HAL Id: jpa-00245564
https://hal.archives-ouvertes.fr/jpa-00245564
Submitted on 1 Jan 1987
HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.
L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.
Recent developments of the two-dimensional technological process simulator OSIRIS
N. Guillemot, G. Pananakakis, P. Chenevier
To cite this version:
N. Guillemot, G. Pananakakis, P. Chenevier. Recent developments of the two-dimensional technolog-
ical process simulator OSIRIS. Revue de Physique Appliquée, Société française de physique / EDP,
1987, 22 (7), pp.477-485. �10.1051/rphysap:01987002207047700�. �jpa-00245564�
Recent developments of the two-dimensional technological process simulator OSIRIS
N.
Guillemot,
G. Pananakakis and P. ChenevierI.N.P.G.-E.N.S.E.R.G.,
Laboratoire dePhysique
desComposants
àSemiconducteurs,
Unité Associée auCNRS n°
840,
23, avenue desMartyrs,
38031 GrenobleCedex,
France,
(Reçu
le 27 novembre1986,
révisé le 10 mars1987, accepté
le 13 mars1987)
Résumé. 2014 La simulation
numérique
des processustechnologiques
est trèsimportante
pour la fabrication des circuitsintégrés.
Dans cetarticle,
les auteursprésentent
une versionplus complète
du simulateur bidimensionnelOSIRIS,
prenant en compte la diffusion simultanée de deuximpuretés.
Les modèles utiliséspour
l’implantation ionique
et la redistribution desdopants
sont brièvementrappelés.
Un nouveau modèle aété
développé
pour la croissance del’oxyde
dechamp :
il permet une très bonne simulation du « bec d’oiseau » obtenu par leprocédé
SEMIROX. Commeexemple,
la réalisation d’undispositif
N-MOScomplet
est simuléepar le programme,
qui
donne leprofil
desimpuretés
et la forme del’oxyde à
la fin du processus.Abstract.
2014 The numerical simulation oftechnological
processes is veryimportant
for the fabrication ofintegrated
circuits. In thispaper,
the authors present a morecomplete
version of the two-dimensional simulatorOSIRIS, taking
into account the simultaneous diffusion of twoimpurities.
The models used for ion-implantation
and redistribution ofdopants
in silicon arebriefly
recalled. A newanalytical
model for oxidegrowth
has beendeveloped
whichgives
verygood
simulation of the « bird’s beak » of SEMIROX structures.Finally,
acomplete
simulation of a N-Channel MOS device ispresented,
with the redistributedimpurity profiles
and the oxidelayer shape
at the end of the process.Classification
Physics
Abstracts05.60 - 61.70 - 02.60
1. Introduction.
The numerical simulation of the
technological
pro-cesses become very
important
for the fabrication ofintegrated
circuits.Especially
for MOS circuits sev-eral two-dimensional simulators
[1-3]
have been pro-posed
in order to take into account theinhomogenei-
ty
of the field oxide thickness and the lateral diffusioneffects.
Similar to the simulatorsgiven
in[1, 2],
the authors havedeveloped
the program OSIRIS[4, 5].
It allows the simulation of acomplete
device fabrication process
including
thefollowing
steps :
- resist
deposition
andremoving
- oxide or nitride
deposition
andetching
-
ion-implantation
orpredeposition
ofboron, arsenic, phosphorus
andantimony
- redistribution of one or two
impurities
in aninert or
oxidizing
ambient-
growth
of thegate
or field oxide.In our program the solution of the diffusion
equation
isperformed numerically using
a finitedifference method. An
original
and accurate simu-lation of the « bird’s beak » formation in the case of
a semi-recessed oxide
(SEMIROX process)
is pre- sented in this paper. Section 2briefly
describes themodelling
ofion-implantation
and the resolution of the diffusionequation.
The detailed simulation of the field oxidegrowth
ispresented
in section 3. Inthe last
section,
the simulation of acomplete
N-Channel MOS circuit
fabrication
process isgiven.
2.
Ion-implantation
and redistribution ofimpurities.
In this section the models for
ion-implantation
anddiffusion of
impurities
arebriefly
recalled.2.1 ION-IMPLANTATION. -
Ion-implantation
andchemical
predeposition
are the two selectivedoping techniques
used to create localizedjunctions
in asemiconductor : silicon
dioxide, polysilicon
or resistact as a mask for
impurities
in silicon.Predeposition
can be treated as an
impurity
diffusion.Therefore, only
models used forion-implantation
ofboron,
Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/rphysap:01987002207047700
478
arsenic, phosphorus
andantimony
aredeveloped
here. The silicon wafer
geometry
ispresented
infigure 1.
Fig.
1. - Silicon wafer geometry formodelling
ionsimplantation.
We assumed that an ion
entering the target
at apoint
y will come to rest at apoint (xo, yo )
with theprobability density P x (xo ) P y (y - yo ). P x
is theprobability density
in the x-direction(vertical
direc-tion
parallel
tothe
direction ofion-beam)
andPy
is theprobability density
in they-direction (lateral direction). According
to Furukawa[6],
thedistribution
Py
ofimplanted
ions issupposed
to be aGaussian function with a lateral deviation
I1Ry.
Tosimulate the vertical direction of the final
resting points
ofions,
thesimple
Gaussianapproximation
isno
longer
valid :experiments
have shown thatprofiles
are skewed and possess tails. Three measured and tabulatedlengths [7]
characterized theseprofiles :
the averageprojected
rangeRp;
thestandard deviation
I1Rx
and the skewness y. From these threeparameters,
two distributions arewidely
used : two
joint
half-Gaussian forarsenic, phos- phorus
andantimony [8]
and a modified Pearson IV function for boron[9].
In the case of a vertical and
infinitely high
maskedge (resist
forexample),
theimpurity
concentration isgiven by
ananalytical expression [10].
In a moregeneral
case of anarbitrarily shaped
maskedge,
it isassumed that the
stopping
power of the masknearly equals
thestopping
power of silicon[11].
The maskis then considered as a silicon
layer
and the two-dimensional
profile
is obtainednumerically.
Theapplication presented
in section IVgives
a firstexample
of boronimplantation
with aphotoresist
mask considered as a vertical mask
edge,
and asecond one
concerning
arsenicimplantation through
a field oxide.
2.2 REDISTRIBUTION OF IMPURITIES. - The process of thermal diffusion of
dopant impurities
is anessential
part
of all semiconductor device fabrication.This effect is described
by
the well known diffusionequation [12, 13] :
where
Nk
is the concentration of the k-thimpurity, Dk
is the effective diffusion coefficient of thek-ti
impurity,
Zk
= 1 foracceptor-like impurities, = -1
foidonor-like
impurities,
ni is the intrinsic carrier concentration in tht
"
semiconductor, and
1
This relation is based on theassumption
of a1 complete impurities
ionization. The effective dif-’ fusion coefficient for
boron,
arsenic andantimony
’ where
Do
is the intrinsic diffusion coefficient of the k-thimpurity, f3 k
is aphenomenological
coefficient1
equal
to 19 forboron,
100 for arsenic and 1 for"
antimony ; fk = pin;
orn/n;
foracceptor-like
ordonor-like
impurities, respectively,
orphosphorus,
l the well known model of Fair and Tsai
[14]
is used.The non-linear diffusion
equation
must be solved1
1
-
l
Fig.
2. -Physical
domain il used to solve the diffusionequation.
for the silicon wafer
geometry
shown infigure
2. Thephysical
do main n is describedby :
, -,n, / 1 - - -
where
Lo
is the useful siliconlayer
thickness andXO(y, t)
is theequation
for theposition
of thesilicon/oxide
interface. In the case of redistribution in anoxidizing
ambient the domain 12 varies with time. It is assumed to besymmetric,
orlarge enough
in the
y-direction.
So theboundary
conditions aregiven
as follows :- Conditions
o f symmetry :
-
Assumption of sufficiently deep
domain :The
boundary
condition at oxide/silicon interface is writtenby assuming
that there is no diffusion into the oxide andthat,
at alltimes,
thesegregation corresponds
toequilibrium ;
so that :where
ks
is thesegregation
coefficient of the kimpurity
atthe oxide/silicon
interface,
m is the fractional total oxide
growth
due to theconsumption
ofsilicon,
vs;o2
is the oxidegrowth
rate,n is the unit normal vector to the
Si02/Si
interface.Then,
thephysical
domain f2 ismapped
into afixed-time invariant
rectangular
domainby
means ofa coordinate transformation
[1].
Next,
the classical method of finite differences[15]
and a
Crank-Nicolson
scheme[16]
are used to adiscretize the so obtained
partial
differentialequations.
The numerical solution isperformed using
the Gauss-Seidel method. Thestrong
non-linearity
of theproblem
does not allow a method of overrelaxation to be used.Using
all these methods we havedeveloped
theprogram OSIRIS of reduced size and reasonable CPU time
[10].
3. Simulation of the field oxide
growth.
Selective oxidation
provides
asimple
way of isolation ofintegrated
circuits on silicon. In the LOCOS process, a nitridelayer deposited
on apad-oxide
isused as an oxidation mask : this process is known to
give
rise to a « bird’s beak », due to latéral oxidation under the mask[17].
An accurate simulation of this effect is necessary in order to ensure a better control of the
tectmologi-
cal oxidation process.
Solving
thecomplete
set ofphysical
differentialequations governing
the oxidegrowth
and the simultaneous viscousflow,
one canobtain
quite good
results but it is difficult andcomputer-time consuming [18-20]. Therefore,
in thissection,
wepresent
semirecessed oxideshapes
ob-tained
by using simple parametric relationship
basedon the
analysis
ofexperimental
data[17, 21, 22].
First,
as is shown infigure 3,
twoshapes
of the« bird’s beak » can be
experimentally observed, depending
on the stress exertedby
the mask. In theFig.
3. - Classification of the bird’s beakshapes
observedexperimentally e shape
1, 0shape
2, A unclassifiedshape.
case of the
shape
1(Fig. 4a),
the nitridelayer
andthe
pad-oxide thickness, en
and eo xrespectively,
arethin, resulting
in a low mask stress. In the case ofshape
2(Fig. 4b),
the nitridelayer
isthick, resulting
in a
large
mask stress.Two
analytical
functionsZ,
andZ2
are thusneeded to fit the contours at the oxide/silicon interface and at the oxide/ambient or nitride inter- face. Two
complementary-error
functions are usedfor
shape
1 : ’For
shape 2,
because of thestrong
mask stress, apinch
of the oxide appears under the nitrideedge,
for the upper
interface,
and shifted back alength 8,
480
T *
Fig.
4. - The twoshapes
of the bird’s beak with characteristiclengths (Eo x, Lbb
andIf)
andprocessing
parameters(eo x
anden) : a) shape 1, b) shape
2.at the oxide/silicon interface.
Therefore,
two differ-ent functions are used to simulate the « bird’s beak » contours on the left side and on the
right
side of thispinch :
Zi (y )
= ai erfc(bi (y - 8 ) )
+ci
fory é
6(3.3) zi (Y)
= ed 1 l
Yfor
Y«:-:::
6(3.4)
dI - Y + q for y - 8 (3.4)
Z2 (y ) = a’ 2 erfc (b2 y ) + c2
fory ’-_ 0 (3.5) Z2(y)
=ez , d2 -y
for
y ~ 0 (3.6)
d2-y+q for y 0 (3.6)
where q
=0.05 03BC
and 6 = 0.04 03BCm.The values of the two
parameters q
and 8 havebeen determined
experimentally :
8 can beeasily
measured on the field oxide
shapes
obtainedusing
SEM
technique ; q
is chosenequal
to 0.05 ktm in order to obtain the bestfitting
of the observed field oxideshape
with the function :d- d’ 2 - Y + q
The
parameters
a,,bl, ai, bi,
... are functions ofprocessing parameters
eo x and en, and three charac- teristic features of the « bird’s beak » :Eo x (given by
Deal Grove’s model
[23]), Lbb (Length
of lateraloxidation
under the nitridelayer)
and H(lifting
ofthe mask
during oxidation) [21, 24, 25].
At thebeginning
of the oxidationcycle,
we assumed that the initialpad-oxide
was etched on the left side of the maskedge
so :Besides,
thefollowing assumptions
are made :1)
There is no oxidation under themask,
far fromthe nitride
edge.
So that :2)
In the fieldregion
and far from the nitrideedge,
the oxide thicknessEo x
isgiven by
Deal andGrove’s model :
where m is the fractional total oxide
growth
due tothe
consumption
ofsilicon.
3)
The thickness of silicon consumed under the mask isgiven by Hl = m H,
whereH
is the1-m
lifting of the nitride mask during oxidation
4)
Thelength
of lateral oxidation under the maskLbb,
is measured between theedge
of the nitride anithe
point
where theslope
of the oxide contour caibe
neglected compared
to theslope
at theorigin.
Sithat ·
with e = 10 %.
Assuming
thèse4 conditions,
the field oxide contours are described as follows.Qhm"+ 1 . ·
where
where
Shape
2 :where
where
where
where
Eo x
isgiven by
Deal and Grove’s model[23], Lbb
and H areplotted
infigures
5-9and
can be describedby :
where
To x
is the absolutetemperature, KL
=8.25 x
10- 3 KH
=402.00,
andEo x,
e0xand en
aremeasured in J.tm.
Within the range of interest : . 0.1
03BCm ~ E0x ~ 1.5
03BCm ,850 °C ~ T0x ~ 1 100 °C , 0.05 03BCm ~ en ~ 0.2 03BCm ,
native oxide ~
e0x ~
0.05 03BCm ,( 100 )
substrate .Hereafter,
we compare theshape
of the « bird’s beak » obtainedby Secondary
ElectronMicroscopy
Fig.
5. -Length Lbb
of lateral oxidation under the mask for the bird’s beak versus field oxide thicknessEox.
Fig.
6. -Length Lbb
of lateral oxidation under the maskversus
pad-oxide
thickness eo x..Fig.
7. -Length Lbb
of lateral oxidation under the maskversus
processing
temperatureT0x.
482
Fig.
8. -Lifting
H of the maskduring
oxidation for the bird’s beak versus oxide thicknessEox’
Fig.
9. -H/Eox
versus nitride thickness en,(SEM)
with simulatedprofiles.
Agood agreement
betweenexperimental
data andanalytical
results canbe observed in
figure
10.4. Simulation of a N-Channel MOS device.
As an
example,
OSIRIS is used to simulate the entireprocessing
sequence for the N-Channel MOS device infigure
11. The process schedule is thefollowing :
Field
implant
with boron(120 keV, 1013
cm-2).
- Field oxidation
(950 °C,
300min).
- Gate oxidation up to 0.05 03BCm.
- Depletion implant
with arsenic(180 keV,
2 x
1011
cm-2).
- Enhancement
implant
with boron(40 keV,
2 x
1011
cm-2).
-
Dry
argon anneal(900 °C, 30 min).
- Source-drain
implant
with arsenic(120 keV, 1015
cm-2).
- Reflow process
(850 °C,
30min).
- Contacts.
The process
employes
six different mask opera- tions and uses a local oxidation of silicon(LOCOS)
scheme for isolation. For
simulation,
the device isdivided into 5 main
parts.
The surfacetopographies
and
corresponding equi-density
contours for im-purity concentrations,
at the end of the process, aregiven
infigure
12.5. Conclusion.
We have
developed
acomplete
two-dimensional simulator oftechnological
processes OSIRIS. The mostimportant
processsteps
for MOS devices suchas
predeposition, ion-implantation,
oxidegrowth
and thermal redistribution of
doping impurities
canbe simulated.
The
modelling
ofion-implantation
isperformed using
a Gaussian function for the lateral distribution while twoempirical
functions are used for the vertical ion-distribution : ajoint half-Gaussian
func-tion for
arsenic, phosphorus
andantimony
and amodified Person IV function for boron.
Concerning
the field oxide
growth,
a newanalytical
model hasbeen
developed, allowing
a verygood
simulation of the « bird’s beak » which appears in the LOCOS process. The diffusion for one or twoimpurities
isdescribed
by solving
the non-linearsystem
of dif- fusionequations.
OSIRIS uses the finite differences method with a Crank-Nicolson scheme. Thesystem
so-obtained is solvedusing
a modified Gauss-Seidel method. The redistribution ofimpurities
can besimulated in an inert or
oxidizing
ambient :the.
physical
domain of the device isalways mapped
intoa fixed-time invariant
rectangular
domainby
meansof a coordinate transformation.
Finally,
OSIRIS is used to simulate acomplete
N-Channel MOS device. The redistributed
impurity profiles
for this latterapplication
arepresented along
with thecorresponding
oxidelayer shapes
atthe end of the process.
Fig.
10. -Comparison
betweenexperimental
and simulated field oxideshapes.
Fig.
11. - Cross sectional view of an N-Channel MOS device. The parts A-E of the circuit are simulated infigure
12.484
Fig.
12. - Results of OSIRIS simulationsshowing
theequidensity
contours andcorresponding
oxideshape
at theend of the process :
a)
part A of the MOS device,b)
part B,c)
part C,d)
part D,e)
part E.References
[1] MALDONADO,
C. D., ROMANS II, a two-dimen- sional process simulator formodelling
and simu-lation in the
design
of VLSIdevices, Appl. Phys.
A 31
(1983)
119-138.[2]
TIELERT, R., Two-dimensional numerical simulation ofimpurity
redistribution in VLSI processes, IEEE Trans. ED 27(1980)
1479-1483.[3]
SALSBURG, K. A. andHANSEN,
H.H., FEDSS,
Finite-Element Diffusion-Simulation
System,
IEEE Trans. ED 30
(1983)
1004-1011.[4]
GUILLEMOT, N.,CHENEVIER,
P., DEROUX- DAUPHIN, P. andGONCHOND,
J. P., Présenta- tion et validation du programme OSIRIS de simulation bidimensionnelle des processus tech-nologiques,
RevuePhys. Appl.
19(1984)
987-995.
[5] GUILLEMOT,
N. andPANANAKAKIS, G.,
OSIRIS-Outil pour la Simulation de la Redistribution des
Impuretés
dans leSilicium,
Solid-State Electron.28
(1985)
I-III.[6] FURUKAWA,
S.,MATSUMURA,
H. andISHIWARA,
H., Theoretical considerations on lateralspread
of
implanted ions, Jpn
J.Appl. Phys.
11(1972)
134-142.
[7] GIBBONS,
J.F., JOHNSON,
W. S. andMYLROIE,
S. W.,
Projected Range Statistics, Stroudsburg,
PA
(Dowdon,
Hutchison andRoss)
1975.[8] GIBBONS,
J. F. andMYLROIE, S.,
Estimation ofimpurity profiles
inion-implanted amorphous
targetusing joined
half-Gaussiandistributions, Appl. Phys.
Lett. 22(1973)
568-569.[9]
ANTONIADIS, D. A.,HANSEN,
S. E. andDUTTON,
R. W.,
Suprem
II, aProgram for
IC ProcessModelling
andSimulation,
StanfordUniv.,
Stan- ford, CA. Tech.Rep.,
June 1978.[10] GUILLEMOT,
N., Simulation bidimensionnelle des processustechnologiques
dusilicium,
élaboration du programme OSIRIS. Thèse I.N.P.Grenoble,
1986.
[11]
RUNGE, H., Distribution ofimplanted
ions underarbitrarily shaped
maskedges, Phys.
Status Solidi(A)
39(1977)
595-599.[12] NUYTS,
W. and VANOVERSTRATEN,
R.,Computer
calculation of
impurity profiles
in silicon(I), Phys.
Status Solidi(A)
15(1973)
329-341.[13] NUYTS,
W. and VAN OVERSTRATEN, R.,Computer
calculation of
impurity profiles
in silicon(II), Phys.
Status Solidi(A)
15(1973)
445-472.[14]
FAIR, R. B. andTSAI,
J. C. C., Aquantitative
modelfor the diffusion of
phosphorus
in silicon and the emitterdip
effect, J. Electrochem. Soc. 124(1977)
1107-1117.[15]
FORSYTHE and WASOW, FiniteDifference
Methodsfor
PartialDifferential Equations (John Wiley
and Sons
inc.)
1960.[16] CRANK,
J., NICOLSON, P., Apractical
method fornumerical evolution of solutions of
partial
diffe-rential
equations
fort heat-conduction type, Proc.Cambridge
Philos. Soc. 43(1947)
50-67.[17] DEROUX,
P., Etude etoptimisation
duprocédé
LO-COS, application
aux structures MOS VLSI.Thèse USM, Grenoble 1984.
[18] MATSUMUTO,
H. andFUKUMA, M.,
Numerical mod-elling
of nonuniform Si thermaloxidation,
IEEETrans. ED 32
(1985)
132-140.[19] CHIN,
D. etal.,
Two-dimensionaloxidation,
IEEETrans. ED 30
(1983)
744-749.[20] CHIN,
D. etal.,
Ageneral
solution method for two- dimensionalnon-planar oxidation,
IEEE Trans.ED 30
(1983)
993-998.[21] GUILLEMOT,
N. andPANANAKAKIS, G., Improve-
ment of the two-dimensional process simulator
OSIRIS,
Proc.of
MIEL’85conf., Ljubljana, Yugoslavia (1985)
307-314.[22]
BASSOUS, E., Yu, H. N. andMANISCALO, V., Topology
of silicon structures with recessedSiO2,
J. Electrochem. Soc. 123(1976)
1729-1737.[23]
DEAL, B. E. andGROVE,
A.S.,
Generalrelationship
for the thermal oxidation in
silicon,
J.Appl.
Phys.
36(1965).
[24]
Wu, T.C., STACY,
W. T. andRITZ, K. N.,
The influence of the LOCOSprocessing
parameterson the
shape
of the bird’s beak structure, J.Electrochem. Soc. 130
(1983)
1563-1566.[25] SHANKOFF,
T. A. etal.,
Bird’s beakconfiguration
and elimination of gate oxide
thinning produced during selective oxidation,
J. Electrochem. Soc.127