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DIAMOND ANVIL CELL ̸≡ SHOCK WAVE GUN ?
M. Madon, J. Peyronneau, J. Poirier
To cite this version:
M. Madon, J. Peyronneau, J. Poirier. DIAMOND ANVIL CELL ̸≡ SHOCK WAVE GUN ?. Journal
de Physique Colloques, 1984, 45 (C8), pp.C8-117-C8-120. �10.1051/jphyscol:1984823�. �jpa-00224323�
JOURNAL, DE PHYSIQUE
Colloque C 8 , supplement au n ° l l , Tome t5, novembre 1984 page C8-117
DIAMOND A N V I L CELL = SHOCK WAVE GUN ?
M. Madon, J . Peyronneau and J . P . P o i r i e r
Institut de Physique du Globe, University Pierre et Marie Curie, 4, Place Jussieu, 75230 Paris Cedex OS, France
Abstract - Transmission e l e c t r o n microscope observations o f o l i v i n e
(MgjFe^SiO,, deformed i n a laser-heated diamond-anvil high pressure c e l l reveal t h a t t h i s device creates deformation c o n d i t i o n s s i m i l a r to those produced by shock waves.
The a ( o l i v i n e ) , (3 ( " m o d i f i e d " s p i n e l ) and y ( s p i n e l ) polymorphs of a composi- t i o n close to the magnesian end of (MgjFe^SiGV are e s s e n t i a l minerals of the E a r t h ' s upper mantle [ 1 , 2 ] , p e r o v s k i t e (Mg,Fe)Si0
3and magnesiowustite (Mg,Fe)0 probably being major c o n s t i t u e n t s of the lower mantle [ 3 , 4 ] . The phase t r a n s i t i o n s between these minerals are the o b j e c t o f sustained i n t e r e s t [ 5 , 6 ] and one of the most promising l i n e s o f i n v e s t i g a t i o n c o n s i s t s i n using transmission e l e c t r o n microscopy (TEM) and e l e c t r o n d i f f r a c t i o n a n a l y s i s to examine high pressure phases synthesized i n the l a b o r a t o r y [ 7 , 8 ] or r e s u l t i n g from n a t u r a l processes [ 9 , 1 0 ] .
In t h i s paper, we present the r e s u l t s of TEM observations of o l i v i n e brought to pressures between 50 and 70 GPa and temperatures between 1000 and 2000 °C i n a l a s e r - h e a t e d diamond-anvil c e l l .
1 - SAMPLES
The s t a r t i n g m a t e r i a l was n a t u r a l San Carlos o l i v i n e (Mg
0_
8 8, F e
0_
1 2) 2
s i0
1 (w i t h 0.5 % of f i n e l y powdered carbon to f a c i l i t a t e absorption of the l a s e r beam. The powdered mixture was imbedded i n the hole (250 \m diameter) o f a s t a i n l e s s s t e e l gasket (200 \im t h i c k ) and the sample was brought to pressures between 50 and 70 GPa. Pressures were measured by the s t r a i n gauge technique described by Peyronneau 4 a l . i n t h i s j o u r n a l . The samples were then r a i s e d to temperatures between approximately 1000 °C (estimated from the b r i g h t n e s s of the sample) and 2000 °C (estimated using the m e l t i n g p o i n t of o l i v i n e under pressure) by scanning across the sample a l a s e r beam focused on a 30 pm diameter s p o t . The quench products were glued on copper g r i d s and ion-beam t h i n n e d . The t h i n edges of the holes were then examined i n a P h i l i p s EM 300 e l e c t r o n microscope at 100 Kev and i n a Jeol 2000 EX at 200 Kev.
2 - TEM OBSERVATIONS
Whatever the pressure applied on the samples, only two types of t e x t u r e s are observed according to the temperature o f the experiment:
i ) The f i r s t type of t e x t u r e i s obtained at "low" temperature (T»1000 °C) and c o n s i s t s i n amorphous zones w i t h i n c r y s t a l l i n e regions o f f i n e l y sheared o l i v i n e ( F i g . 1 ) . The d i f f r a c t i o n p a t t e r n corresponding t o c r y s t a l l i n e regions i s the same a l l over the sample and shows the o l i v i n e p a t t e r n w i t h a second p a t t e r n superimposed on i t t h a t was indexed according to the s p i n e l s t r u c t u r e ( F i g . 1 - a ) . The o r i e n t a t i o n r e l a t i o n s h i p Jjetween the two p a t t e r n s - ( 1 0 0 ) o l p a r a l l e l to (111)sp and 0 0 l ] o l p a r a l l e l t o [ l 1 0 ] s p ( F i g . 1 - b ) - i s compatible w i t h a model r e c e n t l y proposed [10,11 ] of an o l i v i n e - s p i n e l shear t r a n s i t i o n e f f e c t e d by the motion o f p a r t i a l d i s l o c a t i o n s
Résiné - L ' o b s e r v a t i o n en microscopie é l e c t r o n i q u e par transmission d ' o l i v i n e (Mg jFe^SiO,, déformée dans une c e l l u l e à enclumes de diamant chauffée par l a s e r montre que cet a p p a r e i l l a g e crée des c o n d i t i o n s de déformation semblables à c e l l e s p r o d u i t e s par des ondes de choc.
Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyscol:1984823
C8-118 JOURNAL DE PHYSIQUE
F i g . 1.-a) D i f f r a c t i o n p a t t e r n o f c r y s t a l l i n e r e g i o n s showing t h e p r e s e n c e o f t w o s t r u c t u r e s
:o l i v i n e and s p i n e l . -b) O r i e n t a t i o n r e l a t i o n s h i p between t h e two s t r u c - t u r e s . - c ) and -d) TEM images showing g l a s s y z o n e s ( g ) between c r y s t a l l i n e r e g i o n s . on t h e c l o s e packed p l a n e s o f two s t r u c t u r e s . The o r i e n t a t i o n r e l a t i o n s h i p between t h e two p h a s e s is n o t v i s i b l e on TEM images ( F i g . 1 - c and d ) but we c a n s u p p o s e t h a t t h e two p h a s e s a r e v e r y f i n e l y i n t e r c a l a t e d and produce t h i s s h e a r e d s t r u c t u r e . The amorphous z o n e s a r e s e e n between c r y s t a l l i n e r e g i o n s a s p a t c h e s w i t h b l u r r e d
o u t l i n e s ( F i g . 1 - c ) o r f i n e l a n e l l a e a l o n g c r y s t a l l o g r a p h i c p l a n e s o f t h e h o s t c r y s t a l (Fig.1-d) .
T h e
s a n e t e x t u r e of amorphous z o n e s w i t h i n c r y s t a l l i n e r e g i o n s o f f i n e l y s h e a r e d o l i v i n e ( F i g . 1 - c ) h a s been o b s e r v e d i n o l i v i n e deformed by s h o c k waves a t 56 GPa [12]. I f
weu s e t h e c a l c u l a t i o n o f shock t e m p e r a t u r e s measured i n s h o c k e d s i n g l e - c r y s t a l Mg2Si04 [ 1 3 ] , we o b t a i n a t e m p e r a t u r e o f 1000
O Ca t 56 GPa, a s i n o u r e x p e r i m e n t s .
i i ) The second t y p e o f t e x t u r e is o b t a i n e d a t h i g h t e m p e r a t u r e (T=2000 OC) a f t e r o l i v i n e b r e a k s down t o
ana s s e m b l a g e o f ( 4 , F e ) O p l u s (Mg,Fe)5i03 g l a s s ( F i g . 2 ) . The e l e c t r o n d i f f r a c t i o n p a t t e r n s a l l o w t h e i d e n t i f i c a t i o n o f c r y s t a l l i n e p h a s e r n a g n e s i o w i j s t i t e (Mg,Fe)O and show t h e p r e s e n c e o f a n o r p h o u s z o n e s ( h a l o i n d i f f r a c t i o n p a t t e r n s ) e x p e c t e d t o be (Wj,Fe)SiO, g l a s s ( F i g . 2 - a ) . TEM images show - t h e h e t e r o g e n e o u s t e x t u r e of c r y s t a l s and g l a s s : t h e (Mg,Fe)O c r y s t a l s a r e e l o n g a t e d (Fig.2-b) o r more o r less m i c r o c r y s t a l l i n e (Fig.2-c and d) w h e r e a s g l a s s y z o n e s a p p e a r a s s n o o t h a r e a s ( F i g . 2 - b ) o r p o l y g o n a l " g r a i n s 1 ' ( F i g . 2 - d ) . In s i t u X-ray m i c r o a n a l y s i s c o n f i r m s t h a t g l a s s h a s t h e c a n p o s i t i o n (Mg;Fe)Si03 and t h a t i r o n
d i s p r o p o r t i o n a t e s between
(Ng ,Fe)Oand (Mg , F e ) S i Q 3 , g o i n g p r e f e r e n t i a l l y t o m a g n e s i o w i i s t i t e :
T h i s s t r o n g Fe-% a r t i t i o n i n g between t h e two p h a s e s h a s a l r e a d y been o b s e r v e d by
X-ray d i f f r a c t i o n
{ 1 4 ] .Fig. 2.-a) E l e c t r o n d i f f r a c t i o n p a t t e r n o f m a g n e s i o w u s t i t e . - b ) , - c ) and -d) TEM images showing d i f f e r e n t t e x t u r e s o f c r y s t a l s
(Mq,Fe)O a d g l a s s (Mg , F e ) S i 0 3 .
The t e x t u r e c o n s i s t i n g of ( b , F e ) O c r y s t a l s and ( b , F e ) S i 0 3 g l a s s h a s a l s o b e e n o b s e r v e d i n o l i v i n e deformed by shock waves between 78 and 92 GPa [ 1 5 ] . For t h e s e p r e s s u r e s , t h e c a l c u l a t i o n [ 1 3 ] g i v e s a t e m p e r a t u r e between
1800a d 2200
O Cc o m p a t i b l e w i t h o u r e x p e r i m e n t a l c o n d i t i o n s .
3-
DISCUSSIONThe e x p e r i m e n t a l o b s e r v a t i o n s r a i s e s e v e r a l problems t h a t
wew i l l now d i s c u s s . i ) I n "low" t e m p e r a t u r e e x p e r i m e n t s between 50 and 70 GPa, i . e . i n t h e s t a b i l i t y f i e l d o f p e r o v s k i t e and r n a g n e s i o w i i s t i t e , we o b s e r v e t h e l e s s s t a b l e y - s p i n e l . Now, o l i v i n e can t r a n s f o r m t o y - s p i n e l by a s h e a r o f t h e oxygen s u b l a t t i c e and a s h u f f l i n g o f t h e c a t i o n s [ l l ] , a mechanism t h a t d o e s n o t demand h i g h t e m p e r a t u r e s and can b e h e l p e d by s h e a r s t r e s s e s ; t h e t r a n s f o r m a t i o n o f y - s p i n e l t o p e r o v s k i t e and m a g n e s i o w i i s t i t e , on t h e o t h e r hand, p r e s u n a b l y i n v o l v e s d i f f u s i o n , h e n c e c a n o t t a k e p l a c e i f t h e t e m p e r a t u r e is n o t h i g h enough. A t h i g h p r e s s u r e s and low t e m p e r a t u r e s , o l i v i n e might t h e r e f o r e t r a n s f o r m i n t o y - s p i n e l , a more s t a b l e , a l t h o u g h n o t t h e most s t a b l e p h a s e , b e c a u s e t h e e n e r g y b a r r i e r is much lower t h a n f o r t r a n s f o r m i n g t o p e r o v s k i t e and m a g n e s i o w u s t i t e . I n o u r e x p e r i m e n t s , as well a s i n shock waves e x p e r i m e n t s [ 1 2 ] , g l a s s was l o c a l l y o b s e r v e d . T h e r e is a p o s s i b i l i t y t h a t h i g h l y deformed o l i v l n e m i g h t l o c a l l y t r a n s f o r m t o g l a s s , p e r h a p s b e c a u s e a v e r y h i g h d i s l o c a t i o n d e n s i t y makes t h e t r a n s f o r m a t i o n t o g l a s s k i n e t i c a l l y e a s i e r t h m t h e t r a n s f o r m a t i o n t o s p i n e l .
i i ) I n "high" t e m p e r a t u r e e x p e r i m e n t s , i r o n - r i c h m a g n e s i o w u s t i t e is found a s
e x p e c t e d but t h e (Mg,Fe)Si03 p h a s e is a g l a s s i n s t e a d o f t h e e x p e c t e d c r y s t a l s with
p e r o v s k i t e s t r u c t u r e . The swe o c c u r r e n c e h a s been o b s e r v e d i n s w p l e s r e c o v e r e d
from shock wave e x p e r i m e n t s [ 1 5 ] b u t a l s o i n s t a t i c e x p e r i m e n t s on CaSi03 [ 1 6 , 1 7 ]
where a p e r o v s k i t e - s t r u c t u r e p h a s e h a s been i d e n t i f i e d i n - s i t u a t h i g h p r e s s u r e ,
a l t h o u g h t h e r e c o v e r e d s a m p l e s were g l a s s y , presumably d u e t o a r e t r o g r e s s i v e
C8-120
J O U R N A L
DEPHYSIQUE
t r a n s f o r m a t i o n d u r i n g the r e l e a s e o f pressure. We have n o t been a b l e so f a r t o a s c e r t a i n whether t h e (Mg ,Fe)SiOg phase i n our experiments i s c r y s t a l l i n e under h i g h pressure, nor i s i t o b v i o u s l y p o s s i b l e t o know whether i t i s t h e case f o r recovered shock sanples. Two h y p o t h e s i s may t h e r e f o r e be considered ( b o t h f o r t h e dianond a n v i l and the shock wave experiments):
-a) The o l i v i n e i s f i r s t taken t o h i g h pres- sures, w e l l i n t o the s t a b i l i t y f i e l d o f perov- s k i t e , b e f o r e being heated. There i s t h e r e f o r e 1bbq1-
a c o n s i d e r a b l e anount o f energy s t o r e d i n the
-
h,so.system, o f t h e o r d e r o f
l o 5
J/
mole (Fig.3). T.~SOO'<When t h e l a s e r bean h i t s the sample ( o r &en
-
t h e temperature wave h e a t s
i t
i n shock e x p e r i - ment) ,the temperature makes t h e t r a n s f o r m a t i o n ..p o s s i b l e and t h e energy i s suddenly released, much i n the way chemical energy i s r e l e a s e d by
--
t h e e x p l o s i o n o f a s t i c k o f dynanite.The c r y s - t a l l i n e l a t t i c e c o u l d be so much d i s o r g a n i z e d .-
t h a t a d i a p l e c t i c g l a s s c o u l d be formed.
T h i s scenario may perhaps be envisaged .- i n cases where the s y s t e n i s brought very f a r from the Clapeyron a t l o w temperature.
-b) I t may, however, be s i m p l e r t o consider Fig.3.- Free energy d r i v i n g t h e t h a t the h i g h pressure phase was c r y s t a l l i n e , t r a n s f o r m a t i o n o f o l i v i n e i n t o as i t has been shorn t o be t h e case i n a few i t s h i g h pressures phases versus i n s t a n c e s [ 1 4 , 1 6 ] . The pressure r e l e a s e usual- pressure ( a f t e r d a t a o f [18,191) l y t a k i n g p l a c e a t low temperatures, t h e h i g h
pressure phase can be conserved and the d r i v i n g f o r c e f o r t r a n s f o r m a t i o n t o the l o w pressure phase b u i l d s up and e v e n t u a l l y reaches such a h i g h v a l u e t h a t the t r a n s f o r m a t i o n takes p l a c e i n a v i o l e n t manner; i f t h e t r a n s f o r m a t i o n i n v o l v e s d i f f u s i o n , i t i s conceivable t h a t t h e system f i n d s
i t
e a s i e r t o d i s o r g a n i z e c o m p l e t e l y i n t o a g l a s s a t temperatures t o o low t o a l l o w the o r d e r l y t r a n s f o r m a t i o n t o t h e l o w pressure c r y s t a l l i n e phase.Whatever the a c t u a l mechanism f o r the f o r m a t i o n o f g l a s s , t h e r e i s a s t r i k i n g s i m i l a r i t y between the TEM m i c r o s t r u c t u r e s o f s w p l e s o f o l i v i n e recovered frun h i g h p r e s s u r e r u n s i n dianond a n v i l c e l l s and from shock experiments [12,15]. This suggests t h a t t h e d i a n o d a n v i l c e l l p r o v i d e s experimental c o n d i t i o n s t h a t , d e s p i t e appearances, a r e much c l o s e r t o the c o n d i t i o n s obtained i n shock experiments and i n shocked m e t e o r i t e s
[ l o ]
than t o s t a t i c c o n d i t i o n s .I.P.G. c o n t r i b u t i o n N '774
REFERENCES
:I-
2- - 3 .4 - 5 - :6' 7.
' 8 - -9:
ANDERSON D.L., h n u . Rev. E a r t h Planet. Sci.
2
(1977) 179.BASSETT
W.A.,
Annu. Rev. E a r t h Planet. Sci.1_
(1979) 357.I T 0 E. and YAMADA H., Adv. E a r t h Planet Sci. (1982) 405.
LEES A., BUKOWINSKI
A.
and JEANLOZ R., J. Geophys. Res. 88 (1983) 8145.SCHUBERT G. and TURCOTTE D.L., J. Geophys. Res. 76 (1971F1424.
SUNG C.M. and BURNS R.G., Tectonophysics 31 ( 1 9 7 n 1.
LACAM A., MADON M. and POIRIER J.P., Mature 288 (1980) 155.
I T 0 E., TAKAHASHI E. and MATSUI Y., E a r t h p l a n e t . Sci. L e t t . 67 (1984) 238.
PRICE G.D., PUTNIS A. and SMITH D.G.W., Nature
-
296 (1982) 729, - 1 0 MADON M. and POIRIER J.P., Phys. E a r t h Planet. I n t . 33 (1983) 31.111 POIRIER J.P., " P a e l a s t i c i t y i n the Earth", G o d y n a n i T S r i e s 4 (1 981 ) 11 3.
121 JEANLOZ R., AHRENS T. J., LALLY J.S., NORD G.L., CHRISTIE
J.K
and HEUER A.H., Science 197 (1 977) 457.131 AHRENS T r , Science 207 (1980) 1035.
141 MA0 H.K., BELL P.M. axYAGI
T.,
Adv. E a r t h Planet. Sci. 12 (1982) 319.151 SYOM
Y.,
GOT0 T., TAKE1 H., TOKONAMI M. and NOBUGAIKT
Science214
(1981)R. and THOMPSON A.B., Rev. G o z . Space Phys.