Systèmes moléculaires photocatalytiques pour la réduction des protons en hydrogène en milieux aqueux, associant des catalyseurs de rhodium et de cobalt à des photosensibilisateurs de ruthénium

(1)

HAL Id: tel-00849094

https://tel.archives-ouvertes.fr/tel-00849094

Submitted on 30 Jul 2013

HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.

L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

Systèmes moléculaires photocatalytiques pour la réduction des protons en hydrogène en milieux aqueux, associant des catalyseurs de rhodium et de cobalt à des

photosensibilisateurs de ruthénium

Thibaut Stoll

To cite this version:

Thibaut Stoll. Systèmes moléculaires photocatalytiques pour la réduction des protons en hydrogène en milieux aqueux, associant des catalyseurs de rhodium et de cobalt à des photosensibilisateurs de ruthénium. Sciences agricoles. Université de Grenoble, 2012. Français. �NNT : 2012GRENV043�.

�tel-00849094�

(2)

1

1234567389ABC75DEAFC6356AA1234567389A35665A527AF625AAA 1234567389A852EAA1234567389A5A4C35AA652C5AAA

123456

1234526789A45B85C4DE85E85

78915AB6756CDAEF5B4F16756B5E8C56

FADBA75596F66 6

4475A9A74A8B555D2755

5 5 5

1489785D45

61 66418CC66

6 6

85EA4AC85D4555!"E#$$69$$ 66 6

4D485D358A95E357%&6'696!$%($6)79!*555 ED95$+($67($6(66,((,6'6--6

5 4.,/,6$%($,6

&($.,06&6$6%'(6 ',6&,66.'/66$16 106,,(6',6($.,,6'6 '66'6( $626',6

&,, $,,6'6%6

6

5

852378938536BA 388975B866346- 63563!6 E8"D975B85#34$5225E8555

!7668FCCF9!46

142%8834!5&9A"84A7$5'34D!54D2478345

!76:%'%(6C89A5E6

'A4878345E85488485()*F!5&9A"84A75E85+487DC985,-!54D2478345

!76: (68785C6

'A4878345E85488485()*F!5&9A"84A75E85)D9785

!6!"E#$$698CC8!6

'A4878345E85488485()*F!5&9A"84A75E85.48926B85/!586485

!769$675B8E;F5B6

'A4878345E85488485()*F!5&9A"84A75E85.48926B85/!586485

!76<%=6:8B1956

(D4C5E85488485()*F!5&9A"84A75E85.48926B85/!58648

(3)

1

5 5

(4)

12 2

1233456788

1 1

234567894A631BC3C5DEF 1 1 1 1 1 1 1 1 1 1111

1 1 1 1 1 1

DA45F1114F16EC98EDA5F16469D4DE4A8F16851ED15C7894A6317F1 564631F317A756B3F16C5D341F31AEAF8185FF341D8F81DFE1

AEA6B5DA8F 1 1 1 1 1 1 1 1 1 1 1111

21 1 C3C5DEA4C 1 1 1 1 1 1 1 1 1 1 111!1

221 1"C9D3AF1#637DF34D817F1ED15C7894A6316469D4DE4A8F17F1564631D511 1 7F196EFF17F1C4D817F145D3A4A63 1 1 1 1 1 1 111$1 22211 4F16469D4DE4A8F166B3F16851ED15C7894A6317F156463 1 1 11 2%11 4F16469D4DE4A8F166B3F16851ED15C7894A6317F1564631F31AEAF811

1 85FF341D8F8 1 1 1 1 1 1 1 1 1 1&1

1 2%1 4F184AEAD3418319D4DEF8517F1567A8'17(A5A7A816817F1DEED7A81 1 1)1

1 1

2%D1 4F169A*6BA*+,-.1681-+/.

1 1 1 1 1 101

1 1

2%1 4F169A*96EFF1A389ECDA5F17F1567A8*"%¹²*+,-.

1 1 1!1

1 1

2%91 4F169A*CDA*.3⁴*31.

1 1 1 1 1 1 151

1 1

2%91 4F169A*6BE*.3⁴*31.

1 1 1 1 1 1 1$1

1 1

2%F1 4F169A*6BF*.3⁴*31.1F418*825*.3⁴*31.

1 1 1 1 1161

1 1

2%#1 4F1696B69*-+/.

11 1 1 1 1 1 1161

1 2%11 4F184AEAD3418319D4DEF8517F1ED4A3F1 1 1 1 1 111

1 1

2%1D1 .94A7A4C17F1A389ECDA5F17F1ED4A3F1816341DA7D4F'175661F415D96ED4F

1 11&

11 1 1 2%11 .94A7A4C17F196EFF1636389ECDA5F17F1ED4A3F

1 1 1 1 11)1

1 1 2%191 .94A7A4C17F196EFF17F1ED4A3F184A48C1D517F183A4C11

1 1 1 D99F45A9F17(CEF94563

1 1 1 1 1 1 1 1101

1 1 2%171 .94A7A4C17F196EFF1584C3A84ED4A3F

1 1 1 1 1 1151

1 2%&1 4F184AEAD3418319D4DEF85181DF17F196DE41 1 1 1 11$1

(5)

112 2

1 1

2%&D1 4F169A*A*+8:22;1F4169A*A*.3⁴*31.

1 1 1 1 1&11

1 1 2%&1 4F169AA*6:22;12A*.3⁴*31.

1 1 1 1 1 1&&1

1 1 2%&91 4F16A*A*-+/.1F416A**.3⁴*31.

1 1 1 1&&1

1 1 2%&71 4F1AA*-+/.

1 1 1 1 1 1 1 1&)1

1 1 2%&F1 4F169A*A*31.

1 1 1 1 1 1 1 1&1

1 1 2%&#1 4F17*A*-+/.

1 1 1 1 1 1 1&01

2%)1 4F184AEAD3418319D4DEF85181DF17F1#F516817F13A9<FE1 1 1 1 1&01 1 1

2%)D1 4F169A*A*=D3.1F417**-+.

1 1 1 1 1&!1 1 1

2%)1 4F17*A*-+/.1F417**-+/.

1 1 1 1 1&51

C#C5F39F1AEA6B5DA8F 1 1 1 1 1 1 1 1 1 1&$1

1 DA45F1111>565AC4C1CEF94569AA8F1F4184AEAD4A631F316469D4DEF111111111111111 7F15C7894A6317F1564631F316E7D34165BD3A8F17F196EFF11111111

6E5A7A3A8F17F1567A81F417F196DE41F31D69AD4A631D7F91831

646F3AAEAD4F8517F1584F3A8 1 1 1 1 1 1 1 1)1

21 234567894A63 1 1 1 1 1 1 1 1 1 1 1)&1

2211 DFE17F1565AC4C1CEF94569AA8F1F316E7D34165BD3A8F17F196EFF1111111111111111111111 1 6E5A7A3A8F17F1567A81F417F196DE4 1 1 1 1 1 1 1)1 22211 +76E84A6317F1E(CEF9456D94A7A4C17F196EFF1F315CF39F17(D9A7F1 1 1 11111 1 7D313

_&

=1F41EF1,"? 1 1 1 1 1 1 1 1 161

1 2221 "AF1F31C7A7F39F17F1A34F5C7ADA5F17585F1 1 1 1 1 161

1 22211 CD94A7A4C1F315CF39F17(831F917(D9A7F1 1 1 1 1 1&1

1 222&1 +##F417F16E7D34113

&

=171,"?1 1 1 1 1 1 11 2%1 >6469D4DEF17F15C7894A6317F1564631F316E7D34165BD3A8F 1 1 1 101 1 2%1 6D5DA6317F1E(D94A7A4C19D4DE4A8F17F17A##C5F3419D4DEF85111 1

1 1 D69AC181 C1A 1F41-+/.1 1 1 1 1 1 1 101

1 2%11 @4AEAD4A6317F17A##C5F341D9A7F165BD3A8F196F16859F17F1564631 1 1061

%1 "C9D3AF1566C168519F14F16469D4DE4A8F 11 1 1 101

%21 639E8A63 1 1 1 1 1 1 1 1 1 1 10)1

C#C5F39F1AEA6B5DA8F 1 1 1 1 1 1 1 1 1 101

(6)

1112 2

1 DA45F1&11C7894A6316469D4DE4A8F17F1564631F316E7D3411 111111 85FF341D8F8181E(DA7F17F196EFF17F1567A81D69AC1817F1

646F3AAEAD4F8517F1584C3A816817(A5A7A8 1 1 1 1 1 10!1

21 234567894A63 1 1 1 1 1 1 1 1 1 1 10$1

221 /4AAD4A631781316851ED1567894A6317(756B3F1D7F91EF196EFF1

1 A:7;

1

E

1

B

²

1D69AC181 C1A 1F41=D.3*3

1

. 1 1 1 1 1 1!11 2221 6D5DA6317F1E(F##A9D9A4C17814F16469D4DE4A8F1

1 C1A *A:7;

1

E

1

B

²

=D3.3

1

.1D7F917F14F1AAEDA5F1111

1 84AEAD3417(D845F19D4DEF8517F1567A8 1 1 1 1 1 1 1!)1 2%1 +487F17F1EAA4F17F1F5#65D39F17814F11

1 C1A *A:7;

1

E

1

B

²

=D3.3

1

. 1 1 1 1 1 1 1 1!!1

%1 +487F17F1569F817F17C966A4A6317814F11

1 C1A *A:7;

1

E

1

B

²

=D3.3

1

. 1 1 1 1 1 1 1 1!$1

%21 .94A7A4C16469D4DE4A8F17814F1 1 1 1 1 1 A:7;

₁

E

₁

B

²

=D.33

₁

.1F315CF39F17F17A##C5F3411 1

1 646F3AAEAD4F8517F1584C3A81F417(A5A7A8 1 1 1 1 1 151

%221 .F941C9D3A4A8F17814F1 C1A *A:7;

1

E

1

B

²

=D3.3

1

. 1 1 151 1 %2211 DE98E17F1E(F34DEAF1EA5F17F145D3#F5417(CEF945631646A378A417814F111

1 1 C1A *A:7;

1

E

1

B

²

=D3.3

1

.1 1 1 1 1 1 151

1 %22111 1+487F17F1E(F4A394A6317F1ED1E8A3F9F39F17F1 C1A C1D51A:7;

1

E

1

B

²

1 15!1 1 %22&11 +C5AF39F17F1F945696AF17(D654A63145D3A46A5F181E(C9FEEF17F14F11

1 1 7F1ED13D36F9637F1 1 1 1 1 1 1 1 1551

1 %22)1 "C9D3AF1566C16851ED1567894A6317F13

1

1 1 1 1 11 1$61

%2221 639E8A63 1 1 1 1 1 1 1 1 1 1 1$11

C#C5F39F1AEA6B5DA8F 1 1 1 1 1 1 1 1 1 1$)1

1 DA45F1)1134F'1565AC4C1CEF94569AA8F1F416469D4DE4A8F17F1 96EFF16E389ECDA5F1D69AD341D51EADA631967DEF34F18319D4DEF8517F1 567A8181831646F3AAEAD4F8517F1584C3A8 1 1 1 1 1 1$!1

21 234567894A63 1 1 1 1 1 1 1 1 1 1 1$$1

221 34F17F196EFF16E389ECDA5F 1 1 1 1 1 1 611

(7)

132 2

1 221 34F1781EABD371D11F4178196EFF1A8:;

1

:D1;B:>?

0

;

1

1 1 1 611

1 2211 34F178196EFF145A389ECDA5F11 1 1 1 1 1

1 11 AE8:;

1

:D1;F

1

E

1

B:>?

0

;

1: C1AAC1A ;1 1 1 1 1 611 1 22&1 34F178196EFF1A389ECDA5F1A8:;

1

:D1;:7;E

1

B:>?

0

;

&

1: C1AA ;11 1 1 F4178196EFF15C985F851A:7;:3

&

=;E

&

1 1 1 1 6&1 1 1

22&D1 34F178196EFF1A:7;:3&=;E&B

1 1 1 1 6&

1 1 1 22&1 34F178196EFF1A8:;1:D1;:7;E1B:>?0;&1:C1AA;

1 1 6)1 1 22)1 34F178196EFF1A389ECDA5F1A8:;

1

:D1;CEB:>?

0

;

&

1: C1A ;1 6)1 2221 D5D94C5AD4A631CEF94569AA8F1F41F945696A8F11 1 1 1

1 7F196EFF16E389ECDA5F 1 1 1 1 1 1 1 61

1 2221 >565AC4C1CEF94569AA8F178196EFF1 C1AA 1 1 1 1 1 601

1 22211 >565AC4C1CEF94569AA8F178196EFF1 C1AAC1A 1 1 1 1 651 1 222&1 >565AC4C1CEF94569AA8F178196EFF1 C1A 1 1 1 1 61

1 222)1 D5D94C5AD4A631D51F945696AF17(D654A631@%47AAEF1 1 1 1

2%1 .94A7A4C16469D4DE4A8F17F196EFF16E389ECDA5F1F31AEAF81D8F8 11 11

1 2%1 D178196EFF1 C1AAC1A 1 1 1 1 1 1 1 &1

1 2%11 D178196EFF1 C1AA 11 1 1 1 1 1 1 !1

1 2%&1 D178196EFF1 C1A 1 1 1 1 1 1 1 $1

1 2%)1 6D5DA6317F16469D4DEF85134C4AC1D7F91EF196EFF145A389ECDA5F11 1 1 AE:;

1

8:7;F

1

E

1

B

²

1181EABD371634D341963G8B8C11 1 1 161

1 2%1 "67A#A9D4A6317F1ED16859F17F164631 1 1 1 1 1 11

%1 +487F1781C9D3AF17F1567894A6317F13116851EF14F16E389ECDA5F11

1 C1AA 1F41 C1AAC1A 17AD17F1F85F1646A8F 1 1 1 1 1&1 1 %1 F945696AF17(D654A63145D3A46A5F181E(C9FEEF17F1ED13D36F9637F1 1 1)1 1 %11 F945696AF17(CAA631F41F85F17F14F17F17AF17(C4D41F9A4C1 1 101

%21 639E8A63 1 1 1 1 1 1 1 1 1 1 1$1

C#C5F39F1AEA6B5DA8F 1 1 1 1 1 1 1 1 1 &61

1

(8)

32 2

DA45F111>567894A6319D4DE4A8F1F416464A378A4F17(756B3F1F31 1 1 6E7D34185FF341D8F8'1F31D69AD341831646F3AAEAD4F8517F11 11

584C3A81F418319D4DEF8514C45DD9D4D95699EA8F17F196DE4 1 1 1 &1 21 234567894A63 1 1 1 1 1 1 1 1 1 1 &&1 221 34F1F419D5D94C5AD4A63178196EFF1A6:;E

₁

B:E/

₎

; 1 1 1 &1

1 221 34F1 1 1 1 1 1 1 1 1 &1

1 2211 >565AC4C1CEF94569AA8F17F1A6:;E

1

B

²

1F419D5D94C5AD4A6317F1#65F1

1 1 15C78A4F16

²²

1F416

²

1 1 1 1 1 1 1 1 &1

1 1

221D1 +487F1CEF94569AA8F17D313&=

1 1 1 1 1 &1

1 1 2211 DFE17F1565AC4C15C76178196EFF1A6²²²:;E1B²17D31E(FD8

1 1 &!1

2221 >6469D4DEF 1 1 1 1 1 1 1 1 1 1 &51

1 2221 /4AAD4A6317F19637A4A6317F1317F1ED16E84A631D8F8F1 1 1 &$1 1 22211 D(D94A7A4C19D4DE4A8F17814F16EC98EDA5F1 C1A *A6:;E

1

B

²

*3.

⁴

*3

1

.111111111)61 1 222&1 +##F417F1ED17D5AD4A6317F19639F345D4A631781>1F41781D411 1 1 1

1 1 851E(D94A7A4C16469D4DE4A8F1 1 1 1 1 1 1 )1

1 222)1 6D5DA6317F1E(F##A9D9A4C17814F1 C1A *A6:;E

1

B

²

*3.

⁴

*3

1

.1D7F917F11 1 1 4F1AAEDA5F184AEAD3417(D845F19D4DEF8517F196DE416817F1567A81 )&1 2%1 .F941C9D3A4A8F17F1ED1567894A6317(756B3F 1 1 1 1 )01 1 2%1 ,C4F5A3D4A6317F1F34DEAF1EA5F17F145D3#F5417(CEF9456316C5D341 1

1 1 17D31EF14F16469D4DE4A8F1 1 1 1 1 1 )01

1 2%11 ,C4F5A3D4A6317F19A3C4A8F17F1ACBFDBF17F1E(C4D41F9A4C1>C11 1

1 1 D517F145D9C17F114F534%6EF511 1 1 1 1 1 )!1

1 2%&1 +487F1781C9D3AF17F1567894A6317F13

1

17AD17F1F85F1 1 1

1 1 17(D654A63145D3A46A5F11 1 1 1 1 1 1 )51

1 2%)1 "C9D3AF1566C16851ED1567894A6317F13

1

1 1 1 1 1 61

%1 639E8A63 1 1 1 1 1 1 1 1 1 1 11

C#C5F39F1AEA6B5DA8F 1 1 1 1 1 1 1 1 1 )1

1 639E8A631 C3C5DEF 1 1 1 1 1 1 1 1 1 !1

1

(9)

312 2

+F5AF34DE1F94A63 1 1 1 1 1 1 1 1 1 01

21 "D4F5ADE1D3717F7A9F 11 1 1 1 1 1 1 1 0&1

1 21 "D4F5ADE1 1 1 1 1 1 1 1 1 0&11

1 211 ,F7A9F1 1 1 1 1 1 1 1 1 0&11

1 1

21D1 +EFF34DE1D3DEF

1 1 1 1 1 1 1 0&1

1 1 211 "D1F945696

1 1 1 1 1 1 1 0&1

1 1 2191 @%47AAEF1D654A631F945696

1 1 1 1 1 0&1

1 1 2171 +EF94569FA45

11 1 1 1 1 1 1 0&1

1 1 21F1 D1956D46B5D1 1 1 1 1 1 1 0)1

221 3756BF31567894A631 1 1 1 1 1 1 1 1 0)1

1 221 F3F5DE1569F785F1#651646BF3F5D4A6316#1756BF31 1 1 1 0)1

1 2211 "F598516A63A3B1 1 1 1 1 1 1 1 01

1 22&1 DE98ED4A6317F4DAE1#6513

1

1567894A631 1 1 1 1 1 01

1 22)1 ,F4F5A3D4A6316#18D3481AFE716#13

1

1567894A631 1 1 1 001

1 1

22)D1 F8E41#651C1A*A1A485F

1 1 1 1 1 1 051

1 1 22)1 F8E41#651C1AA

1 1 1 1 1 1 1 !1

1 1 22)91 F8E41#651C1AAC1A

1 1 1 1 1 1 1 !11

2221 >646A9 1 1 1 1 1 1 1 1 1 1 !&1

1 2221 H8F39A3B175A7A3B1#659F1 1 1 1 1 1 1 !&1

1 22211 =D36F9637145D3AF341D654A631F9456961 1 1 1 1 !&1

2%1 34FA 1 1 1 1 1 1 1 1 1 1 !)1

IAEA6B5DA915F#F5F39F 1 1 1 1 1 1 1 1 1 !!1

1

(10)

1

123456783952ABC2C4DEFA

1

(11)

1 234567894A631BC3C5DEF1 1

1 1

1

(12)

1 234567894A631BC3C5DEF1 1

1 F17A756B3F1 1F415F96338196F1E83F17F16859F17C3F5BAF1781848518A15F5CF34F1 83F1633F1DE4F53D4A F1D8!1C3F5BAF16AEF"1#$%17F1ED1567894A631637ADEF1D948FEEF17

1

F41 A8F1 7F1 569C7C1 A37845AFE1 7F1 D6&5F65DBF'1 8A1 84AEAF1 5A39ADEFF341 7F1 D4A5F1 5FA5F1765ABA3F16AEF1BD(13D485FE'17569D585F1EA8A7F1F419D5631F415678A417F1BD(1 )1FF417F1F55F1+'1+ "1,3F1D845F1D569F1-785DEF-168515678A5F1

1

F5DA417F15CDEAF51ED1 6467A69AD4A631 7F1 EFD81 681 E8A5F1 AAEF1 C3F5BAF1 6EDA5F"1 *F44F1 5CD94A631 F841 F1 7C966F51 F31 7F8!1 7FA&5CD94A631 .1 ED1 6466!7D4A631 7F1 EFD81 F31 +

1

F41 ED1 6465C7894A631 7F1564631F31

"1/815FBD5717F1ED1EA44C5D485F'1EF14F16EC98EDA5F16469D4DE4A8F17F1 567894A631 7

1

D69AF34'1 6851 ED1 B5D37F1 D065A4C'1 831 646F3AAEAD4F851 8A1 D65F1 ED1 E8A5F'1 831 9D4DEF851 7F1 5C7894A631 7F1 564631 F31

₁

AE1 F8 F341 145F1 9AA8FF341 9633F94C1 F41 831 7633F851 7CEF945631 D95AA9AFE"1 D1 E8D541 7F1 4F1 6EC98EDA5F1 6469D4DE4A8F1 6394A633F341 7D31 7F1 AEAF8!1 65BD3A8F1 681 756&65BD3A8F'1 DA1 F81 7F345F1 F8!1 6341 D94A1 F31 AEAF81 85FF341 D8F8!1 781 DA41 783F1 5DA7F1 7CD94A D4A631 781 9D4DEF8517D31EFD8"126854D34'17F1DEA9D4A6317D317F17A6A4A1646CEF94569AA8F17F1 7A69AD4A6317F1EFD813C9FA4F341E84AEAD4A6317F19F16E D34"1,3F1D D39CF1AB3AA9D4A F17D319F1 76DA3F1963A4F5DA4176391F31ED1AF1D816A3417F14F16469D4DE4A8F16851ED15C7894A631 7F1564631F31

18A16394A633F5DAF341 FA9D9FF341F31AEAF8185FF341 D8F8!"1*F417D31 9F1 9634F!4F1 8F1 A395A41 9F1 45D DAE1 7F1 4F1 D F91 EF1 7C FE6FF341 7F1 368 FD8!1 4F1 6EC98EDA5F1F565D341F316E84A63166B3F1 6851ED1567894A6317 1)1D54A517F1EFD81F41 8A1 D69AF341 7F1 9D4DEF851 7F1 5C7894A631 7F1 564631 7F1 567A81 681 7F1 96DE41 )1 7F1 646F3AAEAD4F8517F1584C3A815A39ADEFF34"1

3D31 EF1 5FAF51 9DA45F1 6341 5C8C1 EF1 F30F8!1 69AC4D8!1 F41 C9636A8F1 7F1 9F44F1 4CD4A8F1 F41 6341 5DFECF1 EF1 7633CF1 AEA6B5DA8F1 851 EF1 4F1 6EC98EDA5F1 6469D4DE4A8F17F15C7894A6317F15646316394A633FE1F31AEAF8185FF341D8F8!"1

F1 F96371 9DA45F1 9639F53F1 EC DE8D4A631 7F1 ED1 5CD94A A4C1 7F1 7AC5F341 96EF!F1 6E5A7A3A8F1 7F1 567A81 F41 7F1 96DE41 6851 9D4DEF51 ED1 5C7894A631 7F1 564631 F31 6E D341 65BD3A8F1 D51 CEF94569AAF1 D3DE4A8F1 8A1 D51 6AF1 6469AA8F1 E658AE1 6341 D69AC1 D81646F3AAEAD4F8517F1584C3A8145A&A5A7A3A8F1458 6

⁷

"1*F1C487F1F5F445631 7A7F34AAF51 8FE1 6341 EF1 9D4DEF851 64F34AFEEFF341 EF1 E81 D94A1 7D31 EFD81 6851 ED1 5C7894A6317F1564631F317A756B3F"1

F1 456AAF1 9DA45F1 654F1 851 ED1 567894A631 6469D4DE4A8F1 7756B3F1 F31 AEAF81

85FF341 D8F8!1 D F91 831 4F1 6EC98EDA5F1 D69AD341 831 9D4DEF851 6E5A7A3A8F1 7F1

(13)

1 234567894A631BC3C5DEF1 1

81 567A81 F41 EF1 646F3AAEAD4F851 458 6

⁷

"1 F1 F565D39F1 7F1 9F1 4F1 F56341 F38A4F1 96D5CF1 )1 9FEEF1 7F1 8FE8F1 4F1 6469D4DE4A8F1 7C0)1 7C95A41 7D31 ED1 EA44C5D485F184AEAD3417D845F19D4DEF851681646F3AAEAD4F85"1F1C9D3AF15CD94A633FE1781 4F1 EF1 E81 F565D341 F5D1 CBDEFF341 F!DA3C1 F31 7C4DAE1 D51 7F1 F85F1 F945696A8F17CAA631F417D654A63145D3A46A5F"1

F1 8D45AF1 9DA45F1 F5D1 963D95C1 )1 ED1 34F'1 ED1 9D5D94C5AD4A631 F41 EC DE8D4A631 7F1 F565D39F16469D4DE4A8F16851ED15C7894A6317F1564631F31AEAF8185FF341D8F8!17F1 368 FD8!1 96EF!F1 6E389ECDA5F1 D69AD341 D51 EADA631 96 DEF34F1 831 681 7F8!1 9F345F1 646D94A17F14F1458

6

⁷

1)18319F345F19D4DE4A8F1)1DF17F1567A8"1

93A31EF19A38AF19DA45F15CF34F18314F16469D4DE4A8F1FA9D9F17D31EFD8184AEAD341

9F44F16A18319D4DEF851D95699EA8F17F196DE4'1D69AC1D81646F3AAD4F851458

6

⁷

"1

84AEAD4A63178319D4DEF851)1DF17F1C4D8!1363136EF19634A48F183F15FA5F1C4DF1 F51EF1

7C FE6FF3417F14F16469D4DE4A8F164F34AFEEFF34184AEADEF1)1B5D37F1C9FEEF"1

1

(14)

1 234567891A11

1 123456738 69ABCDAEF738 949CE4EA24FD738 9D8 AE8 BDC4F98 738 94938 78 F29578 9BE48 78 6FAF7D8 D76748 ED7D8E7A38FAF9EFD738

1

(15)

1 234567891A1 1

1 1

B1 1

1

(16)

1 234567891A1 1

1 1

C1

BC 1 DEFE8467E1

1D4E91 F1 4974761 781 65874791 91 41 554761 6491 971 F1 9561 91 41 E476198769119151841611A

⁶⁹¹

6E9197191 955997191 91 91 58E761 987691 F1 41 61 6471 971 89 94!9"1 #91 1 $81 41 E47619876914991197197691F1%&'1 1 1A(

⁽

1)

^*A+

1E977919869158 6971F1'&1 ,191 E!76!91691E9191E348!191 4-19157891 46619191 E!76!91 E46891 .8461 971 73861 91 4$867/

^*+

"1 041 54871 8974791 89E 891 91 98691 89 94!91 E91 91 46891 691 91 E!76!91 91 !6491 1 9E891 3189E786E67

^*2+

"1

31 51 91 981 7E41 6671 91 98691 691 71 49971 41 E491 91 89$971 658747191619191E48!91414753891E786!471F14974761919971 91 98891 8954!91 91 !9 989971 E647691 91 E8"1 091 9559971 91 991 8E91 98691 F1 41 61 89 94!91 971 84!91 971 E1 91 E9671 581 546981F141E86919876916191969"1

578917691919614558791E3491491F14184E911!919 6811211A(

²¹

)1671581 91616916141E4761499

^*%+

"10766476191E977918E9141E115797691 781658747197197146981F141!491158E91497419141!65389179889789161 415371739"104153717391598971415479141491971F1E9874691!4E7869191 E86789187E91F14158E76191!649"181E987461!8919158$971 6971F19567981E91 58E919146891689E7154814158E761489E48!8471E95947141E5767614 9E1 486E789146974689191E94165691891E91715919158E76166E699714556E4!91 416 9416491E5791791914EE8699717816587471914155476"11

891 47891 691 7664761 91 98691 46891 971 91 537 74:91 61 598971 41 78484761 91 98691 46891 91 E8471 9E7869"1 297791 79E3691 971 !94E51 9559141E819141986891E9691461991913987919E891F1E98746158!91 638971 F1 41 E 9861 689E791 91 98691 46891 91 9E786E67"1 31 9971 91 8419971 46891 971 5481 47891 6798677971 91 91 E1E91 $8;671 461 49971 786!746891 91 E6761 78691 91 51 41 9491 987691 971 9969971 91 71 91 7818489971E88"1#41E91E48919$91971E1917E449191E977919869

^*21&+

"1

04158E7613189154819E7819191941971911$819119191515847691

917E4981918519869158671548191537 74:91E959471E91656761E96791

7664761 91 547691 E91 E4741981 91 8E761 971 14761 91 94"1

(17)

1 234567891A1 1

1 1

'1

<439899971 91 547691 971 1 741 !91 971 84891 971 E1 1 7664761 581 91 955997191 E97791 79E3691F1781 8491E39919715419 6494!9"12959471 31891 971 89E1 E91 1 9E7981 98691 581 91 781 971 89589791 91 4798476 91 781 86991 41 E!76!91 691 61 971 58671 F1 5487681 91 898E91 84!9

^*B+

"1 031891 5884671 481 =7891 7661 41 91 656761 91 71591 5691 F1 E!76!9"1

>81 E91 689791 8461 1 841 !891 6591 91 89E398E391 F1 784 981 91 91 784 46971 F1 41 691 41 5671 91 656761 598977471 91 586891 91 31891 F1 5487681 941971986914689"11#4191E41641E916567611E99153799E78E36691 59897784697116884647616991916E69819419191E547149741 3189197119"11

1 819959191E99153799E78E36691F1!491911791E468919715897181 91?E341A"1391971E767919191969569181548915481919!849"1#41 E3491E54876971153796!6647981971E348191E9E798191537156187E91F1 98691 4661 944691 E34981 91 9E781 4 9E1 1 E4741981 91 8E761 91 5871 F1 41 E47391 1 14761 91 941 F1 49"1 @61 91 598977891 91 7849871 9E7819789191969569191EE39191969EE7981.9171591158149197191 71591 51 581 41 E4739/1 9871 67984E91 97891 91 9E7891 971 91 E91 4E76 9"1 04E6476191E919184E76158671499711E84719E786915379667"1291 784 4619173916789915154876E68997141E7674711E54876971E473691 598977471 41 8E761 537966791 91 5871 91 31891 4 9E1 91 1791 E46891F1!49191E59919174191784676"11

091 E5991 91 741 91 7846761 71 771 F1 4671 44571 41 58E91 E8671 E69

91 7471 41 6 941 91 41 53796!664761 91 91 41 E47419

^*C+

"1 31 9971 E987461

E5991 71 9E9971 53796!6647981 E481 61 4!8!971 91 46891 781 6587471

41 91 981 91 1 66!91 971 5971 91 7471 9E671 91 891 91 691

64971915818469819178498719E78"1

(18)

1 234567891A1 1

1 1

A1 1 3E41A161?E34191586E659191E99153799E78E366915814153796E6476191

941548191E4741981E46891

>4814698191E59919174191784676159 971=789191E474198196E4E91E481 61 5971 41 E454E671 91 7E4981 56981 6 4971 9E78691 1231 981 68971 7471815989774714661918469819184E761769E78691E91418E761F1 91 9E781 91 5871 91 3189"1 >4861 99!91 91 5!6E4761 78467471 91 41 58E761537966791318919178184914$867145569181766476191E91 7159191E599"1111111111

BBC 1 E4F691 F49F741 91 41 8E76F1 5374747691 91 587F1548191599191E74191784F676F1

#91 46891 8491 71 91 E591 81 5471 1 5797691 1 51 8E7981 91 91 E591B C;B

1

.ED979F968919(%AE1 135B1F15B1C(/171E454!919189819131891 916691491. ?E341 .4//"1

1 3E41161>797691918E761F11971919E78191587141941F15B1C(1A'1F1 589617448191B

1914753891EE9784761914789195E91F1A1<"1

1 2959471915847691E9779184E7619717819791914!9E911E47419814558586"131 9971E916614191?E341.!/1918E761F11971F1919E78191B

^G1

71 98769971 4 84!9"1 #91 E91 4671 91 6798646891 1 B

^H

1 971 B

⁹

1 6 971 =7891 74!661 461 47796891 91 67991 91 84E761 4EE9574!9"1 #41 E91 E4891 91 !8991 79

^*C9'+

1 1B

^G

G119

⁹

I1B

9(%A1E114 35B1.4/

B

^G

G19

⁹

I1B

^H

9BA1E114 35B1.!/

B

^H

G19

⁹

I1B

⁹

G((21E114 35B1.E/

B

^G

G119

⁹

I1B

⁹

9A221E114 35B1./

(19)

1 234567891A1 1

1 1

A(1 814158E761318919153491391971814E76 476191318914-91 71 61 91 69E91 91 8J91 E8E641 91 318891 91 741

^B

1 .71 <

^KKK

.0/B

⁹

1 L1 <1 971 91 E97891 74691 971 01 9./1 64.//"1 091 84E761 691 91 $91 581 91 1791

^B

9

^'

1 .<

^KKK

9<

^K

/1718958979141914761E699"1

<

^KKK

01G19

⁹¹¹

1 1<

^KK

01 1 1 1 1 1 1 1 1 1 1111.A/11111111111111111

<

^KK

01G19

⁹

111 1<

^K

01 1 1 1 1 1 1 11 1 1 1111./1

<

^K

01G1B

^G

11 1<

^KKK

0.B

⁹

/1 1 1 1 1 1 11111 111 1 1111.2/1

<

^KKK

0.B

⁹

/1G1B

^G

111

₁₁₁

<

^KKK

0.B

/11

₁₁

<

^KKK

01G1B

1 1 1111 1 1 111111111111

¹

11

¹

.%/1 1<

^KKK

0.B

⁹

/11

111

<

^KKK

0.B /1G1<

^KK

011

1

<

^KK

01G1B 1 1 1 1 1 1111.&/1

<

^KKK

0.B

⁹

/1G19

⁹

1 1<

^KK

0.B

⁹

/1 1 1 1 1 1 1 1 1 1111.B/1 091E599174691667641

^B

11

^C

1.<

^KKK

11<

^KK

/197186719111E5991

^'1

.<

^K

/1.3"1 A/1 61 91 E761 91 1 5F41 971 91 4E6671 91 41 761 5971 !681 91 46761 1476 919161B

^G

1971811318891

^B

1.<

^KKK

0.B

⁹

//1.3"12/"1091E59913188915971 4815868919131891919184E761158969818891548184E7614 9E115871 .3"1 %/1 1 91 91 84E761 1 9E1 8891 5481 84E761 4 9E1 1 6 4971 559746891 91 E5991 318891 .3"1 &/"1 361 61 91 E5991 318891 971 541 64971 84E761 61 671 =7891 8671 91 <

^KK

0.B

⁹

/1 .3"1 B/1 581 586891 91 31891 6 4719184E7616646891F11E991E8679158191E599131889191<

^KKK

1.3"1%&/"1

#4111791537E47417691919E781E946891F141847619131889171

455871 1231178498719E78691537966719561153796!6647981.>?/"1297791

E91971E454!91168846476147796891174719E671F141618E79819711471

971 971 7661 E$679971 F1 1 981 9E781 4E866E691 598977471 91 8681 91

9E781 E946891 F1 41 E47419"1 091 68971 1791 E46891 967471 581 41

8E761 537966791 91 5871 E589971 E1 4$8674689971 1 E4741981 .247/1

1 53796!6647981 .>?/1 971 1 981 9E781 4E866E691 .#?/"1 #41 E987461 E41 1

89461 9E781 5971 49971 =7891 7661 971 4671 E91 1 647981 81 97891 91

53796!6647981 971 91 E474198"1 091 ?E341 2 1 589791 91 91 E4691 56!91

581 41 58E761 537E47417691 31891 4 9E1 1 1791 F1 7861 E547"1 091

58E9197166761417191E4154814!8576115371548191>?1E647117471

9E67171>?M"11

(20)

1 234567891A1 1

1 1

AA1 1 3E41161<E469114761.@/19718E761.N/14111791F17861E5471.>?1I1

53796!66479812471I1E4741981#?1I19819E7814E866E69/1581418E761 537E4741769191587"1K1971F1798191E91E46917165661E4814158E761 3189189689191784987191919E781E14!857611537167191586891

9161E6471F11784987191919E7818191E474198"1

#4191E411E469114761.?E3412.@//1>?M19715615481178498719E781 981 91 E4741981 8471 41 891 191 >?

^G

1 61 971 481 881 41 1 7471 4974145818E761548191#?"1091E46918E761.?E3412.N//165691771 4!819156949191>?M15481178498719E781956191#?184714189186791 1 >?1 >?

⁹

"1 81 7849871 9E781 91 >?

⁹¹

981 91 E4741981 E5791 481 91 E1E9"1 074!699711E469154818455871F14789159841997699971915858671 819168971E591.>?

^G

;>?M1>?M;>?

⁹

1247;247

⁹

1#?;#?

^G

/197191981EE9784761 89476 9"1 041 469774671 91 E91 1791 E96791 91 846981 91 537191 1 4753891698791461 679819184E761548467919789191>?M197119191468"1

BBBC 1 79153747476913 F91581418E76F191587F11

09117919158E761537E4741769131891714671!$971189461678=71 E684!9141E819141986891E96913189174718461E681E91 91 8E91 D98691 57976991 581 D4 968"1 091 5896981 1791 537E47417691 96E4E91 E8671 1 41 61 91 491 AAC(

^*A+

1 E!6971 1 53796!6647981 971 1 E4741981 91 8E761 91 5871 .391 1 3789/1 4661 1 981 9E781 4E866E691 .E51 1 1 4 9E1 1 647981 8/"1 291 986891 491 91

!8911791E468913917171845587

^{*B1 A(+}

15196E4E919179891 91!89191E1E91E474176915814158E7613189"1295947158141554871 6158971916691846911318984691.&1F1&(,194/"1>4861E911791 1 78 1 49971 1 E987461 !891 91 1791 584E46891 41 991 91 E47419819719153796!664798171E515481916461E 49791847191991 E9145599149971 O1537E4741981P"1Q!49971911791E4689191

123

⁴

56

⁷

56

⁸

56 9AB

⁷

B

₉

C6 C6

⁷

D1 123

123

⁴

56

⁴

568 9AB

⁷

B

₉

C6

⁷

D1

123 143

(21)

1 234567891A1 1

1 1

A1 6691 391 58471 91 6691 589971 491 998971 8489"1 29E61 99891 E959471 91 E6761 E946891 F1 981 7664761 7869891 41 91 656761 5379 9E78E36691 91 6E64761 91 94"1 #91 51 41 41 4$8671 91 E41 61 71 8971 96E4E91 1 4671 91 845691 4E76 4761 1 E4741981 97;1 1 53796!6647981 41 94"1 091 ?E341 %1 91 1 4598R1 91 586E65491 4691 91 E474198153796!66479819719819E7814E866E6916171717669158141 8E761537E4741769191587191669184691318984691149"1041 8491 4$8671 91 53796!6647981 7661 71 91 E5991 5151866691 91 741 !91 .87361 68661 54769/1 !691 91 91 585318691 91 -6E1 1 91 53796!664798184691.69181738691S"/1469717149971951"11

1 3E41!1613959191E54717661581418E761537E47417691915871

T47141E47419816159 971916 698191918491E4916191E5991F1!491

91741!91E9191E599115151866691918361547691154461

1F1!491917411!91E9191E599191E!471F16415151866691

14E8E1E691.E!469/1916E491F1641535369197191981F1641E48!191

971 81 .91 31849/"1 091 981 9E781 849971 9511 71

9146917987646891.7867344691U3C@17867314691U3@1673146691#<@11

(22)

1 234567891A1 1

1 1

A21 73191 64691 3#U@/"1 04E8!4791 91 61 .54B@/1 971 49971 7661 586E6549971 1 91 6691 49"1 091 E341 14761 688 986!91 91 E91 981 9E7814E866E6919871956E671519174614191E34567891KK1971KKK"1

091 1791 E46891 581 41 58E761 537E47417691 31891 4E761 91 669184691971318984691617171489971E8671411841!891 91 89 91 8E9791 91 9871 541 4 47491 7461 6E6

^{*1 B1 AA+}

"1 #41 91 5484845391 6 471 11E469816997181419E86576174691911791E4689191 41677847891617171 955191669158997149"11

B"C 1 79153747476913 F91581418E76F191587F1 9F166915899F71491

291 1791 9871 E41 91 E761 91 41 47891 91 741 1 E97891 E4741769161 91 E5991 F1 !491 91 8361 68661 971 91 54461 41 1 5896981 7951 561 91 E5991 91 547691 971 961 91 E5991 91 E!47"1 091 53796!6647981 9511 91E!64614 9E1E9168971E474198171589718191?E341&"11

3E41#1$1?78E78919153796!6647981766141911791537E47417691916691 58997149" 11

291 1 41 91 681 41 554871 91 E91 1791 537E47417691 895971 81

766476191*V.!51/

2

+

^G

1.%A/1E9153796!664798"1

(23)

1 234567891A1 1

1 1

A%1 56787 1 9A4BCDE4FB2243BFF3B3A4EFEF2DF222DFFEF332DF

091?E341B1849!9191689717159191E4741981F1!49191V31K81971>1E867141 E97791 95487691 971 91 U4!941 A1 91 59884E91 537E47417691 91 E91 179"1 091 17916564711E469114761.?E3412.@//198717714!81589715481 8891E3869156114!8981E9161E76971 6411E46918E76"11

3E41&1$1?78E789191E4741981F1!49191V31K81971>"1

(24)

1 234567891A1 1

1 1

A&1 '4(941A1$1VE456747619159884E9197191E6761537E4741769141941589191 689711791769E547176647191E474198191V31K8197191>"11

)1 .EE191

"0^9A/1

2471 .EE"191

"0^9A/1

V4761

>?;2471

#981 .EE"191

"0^9A/1

5B;4E6917661 .EE"191

"0^9A/1

WB1

.X1/1

UC52471 .795/1

UCD2471 .0"3^9A/1

?8E91 688464761

EB1 .0/⁴1

891

%A1 .AA1_A(^9%_/1

%3A1 .AA&1_A(⁹²_/1 G10A1 .2A1_A(⁹²_/1

A61 U3C@1 .(%/1

C(;B?C_%1 1 1 (A'1 045911 3491 1X1Y1%((11

1 ^*A9+1

%A1 .%%1_A(^9%_/1

%3A1 .A&B1_A(⁹²_/1

A62&1 3#U@1 .(/1

&;B?C%1 1 B1 .23/1

A1 04591 3491 1X1Y1%((11

BB1 .23/1

*A9+1

%A1 .%1_A(^9&_/1

%3^!1 .A1_A(^9%_/1

A6&1 3#U@1 .((2/1

&(;7451 4E74791.(A/1

1 %(1

.&3/1

1 04591Z91 (AC'11 ^*A+1

%A1 .%1_A(^9&_/1

%3^!1 .A1_A(^9%_/1

A6&1 3#U@1 .((2/1

&(;7451 4E74791.(A/1

1 %&1 .&3/1

1 04591Z91 ((A1 ^*A+1

%A1 .%1_A(^9&_/1

%3!^!1 .A1_A(^9%_/1

A6&1 3#U@1 .((2/1

&(;7451 4E74791.(A/1

1 21

.&3/1

1 04591Z91 (A(%1 ^*A+1

%A1 .%1_A(^9&_/1

%3#^!1 .A1_A(^9%_/1

A6&1 3#U@1 .((2/1

&(;7451 4E74791.(A/1

1 AA1

.&3/1

1 04591Z91 (('B1 ^*A+1

%A1 .%1_A(^9&_/1

%3&⁽¹ .A1_A(^9%_/1

A6&1 3#U@1 .((2/1

&(;7451 4E74791.(A/1

1 ((A1

.&3/1

1 04591Z91 (((%1 ^*A+1

B8A1 .&1_A(^9&_/1

%3#(6¹ .&1_A(^9&_/1

A6A1 U3@1 .(B/1

1 1 221

.(3/1

1 ?96148766E6911 X1Y112&(11

1 ^*A2+1

%A1 .BC1_A(^9C_/1

)A1 .&'1_A(^9&_/1

A16'B1 @B1 .2&A(⁹²/1

%B;7451 535347911

(((1 AB1 .%3/1

(1 04591Z911 A11 ^*A%+1

%A1 .AA1_A(^9%_/1

%3*1 .AA1_A(^9%_/1

A6A1 54@B1 &(;B@1.(A/1 4$714 9E1 54CB1

(21 [A(((1 A1¹ 0459191 58$9E7981 X1Y1%('11

1 ^*A&+1

%A1 .BBC1_A(^9%_/1

%3*1 .ABC1_A(^9%_/1

%6A1 54@B1 .(AA&/1

%&;B@1.(&/1 1 Y(((1 .%3/1

1 04591\9

3491 X1Y1%((11

ABB1 ^*AB+1

%A1 .1A(⁹²/1

%3+1 .A1A(⁹²/1

6A1 54@B1 .(2/1

%(;B@1.('/1 (((1 .%&(/1

A((1 .23/1

1 04591Z91 X1Y1%2(11

1 ^*AC+1

%A1 .1_A(⁹²_/1

%B811 .A1_A(^9%_/1

(6A1 54@B1 .(2/1

%(;B@1.('/1 ((A&1 .%&(/1

%(1 .3/1

1 04591Z91 X1Y1%2(11

1 ^*AC+1

,1 %%3%1

.B&1A(^9&/1

1 U3C@1 A'1 1 A(1

.%3/1

1 #301

1X1I1%C(11

(BB1 ^*A'+1

,1 %%3%1

.B&1A(^9&/1

91 U3C@1 CA;2D₂?C₂B1 1 A21 .%3/1

1 #301

X1I1%C(11

('%1 ^*A'+1

,1 %%3%1

.B&1A(^9&/1

91 U3C@1 CA;BN81 1 B1

.%3/1

1 #301

X1I1%C(11

AB%1 ^*A'+1

1 %%3%1

.B&1A(^9&/1

91 U3C@1 CA;B₂>C_%1 1 A1 .%3/1

1 #301

X1I1%C(11

A'%1 ^*A'+1

4

1EB

1.0/189E4E91581A(10191761E47417691

!

1 #41 E91 1791 537E47417691 1 89461 9E781 91 7311 691 .<E

^G

/1 971 4$71 1 F1 41 EE978476191A(

⁹²

1"0

^9A

"11

16117986

(25)

1 234567891A1 1

1 1

AB1 KE"A"4" 2 ?1791%A;%3A;3#U@11U3C@1

0931 ?4 491 971 E"

^*A9+

1 71 E8671 91 AACA1 1 91 5896981 1791 91 8E761 91 5871916691589971491E671153796!6647981*V.!51/

2

+

^G

1.%A/11 E4741981*V3

^KKK

.!51/

₂

+

^2G

1.%3A/197191U3C@113#U@1E919819E7814E866E691 .?E341 &1 971 ?E341 B]1 U4!941 A/"1 0688464761 91 6891 66!91 91 E91 1791 91 58671914767178146!913189"181!89191E1E91E47417691491F1B15481 E9191E4741981.71UC5

₂₄₇¹

.UC51I1U81C 9815!98//1971!791419196981 91 E41 4 9E1 3#U@1 F1 5B1 &"1 @1 5B1 C(1 4 9E1 U3C@1 4E76 671 971 46971 9"1 091 E4691 91 58E761 31891 5851 4 9E1 3#U@1 971 81 5481 91 4761 6 479161

*V

^KK

.!51/

₂

+

^G

1 1*V

^KK

.!51/

₂

+

^G

M11111111111111111111111111111111111111111111111111111111111111111111111111111111111111111111.C/1

*V

^KK

.!51/

₂

+

^G

M1G1*V3

^KKK

.!51/

₂

+

^2G

1 111*V

^KKK

.!51/

₂

+

^2G

1G11*V3

^KK

.!51/

₂

+

^G

1

¹¹¹

11111111111111111111111111111111.'/1 1*V3

^KK

.!51/

₂

+

^G

1 11*V3

^KKK

.!51/

₂

+

^2G1

1G1*V3

^K

.!51/

+

^G

1G1!511111111111111111111111111111111 1111111111111111.A/1

*V

^KK

.!51/

₂

+

^G

M11G1*V3

^KK

.!51/

₂

+

^G

1 11*V

^KKK

.!51/

₂

+

^2G1

1G1*V3

^K

.!51/

+

^G

1G1!5111111111111111111111111111.A(/1

*V3

^K

.!51/ +

^G

1G1B

2

C

^G

1 11*V3

^KKK

.B/.!51/ .B C/+

^G

1 1 1 1 1 1 11.AA/1 1*V3

^KKK

.B/.!51/ .B C/+

^G

11 111*V3

^KK

.!51/ +

^G1

1G1B

1

1 1 1 1 11.A/1

*V3

^KKK

.B/.!51/ .B C/+

^G

1G1B

2

C

^G

1 11*V3

^KKK

.!51/ .B C/ +

^2G

1G1B 1 1 1 11 1

1

.A2/1

*V

^KKK

.!51/

2

+

^2G

1G13#U@1 11*V

^KK

.!51/

2

+

^G

1G13#U@

^G

1 1 1 1 1 11.A%/1

?6791 F1 9E674761 5481 688464761 91 %A1 .3"1 C/1 95E91 *V

^KK

.!51/

2

+

^G

M1 891 84671 689E79971 4 9E1 *V3

^KKK

.!51/

2

+

^2G

1 581 981 91 E5991 *V

^KKK

.!51/

2

+

^2G

1 971 *V3

^KK

.!51/

2

+

^G

1 .3"1 '/"1 *V

^KKK

.!51/

2

+

^2G

1 971 481 8671 5481 3#U@1 581 88981 %A1 .3"1 A%/"1 #41 E91 1791 41 691 91 569491 91 *V

^KK

.!51/

2

+

^G

M1 971 E1 1476 9"1 091 =91 E4691 5979=78915851581U3C@"129114 1956E67141419E91548769191E97791 678E761 91 E5991 E9576!91 91 84681 4 9E1 1 5871 581 8981 1 318891 6 971 5981 1 E97891 74691

^'

"1 @581 91 5896981 7849871 9E78691 9561 91 53796!6647981 91 E97891 74691 1 E4741981 971 1 41 891 V3.KK/1 .

^C

/1 971 671 E1 !681 91 8E761 55974689"1 #91 691 71 56!91 581 41 84761 1 V3.K/1614158968919714167476191916 497191*V3

^KK

.!51/

₂

+

^G

1.3"1A/1419E91 971178498719E7869155974689195619153796!66479819E671.3"1A(/"1K1 471 7981 91 41 9E91 8E761 1 8361 9714EE5491 91 41 E864761 1 641!511581898191E5991836.K/1*V3

^K

.!51/

+

^G

11541E488"12969E615971481

3^1

(26)

1 234567891A1 1

1 1

AC1 84681 4 9E1 B

2

C

^G

1 971 981 91 E5991 318891 *V3

^KKK

.B/.!51/ .B C/+

^G

1 .3"1 AA/"1 2971 31889159716!8981318919191E469168971671548184E7614 9E11 6 497155974689191B

2

C

^G1

.3"1A/1671548184E7614 9E1147891E5991318891 .3"1A2/"13616141717814 9E1U3C@ 1 914$711E:9191547691F141761 537E47417691 598971 497981 91 46891 65874791 4E76 671 1 1791 .A('1 UC5"3

^9A

/"1 091 E5991 91 8361 $471 997699971 91 8J91 91 89461 9E781 41 E47419197148191849154876913789"1

KE"A"!" 2 ?1791%A;E5991!6E4689191836;<E

^G

;3#U@1

>1 8E9971 ?44461 1 971 E"

^*A+

1 71 9551 91 8691 91 E5991 !6E46891 91 836.KK/1F16461749741.V3.KK/

/1.E5991%3,%3&1?E341B1971U4!941A/161 7171766141911791537E474176916646891F1E9191?4 49"12959471 41 E91 1791 91 51 1 53796!6647981 %A1971 1 981 9E781 3#U@1 41 589E91 1 89461 9E781 91 7319 691 .<E

^G

/1 971 E946891 F1 41 58E761 3189"1 291 89461 9E781 598971 91 7849871 9E781 9561 7471 9E671 1 53796!6647981 98191E474198"131997141E911791F147891E5471%A1 .% 1 A(

^9&

1</;V3.KK/

1

.A 1 A(

^9%

1</;<E

^G1

. 1 A(

⁹²

1</;3#U@1.2 1 A(

^9%

1</1F15B1&(1.74514E74791 (A1</1174719E671153796!664798197156191468911476 915481<E

^G

158971 91 4891 9E1 5481 8455871 41 7861 47891 E767471 .3"1 A&/1 561 1 7471 667641 971 881548184E7614 9E13#U@1.3"12A/"11

*V

^KK

.!51/

₂

+

^G

M11G1<E

^G

111 1*V

^KKK

.!51/

₂

+

^2G

11G1<E

^HG

111 1 1 1 1

¹

11.A&/1

<E

^HG1

1G1V3.KK/ 111 11<E

^G

11G11V3.K/V3.KK/111 1 1 1 1 1 1

¹

1.AB/1 V3.K/V3.KK/11G1B

^G

11 11B9V3.KKK/V3.KK/1 1 1 1 1 1 11 11

¹

.AC/1 B9V3.KKK/V3.KK/1G1B

^G

11 1V3.KKK/V3.KK/1G1B 11 1 1 1 1 1 11

¹

.A'/1 1B9V3.KKK/V3.KK/111 11V3.KK/

11G1B

1 1 1 1 11111111111111111111111111111111111111.AA/1 V3.KKK/V3.KK/1G19

⁹

11 1V3.KK/

111 1 1 1 1 1 1 1 1

¹

1.(/1

*V

^KKK

.!51/

2

+

^2G

1G13#U@1 1*V

^KK

.!51/

2

+

^G

1G13#U@

^G

11111 1 1 1 1 11

¹

.A/1

091 846E41 691 <E

^HG

1 5971 481 86891 91 6981 V3.KK/ 1 581 8981 1 E5991 F1

49E916791V3.K/V3.KK/1.3"1AB/"1091E97891V3.K/1

^'

191587919166914E6915818981

1 318891 B9V3.KKK/V3.KK/1 .3"1 AC/"1 031891 971 96791 6!81 5481 84E761 4 9E1 1

5871116 497191E5991318891559746891.3"1A'1971AA18959E76 997/"1

K14716981919184E761E8679141914761AB1971AC159 971=7891EE98791

(27)

1 234567891A1 1

1 1

A'1 1 41 891 91 84E761 91 71591 >23U1 .>871 2591 39E781 U84987/1 L1 41 84E7619178498719E781971E591F14158747611E474198"1

#1567191 91914E76 671E47417691E91E5991!6E4689191V3.KK/171781591 96E4E91]1419698914E76 671E4741769191%&1UC5

247

14147171!79914 9E1%3"1297791 46!91 58E761 31891 5481 91 1791 537E47417691 766471 91 E5991

!6E46891 91 V3.KK/1 E91 E4741981 41 71 E6891 781 8E9971 5481 91 791 91

\41971E"

^*A2+

"1 0911791766911449191 %3#1%3#(61.?E341B/1L191641

!65186691 71 71 8954E1 5481 91 641 534738691 4E61 F1 1 53796!664798168661E1E741.B8A/1 .?E341&/1 971F1U3@"1317614991 5891914614E76 671!79197191221UC5

₂₄₇

1.U4!941A/"1

KE"A"E" 2 ?1791%A;)A;B@

⁹

;B @1

31 AA'%1 D63981 971 299B467

^*A%+

1 71 8671 F1 586891 91 31891 5481 688464761 91 761 F1 5B1 %B1 91 %A1 .B& 1 A(

^9C

1 </1 971 4E691 4E8!691 .B @/1 .2& 1 A(

⁹²

1 </1 E79471 1 E4741981 91 54461 *>B.>37

2

/

2

+

^G

1 .)A1 ?E341 B/1 .&' 2 1 A(

^9&

1 </"1 041 58E761 31891 971 781 46!91 AB1 UC5

247

1 971 991 971 4E691 F1 1 899971 47691464191889191(((,1.U4!941A/"1

1*V

^KK

.!51/

2

+

^G

M11G1B@

⁹

1 1*V

^KK

.!51/ .!51

^H9

/+

^G

11G1@

^H9

1G1B

^G

11 1 1 1 11

1

./1 8916191E5991918736186715481B@

⁹

1.3"1/1615971784898119E781 981 91E4741981 9718981 95E91 846E446891*>B.>37

2

/

2

+

^H

1771918978471F117471667641 .3"12/"1

*V

^KK

.!51/

.!51

^H9

/+

^G

11G1*>B.>37

₂

/

₂

+

^G

1 1*V

^KK

.!51/

₂

+

^G

1G11*>B.>37

₂

/

₂

+

^H

111 1 11

¹

.2/1

>81 6!8981 31891 91 E5991 *>B.>37

₂

/

₂

+

^H

1 5971 481 84681 4 9E1 1 5871 971

*V

^KK

.!51/

.!51

^H9

/+

^G

1.3"1%/"1

*>B.>37

₂

/

₂

+

^H

1G1B

^G

1G1*V

^KK

.!51/

.!51

^H9

/+

^G

1 1*>.>37

₂

/

₂

+1G1*V

^KK

.!51/

₂

+

^G

1G1B

11111111111111111

¹

.%/1 8919E91 69156!91656914184761168919154461F15716318891 6159714816!8981B

1.3"1&1971B/"1

1*>B.>37

2

/

2

+

^H

1 1*_>B.>37

2

/

2

` +11 1 1111111111111111111111111111111111111111111111111111111111111

1

.&/1

*_>B.>37

₂

/

₂

`

+1 1*>.>37

₂

/

₂

+1G11B

1 1111111111111111111111111111111111111111111111111111111111111111111111111

¹

.B/1

(28)

1 234567891A1 1

1 1

AA1 095E916676491*>B.>37

2

/

2

+

^G

1971889154814184E7611E5991*>.>37

2

/

2

+181F1 416!8476191318914 9E115871.3"1C/"1

*>.>37

₂

/

₂

+1G11B

^G1

1 1*>B.>37

₂

/

₂

+

^G

11 1 1 1 1 1 1 11

¹

.C/1 KE"A"" 2 ?1791%A;%3*;@B

⁹

;B @1

091 5896981 1791 537E47417691 8455871 E91 7471 781 4E761 581 41 8E761 91 58719166915899714914171E86715481C636

^*A&+

191AA'C"1091E47419817661971 1 E4741981 91 \6461 *V3

^K

.5/

₂

2+

²⁹¹

.%31 ?E341 B/1 .51 I1 6539153536!9-999953479/1891318!915481678E76191E761 479181916415391535369"1297791E49191E4741981971667649971E91 581 91 5858671 3184761 91 E51 84691 1231 41 84761 318891 91* 836.KKK/

^*AA+

"1091E4741981 **%3*1.AA** 1 A(

^9%

1</14E61F1%A1.AA 1 A(

^9%

1</14117451 B@

⁹

;B @1 .(A1 <1 5B1 &(/1 84691 51 91 A(((1 UC51 91 %&1 6791 1 688464761 66!91 .U4!941A/"131AAA%1N49819714"

^*AB+

171876981E91179197171781914158E761 318915 4671477968915191(((1UC5

247

1F15B1%&191589E9119"1291 41 99591 91 D63981 971 4"1 .5484845391 58E97/1 41 691 91 569491 1 53796!66479819718E786E91 .3"1C1971/"1 091 E5991667641911836.K/17471 541 64971 84E761 581 8981 1 318891 971 671 !681 91 8E761 5844!91 F1 41 84E7614 9E115871.3"1'1971A/"10416!847619131891918919679191 1E4691!6E4689197891916798646891318891.3"12(/"1

*V3

^K

.5/

₂

2+

²⁹

1G1*V

^KK

.!51/

.!51

^H9

/+

^G

1111 111*V3

⁽

.5/

₂

2+

^%9

1G1*V

^KK

.!51/

₂

+

^G

111111111111111111.'/1

*V3

⁽

.5/

₂

2+

^%9

1G1B

^G

111 11*V3

^KK

.5/

₂

.B/2+

²⁹¹

111111111111111111111111111111111111111111111111111111111111111111.A/1

1*V3

^KK

.5/

2

.B/2+

²⁹

11

¹

1111*V3

^K

.5/

2

2+

²⁹

111G1B 1111111111111111111111 1 1 11

1

.2(/1

81 459E71 781 6789471 1 784 461 C6361 971 791 91 59884E91 E47417691 1

179191E76115B1.911F1B/16171 98915481918476191EE978476197891

4E8!4791 91 61 .B@

⁹

1 981 9E78/1 971 4E691 4E8!691 .B @1 981 91

587/1 .5F41 I1 %(/1 . 681 234567891 2/"1 @1 5B1 9 1 41 891 @B

⁹

1 58691 91 761

89471915694918E761153796!664798178196E4E914614146!91EE9784761

91B

2

C

^G

1667914184E76 6711E474198"1@146!915B141891B @15869191761971

58E891 91 EE9784761 65874791 91 B

2

C

^G

1 598977471 91 84E76 671 65874791 1

E4741981 E959471 41 47671 86791 91 981 9E781 8497671 91 569491 8E761

91)A1971E1418847611E474198"1291E5861978914184E76 6711E4741981

(29)

1 234567891A1 1

1 1

(1 971 96E4E671 1 7849871 9E78691 53796671 971 971 1 4E7981 61 66791 96E4E671911791537E47417691918E76191587"11

KE"A"9" 2 ?1791%A;%3+;@B

⁹

;B @1971%A;%B8;@B

⁹

;B @1

>4849971F1E91784 461917391D4-61971E"

^*AC+

171845587191(AA191 941 1791537E474176916646891F1E96191C6361766471%A19711745154B@;B

@

₁

E91 981 9E781 971 91 5871 971 E91 E4741981 91 E5991 91 8361

*V3

^KKK

.!51/25M.B

C/+?C

_%

1 .%3+1 25M1 I1 2

^&

92

_&

<9

_&

1 ?E341 B/1 1 1 E5991 6E46891 8736;68661 *K8

^KKK

.25M/.B

C/.!5/V

^KK

.!51/

+.?C

_%

/

1 .B8%1 !51 I1 9!651866691

?E341B/"1096E4E6714649191E911791971!7991F15B12B"11

04E76 671 91 E91 91 1791 971 49-1 67894791 5691 A((1 UC5

₂₄₇

1 71 !791 91 78613989168846476158191761E79471 %A1. 1 A(

⁹²

1</;%3+1.A 1 A(

⁹²

1</;1B@

⁹

.(21</;B @.('1</1971$DF1%(1UC5

2471

7184619191398914 9E1911791%A1 . 1 A(

⁹²

1</;%B81.A 1 A(

^9%

1</;1B@

⁹¹

.(21</;B @1.('1</1.U4!941A/"1K1971F179819158191 9E1179141589E9191%A1971E946891F14E76 671E4741769148141589E91 176187369786166691419619141E9"1091E4691916!847615851 5481 D4-61 971 E"1 581 91 91 71591 91 E5991 7661 E88951 F1 1 569491 8E761153796!66479819E6715481B@

⁹

1.3"1C1971/"1091E9789174691V3.KKK/1 971 K8.KKK/1 .<.KKK//1 !6971 91 8E761 9E78691 5481 *V

^KK

.!51/ .!51

^H9

/+

^G

1 581 8981 91 E5991 91 V3.KK/1 971 K8.KK/1 .<.KK/1]1 3"1 2A/1 61 71 481 91 67981 581 981V3.K/1971K8.K/1.<.K/1]13"12/"11

<.KKK/11G1*V

^KK

.!51/

.!51

^H9

/+

^G

1111 1111<.KK/1G1*V

^KK

.!51/

₂

+

^G

111 1 1 1 11.2A/1 1<.KK/1 <.KKK/11G11<.K/111 1 1 1 1 1 1 1 1 11.2/1 091 E5991 <.K/1

^'

1 91 587971 481 581 8981 91 318891 .3"1 2/1 61 846971 4 9E1158715597468919716!8971B 1.3"1%/"18147891459E71658747191E91784 461 9714169191 69E91916798646891V3.KK/1614151=7891!98 187E91F1917911 1791548159E78E56914!8576178467689"1

KE"A"" 2 ?1791%%3%;U3C@1

N89a981 971 E"

^*A'+

1 71 E8671 91 ((A1 1 E5991 51E46891 5471 91 E97891

V.KK/15374E7619711E97891V3.KKK/1E47417691.%%3%-1?E341B/"1N69191E917159191

E5991 671 54861 91 537E4741981 91 51 96E4E91 91 6691 318984691 61

(30)

1 234567891A1 1

1 1

A1 59897146977499719814E76 671916691589971491. 681E34567891KE/"1319971 91537191F1%C(1141941F115B1E586197891A'1971CA1E79471U3C@1.A"&1</1 971 %%3%1 .B& 1 A(

^9&1

</1 586971 91 47671 31891 781 46!91 E8895471 F1 91UC5

₂₄₇

191A(1F1A1.U4!941A/"1091E469158E6191499713189141 941 41 541 71 E61 E959471 91 91 47981 41 5896891 74591 971 91 569491 8E761919671V.KK/15481U3C@1.6 4971F1E96191%A.15481@B

⁹

13"1C1971/"1 K1 91 671 1 5896981 7849871 9E781 981 91 E4741981 581 8981 V3.KK/1 561 1 96915818981V3.K/"1V3.K/15971481846815816!8981B

19191476129&"1 5677 1 9A4BCDE4FB2243BFF3B3A4EFEF3B2EF

091 8591 91 F91 ?44461 971 58!4!9971 91 8591 91 51 586691 91 41 677847891 EE98471 91 9559971 91 1791 537E47417691 91 8E761 91 5871 91 669158997149"1291859141919971845587191548491911791!418191 E5991 !6E46891 91 8361 E8671 58E9971 581 91 E64791 1791 6564714$867468997191E59911971!6E4689191547691E91E474198"1

?61 1 841 !891 91 E4741981 71 71 7661 F1 689791 EE9784761 91 47891 E5471 1 1791 71 7$81 697691971 6646891 F1 E991 91 E5991

!6E4689191V3.KK/619153796!6647981%A1F141EE978476191%A(

^9&

1<19714E61 419819E7813#U@1F12A(

⁹

1<197141894619E7819731 691F1A(

⁹²

1<1 419176158997149917451F15B1&(1.74514E74791(A1</"1298746191 E91 E5991 5471 91 641 !7671 5481 91 859971 4EE957981 9E781 .5186661 1 731 69/1 71 49971 71 761 91 4!9E91 91 <E

^G

"1 091 59884E91 537E47417691 91 99!91 91 E91 1791 71 849!91 41 91 U4!94119719174!9412"1

1

(31)

1 234567891A1 1

1 1

1 '4(941 161 VE45674761 91 E6761 971 91 59884E91 537E47417691 41 941 5891 91 689711791769E547176647191E474198191>711688464761914591Z91F1 5B1I1&(141174514E74791.(A</191589E91913#U@1.((21"0

^9A

/"

²

>?1 .%A(

^9&1

"0

^9A

/1

2471.EE"191

"0

^9A

/1

<649 798181

.A(

⁹²¹

"0

^9A

/1

WB

1

.X1/1

UC5

2471

.795/1

UCD

2471

.0"6

^9A

/1

?8E91 688464761

EB.0/⁴1

891

%A1 )7A1.1

A(

^9%

/1 <E

^G

1 (A(1 1 1 X1Y12&(11 AA1.A'3/1

^*(+

1

%A1 )71.1

A(

^9%

/1 <E

^G

1 (2A1 1 1 X1Y12&(11 1.&3/1

^*(+

1

%A1 )71.&1

A(

^9&

/1 <E

^G

1 (&1 A((A.&3/1 AC&

1

A(

⁹²

1 X1Y12&(11 B1.&3/1

^*A+

1

%A1 )71.1

A(

^9%

/1 <E

^G

1 (&1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7!1.1

A(

^9%

/1 <E

^G

1 (A21 1 1 X1Y12&(11 (B1.A'3/1

^*(+

1

%A1 )7#1.1

A(

^9%

/1 <E

^G

1 (21 1 1 X1Y12&(11 1

^*(+

1

%A1 )7&1.1

A(

^9%

/1 <E

^G

1 ((1

1 1 X1Y12&(11

1

^*(+

1

%A1 )7*1.1

A(

^9%

/1 <E

^G

1 (A%1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7+1.1

A(

^9%

/1 <E

^G

1 (((1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7/1.1

A(

^9%

/1 <E

^G

1 ((A1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7/1.%1

A(

^9%

/1 <E

^G

1 ((1

1 A&1

1

A(

⁹²

1 X1Y12&(11 (A21

^*A+

1

%A1 )7A01.1

A(

^9%

/1 <E

^G

1 (1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7AA1.1

A(

^9%

/1 <E

^G

1 ((1

1 1 X1Y12&(11

1

^*(+

1

%A1 )7AA1.%1

A(

^9%

/1 <E

^G

1 ((AA1 1 A%

1

A(

⁹²

1 X1Y12&(11 ((&1

^*A+

1

%A1 )7A1.1

A(

^9%

/1 <E

^G

1 (1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7A1.1

A(

^9%

/1 <E

^G

1 (1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7A!1.1

A(

^9%

/1 <E

^G

1 ((%21 1 1 X1Y12&(11 1

^*(+

1

%A1 )7A#1.1

A(

^9%

/1 <E

^G

1 (1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7A#1.A1

A(

^9%

/1 <E

^G

1 (1 2CA1 A%A

1

A(

⁹²

1 X1Y12&(11 ('21.&3/1

^*A+

1

%A1 )7A&1.1

A(

^9%

/1 <E

^G

1 (%1

1 1 X1Y12&(11 1

^*(+

1

%A1 )7A&1.A1

A(

^9%

/1 <E

^G

1 (%1 1 ABA

1

A(

⁹²

1 X1Y12&(11 AA'1.&3/1

^*A+

1

%A1 )7A*1.1

A(

^9%

/1 <E

^G

1 (1

1 A%A

1

A(

⁹²

1 X1Y12&(11 (A21.&3/1

^*(9A+

1

%A1 )7A+1.1

A(

^9%

/1 <E

^G

1 (AC1 'B1.&3/1 AAA

1

A(

⁹²

1 X1Y12&(11 (B%1.&3/1

^*(9A+

1

%A1 )7A/1.1

A(

^9%

/1 <E

^G

1 ((A1 'A1.&3/1 (

1

A(

⁹²

1 X1Y12&(11 (A1.&3/1

^*(9A+1

%A1 )701.A1

A(

^9%

/1 G1 5421.

1

A(

⁹²

/1

<E

^G

1 (B1 BA.&3/1 A'2

1

A(

⁹²

1 X1Y12&(11 A&&1.&3/1

^*+

1

%A1 )7A1.1

A(

^9%

/1 <E

^G

1 ((%1 1 1 X1Y12&(11 1

^*(+

1

%A1 )7A1.1

A(

^9%

/1 <E

^G

1 ((%1

1 A'

1

A(

⁹²

1 X1Y12&(11 (A%1.&3/1

^*A+

1

%A1 )7A1.%1

A(

^9%

/1 <E

^G

1 1 1 1 X1Y12&(11 (C1.23/1

^*2+

1

,1 )7A1.%1

A(

^9%

/1 <E

^G

1 1 1 1 X1Y12&(11 (2A1.23/1

^*2+

1

,1 )7A1.%1

A(

^9%

/1 9

2

1 1 1 1 X1Y12&(11 (1.23/1

^*2+

1

,1 )7A1.A1

A(

^9%

/1 91 1 1 1 X1Y12&(11

((A1 ^*%+

1

,1 )7112A1

A(

^9%31

91 1 1 1 X1Y12&(11

(A

1

^*%+

1

%A1 )711.1

A(

^9%

/1 <E

^G

1 ?6646891 F1>7(11

1 1 X1Y12&(11 1

^*(+

1

%A1 )7!11.1

A(

^9%

/1 <E

^G

1 ?6646891 F1>7(11

1 1 X1Y12&(11 1

^*(+

1

%A1 )7#11.1

A(

^9%

/1 <E

^G

1 1 U84E91

1 X1Y12&(11

1

^*(+

1

%A1 )7&11.1

A(

^9%

/1 <E

^G

1 (2C1 1 1 X1Y12&(11 AA1.A3/1

^*(+

1

%A1 )7&11.1

A(

^9%

/1 91 1

1 1 X1Y12&(11 (%&1.A3/1

^*(+

1

%A1 )7*11.1

A(

^9%

/1 <E

^G

1 (%1 1 1 X1Y12&(11 (C1.A3/1

^*(+

1

%A1 )7*11.1

A(

^9%

/1 91 1

1 1 X1Y12&(11 (&1.A3/1

^*(+

1

%A1 )7+11.1

A(

^9%

/1 <E

^G

1 (1 1 1 X1Y12&(11 (&&1.A3/1

^*(+

1

%A1 )7/11.1

A(

^9%

/1 <E

^G

1 (A1 1 1 X1Y12&(11 1

^*(+

1

4