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CHEMICAL EFFECTS IN MULTIELECTRON PROCESSES IN THE FLUORIDE ANION
R. Hessabi, D. Urch
To cite this version:
R. Hessabi, D. Urch. CHEMICAL EFFECTS IN MULTIELECTRON PROCESSES IN THE FLUORIDE ANION. Journal de Physique Colloques, 1987, 48 (C9), pp.C2-777-C2-780.
�10.1051/jphyscol:19879136�. �jpa-00227246�
Colloque C9, supplkment n012, Tome 48, dkcembre 1987
CHEMICAL EFFECTS IN MULTIELECTRON PROCESSES IN T H E FLUORIDE ANION
R. HESSABI and D. URCH
Chemistry Department, Queen Mary College, Mile End Road.
GB-London El 4NS, Great-Britain
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1. Introduction
I n c h e m i c a l c o m b i n a t j . o r ? f l u o r i n e w i l l . a t t e n ~ p t t o ac:hi.eve a n e o n - - l i k e c o n + i g u r a t i n n , e i t h e r b y c o v a l e n t : . o r b y i o n i c boi7d f c~r-mati.t3n.
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~ . j i l l b e c o n v e n i e n ' t t o r e g a r d f l ~ i ! n r - i d e ( F - - , l s " 2 s = 2 p h : j a s t h e s t a r t i n g p o i r i t f o r t h e v a r i o ~ t s e l . e & o r ~ i c . t : r a n s i t i a n ? + t o b e d i s c ! - t s s e d b e 1 a w . The? c r e a t i o n o f a is c o r e vacanc:y ? ' t n g i v e % ~ ; ~ 2 s " 2 p ~ > i n a c h e m i c a l l y bot.rnd f l u o r i d e w i l l 1.eaci t o r e ? l a : . : a . t i a n b y e i t h e r X - r a y ( ' t o 1.55z2r52:Zp5) or- ta)i At..tger e l a c t r o n ? ' t o I s"ZsZ:!2f3" etc: i e m i ssi o n i tr whi t r t l the:
o r b i t a l s a f . t h e Cir1a.l. s t a t e w i l l . b e l . n v o l . v e d i n I:sondj.ng. I n % h e X - r a y s p e c : t r u m h i g h - e n e r g y s a t e l l i t e s a r e a l s c a ( ~ l h z e r v e d i K a,>.-) w h i c h a r e I3el i e v e t j E 1 3 t n u-esr.tl.t f r o r n .t:r-ansi t i r 3 n s o f t h e % y p e 1.s'2s-"2p5 -3
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d r - a i n a . t i c r a l l y , w i t h tl..~e c:heniicral env:i.r-onment c3f %I.?e C l i . t o r i . d e anir-?n.
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Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyscol:19879136
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E 4 J StiAW, ti. !A. a n d ~T'tiOMAG, T. D. Phy:;.; R e v . . l l A (1975) 1 4 . 9 % C51 tJCITUF., H. and I.:[NEBERGEI"(, W. C . J , P h y ~ . C h e ~ , R e f , U a t a 4 ( 1 9 7 5 ) I"" ,~.:;9
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