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Spatial correlations and temporal heterogeneity of the
slow dynamics of a colloidal fractal gel.
Agnes Duri, Luca Cipelletti
To cite this version:
Agnes Duri, Luca Cipelletti. Spatial correlations and temporal heterogeneity of the slow dynamics of a colloidal fractal gel.. HERCULES (Higher European Research Course for Users of Large Experimental Systems) European School, Feb 2007, Grenoble / Saclay, France. �hal-02923795�
Time (N° 1) and Space (N° 2) Resolved Degree of Correlation :
“Multispeckle” Light Scattering experiments (Single Scattering)
• N°1 Far field – Several q ( 4337 cm-1 < q < 52177 cm-1) – Time Resolved Dynamics – V⇔ All the scattering volume
⇔ All the speckled image
• N°2 Imaging geometry – Single q (q = 104cm-1) – Time and Space Resolved Dynamics – V⇔ Portion of the
scattering volume ⇔ Portion of the speckled image
2 . 4 x 1 05 2 .8 x 1 05 3 .2 x 1 05 3 .6 x 1 05 4 .0 x 1 05 0 . 0 0 . 2 0 . 4 0 . 6 cI ( t , τ ) t ( s e c ) τ = 1 0 s e c τ = 1 0 0 s e c τ = 1 0 0 0 s e c τ = 5 0 0 0 s e c τ = 1 0 0 0 0 s e c τ = 2 0 0 0 0 s e c τ = 4 0 0 0 0 s e c τ = 6 0 0 0 0 s e c τ = 8 0 0 0 0 s e c
Agnès Duri
1,2and Luca Cipelletti
11 Laboratoire des Colloïdes, Verres et Nanomatériaux (LCVN), UMR n°5587, Université Montpellier II, 34095 Montpellier, France 2 Desy – Hasylab, 22607 Hamburg, Germany
time t
References :
Ip(t): intensity p-th pixel at time t
Spatial Correlations and Temporal Heterogeneity
Spatial Correlations and Temporal Heterogeneity
of the Slow Dynamics of a Colloidal fractal gel
of the Slow Dynamics of a Colloidal fractal gel
lag τ
( )
( ) ( )( )
( ) 1 ) , - τ t I (t) I τ t (t) I I r (t,τ c r V p p r V p p r V p p p I r r r r ∈ ∈ ∈ + + =[1] L. Cipelletti, H. Manley, R.C. Ball, D. Weitz, J. Phys. Rev. Lett., 2000, 84, 10
[2] L. Cipelletti, H. Bissig, Trappe V, P. Ballesta, S. Mazoyer, J. Phys.: Condens. Matt., 2003, 15, S257- S262 [3] A. Duri and L. Cipelletti, Europhys. Lett., 2006 , 76 , 972-978
Average Dynamics :
Spatially Resolved Intensity Correlation Function (N°1): Spatial Correlation of the Dynamics (N° 2):
( )
τ,r - c (t,τr)t g2 r 1= I ,rExperimental
Experimental
System
System
Polystyrene colloids (d = 20 nm ) suspended in a buoyancy-matching H2O/D2O (45/55 vol/vol) ⇔ φPS= 6 10-4
+ MgCl2⇔ CMgCl2=10 mM
⇒
Fractal gelExperimental
Experimental
Set Up
Set Up
101 102 103 104 105 -0.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 g2 ( q , τ ) - 1 τ (sec) q=7355 cm-1 q=9538 cm-1 q=12393 cm-1 q=16004 cm-1 q=20656 cm-1 q=26506cm-1 q=37771 cm-1 q=42396 cm-1 q=52177 cm-1
Fit by a “compressed” exponential
g2(q,τ)-1 ∝ exp[-(τ/ τf) 3/2] 104 103 104 slope= - 0.98 τf (s ec ) q (cm-1 ) τf∝ q-1⇒ Drift motion τ f t⇒ Aging behaviour
Time Resolved Dynamics – Fluctuations Study:
2 .5 x1 05 3 .0 x1 05 1 03 1 04 τf (s ec ) t (s e c) 1 04 1 05 1 06 1 01 1 02 1 03 1 04 1 05 τf (s ec ) t ( s e c ) Large fluctuations ofτf Heterogeneous dynamics⇓ 102 104 1E-5 1E-4 1E-3 0.01 τf σ2 cImax τmax σ 2 c I (τ ) τ (sec) q=20656 cm-1 ⇔ 3 μm 0 .0 5 .0 x1 03 1 .0 x1 04 1 .5 x104 2 .0 x1 04 0 .0 5 .0x1 03 1 .0x1 04 s lop e = 0 .8 τ ma x (s e c ) τf (sec) 0 .0 2 .0 x 1 04 4 .0 x 1 04 6 .0 x 1 04 0 .0 0 0 .0 5 0 .1 0 0 .1 5 σ 2 cmaI x q (c m- 1 ) s lo p e = 1 .1 σ2 c Imax ∝ q 4337 cm-1 < q < 52177 cm-1 τmax∝ τf Statistics treatment
Time and Space Resolved Dynamics – Local dynamics Study:
τ
<
τ
f:
Very long-ranged correlation
⇒ « solid-like » behavior
0 1 2 3 4 5 6 7 0 .0 0 .2 0 .4 0 .6 0 .8 1 .0 Xc I Δr (m m ) τ = 500 sec τ = 2500 sec τ = 5000 sec τ = 10000 sec τf = 1000 secExperimental
Experimental
Results
Results
[
] [
]
r c c t t I I t I I r r t r t r r t c r r t c r t c r t c I I r r r r r r r r r r ) , , ( ) , , ( ) , , ( ) , , ( ) , , ( ) , , ( 2 2 +Δ Δ + − Δ + − τ σ τ σ τ τ τ τ Speckled Images Δr( )
= ΧcIτ ,rrτ
>
τ
f:
Spatial correlation decay
⇒ « fluid-like » behavior
⇓
Fluctuations max at large length scale
et N Laboratoiredes Colloïdes Verres anomatériaux