ ncm-Fig
6 Polarization values calculated for 1= 7 and 5 mwcm~~. Theexperimental
data are thepolarization
values measuredby
aprobe
laser(metastable)
andby
a Mottpolanmeter
(electron).
same values for metastable and electron
polarization
because the spin is well conservedby
thechemi-ionization reaction [4]. This
large
difference indicates that other factors aredepolarizing
the metastablesjust
before the chemi-ionization and(or)
the electrons freed from this reactionbefore the measurement
by
thepolarimeter.
Actually
unpolarized
electrons areproduced
by
metastables in thesinglet
state(2~So).
But our measurements indicate for these atomsa relative
density
less than5%.
Otherexplanations
such asmagnetic
fieldgradient
effects,
depolarizing
chemi-ionization concurreqtreactions,
and elastic collisions of the electrons with the helium gas have been estimated to benegligible by
the Rice team [2] and atOrsay,
too.Only
the ionization of thebackground
gas at the extractionregion
remains as anexplanation
N°I RADIATION TRAPPING 101
It is known [10] that in a
cylindrical
tube the radialshape
of the metastable atomdensity
is well fitted
by
the functioncos(lrr/2R),
where r is the distance to thecylinder
axis and Rthe
cylinder
radius. We haveperformed
a calculation in which this radial variation of themetastable
density
is taken into account. This calculation shows apolarization
reductionof some ten
percent;
and thus does notquestion
our conclusions. We aredeveloping
a moreefficient program in order to take into account not
only
the metastabledensity
radialvariation,
but also itslongitudinal
variation and thenonuniformity
of the laser beam as well.5. Conclusion
We have studied the
importance
of radiationtrapping
for theOrsay polarized
electron sourceand have shown that this
phenomenon
explains
in aqualitative
way the metastabledepolar-ization observed. Recent calculations lead to the same conclusion for the Rice electron source
[13].
But atOrsay
some otherparasitic
effects have still to beanalyzed
toexplain
the electronpolarization
degradation.
From the present calculations we propose for animproved
design
ofthe source:
I)
increase the laserintensity;
it)
concentrate the laserlight
on a smallerpumping
volume;
iii)
optimize
the diameter of the pyrex tube.Acknowledgments
Our
acknowledgements
are due to L. W. Anderson for many concrete comments. G. K. Waltersencouraged
us toperform
this work and it is apleasure
to thank him. We are verygrateful
toM. Lecuc for many fruitful
discussions;
N.Sadeghi
illuminated differentpoints
withpatience.
We thank him very much. B.
Cagnac
spent
many hoursexplaining
the difficulties of thespatial
radiationabsorption
cross sections. We would like to thank him also. The kindness ofG. Rutherford was without limit in
sending
us information and comments withrespect
to theRice
University
experiment.
Hiscooperation
isgreatly
appreciated.
Our thanks are due toM.
Campbell
and T. Tombrello forreading
this paper and to M. Givort for hishelp
in thex2
procedure
calculations. We wish to thank A. Talbot for theperfect typing
of themanuscript.
This article is dedicated to the memory of L. Schearer who
participated
in the firststage
ofthe
development
of theOrsay polarized
electron source.Appendix
The
trapping
contributions(Eq. (3))
need theabsorption
cross sections for thepolarized decay
radiation: terms
aj
where i means the Am for emission and j the Am forabsorption.
Thequantities
arespecific
for the helium2~Si-2~Po
transition.Following
reference[10]:
a((9)
= 2asin~
ba(i(b)
=a°
i(b)
= acos~
ba()(b)
=
aI)(b)
= asin~
b/(1
+cos~
b)
a+)(b)
=
aj)(b)
=a(1
+cos~
b)
a)~(b)
=
ap~(b)
= 2asin~
b/(1
+cos~
b)
~2
References
ill
Arianer J., Aminoff C.G.,
BnssaudI.,
Proceedings
of theWorkshop
on "Future of NuclearPhysics",
Orsay
(July
1990).
[2] Rutherford G.
H.,
Ratliff J.M., Lynn
J.G.,
Dunning
F. B, Walters GK.,
Rev Sm. Instrum.61
(1990)
1460 and references therein.[3] Arianer J-, Brissaud
I-,
Humblot H-, ZerhouniW-,
Nucl- Instr Meth. A337(1993)
1.[4] Keliher P. J-, Ph-D- Thesis
(1975),
RiceUniversity,
unpublished,
Walters G R.,private
communication.[5]
Ferguson
E. E. etal.,
Advances in Atomic and MolecularPhysics,
vol. 5(Academic
Press,
NewYork,
1969)-[6] Schearer
L-,
Arianer J,
Brissaud I-, Humblot
H-,
Zerhouni W, Nucl Instr- Meth. A344(1994)
315.
iii
Mitchell A CG.,
Zemanskl M.W.,
Resonance radiation and excited atoms(Cambridge
Univer-sity Press, London,1961)
[8]
Corney A-,
Atomic and LaserSpectroscopy
(Clarendon
Press,
Oxford,
1979)-[9]Phelps
A- V-,Phys.
Rev 99(1955)
1307,Phelps
A. V-, MoInar JP.,
Phys
Rev. 89(1953)
1202[10]
Tupa D,
Anderson, L. W-, Huber D- L., Lawler J-E.,
Phys.
Rev- A 33(1986)
1045;Tupa D-,
Anderson L.W-, Phys.
Rev- A 36(1987)
2142ii
Ii
Abramowitz M,
Stegun
I- A,
Handbook of Mathematical Functions with
Formulas,
Graphs,
and Mathematical Tables,chap
7(Dover,
New York,1970).
[12] Schearer L.
D-,
Padetha Tin,Phys.
Rev. A 42(1990)
4028.[13] Brissaud I
,