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Two case studies of N2O measurements by eddy covariance during field campaigns: data analysis and uncertainty sources.

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HAL Id: hal-02738941

https://hal.inrae.fr/hal-02738941

Submitted on 2 Jun 2020

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Two case studies of N2O measurements by eddy covariance during field campaigns: data analysis and

uncertainty sources.

Agnès Grossel, Jordan Bureau, Benjamin Loubet, Patricia Laville, Raia Silvia Massad, Catherine Hénault

To cite this version:

Agnès Grossel, Jordan Bureau, Benjamin Loubet, Patricia Laville, Raia Silvia Massad, et al.. Two case studies of N2O measurements by eddy covariance during field campaigns: data analysis and uncertainty sources.. InGOS International Conference, final meeting. Non–CO2 Greenhouse Gases, Sep 2015, Utrecht, Netherlands. 2015. �hal-02738941�

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2  case  studies  of  N2O  measurements  by  eddy  covariance  during  field  campaigns:  data   analysis  and  uncertainty  sources.  

Agnès  Grossel  a,  Jordan  Bureau  a,  Benjamin  Loubet  b,  Patricia  Laville  b,  Raia  Massad  b,  and   Catherine  Hénault  a    

aINRA,  UR  0272  Science  du  sol,  Centre  de  recherche  d’Orléans,  CS  40001  Ardon,  45075  Orléans  cedex   (France)  

bINRA,  UMR  EcoSys,  F-­‐  78850  Thiverval-­‐Grignon  (France).  

 

Evaluations  of  N2O  fluxes  by  the  eddy  covariance  method  remain  challenging  because  of  the   high   sensitivity   and   high   frequency   required   in   N2O   concentration   measurements.   Two   datasets  from  different  field  campaigns  with  the  same  QCL  gas  analyzer  measuring  N2O,  H2O   and  CH4  by  absorption  spectroscopy  (Aerodyne  Research  Inc.)  were  compared  with  the  focus   on  signal  quality  control  and  flux  error  analysis.  The  first  dataset  was  recorded  from  6  to  27   June   2013   with   a   2   m   high   mast   over   fertilized   grasslands,   during   the   inter-­‐comparison   INGOS   campaign   for   N2O   flux   measurements   at   Easter   Bush   (Edinburgh,   UK).   The   second   dataset  was  recorded  from  1  April  to  18  May  2015  with  a  15  m  high  mast  within  a  cropped   area   mainly   dedicated   to   cereals   and   rapeseed   crops   in   Centre   France.   Both   campaigns   enabled   to   capture   emissions   following   fertilizations.     Offset   drifts   on   the   raw   N2O   mixing   ratio  signal  were  observed  during  the  second  campaign  probably  because  the  gas  analyzer   was  housed  in  a  simple  vented  box  which  could  not  fully  dampen  temperature  variations.  

Oppositely   no   drift   was   observed   during   the   first   campaign.   We   used   a   recursive   running   mean  filter  on  raw  signal  (Mamarella  et  al.  2010)  and  the  time  constant  needed  for  the  filter   was  determined  using  Allan  variance  analysis.  By  this  way,  the  artificial  fluctuations  of  the   estimated  flux  due  to  raw  signal  drift  were  successfully  eliminated.  

 

Mammarella, I., Werle, P., Pihlatie, M., Eugster, W., Haapanala, S., Kiese, R., ... & Vesala, T.

(2010). Biogeosciences, 7(2), 427-440.

 

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