HAL Id: hal-01072193
https://hal.archives-ouvertes.fr/hal-01072193
Submitted on 7 Oct 2014
HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.
L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.
Charline Denneval, Sylvain Achelle, Christine Baudequin, Françoise Robin-Le
To cite this version:
Charline Denneval, Sylvain Achelle, Christine Baudequin, Françoise Robin-Le. Prediction of photo- physical properties of pyrimidine chromophores using Taguchi method. Dyes and Pigments, Elsevier, 2014, 110, pp.49-55. �10.1016/j.dyepig.2014.05.030�. �hal-01072193�
0 12 34 56 78 9
15 5 89
! "#$ "% $ &'"! "&'() *+ $ & "& ! )$ "% $
&( , #$ ' ","&'" )$ -) #.$ /*.- ' $ ,! '"0 $ $
1'*+#$2##3*+45$6(+3*#$7 '++489$1')!#$:*-;-#45$*#$<*#=")$>"?#@+$A-#08$
5$B",*#$C#30$1D:>74$CE>$FG5H$!$<>$IGIJK$C#30$>"-#K$LB67$>"-#K$1B>64$ L>1D<4$5$-$/)#M4$NFJ85$E"#!$6*#!$7.#*#$1O4$<*# $
8$L#)!!-!$)$6 # )$1',;-)$$>##)$CE>$1B>6$F88F4$LC/$$P*##"#4$-$Q"-*$ :*#+(4$:$IG85R4$<88IG8$P*##"#$1O4$<*# $
1")&"##.$*-!'"S$)(+3*#0* '++T-#3@##)50%$/+S$UII$VGW8$RF$HF$RH$HJ$<*O$S$U$II$
VGW8$RF$HF$RI$XH0$$
$
0 12 34 56 78 9
15 5 89
!"
#$%&'()(*+'(+*&*,-&'-$*'($.-.($/&%0)1'(+.(*+-%*&'.2')'&*+%*&'.2'(/+%3%4%,*'0$+.3.($.+*&5''#$*'
%,216*,0*'.2'-$+**'()+)3*-*+&'$)&'7**,'&-64%*48'-$*',)-6+*'.2'-$*'*1*0-+.,94.,)-%,:':+.6('),4' .2'-$*';90.,<6:)-*4'1%,=*+')&'>*11')&'-$*'&67&-%-6-*4'(.&%-%.,'.2'-$*'(/+%3%4%,*'0.+*'?@A'B'),4'C' (.&%-%.,D5''#):60$%'4*&%:,'.2'*E(*+%3*,-'0.37%,*4'>%-$'),)1/&%&'.2'F)+%),0*'3*-$.4.1.:%*&'
$)F*'7**,'*3(1./*45'#$%&')((+.)0$'$)&'(*+3%--*4'-.'$%:$1%:$-'-$*'3)%,'2)0-.+')22*0-%,:'-$*' )7&.+(-%.,'),4'*3%&&%.,'>)F*1*,:-$&'.2'-$*'&-64%*4'0.3(.6,4&5'G7&.+(-%.,'3)E%3)'.2'-$%&' 2)3%1/'.2'0.3(.6,4&'0),'7*'(+*4%0-*4'>%-$'+*1)-%F*1/':..4'(+*0%&%.,'?H'IJ',3D5'#$*'*3%&&%.,' 3)E%3)'0),'7*')1&.'(+*4%0-*4A'$.>*F*+'-$*'(+*0%&%.,'%&'1.>*+'?H'KL',3D5'#):60$%' 3*-$.4.1.:/'$)&'7**,')1&.'*3(1./*4'>%-$'-$*&*'2)3%1%*&'.2'0.3(.6,4&'-.'.(-%3%M*'-$*'
%,-+)3.1*061)+'0$)+:*'-+),&2*+'*&-%3)-*4'7/'*3%&&%.,'&.1F)-.0$+.3/5''
'NOP"QRST'U/+%3%4%,*A'U$.-.($/&%0)1'U+.(*+-%*&A'V,-+)3.1*061)+'W$)+:*'#+),&2*+A'X*&%:,' .2'YE(*+%3*,-A'X/*&''
'
Z[\]^RS_!`R^"
X.,.+9)00*(-.+';90.,<6:)-*4'?X9;9GD'3)-*+%)1&A')1&.'0)11*4'(6&$9(611'3)-*+%)1&A'>%-$'7.-$'
*1*0-+.,94.,)-%,:'),4'*1*0-+.,9>%-$4+)>%,:':+.6(&'1%,=*4'7/')';90.,<6:)-*4'7+%4:*'$)F*' 7**,'*E-*,&%F*1/'&-64%*4'46+%,:'-$*'()&-'4*0)4*&'aIb5'V,'&60$'3.1*061*&A'V,-+)3.1*061)+' W$)+:*'#+),&2*+'?VW#D'-$)-'.006+&'0),'7*'*)&%1/'%116&-+)-*4'7/'->.'1%3%-%,:'+*&.,),0*'2.+3&'
?)+.3)-%0'),4'c6%,.%4dM>%--*+%.,%0')++),:*3*,-&D'a@b5'U6&$9(611'&-+60-6+*&'$)F*'2.6,4'6&*261' )((1%0)-%.,&'%,'216.+*&0*,-'4/*&'),4'&*,&.+&'aKbA'&*,&%-%M*+&'2.+'X/*9e*,&%-%M*4'e.1)+9W*11&'
?XeeW&D'aBb'),4'*3%--*+&'2.+'f+:),%0'g%:$-9Y3%--%,:'X%.4*&'?fgYXD'ahb5'#$%&'3.1*061)+' 4*&%:,'%&')1&.'-/(%0)1'.2'&*0.,4'),4'-$%+4'.+4*+'i.,9g%,*)+'f(-%0)1'?igfD'0$+.3.($.+*&'aCb5' e*0.,4'.+4*+'igf'3)-*+%)1&'$)F*'2.6,4')((1%0)-%.,&'%,':+**,'1)&*+'.7-)%,*4'2+.3'+*4'&.6+0*&' -$+.6:$'2+*c6*,0/'4.671%,:A'%,'&*0.,49$)+3.,%0':*,*+)-%.,'3%0+.&0.(/'.+'%,'-*+)$*+-M'>)F*'
0 12 34 56 78 9
15 5 89
!"#$%&'#()!*#"*#+,-.#!#/!012# 3"4/)" "#56"/ !"#7(89:#; !26#)<#
26"# 0 *#0"6!*52# !"#*1# "# )!#//2!0 !"6#!#/)" "*=;!0# )/=.# 0">"02#;!0"60"/=.#"/ !02#/"3#2!;!!.#?@#* #6 "#*#;!0">5!0 !"#$A&'#B# 06#">#60"*#"*#+,-/)"6.#)#+,-#63#7CD:#!6#*!0 2=#2*#"#)#!6!=#">#
)#BE(#/)";#$F&'##
8=!;!*!.#3)!0)#!6##)!)2=#G4*>!0! #) "0=02.#0#5#16*#6#20 "43!)*3!# /#!#/16)4/122#6 10 1'#()#5!2!=#">#/" " !".#)=*"#5"*#>"; !"#*#0)2!"#
"># )#!"# ";6#"># )#/=!;!*!#!##26"#"># #!;/"0H#610)#*!< !<6#
0"12*#5#)>"#16*#>"# )#>"; !"#">#61/;"2012#66;52!6#*#6#66"6'#()#
16#">#/=!;!*!#!#!#)#6 10 1#">#G40"I1 *#; !26#)6#5#0 2=#<!3*#
$JK&'#@1!# )#/6 #*0*.#)1**6#">#/=!;!*!#0)";"/)"6#)<#5#*6!*'#B# /!012#1;"16#=2/=!;!*!#*!< !<6#)<#5#6 1*!*#6#>21"60 #*=6#$JJ&'# L""<.#!#6)"12*#5#" *# ) #M.N4*!7=2<!=2:/=!;!*!#!6#"3##322#6 52!6)*#
6 10 1#">#(89#*=6#$JO&'#P0 2=.# )#60"*#"*#+,-#/"/!6#">#M4 =2<!=2/=!;!*!#)<#5#26"#6 1*!*#$J?&'#
Q<#!># )#6"2< #/"2!=#>>0 6# )#56"/ !"#6/0 #">#/16)4/122#0";/"1*6#$JM&.# )#
;!66!"#6"2< "0)";!6;#!6#22=#;"#!6'#R"*#6 10 1266#*#6)!>*#;!66!"#
!6#"56<*#"#!06!# )#6"2< #/"2!=#2"#3!)##610066!<#*06#!# )#
>21"600#!6!='#()!6#6"2< "0)";!0#5)<!"#6126#>";# )#6 5!2!S !"#"># )#
)!)2=#/"2#;!!#6 #5=#/"2#6"2< 6#$JT&'#()>"#6 1*=!# )#;!66!"#
6"2< "0)";!6;#!6##3=#"#<21 #BE(#1/"#U0!!"#!#/16)4/122#6 10 16'#@!>> # 6026#)<#5#*60!5*#>"#V1 !>!0 !"#">#6"2< #/"2!=#$JN&.#"#"># );#!6# )#
@!;" )4P!0)* #7Q(7?K::#/"2!=#602#56*#"#)#6"2< "0)";!0#; )"*#$J%&'#
(10)!#"516 #*6!#; )"*#!6##0";5! !"#">#; ); !02#*#6 !6 !02# 0)!V16#
16*#!##;/!!02#6 1*=#$JA&'#()#(10)!#*6!#">#U/!; #; )"*#)6#50";##
0 12 34 56 78 9
15 5 89
!"#$%!%!#$&#!$#!'()*+!%,!- %(&!!- %&##.!/!- *&*-)#0!$#!12(&$*3!
#*2!%,!#4-# *"#!*!(#!%!2#!*,% "*%!(&$!!"*!#,,#&!!*# &*%!#,,#&!
%,!#*2!- "## !,%"!"**"("!("5# !%,!#4-# *"#.!/!&%*!*!!#4-# *"#)! #2+!*!6$*&$!$#!#,,#&!%,!"()*-)#!,&% !#!(*#!*"()#%()+!5+! (*2!#! 6*$!$#!&% #!,&% !!7 *%(!)#7#).!/!$#!12(&$*!-- %&$0!#4-# *"#! #!#*2#!
(*2!-#&*)!% $%2%)! +!$!))%6!$#!- "## !-&#!%!5#!#4"*#!5+!-# ,% "*2!
!)*"*#!("5# !%,!#4-# *"#.!/!*!$# #,% #!#&%%"*&)!,% !&$ &# *8*2!!&%"-)*&#!
- %&#.!9#6# !#4-# *"#!#!#'(*#!%!(+!))!)#7#)!%,!))!*-(!- "## 0!!,*)# !
%(!%"#!#,,#&!(#!%!**&)!7 **%.!12(&$*!#*2!%,!#4-# *"#!"#$%!$!5##!
6*#)+!(#!*!&$#"*+!,% !$#!%-*"*8*%!%,!+$#*&!- %&#( #!:;<=.!>%6#7# 0!%)+!,#6!
#4"-)#!%,!**&)!(*#!#*&#!%!$#!-$%%-$+*&)!!%,!# *#!%,!+#!$7#!5##!
#& *5#.!?( #@!!&%6% A# !(#!**&)!#"#!%!*%)*8#!$#!-$%%-$+*&)!!
%,!!# *#!%,!$## %&+&)*&!&%"-%(!:BC=0!!"% #! #&#)+0!D$#!EFGHI!#& *5#!$#!
%-*"*8*%!%,!)("*#&#&#!- %-# *#!%,!"# *)!5+!#*2!%,!#4-# *"#!"#$%%)%2*#!
:B;=!
1$#!*"!%,!$#!6% A!#& *5#!*!$*!--# !*!%!- #*&!$#!5% -*%!!#"**%!"4*"!
!%!%-*"*8#!/D10!#*"#!5+!$#!*"-% &#!%,!#"**%!%)7%&$ %"*"0!%,!!# *#!%,! -+ *"**#!&$ %"%-$% #!J9*2( #!;K.!1$#!*,)(#&#!%,!$ ##!- "## !$!5##!(*#L!$#!
( #!%,!$#!#)#&%M%*2!2 %(-!!%,!$#!NM&%O(2#!)*A# !!6#))!!$#!(5*(#!
-%**%!%,!$#!-+ *"**#!&% #!JB0!P!!Q!-%**%K.!! RSTUVWXYZ[
\]^_`aXWT`bc[`de[fXaghe[
ijkjGlEFmnoGG
/!% # !%!- #*&!$#!5% -*%!!#"**%!"4*"!!%!%-*"*8#!/D1!*!-+ *"**#!
&$ %"%-$% #0!$ ##!- "## !$7#!5##!(*#L!$#!( #!%,!$#!#)#&%M%*2!2 %(-0!
0 12 34 56 78 9
15 5 89
!"#$%&'#(!) *+,-" *.!/.,!*0#.,,##$01",2,*,'#"34#"
'0 " 2"5"+6+. 6/'#.,*"*78 /+9:38#"#)# + "" 1#$;<10
= .!.* *,."0".*,8 /+>5="'#+!2?,.!.* .'#"#+#''-,$"
"," ',#./=$ '#".@&A38'#"".0#*,)'#20#!*. ""0".*,4,)!"
>3B.#!+*/#* ,' .#$'#20#!*C5$#".#+!/,+,1" .#.52#D1)"#!0.
6/"0+ '*/1D1+#D1)"#!038,.2#*,$,' ,#,..!00#.*# 6 )+,),/+
,$+!'#0##01.,' +0 " 2"..!*,*3 EFGHIJKLM EFGHIJKNMK EOPQRSJKNM
TUTUVWXWYZ[\W]^WY_`WXaZ[\
@++.#+6.="" ))" *38. ",)2 ", +.="0!"' .*$"#2b,)2 &@+*",'
#"@'"#. *!.*=,#!$!""0!",$,' ,#34#" ," *2#,.!"&..,,6" ',#.5 ++ )+ ..= "0,'.="$+ 2&*",* *'##+*!*","#)3cde.0'"=""'#"**, A?A+f5# g"!-"@*6 'fhh.0'"#2"79i fhhdij *9fA kldij:38 '2,' +.,$.m ""0#"*,002"+,6#".,*! +.#+67AiA+f:38'#!0+,) '#. .n "),6,ij3B9icde.0'" 5$#++#=,) //"6,,#. "!.*#
*.'",/0 -0 ".o.7.,)+:5*7*#!/+:5**7*#!/+#$*#!/+:57",0+:52 72!+,0+:3B9fAcde.0'" 5 !"#$' "/#.7A5Ai5Ai>#"Aif:= .
*"2,*/10"$#"2,) pdq?D0",23d+,)0#,.7rA:="2 .!"*#
s#$+"#&. )=, 0"',.,##$>*)".7t>rA:3i,)&".#+!,#2 .. +1..="
0"$#"2*uA"ev),# +*d.!".w1.,x!.*+yq!.z7Aedwq5{,6".,1#$
e.9:!.,) g"!-"d,'"#8q4&|BB 00 "!.3@ +1,' +,+ 1"'"#2 #)" 0,. 78;A:="0"$#"2*#.,+,' )+0+.7d"'-}h4>l~: *'#20#!*.="6,.! +,j*
0 12 34 56 78 9
15 5 89
! "#$%"&'()*&" "+,- $!./,$012) 3&4� "#* 5&% 3567#06!83$*
3)4 94#3:;/<=/<>+<<063&9:?@A1'(>(3)63564"%6664#!6!#$( $B ,<34 $3564"#5&#"#06"612)8#6346$463564"#34#53"8!63%664#$!84"6!#$ ( $ B C4)5363564"#5&#"#06"61B#05#8$!3%666D4"6! ""&6 3#5"#$0 D0 = $!
#7)#%63"6$6*A7#64#!$*"&66033#$3564" 19))3#)8"#$3%6606 386!%""4 )
!6$3"636)#%<1E12)8#6346$46F8 $"806)!=GE<HA!6"60$6!6) "I6"#F8$$6 38)7 "6$E@J+:K-=L2M<1,-A#& 0 $6$<1E@J+:K- 33" $! !=L2M<1N.A1:"#O63 3&7"3%664 )48) "6!4#$3!6$*"&6)#%63"6$6*6"4 3#5"#$ $!1
PQRQSTUVWXYZ[ZS
B#05#8$!3\]^++_`a]^+._`b]^+-_`c]^E. _`d]^EE _`e]^++_& I666$3$"&63f6! 44#!$*"# 65#"6!06"&#!31?&63$"&6"4#8"63"#4�#5?g`h`i $!\a 665#"6!$ 34&6063E>-1
jklmnon]\p]
jklmnon]ap]
jklmnon]bp]
jklmnon]gp]
1
PQqQrYVYstuSvVwYxYVtyYuSzwV{YVZtW[wVS|swzY{}sYS
93"6!0D"86#706"&)50!$6!6I "I6=E1,00#)A $!4#635#$!$* )!6&!6
=E1,00#)A$ F86#833#!80&!#D!6=,@`E,0~A4#$"$$*9)F8 "../=/-0*`<1E, 00#)A% 3&6 "6!8$!667)8D7#.&1?&60D"86% 3 ))#%6!"#4##)`"&65645" "6% 3 7)"66!#77` $!% 3&6!%"&% "61
PQQTUVWXYZ[ZSwSS
B#05#8$!g% 33$"&63f6! 44#!$*"#*6$6 )$#6I6$ *6)4#$!6$3 "#$5#46!86 $!
"&648!65#!84"% 35876!4#)80$4� "#* 5&=:K+`94KC"6"#)680C"&6`
0 12 34 56 78 9
15 5 89
!""#$%#"&'()*+ &!"'),-*.,/01(23456789::64;<3=3"9>9?: 8%<)4<)?@8'<4<AB/?:4;<@?:8C<4<AB,?D4;<@?:98'<4<AB)?(4;<@?198'<
(4<AB/?:4;<@?/(8'<4<AB)?(4;<D?)18'<(4<AB,?D4;93567EF'G6H=8@1 64;<3=3"9>)1?@83<1)?/834<1?83<9D?1834<(/?83<(,?83<((?1 834<@?)834<(?834<,:?(8349IFE"?3E"J'K#L3,41593<@,?),4<)?@5<
D?)1?M#NF'3<@,?14<)?/15<D?9@?
OPQPRSTUVWXYZYR[\R]^R
3#*.#NF'_`$E%% FCa!%&;!'EJJ#L'&F+C#+!F!LE"bF#!c!FE+!"J#F'!F%EC&#F.L#J!'NL! EF'Ca!JLN'!.L#'NJC$E%.NL&K&!'d J#"N*FJaL#*EC#+LE.a 8e&H(<IJHfCgh!CL#"!N*
fCa!L<JL!E*%#"&'@(*+ &!"',,-456789::64;<3=3"9>@?(8C<4<AB ,?D4;<@?((8'<4<AB)?(4;<@?,D8'<4<ABD?@4;<@?1(8'<(4<ABD?@4;<@?/8'<
4<AB)?(4;<D?@(8'<(4<AB,?D4;93567EF'G6H=8@164;<3=3"9>),?@ 83<1@?834<9)?D834<9,?/83<9(?:834<(/?:834<(D?834<(9?83<
D?@834IFE"?3E"J'K#L3(4/iL5(3<11?(:4<9?,@5<:?@9?M#NF'3<11?14<
9?1)5<:?1@?
OPjPRkXUXlmnRSopoqZRrl[YYsr[otnZUuRlXmrVZ[URtl[rXvolXR
I%C&LL!'*&wCNL!#KaE"#+!F#'!L&cEC&c!8**#"<J#LL!%.#F'&F+.a!F "d#L#F&JEJ&' 8?(**#"<h'8hha9,81D*+<:?:1**#"<ExN!#N%6%#'&N*JELd#FEC!8**#"<*y EF'!CaEF#"8*y&F'!+E%%!'C#"N!F!8:*y$E%a!EC!'NF'!LF&CL#+!FK#L(,a8,:a&F JE%!#K_z?{a!L!EJC&#F*&wCNL!$E%J##"!'<K&"C!L!'<EF''&%%#"c!'$&CaE*&wCNL!#KfCHIJ EF'$EC!L81:*yEF'Ca!#L+EF&J"E !L%!.ELEC!'?{a!ExN!#N%"E !L$E%!wCLEJC!'$&Ca fCHIJ8(|(1*y?{a!J#*d&F!'#L+EF&J!wCLEJC%$!L!'L&!'$&Ca6+eH,EF'Ca!%#"c!FC%
!cE.#LEC!'?R
OP}P~STUVWXYZYR[\RR
0 12 34 56 78 9
15 5 89
!"#"$%&"&' ()*&+,*!"%--.!+ /"("/* *.%0"1,2+"-.&&"-0+ /".*%-(+ ".-*!.*"
% !"()*"-.!*".!-("$%&".+3+*!"4'"-0 "-).%(/.%)'"51+678"9-6:(;<*(.0*"
:()*.8"=>=?@"'*00$"&0+!@"7AB"/@"'+*0!"CDE@"">"=F7G=FBH@"=I"JKL"5MDD"KI,8"N0M?"O"
CP=DGCPDM"58"MI?8"CP=BGCP=7"58"CI?8"CPM=GCP7F"58"QI?8"CPR7"5!8"7I8"S"T"FPC"I,?8"CPB7"5!8"
7I8"S"T"FPQ"I,?8"CPBA"5!8"7I8"S"T"FPQ"I,?8"FPDM"5!8"=I8"S"T"=BP7"I,?8"FPCQ"5!8"7I8"S"T"QPF"I,?@"
=M"JKL"% !"UK6N"5CR"KI,8"N0M?"O"=BRPD"5?8"=RCP="5I?8"=QCPB"5?8"=QCPR"5?8"=Q=PM"
5?8"=MCPF"5I?8"=MQPR"5?8"=MQP="5?8"=7APM"5I?8"=7FP7"5I?8"=7CPB"5I?8"=7CPD"5I?8"
=7BPA"5I?8"=7QPB"5I?8"=7MPC"5I?8"=7MP="5I?8"==FPQ"5I?@"ILK1"5:1VW8"919<?";,"
-%0-0%(*!"3."MDI7QJM"XKWIYW"Q7BP=ACD8"3 !"Q7BP=ABFP"
Z[\[]^_`abcdcefgehhe
!"ii"$%&"&' ()*&+,*!"%--.!+ /"("/* *.%0"1,2+".&&"-0+ /".*%-(+ "
.-*!.*"% !"()*"-.!*".!-("$%&".+3+*!"4'"-0 "-).%(/.%)'"51+678"
9-6:(;<*(.0*":()*.8"=>A?@"%0*"'*00$"&0+!@"7RD"/@"'+*0!"CDE@"">"=QCG=QAH@"=I"
JKL"5MDD"KI,8"N0M?"O"CP7DGCP=D"58"FI?8"CPMCGCPM="58"QI?8"CPBR"5&8"=I?8"CPAQ"5!8"7I8"S"
T"FPC"I,?8FPAB"5&8"=I?@"=M"JKL"% !"UK6N"5CR"KI,8"N0M?"O"=BRP="5?8"=B=PR"5?8"=RFPA"
5I?8"=R=PM"5?8"=QBPC"5?8"=7APC"5I?8"=7FPQ"5I?8"=7CPR"5?8"=7RPC"5I?8"=7QPQ"5I?8"
=7=PM"5I?8"==RPF"5I?@"ILK1"5:1VW8"919<?";,"-%0-0%(*!"3."77I=C0JM"XKWIYW"
MRFP==DB8"3 !"MRFP==DAP"
"
Z[jk[l ]^_`abcdcefgeme
n"%"&(+..*!"+o(.*"3"- !"ii"5=RD"/8"DPQ7"0?8"&!+")'!./* -%.4 %(*"
5QM"/8"DPRD"0?"% !"<!G"5R"/8"DPDQ"0?"+ ":(6I"5R"p?8"!+)'!./* "$%&"
+ (.!-*!"+ "4440*&"%(".("3."7D")P"n)*"+o(.*"$%&"()* "3+0(*.*!"$+()"-*0+(*"% !"()*"&0q* ("
.*q*!P"n)*"-.!*".!-("$%&".+3+*!"4'"-0 "-).%(/.%)'"51+678"
9-6:(;<*(.0*":()*.8"=>Q?@"'*00$"&0+!@"=7Q"/@"'+*0!"A7E@"">"=DQG=DCH@"=I"JKL"
0 12 34 56 78 9
15 5 89
!"#$#%&'()*+(),(-"* &"()./+()-"0 &"()1,2"34/ !", &"()5/2"
34*)( !". &"*)1(2"34/ !", &"5),56", &7,#89:;2<=$(/ !"#$#%&
',1)#&",/*)5# &",/()#&",/)(# &",01)5# &",.5)/# &",.*)5#&",.*),# &"
,./)0# &",.0)# &",.,)(# &",,1),#&7 9>?>@A"B>BC&-D!E:%EF%:GH2IJK
#.. ,(8LA MA.0),/,"IJF;2.0),/,, NOPPOQ RSTUVWXYXZ[\Z]^Z
#J-_JF;2`ab:66c;GdH6e!H2:EEJK2e;fGJfH;HK:%>F!Fge#KJ66EJF_%e;fKH:EGeJ;
_KJEH2FKH:;2GdHEKF2H_KJ2FEGb:6_FKeIeH2hcEKc6G:%%e!:GeJ;IKJ-JI-eiGFKHJI
$#D_H;G:;H7JK:;fH6J%e27.1,-f7ceH%20j7-_k,./+,l#7, 89 !"
#$#%&'()+()/-"1 &"(),.+(),1-",. &"().1+().-"5 &"()/,2"34*)( !"0 &"
*),2"34*)( !"0 &"*),/2"34*)( !"0 &"()5/2"34,/)5 !". &"5),.6", &7,# 89:;2<=$(/ !"#$#%&',1.)5#&",/*)*#&",0()*#&",0()1#&",0,)(# &"
,1)*# &",0),#&",)*#&",.5)/# &",.*)# &",.()(# &",.()# &",./)/ # &",.0)(# &",.)(# &",.)# &",,1)1# &7 9>?>@A"B>BC&-D!E:%EF%:GH2 IJK#/1 0.80LA MA((,)0*"IJF;2((,)0**)
mnopqrsturvwxyvyzr{srrz|xv
}dH~+e6:;2_dJGJ%F-e;H6EH;EHC&6_HEGKJ6EJ_eE2:G:JIEJ-_JF;26`+-H:6FKH2e; 2eEd%JKJ-HGd:;H:G./l#:KH_KH6H;GH2e;G:h%H)B;:%c6H6d:HhHH;E:KKeH2JFGF6e;f%Jb EJ;EH;GK:GeJ;6J%FGeJ;6e;JK2HKGJ:Je26H%I+:h6JK_GeJ;HIIHEG)B6:;Hi:-_%H"GdH6_HEGK:IJK 2HKe:GeH:KH6dJb;e;efFKH)B%%EJ-_JF;26:KH_dJGJ6G:h%H2FKe;f_dJGJ_dc6eE:%
Hi_HKe-H;G6)
wtqvmv v
zsqvm
0 12 34 56 78 9
15 5 89
!"#$%&"''()&!!&"')*&)+ '!%,(&(--"#(&'.%".,-&)%"("/".0 '('/0!&!"1+#&'-23456378!-"'(,-%(%"(%#)&'%!&.'&1&-'-"1- 1-%"#9:"# !"#$%&"';%11-%!"1-/+/"1-1-%"##$#!'%(&' /<'(%
#!,/%!"134563-/-,/%&"'!#.&+'&' /=9+#. !"#$%&"'8+/'.%&!
>?@')93!!"8'&' /<;%(&$'0/)&'".#",$2/+/>"11-%"#37&!%
!, !%&%,'%/(&'.%"%)"!%#(A!&1%( !"#$%&"'9BA!, !%&%,%($0#&)&(&'2/+/C;
1-%"#D7#%)"!% /,!&1%(8#!<;?A(&!, !%&%,%((#&+%&+!2/+/>;1-%"#D7#
%)"!%#(!&1%(9E"'-#'&'.%FA-"'G,.%(-"#;$'0/'+&'0/'(#&+%&+!2/+/
B;1-%"#E7#%)"!%#(!&1%(9
H&)&/#% /!1"#)&!!&"'#.&+'&'!,$$"#%&'.&'1"#)%&"';%+#.)&!!&"' 8+/'.%&!<@?')9I%!",/( '"%(%%%!, !%&%,%&"'$"!&%&"'"1%$0#&)&(&'-"#
11-%(&11#'%/0% !"#$%&"''(%)&!!&"'J<A)"'"!, !%&%,%((#&+%&+!2/+/B;
1-%"#D7#)"##(!&1%(&')&!!&"'%'<;?A(&!, !%&%,%($0#&)&(&'!2/+/>;1-%"#
D79
K&%#1"#L !'(L);%&'1/,'-"1#!&(,&!/"82 /"8>9>M7&'(&-%&'.%%%#&! '"&'%#-%&"' %8'%%#1-%"#!!%,(&(9:A#%&"%!%8!-"'(,-%(%"+/,%
%11-%"1-1-%"#"'%!&.'/N'"&!#%&"9:"# !"#$%&"';%%#1-%"#!3;D'(E +:A#%&"!!,$#&"#%"%:A+/,1"#OPM-"'1&('-/+/2:A+/,P9OQO7)R&'.%)
!&.'&1&-'%9:"#)&!!&"';"'/01-%"#!3'(E#!&.'&1&-'%93!!"8'&'% /<;%'%,#
"1%/-%#"'A("'%&'..#",$21-%"#3;<S9PM7'(%!, !%&%,%($"!&%&"'"1%
$0#&)&(&'#&'.21-%"#D;BS9<M7#%)&'1-%"#&'1/,'-&'.% !"#$%&"'8+/'.%9 )&!!&"'8+/'.%)&'/0($'(!"'%'%,#"1%FA-"'G,.%(-"#21-%"#E;
<=9>M7'("1%/-%#"'A("'%&'..#",$21-%"#3;<<9>M79
!"#$%&"'8+/'.%!-/-,/%(--"#(&'.%"%+#.+/,'(%11-%!"1% -"##!$"'(&'./+/"1-1-%"#2 /<7#&'.""(.#)'%8&%*$#&)'%/+/,!
0 12 34 56 78 9
15 5 89
!"#$%&'('!(")*!')& !+)!,%!-./012(!!(%$$)&4)&#,)&567
!#)(()&3 !')!!&"!(*!8!!&",+"%+,!',&'!9$!)#!&,+:,+%!(,!,*) )4 !-./0
;<(!!(%$$)&4)&#,)&5)&$,)"%+, !#(!'=( )!'"#$%&'(6
>?@ABCDEFD
>?@ABCDGFD
H&,&!4,)&% !)&()4 )& !$ $ I()",+$"!((8) )& )((!)!(
$I)#)')&!$%( =$%++" #$ !(38!)&:!()4,!' !!#)(()&*! ,:)"#$%&'(J=K )&')!!&,$)"(+:!&(6L !!(%+( !(!)&:!()4,)&(,!(%##,)M!')&L,*+!N6O(
,&!9,#$+! !!#)(()&($!",)&:,)%((+:!&("#$%&'P,!( 8&)&7)4%!;6 7,++"#$%&'(3 !!#)(()&#,9)#,8!!$+!'QRSTUT !V)# =W!)" ,'$+,)I
$,,#!!-.XL-;Y556H&,++",(!,4'+)&!,)I8,(*,)&!'-(!!(%$$)&4)&#,)&56 L !(+$!( !"!($&')&4!4!(()&+)&!(-Z[5,!4')&')",)&( !)&!&()I !H\L)& !" #$ !(6L ! )4 !(:,+%!Z[)(*(!:!'"#$%&'G6D
>?@ABCDPF
>]^_`aCDEF
L !ObcdO#! '8,(!#$+I!'(%'I !)&+%!&"!!," ,"& !:,+%!Z[
)&,()#)+,#,&&! ,&,*($)&,&'!#)(()&#,9)#,6L !!(%+(,!4):!&)&L,*+!(
e,&'26L !,:!,4!:,+%!Z[)(16e;6c&"!,4,)&3 !)&+%!&"! !!()'%!)(+8 -f61g56L8,"(()4&))",&+I!9$+,)&Z[,""')&4 !)7=,)(h !&,%! !
!+!"&='&,)&44%$-,"O3iN62g5,&' !j="&k%4,!'"!-,"\3iY6ig56 L !(%*()%!'$())& !$I)#)')&!)&4(!!#(*!+!(()#$,&6O""')&4L,*+! e3 !$)#,+"&)4%,)&"&()(()&')$ !&I+,#)&'&4%$(-+!:!+;,"O5+)&l!' ,i=N=')(%*()%!'$I)#)')&!-+!:!+;,"m5*I,*)$ !&I+!&!:)&I+!&!*)'4!-+!:!+;
0 12 34 56 78 9
15 5 89
!"#$!%&'! '()*+,*-!(.. '!/0).*+!123!'4&,5,(!!&,-&' !67!89.'!&*!
0).*+(!1:;!<&,&!89,+'(!&'!0'&+9-=$!
>?@ABCDEFD
>?@ABCDGF!
!
HIJKLMNBOPQLMD
%!*9.+'R!<'!&8'!(&<*!&!%-.&,!+'(,-*!!'4)' ,0'*!0'&+9-=!*!5'!
',,'*9=!))9,'+!!) '+,!&'!)&)&=(,9!) )' ,'(!/5( ),*!*+!'0,((,*!04,0#! !!0,9=!!)= ,0,+,*'!& 0)& '($!S"%!,*!&'('!0).*+(!'(,0'+!5=!'0,((,*!
(98& 0=!&(!5''*!9(!),0,T'+!.(,*-!&'!(0'!)) &$!%-.&,!+'(,-*!! '4)' ,0'*!0'&+9-=!))' (!.('.9!!(.+=!&'!,*9.'*'!8 ,.(!!) 0'' (!,*898'+!,*!
&'!)&)&=(,9!) )' ,'(!!!(' ,'(!!+='(!*+!!,+'*,=!U.,V9=!&'!),0,T'+!
& 0)& '$!%&,(!('-=!.9+!5'!))9,'+!!&' !0,9=!!& 0)& '($!!!!
! !
0 12 34 56 78 9
15 5 89
!"#!$%&%'()*+,'-.,-'%*/0*,1%*+,-23%2*24%+5* !6#*71'/8/91/'%+*":*6:*;:*<:*=:*>:*?:*@:*A!
!;#*BC+/'9,3/&*DC'/E%&*)3&%F*(&2*%83++3/&*+9%.,'(*D+/)32*)3&%F*/0*.1'/8/91/'%+*A** !<#*G/'8()3H%2*%83++3/&*+9%.,'(*/0*.1'/8/91/'%*>!3&*I('3/-+*+/)I%&,+5*
!
JKL M !"#!N4&,1%+3+*/0*./89/-&2*<!
JKL M !6#!N4&,1%+3+*/0*./89/-&2*?#! JKL M !;5*N4&,1%+3+*/0*./89/-&2*@#! JKL M !<5*N4&,1%+3+*/0*./89/-&2*"65*
!
OPQR !"#*S('(8%,%'+*(&2*,1%3'*I()-%+*./''%+9/&23&T*,/*,1%3'*)%I%)+*,/*C%*+,-23%2*3&*
%U9%'38%&,+5**
OPQR !6#*VU9%'38%&,()*)(4/-,*-+3&T*,1%*WX*/',1/T/&()*(''(45* OPQR !;#!YZ[Z3+*(&2*91/,/)-83&%+.%&.%*DSWF*2(,(*
OPQR !<#*V00%.,*/0*%(.1*)%I%)*/0*%(.1*0(.,/'*/&*\(C+*3&*&8*
OPQR !=#*B&()4+3+*/0*I('3(&.%*DBG]ZBF*0/'*/&*\(C+*3&*&85*
OPQR !>#!V83++3/&*+/)I(,/.1'/83.*'(&T%*/0*94'38323&%*.1'/8/91/'%+*"^A**(&2*"6*3&*I('3/-+*
(9'/,3.*+/)I%&,+!
OPQR !?#*V00%.,*/0*%(.1*)%I%)*/0*%(.1*0(.,/'*/&*NS*
OPQR !@#*B&()4+3+*/0*I('3(&.%*/0*NS*
*
!
!
!
!
0 12 34 56 78 9
15 5 89
!"#$$%&'()*+%&,-./"+"&0122%$3"&0456738353%9:0;<%23&"+4=73%#7>?&"6%7@"&
AB%"&8%7+9C58<98+*C<"2D7@"&E%FG3%&8<7.1+*%FHB%#I+3;9;+*<JKKLMNOPQN0 RR.6 S8T<G(/8%9%&82BU.12%3=<%+%09%&8T%973&"+*"&*+8222%$3"&7@"&$<+&+9 +"+$<+&$57B0$5<<2B&"#"$B"&%7.122HB%#'%7LPMOMQR0PK.
MS5<BV+%DW(C5&%XU(Y$&X<W(S5Z+8D)(G8D=7%DA('[\8]D1.(P0?B%+=<%+%+9M(R0 3B8%+=<%+%^0<8+D%&78+2B&*%03&+7@%&2B&"#"$B"&%7.178+WY&*HB%#M_QLMOPMM0Q.
Q4%%@"&%`#$<%O!5<8=%T'(H"7D5+1(1DD=;-(/%78*+73&3%*8%7@"&&38"#%3&82 2B%#"7%+7"&7O#"95<38"+"@%`28338"+%+%&*=3&+7@%&33B%%+%&*=9"+"&783%.W1#HB%#
4"2M__JLQOJ__N0Q.6 H"73%&"1G(?&&G(!8<4(!"3"&'(G+28+8?G;(G&3a+%Z0 GVb%Z'(4+2%+c+U('"="4.HB&"#"0@<5"&"*%+829%3%238"+"@+%&T%0*%+3#8#827578+*
3&8**%&%92=2<8Z38"+&%238"+78+$57B0$5<<9=%7.HB%#178+WM__LRORNQ0KR.2 ,99H(
12B%<<%4(dc$%Z04"<%&I(!&2a0G&3a+%ZWH.G%3<238"+2"#$<%`38"+73598%7"@P0
&=<T8+=<0M(e098f$=&898+0M0=<$=&8#898+%7O%@@%23"+3B%"$382<$&"$%&38%7./=%7?8*#
M_QOJNOMQ_0N.9 E%$&XG(1<#"+7=E(C5&%XU(S5<BV+%DW(/T"gVDG(G82B<G.
U<5"&%72%+2%+9$B"3"$B=782<$&"$%&38%7"@/0:01$57B0$5<<7=73%#7@%35&8+*P(R0 982=+"8#89Z"<%5+83./=%7?8*#M_LJOPee0NQ.% /%++%T<H(G"<9"T+Y(C59%h58+ H(12B%<<%4(C<9%2D?(?<iE(/&6+35G('#"+9%+2j.4=+3B%787+9$B"3"$B=782<
$&"$%&38%7"@$57B0$5<<73&5235&%78+2"&$"&38+*98Z8+%7733&238+*$&3F83B@<5"&%+%
2"&%.;5&WY&*HB%#M_QLRRJ0_e.
P d8+j(d8j(kB+l.4#<<#"<%25<%7%#82"+9523"&7@"&B8*B0%@@828%+2="&*+82
$B"3"T"<3827.HB%#4"2'%TM_MLPOPMPR0NM.6 ,*@%<931(C"72B<""!(45+d(S<""d(
?%33%&77"+,./=%07%+7838Z%97"<&2%<<7.HB%#'%TM__L_OeRJR0eeQ.2 !m+%74(
E%5*%65%&,(4&828@328E4.H"+n5*3%9$"<=#%&067%9"&*+827"<&2%<<7.HB%#'%T M__NL_NOQMP0QK.
0 12 34 56 78 9
15 5 89
!"#$%&'($))*+,'-.$*..$%('/$0&12*+3"4$..*5*$)60%+)*57$8*5$9:9$70)
$"$56%*5""470;$76%)9;0%6"4$%91<3$=>$8?@@ABC@ADC?EEFAC1: G)+G'H30IG'2$
JK'2$<'G)+<2',*L/'/*GL1M0"I6*0)F;%05$99:"$%$7F$=*99*0)0%+)*5=6$%*"9 50)6*)*)+6%*;3$)4"=*)$)7:$)#063*07*#0"$I)*69D94)63$9*9)7;;"*56*0)9*)0%+)*5
"*+36F$=*66*)+7*07$91N-349<3$=,?@@OBCCEDAAPF?1
Q ,%"0RM'(%7$%M>1S0)"*)$%T;6*5"-%0;$%6*$90.T%+)*5(6$%*"91U)D LI)56*0)"T%+)*5(6$%*"9B(V""$%'WNN',I)#X2L'Y791B!*"$4FZ<2D!$*)3$*=' K$%=)4'?@@AB;1EOEFPEA1: M#:"$R9[*('W30=9->'W30%)60)\',"00%]'<%099K2'
<0"$N('20R%7N\&'("+0"*('($4$%9L',%^79N/'!$)9$"$$%9!'K008$%69Y1 2*+3"47*;0"%'0;6*5""4)0)"*)$%77I5690.6$6%54)0F_F`I*)07*=$63)$D94)63$9*9'
;349*5"53%56$%*#6*0)')763$0%$6*5"9;$5691N\=<3$=M05COOADCCOBECPPFP15 W4[R*)9[*>>'KI:"$%X'(%6*)>Y']*$7$%*53L',0993%7<'KV)6$%-1M6%I56I%$a;%0;$%64
%$"6*0)93*;9*)63*%7F0%7$%)0)"*)$%0;6*5"53%0=0;30%$91N-349<3$=,COObBC@?DPPCF Q1
A W)*I53*W'T[7M'S[)*93*21!*7$"46I):"$6$%3$%6#FR8$+$)$%6*0)*)) 0%+)*55%496")7*699;$56%0950;*5;;"*56*0)1N\;;"-349?@@PBODObPFb1: W)*I53*W' U[$7M'(*)$)0G'T[7M'S[)*93*21W$%3$%6#;%0;$%6*$90.)$R0%+)*55%496"'PcF 7*=$634"=*)0FdF=$634"FPF96*":#0"*I=_F53"0%0:$)#$)$9I".0)6$1N;)N\;;"-349
?@@BPPD/OE?FP15 M53)$*7$%\'M6*""3%6('KV)6$%-12*+3$..*5*$)54+$)$%6*0))7 7$6$56*0)0.6$%3$%6#;I"9$9I9*)+"9$%;I"9$966$"$50==I)*56*0)R8$"$)+6391T;6 Ye;%$99?@@QBCPDEAQFbP17 G)+H'(I66$%/'M6*""3%6('>I*#,'\%8#3*M'N#:*)9$[
('M53)$*7$%\'K%="*53Z'KV)6$%-1/%+$F9*#$:I"[)763*)F.*"=96*":#0"*I=F9"69*)+"$ 5%496"9.0%)0)"*)$%0;6*59)7W2#+$)$%6*0)1\78LI)56(6$%?@@ABCAD?@CbF?E1
b 2$KM'W)/M'H3$)+J'-%97-S1(I"6*;3060):90%:*)+=6$%*"9D=0"$5I"% 7$9*+)9'53%56$%*#6*0)9')7;;"*56*0)91<3$=>$8?@@bBC@bDC?PFEE@1: ("8"N-'N*)
0 12 34 56 78 9
15 5 89
!"#$%&%'()*%+,!-./!0-12$33!%4$5*!+ 67+-%+7% 8!59:;<
=1*%15!,!1"0"*!">#3*"1-1-"-%"-1?!00-5-!15'0%"*-@%1"*1!8!-&%"-&!"*+?*%
5*!&1#A*%3!8%5*-"!5"+!<)*!,<%"!<BCDDEBFGFHDD#BC<5IJK%'%A*-JJ%1$$<
+ "-%'!!83"-5% A"%?!>-"*11 -1!%!%8>-"!<43"L!&DMMNEBGBC#F<
OMP:% !'$.%-AQ;A!.7%+,!"Q)7R9 +18S)Q+18"/6>-!?LQ<2 A &%"5*,-5,!"*808!"!,-1-1?A!518#8!3 %-T%K--"-!A0?%1-5, !5+ !A<Q 4?)*!,DMUMENHGFVVH#U<
ODCP%I25*! !$: WX<:'-,-8-1!-1?%AK+-8-1?K 590"*!A'1"*!A-A00+15"-1% -T!8 :-#51R+?%"!8,%"!-% A<)+4?$'1"*BCDBEMGDYF#UV<KI25*! !$7%+8!Z+-1)<L!5!1"
%8&%15!A-13'-,-8-1!8!-&%"-&!A%A +,-1!A5!1"3*"& "%-5%1811#-1!%3"-5%
,%"!-% A<6%?!"A.!"!5'5 $'A"!,ABCDFEDVG+18!3!AA<
ODDP$!!0!@%,3 !G%I25*! !$L%,18!15[%A%-A(: WX<$"%#%18K%1%1%#A*%3!8 -?,!A>-"*%3'-,-8-1!5!GA'1"*!A-A%18 -?*"#!,-""-1?33!"-!A<=+Q4?)*!, BCCUEFDBM#HC<KI\"%,-J[%,%T%9-/[A*-8%Q-<:'-,-8-1!#5!!@"!18!8]#A'A"!,AG
?!1!% A'1"*!A-A%18-1"!!A"-1?0+!A5!1"33!"-!A<Q2,)*!,$5BCCHEDBYGDNFMY#V<
5I7%? !');-1^:3!$Q2<7%-+,,%1?%1%"!-1,-5>%&!#%AA-A"!8@-8%"-1 !%5"-1AG A'1"*!A-A 0 A &%"5*,-5 BHY#"-%' 3'-,-8-1!A< 6!"%*!81 ;!""
BCCMENCGYUDU#BB<8I6+,9!&-_-+A$`-"!5*&-_-+A228,a1%A:$'1"*!A-A01&!
BHY#"-%' 3'-,-8-1!A)*!,-R%BCDBEBFGYD#V<
ODBPA!!0!@%,3 !%I;-+7.+b;;-+Q^*%[/.+%1?^;<$'1"*!A-A%18 3*"3*'A-5% 33!"-!A01&! 3'-,-8-1!#K%A!8">#3*"1%KA3"-15*,3*!A<
6!"%*!81;!""BCCVEHUGNMNU#YB<KI;-;S!Qc+.b+d.[%$d<4?%1! !#A3!5-0-5 8!"!5"-103*A3*%"%A!%5"-&-"-!A>-"*">#3*"10+?!1-53K!A-15! A%18"-AA+!A<Q 2,)*!,$5BCDBEDFHGDBDNV#YV<5I25*! !$% &% Q:2 eA!$7%A! %2
$3%1?!1K!?2%?!;298%A#J--?.(-%+"Q;)%7LK-1#!S+!1(<$'1"*!A-A
0 12 34 56 78 9
15 5 89
!" #$%&#%%'!%($)#!"$'#)()!( #*# !'+(%!&#)!,!&!%(-+$ (&#&( #+($)!%.#
,('(%()$%#&%)#.)/ 0#1(, 1(,#23456478292:-5;0##
<45=#$>#?"(''(#@A#B$) (''$#?A#B$/&(C/!%#1A#1$)#BA#D+!%-'(#E/(%#F0#@%( ! #$%&#
!"$'#!%G( !.$!%#*#$# ()!( #*#/ -/''#$)'G!%'&!$H!%(#"),)( 0#I#J).#
1(,#2342699873K9-L;0#+>#1$ (#FA#M!"#?A#1$,$.%(#BA#N!%($)#$%&#%%'!%($)#!"$'# )()!( #*#$)'G!%'&!$H!%(#&( 8#$#()(!"$'#!%G( !.$!%0#O( #M!.,#&!8# 430434;PQ0&(!.023470350324#####
<47=#$>#B/)(R#FA#M('$#JA#O!(&()!"#F0#@'G(%#(**(" #%#('(")%!"#$+ )!%# (")$#*#
&%)- /+ !/(,A44A42A42-()$"$%-LA43-$%)$C/!%&!,($%( #ST1?U >#I#M #J).#
1(,##233L62284::-;20#+>#B/)(R#FA#M('$#JA#V!G$'$#WA#O!(&()!"#F0#@'G$"),! ,#$ #$%#
(**!"!(%#'## /
X-&!,('$,!%-#$%&#"$%- /+ !/(&#Y-"%Q/.$(&#,'("/'( # Z!#$%#!%)$,'("/'$)#"$).(-)$% *()#$+ )!%##I#M #J).#1(,##23446278297-K40#
<4:=#$>#N$)!$#DA#?''$!%#1A#B)&($/#EA#@",!&#FA#F!)!%!-O(+/! "()A#1$))$#FA#T(/'$&(- F!"/#WM0#@%(!"#)$(.!( ##&()!G$!H$+'(#)!(%'$,!%( #&! '$!%.#!.#Z-%#
$+ )!%0#I#J).#1(,#233K69584952-770#+>##V$$%#1A#T()(%H!$%!#FA#W%.!%#JA#[() #W\]A# M))^ #NA#M% #TA#W()H#IA#T)(!$_#@A#B'$%"$)&-O( "(#W0#`**(" #*#S,/'!>+)$%"!%.#*#
&!'$)#"),)( #%# !"$'#)()!( #$%&#Z-%#$+ )!%0#I#M #1(,#
?#233:643L85327-53590#">#O(()#\A#@",!#]0#U/$&)/'$)#&%)-$""()# /+ !/(&#
'!.S(%'(%(G!%'(%(>a %( ! #$%&# 'G$"),! ,#*#(#*'/)( "(%"(0#I#M #J).#
1(,#2337649843:4-;0#
<4;=#$>#V$)!H_#?DA#F$)$#O1A#b$%.#\A#Tc,,#V0#U/$%!$!G(#,($ /)( #*# 'G(%#'$)!0# 1(,#D(G#23376437849:-LK0#+>#W$%"!%!#MWA#?&$,#1EA#F)/%$#EEA#]()#ND0#?#
",$)! %#*#%% ("!*!"# 'G(%# "$'( 0#O(.)((#*#$.)((,(%#*#,!") "!"#'$)!#G$'/( # +$!%(&#+#&!**()(%#,($ /)(,(%#,(& 0#?)_!G"#23396dG!82;;-K30#
0 12 34 56 78 9
15 5 89
!"#$%& '()*+,-./ )-%&'-0$%(1#2 22-./#3)4-. '$)1$3($% )-'2+*�"#/
55675689:5;<=+>!*#'?3;* '' 2%-@AB@ %CD#0$3EBF D'#3%#*BA. 3%& )GB"#$%& '()*B ,' H($I+,-./#3)4-. '$)12% .#28(#)#'0$3 )$-3-J3#KLMN:O!/ .D#2J-'=6-'P 3$%2-./#3)2+
@A&12Q'P*	O6798<9;=+
= !M PD%&$RN#(+!+,12)#0-J#S4#'$0#3) .(#2$P3+T&$)#A. $32BU@8VD .$)1"#2-D'%#2 A'#2275=+>!M PD%&$RN#(+!+M PD%&$0#)&-(28-')&-P-3 . '' 12 3(.$3# 'P' 4&2 N2-J)%-/#'#(3!+E# '>-'3BW$%&BX,G8G0#'$% 3,D44.$#'Y32)$)D)#75=+%!"-22A@N#(+!+ M PD%&$)#%&3$CD#2J-'CD .$)1#3P$3##'$3PN& '(%-/#'#(3!+*$)1-JU#KZ-'[BU#KZ-'[B X,G8W%R' K;\$..755]+
5,##J-'#S 04.# !A-D'^ / ($GBG11 '$WBG0$3$;_ `.W,+M PD%&$-4)$0$`#(
213)$2-J%-.. P#3;P;4-.1N %'1.$% %$(!a[ -.$3%-04-2$)#2D4#' >2-'>#3)&1('-P#.+LD' A-.10@9OO=76689O5;]+>!W 2-D0$\"_BI 22$0GBb 2'$WBG>(D.. &EI+E#)#'0$3$3P -4)$0D0%-3($)$-32J-'.$4 2#;% ) .1`#(213)$2-J)'$#)& 3-. 0$3#NMLG!;> 2#(#2)#'CD )
% )$-3$%2D'J %) 3)>1M PD%&$'->D2)(#2$P30#)&-(+W-.#%D.#29O7]86]9;=O+%!E'-P ) UBb ''$c'#WBR' 3#)"B,-.dBI' D2`A+\$P&1$#.(4'#4 ' )$-3-J4D'4D'$3;=J'-0 efghijgklmnlognl+E1#2A$P09O7==89<;+
9OID.&p3#[@BbD'#q_BA1)#. QBW$[12#[MBFD(/r[@B"st$u[ G+AD&;AD..0-.#%D.#2 K$)& 212)#0 )$% ..1#S)#3(#(v;%-3^DP )#(212)#0J# )D'$3P6B<;($%1 3-$0$( `-.#+E1#2 A$P09OO7=<8<;]<+
9*FB*&D*YB*I@B*AZB\D,_BF$D",+G3$3)#..$P#3) 44'- %&)-)&#
($2%-/#'1-J.D0$3#2%#3)0 )#'$ .2D2$3P%-0>$3 )-'$ . 44'- %&%-0>$3#(K$)&M PD%&$
0#)&-(-.-P1+FD0$3#2%#3%#9O79]8995;:=+
99wPxB,-3PbBxDb+A .. ($D0;% ) .1`#('#P$-2#.#%)$/#*;\b-3(-')&-;
%#)-S1. )$-3-J '1.41'$($3#29OO76:];=O+
0 12 34 56 78 9
15 5 89
!"#!$%&'!()*(+,()*--&'!(.!/*01*2*3&45167" &87#9*$:&;!(<=&>6?*0+&
%*7"7(@A&'!(460(%B&A059(C+&D60(7$-&E0F)!"-%GH,(<9*"7"!()#9!0!#<*07I!<76(6J (6/*$KLMLN!()OPQLNR9*(,$*(*/7(,$*(*)*07/!<7/*"SJ7(*<5(7(@6J<9**$*#<06(7#!()6R<7#!$
R06R*0<7*"6J#6(?5@!<*)T!<*07!$"G- 9,"D9*TEUUVWUXSXYYNZUG
Y:#9*$$*H&C6570![& J!JJ7(@*0E&;!T6()*(#3& $FC&;6)0\@5*IN%]R*I-G'N"9!R*) Y&XN17"^!0,$/7(,$_R,07T7)7(*6$7@6T*0"S",(<9*"7"!()6R<7#!$R06R*0<7*"G-B0@D9*T UU`VaYSaWWNaG
0 12 34 56 78 9
15 5 89
!"#$
% & '
()*+,-#.,/0 1,/2/3 3,+4
56 *6& *7&
8)9+:$2+1 4,$22,/$ ,- 7 4;2212/ .,<
& = = /1 >
?)*+,-@0.,/A+31
#2/B C
0 12 34 56 78 9
15 5 89
!"!#!!$!
%& '!'!'!'!
(& '!)!)!)!
*& '!+!+!+!
,& )!'!)!+!
-& )!)!+!'!
.& )!+!'!)!
/& +!'!+!)!
0& +!)!'!+!
1& +!+!)!'!
2
0 12 34 56 78 9
15 5 89
!"#$%&'( )*+ ,-*./012/03
45 '( )*+
678
9:;<&&=%>: 2/0
?@ ABC,ADDEE3 CFD GEHE0 IAJF
K@ CCB,ABFEE3 J0B GEHE0 FDDA
L8@@ CIC,DEFEE3 JBC EHFM D0ED N@ AF0,0BMEE3*CIM,C0MEE3 JIA EHE0 F0MM OP@ AMD,AJDEE3*CBD,CAJEE3 FIE EHDD BCDA Q@ AMM,0DEEE3*CIB,CB0EE3 JAM EHIA C0JF R@ CEC,CBJEE3*CIC,CDFEE3 FCE EHDE IMJA S@ CEE,0CEEE3*CDI,C0JEE3 JBA EHFF DFE0 T8@ CE0,CBMEE3*JAI,JIDEE3 FJE EHFF JME0 UVV&<2:WXY<W<W<2W<%+ZAVA&V[:%+&X:W:<<WX:[W<X:P\0HE]0E/F .:CHE]0E/F.>WX^&W:%+X+P\0HE]0E/D.:CHE]0E/D.>W<%&&%+H8 7V[W<&2<+2<_[X+:[`%<V,a0Eb3<:<W%+<W<VX:%$<:_[%+%+<&[V>X:<%+0.
ZA9cJ,67\EHFJ3W=XWX+<%+EH0.ZA9cJX&&:X+XW,67\EHBC3H8X:X>WW<>
dAJeHPX:X>WW<>d0CXeH f
0 12 34 56 78 9
15 5 89
!" #$ %& '()* +,-.)/0# 12 3 4546 7 7875 94:6 ;5:<
= 9;67 7 >?9> 7>:> 75:;
@ 7?>9 7 >946 >6:4 77:7
A0B)#C0 >6; 7 57 >:9
D. >775> 5 ><<
" !CE BFC0# #0G))/B E H0 E0/:$ #0I00 00#E:& G)/0J E0/
BFC0B -0 #: * ) K0L00/ BFC0# #0G))/ /# H0 E0/ BFC0 0B)#C0:2 0.)G0 00B H0 B / MNKB:
O
0 12 34 56 78 9
15 5 89
!" #$$%& !" #$$%& !" #$$%&
' ((' )(* (+, )-- (+( )-+
- (.' '+ (*+ )( (.' '+
( (./ -- (/( -* (00 '1
2
0 12 34 56 78 9
15 5 89
!"# $%&'"( $)*( +),+&,( -./0( ( 12$3456
7(8(595(12$34567(8(:49;(12$34567(8(,<9,(12$34567(8(=59<(12$34567(8(>?95( /@A( BC(3"C6 BC(3"C6 BC(3"C6 BC(3"C6 BC(3"C6
DE F( F( 4>,( 4>;( F( 5945(
GE 4H=( =5:( =:5( =:H( =,<( 59<5(
IE =5>( =,,( =>H( =H4( >5?( :9H>(
JE =,4( =4?( =;5( =<,( =?<( :9,>(
KE =>4( =?5( >>=( >;?( ;4,( 495:(
LE 4<4( =54( =4:( =4>( =H5( :9<5(
ME =:H( =>H( =?H( >45( >;;( ,9>,(
NE =55( =45( =>;( =H,( >5?( :9H>(
OE ==4( =<;( >:>( >=5( >H=( ,94H(
DGE ==5( =H:( >=>( >H>( ;,4( 49=4(
7(-PCQ% RSPT!QU (%&!QPV(!Q!C QW(XYC%&R:9(A(/@Z([&%(%\((Q]Q[[P%"(&P"(BC(3"C6(
^_`aba#12$3456(P"("C(C%&(X:9(FU'(%(cQV(&%d(CP[[P%"(P" "[PV("%(CP[[P%"(C!ePC!(T!"(
f(%f !P"U9(
0 12 34 56 78 9
15 5 89
!" #$$%& !" #$$%& !" #$$%&
' ()*+ ,()-. ')/0 ,()/- ')1. ,()2+
1 ')** ()10 ').+ ()'1 ')22 ,()1*
/ 1)1+ ()+1 ')*. ()1+ 1)20 ()-/
3
0 12 34 56 78 9
15 5 89
!" #$% &' ()* +,-.)/0# 12 3 45678 4 9584 4457 8:56
; <5:8= 4 <574 =59< 9<5>
? 45888 4 9544 9@57 8<58 A0B)#C0 <594> 4 <5<7 459
D. :5<=9 6 9<<
" !CE $ BFC0# #0G))/B $E H0 E0/5% #0I00 $ $00#EJ' G)/0K E0/ $ BFC0B -0 #$5*L) M0N00/ BFC0# #0G))/ /# H0 E0/ $ BFC0 0B)#C052 0.)G0 0$$0B $H0 $B / !O5
P
0 12 34 56 78 9
15 5 89
!"#$%&'()*%+ ,
,'-'%(%$+.&#$)"'"+!/ 0
0 12 34 56 78 9
15 5 89
!" !"
#
#
# #
$%#
$%#
$%#
$%#
&
'
(
)
*
+
,
-
. /
0 12 34 56 78 9
15 5 89
0 12 34 56 78 9
15 5 89
0 12 34 56 78 9
15 5 89
!"#$%!&'(()
!'*
+'(,
-'')./ 0
0 12 34 56 78 9
15 5 89
!"#$%&'!%(
)*+,-,$./'0 12&#
&340#35'0"&
&
662789
0&$3
%0'!
./'0 :/2&8
&
;2<&9 =
0 12 34 56 78 9
15 5 89
!""#
$%!&' (!")
*+
,%$
*+
-./--)"0123,$"!4 5678729 $%
(!31)
-)3
:;<<11=
><?@=
-)3A,#%1A*/$%03
B
0 12 34 56 78 9
15 5 89
!"#$%&'(!)%*+
,-./010$23(4 5)#6
&7'84#7(4"&
& &
&
&
9:)!#;
<
0 12 34 56 78 9
15 5 89
!"#$%&''#"(!'#)#*#+$')'"%,-+" .*#*/
#+(&.+$('%'%) '"%"-+" .*#*-!%0.$#) *&0!/
1+ '+%&$%'0'%+"('" #)% *-!)#""#+"&,% $')!%"-+ #)#2*/3
0 12 34 56 78 9
15 5 89
!"# !$ # %&! !%&'( )* # % !% (# !$ #
%' + "# & !+!%&! (# ,( "-# .)-,& # + &!/ # #
0&)*"#1""2)*34#5'*2)"#6&**378#0&( "#9),:,"34#)"#;)"<!(#=!>"?*#@,"/7#
4#A!+)"#B"2/#0C9=63#BD=#EF4G# #;=#HFHIJ#B"2/#=!,"J#KA56#=!,"J#0A=53# K=0C;3#4#,#.("L3#MEI74#D!" #5)" #6-")"#0N3#;)"#
7#K"( , #(#5"(#0&+:,(##=""(#BD=#0A=5#E77E3#KB.##O)""!"3#,#P!,)# 9)"*'3#9#HF74Q3#;77HF7#O)""!"#0N3#;)"#
0!(%!""-#), &!R#('*2)"/)&**S,"2?""(4/$#.*R#THH#UFV7#QE#GE#QG#GI#;)N#R#T#HH#
UFV7#QE#GE#QH#WG/##
P* !" # (,%%! "-# "$ ! +) !"(#
XYYZ[\]^Y]Z_[`]aZbZa]^Y]Z_[`]Y_[\^c]^d]eeeeZf]gd]df]] ] ] ] ] hi]
jd_aklgl]^Y]b_cg_d[Z]mjnopjq]Y^c]^d]eeeeZf]gd]dfr] ] ] ] ] hs]
t_a[ua_\Zv]_dv]ZwxZcgfZd\_a]x`^\^x`klg[_a]v_\_]mgd]tystasq]Yc^f]ag\Zc_\ucZ]^Y]l^fZ]
xkcgfgvgdZ][`c^f^x`^cZlr]] ] ] ] ] ] ] ] hs]
e e e
eZf]mdfq]bZclul]zzzzX{m|}q]m~f^aq]Y^c][^fx^udvl]i]_dv]is] ] ] ] h|]
t^xk]^Y]iy]_dv]i|t]n]lxZ[\c_]^Y][^fx^udvl] ] ]]_dv]i}is] ] ] h]
ZYZcZd[Zl] ] ] ] ] ] ] ] ] ] ] hii]
# ]]
{_aZ]hir#P$$ #!$#)&#*2*#!$#)&#$) !#!"#e+#"#"+#
# 6# 9# 0#
# 62)-# P$$ # 62)-# P$$ # 62)-# P$$ # 4# G4Q# ?WM# GWH# ?7G# G7G# ?W7#
7# GQ7# 4E# GQF# 4G# GMM# F#
0 12 34 56 78 9
15 5 89
! " #
$%&'()*+,-./01232456/73/.89:-;<=->5474.?9@3..@A
B/8C47 D/ E45F =8 BG7/C34E HIJ0/3.9EK9
- !# # ! A# A
L ##" # #!" #A A
M !" # ""N A A
O923EP9 # N A
Q4C/0 N ""
/DP@452RP/79EE963/C34.2574@CS9@9/.FE9T799455799E4@86/73/.89U@9/.45 2RP/792J97E45E7/C34F9CV99.2RP/79EE963/C34./.ECS9@9/.452RP/797923EP99790/C369 95598C245CS95/8C4724.?9@A
W
$%&'()*X,M/08P0/C9E/.E9IJ973@9.C/0JS4C4JS1238/0E/C/:3.MY#M0#>574@03C97/CP7945 24@9J173@3E3.98S74@4JS4792A
W
M4@J4P.E2
M/08P0/C9E
?/F23..@
:9IJ973@9.C/0
?/F23..@>
M/08P0/C9E
?9@3..@
:9IJ973@9.C/0
?9@3..@>
Z Z
[\]Z Z[\]
#:#N> "#:">
Z Z
[\^ ^[\
:> #N:"!>
Z Z
_`]Z Z_`]
#N:#> #:">
0 12 34 56 78 9
15 5 89
!"#!$ %%&"%'($
)
&("&&*$ &&" *$
&'("&'&$ %#+"**$
,-
##"##$ %& "%(+$
)
&&*"&+$ *"!$
&**"&*+$ %%!"%!#$
,-
&'+"&*$ %*("%+&$
.
