• Aucun résultat trouvé

Sealing of joints in construction

N/A
N/A
Protected

Academic year: 2021

Partager "Sealing of joints in construction"

Copied!
26
0
0

Texte intégral

(1)

Publisher’s version / Version de l'éditeur:

Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n’arrivez pas à les repérer, communiquez avec nous à PublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca.

Questions? Contact the NRC Publications Archive team at

PublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. If you wish to email the authors directly, please see the first page of the publication for their contact information.

https://publications-cnrc.canada.ca/fra/droits

L’accès à ce site Web et l’utilisation de son contenu sont assujettis aux conditions présentées dans le site

LISEZ CES CONDITIONS ATTENTIVEMENT AVANT D’UTILISER CE SITE WEB.

Technical Translation (National Research Council of Canada), 1970

READ THESE TERMS AND CONDITIONS CAREFULLY BEFORE USING THIS WEBSITE.

https://nrc-publications.canada.ca/eng/copyright

NRC Publications Archive Record / Notice des Archives des publications du CNRC :

https://nrc-publications.canada.ca/eng/view/object/?id=3480eef4-17f0-4912-acd9-9d48429f4791

https://publications-cnrc.canada.ca/fra/voir/objet/?id=3480eef4-17f0-4912-acd9-9d48429f4791

NRC Publications Archive

Archives des publications du CNRC

For the publisher’s version, please access the DOI link below./ Pour consulter la version de l’éditeur, utilisez le lien DOI ci-dessous.

https://doi.org/10.4224/20359156

Access and use of this website and the material on it are subject to the Terms and Conditions set forth at

Sealing of joints in construction

Walter, A. H.; National Research Council of Canada. Division of Building

Research

(2)

P R E F A C E

T h e development of industrialized building s y s t e m s in Europe

h a s g r e a t l y i n c r e a s e d the u s e of prefabricated wall e l e m e n t s . This

development h a s not been without i t s p r o b l e m s and one that h a s r e -

sulted in extensive investigation i s the sealing of the joints between

l a r g e wall components. Traditional m a t e r i a l s w e r e not able t o

withstand t h e s t r e s s e s imposed by dimensional changes in t h e panels

after prolonged exposure t o the weather.

T o overcome t h i s problem a number of s e a l a n t s of different

types have been introduced

to

provide the r e q u i r e d s e r v i c e life and

much attention h a s been given t o the design of the joint and t h e b e s t

configuration of the sealant.

This t r a n s l a t i o n d e s c r i b e s the various s e a l a n t s that a r e now

available in Sweden and the way in which they should be u s e d for

maximum s e r v i c e life. S e v e r a l c a s e h i s t o r i e s a r e included t o i l l u s -

t r a t e t h e r e s u l t s of i m p r o p e r joint design.

With the introduction of new building s y s t e m s in Canada,

many of which u s e l a r g e p r e c a s t c o n c r e t e e l e m e n t s , t h e Division of

Building R e s e a r c h h a s a keen i n t e r e s t in s t a t e - o f - t h e - a r t r e p o r t s

s u c h a s t h i s paper by Alexander H. Walter of Malm6, Sweden.

T h e Division wishes t o thank M r . D. A. S i n c l a i r , National

Science L i b r a r y , National R e s e a r c h Council of Canada, for t r a n s l a t i n g

t h i s paper and M r .

G. H.

Kuester of this Division who checked t h e

t r a n s l a t i o n .

Ottawa

M a r c h 1970

N. B. Hutcheon

D i r e c t o r .

(3)

NATIONAL RESEARCH COUNCIL OF C A N A D A T e c h n i c a 1 T r a n s l a t i o n

1 4

10 T i t l e : S e a l i n g o f j o i n t s i n c o n s t r u c t i o n ( V e r s i e g e l u n g von Fugen am B a u ) A u t h o r : A l e x a n d e r H . W a l t e r R e f e r e n c e : B a u w e l t , 60 ( 2 ) : 6 0 - 6 5 , 1969 T r a n s a l t o r : D . A . S i n c l a i r , T r a n s l a t i o n s S e c t i o n , N a t i o n a l S c i e n c e L i b r a r y

(4)

SElALING O F JOINTS IN CONSTRUCTION

T h e sealing of expansion joints h a s become m o r e and m o r e important in p r e c a s t construction i n r e c e n t y e a r s . At t h e begin- ning of t h e 50's t h e s e p r o b l e m s w e r e given l e s s attention and b u i l d e r s w e r e s a t i s f i e d with t h e application of t r a d i t i o n a l jointing p l a s t e r , o r pos,sibly p l a s t i c jointing s u b s t a n c e s . About 1955 a change began t o t a k e p l a c e in t h e qualitative choice of s e a l i n g m a t e r i a l s , a s a consequence of n u m e r o u s f a i l u r e s .

1. F o r e w o r d

A s a r e s u l t of e x p e r i e n c e in t h e a i r c r a f t and shipbuilding i n d u s t r i e s , w h e r e the s e a l i n g of joints had become a m a t t e r of vital i m p o r t a n c e , s e a l i n g m a t e r i a l s with s o - c a l l e d e l a s t i c p r o p e r t i e s , despite t h e i r c o m p a r a t i v e l y high p r i c e , began t o b e u s e d m o r e and m o r e . Although t h i s m a d e p o s s i b l e g r e a t e r s a f e t y in the s e a l i n g of joints, it was n e v e r t h e l e s s found t h a t t h e attainment of t h i s goal depends not only on t h e a p p l i c a - tion of a n excellent s e a l i n g m a t e r i a l , but a l s o on o t h e r i m p o r t a n t f a c t o r s .

T h e specific p r o p e r t i e s of t h e s e a l i n g m a t e r i a l , t h e design and moving function of t h e joint unit, t h e s u r f a c e quality of t h e edges of t h e joints, the n a t u r e and m a n n e r of application and a knowledge of the s t r e s s e s t o which t h e s e a l i n g m a t e r i a l is s u b j e c t e d in t h e joint, constitute a single complex within which a s a t i s f a c t o r y solution t o each s e p a r a t e p r o b l e m m u s t be found.

In what follows, a s u r v e y of t h e e n t i r e question will be made. We s h a l l devote o u r s e l v e s m a i n l y t o a d e s c r i p t i o n of solutions which h a v e led t o s a t i s f a c t o r y p r a c t i c a l r e s u l t s . T h i s does not m e a n , however, t h a t other solutions might not lead t o equally good o r even b e t t e r r e s u l t s . T h e l i m i t e d m e a s u r a b i l i t y of t h e quality of a joint s i m p l y does not p e r m i t t h e value o r t h e quality t o be e x p r e s s e d in definite f i g u r e s ; one m u s t build on e x p e r i e n c e and r e l y on s a f e solutions.

F r o m t h e author's point of view, of c o u r s e , t h e p r o p e r t i e s of t h e s e a l i n g m a t e - r i a l s constitute t h e c e n t r a l p r o b l e m . I m u s t point out, however, that t h e b e s t of m a t e - r i a l s will f a i l if t h e joint itself i s badly designed and t h e r e q u i r e m e n t s of good w o r k - manship a r e neglected. H e r e , a s in m o s t advanced technological f i e l d s , i t is n e c e s s a r y f o r d e s i g n e r s , c h e m i s t s and j o i n t e r s t o c o o p e r a t e in a logical m a n n e r .

(5)

T h e r e i s a n o t h e r d i s c o v e r y t h a t s e e m s t o b e i m p o r t a n t , n a m e l y t h a t i n t h e c h e m i c a l d e s c r i p t i o n of p r o d u c t s it is g e n e r a l l y n e c e s s a r y t o d i v i d e t h e n ] i n t o d i f f e r e n t c l a s s e s a c c o r d i n g t o t y p e . F o r e x a m p l e , we t a l k of p o l y s u l p h i d e , a c r y l a t e , s i l i c o n a n d butyl m a t e r i a l s , o r t h e s e a l i n g m a t e r i a l s a r e d i v i d e d i n t o p r o d u c t s with e l a s t i c o r p l a s

-

t i c p r o p e r t i e s . T h i s c l a s s i f i c a t i o n , e s p e c i a l l y w h e n i t c o n t r i b u t e s t o a q u a l i t a t i v e i d e n t i f i c a t i o n , m a y e a s i l y l e a d t o e r r o n e o u s r e s u l t s . Within e a c h c l a s s t h e r e a r e p r o - d u c t s w i t h q u a l i t a t i v e l y d i f f e r e n t p r o p e r t i e s and t h e s e a r e t h e n u s e d , g e n e r a l l y s p e a k i n g , f o r d i f f e r e n t a p p l i c a t i o n s , o r t h e r e a r e d i f f e r e n c e s f r o m t h e s t a n d p o i n t of e c o n o m y . J u s t a s t h e r e a r e p o l y s u l p h i d e m a t e r i a l s which c a n n o t b e r e c o n ~ n ~ e n d e d f o r t h e s e a l i n g of j o i n t s in p r e c a s t c o n s t r u c t i o n , s o t h e r e a r e butyl m a t e r i a l s w h i c h i n c e r t a i n c a s e s I n a y g i v e v e r y s a t i s f a c t o r y r e s u l t s . T h e u n a v o i d a b l e c l a s s i f i c a t i o n [ n u s t t h e r e - f o r e b e r e f e r r e d t o t h e a c t u a l f i e l d of a p p l i c a t i o n . T h e r e f o r e , when I m e n t i o n t h e u s e f u l n e s s o r t h e l i n ~ i t e d a p p l i c a b i l i t y of c e r t a i n c l a s s e s , t h i s a p p l i e s s o l e l y t o t h e s e a l i n g of e x p a n s i o n j o i n t s in ~ ) l . t ~ c . , ~ s t c o n s t r c ~ c t ion and it i s a s s u m e d , m o r e o v e r , t h a t t h e s p e c i f i c p r o d u c t of t h i s c l a s s which i s m e n t i o n e d i s s u i t e d t o t h e s p e c l a 1 r e q u i r e n ~ e n t s of t h i s a p p l i c a t i o n . T h e s t a t e m e n t s m a d e i n t h i s c o n n e c t i o n a r e b a s e d on t h e k n o w l e d g e t h a t h a s b e e n d e r i v e d p r i m a r i l y f r o n ~ p r a c t i c a l e x p e r i e n c e . 2. T h e d e s i g n of t h e joint F i g u r e 1 s h o w s t h e c o r r e c t d e s i g n of a n e x p a n s i o n joint. A c c o r d i n g l y , i t c o m p r i s e s t w o s t r u c t u r a l c:lenlents a d j a c e n t t o o n e a n o t h e r . T h e s p a n b e t w e e n t h e s t r u c t u r a l u n i t s i s c a l l e d t h e a n ~ p l i t u c l e ( o r width) of t h e joint. T h e joint i s p a r t i a l l y f i l l e d by t h e s e a l i n g m a t e r i a l .

2. 1 S p a n of t h e joint

T h e ~ n a x i r i i u n ~ s p a n is t o b e c h o s e n on t h e b a s i s of two e s s e n t i a l p o i n t s of view: on t h e o n e h a n d t h e jolnt I T I L L S ~ be w i d e enough t o g i v e t h e a d j a c e n t building corr>l>onents

s u f f i c i e n t r o o m s o a s t o be ; ~ b l e t o f r e e l y a b s o r b a n y c h a n g e s of s i z e t h a t n l a y r e s u l t f r o m t h e r m a 1, clitmatic o r a g i n g c o n d i t i o n s . T h i s i n v o l v e s n o t o n l y c o n t r a c t i v e a n d e x p a n s i v e m o t i o n s , but a l s o s h e a r i n g m o t i o n s . T h e l a t t e r o c c u r e s p e c i a l l y when t h e a d j a c e n t p r e c a s t p a r t s ( 2 ) a r e of d i f f e r e n t m a t e r i a l s ( e . g. , c o n c r e t e and s t e e l ) . T h e a n ~ p l i t u d e of t h e m o t i o n s d e p e n d s l a r g e l y on t h e s i z e of t h e building e l e m e n t ; ~ n d t h e t 6 1 r i p e r a t u l - ~ : graclient, and v a r i e s I,etween

+

2. 5 r r i r r ) .

(6)

Another f a c t o r d e t e r m i n i n g the s p a n of t h e joint i s d e r i v e d f r o m t h e conditions of application and t h e subsequent functioning of the s e a l i n g m a t e r i a l . P r a c t i c e h a s shown t h a t placing i s difficult w h e r e s p a n s a r e l e s s than 10 m m and u n s a t i s f a c t o r y if t h e y a r e

l e s s than 5 m m . T h e r e a s o n s for t h i s will be t a k e n up l a t e r ( 3 ) .

Finally, s t u d i e s of placing technique show t h a t t h e o u t e r edge of t h e joint ought t o be r e c e s s e d in the f a c a d e plane, b e c a u s e in t h i s way t h e jointing o p e r a t i o n gives a r e l i a b l e r e s u l t .

2. 2 T h e c h a r a c t e r of t h e edge of the joint

Another i m p o r t a n t condition i s the c h a r a c t e r of the edge of t h e joint, which s e r v e s a s an a d h e r i n g s u r f a c e for t h e s e a l i n g m a t e r i a l . Not only m u s t i t be d r y , dust f r e e and c l e a n , but t h e r e should be no m a j o r i r r e g u l a r i t i e s due t o b a l l a s t m a t e r i a l , d a m a g e o r porosity. Not only i s t h i s d e t r i m e n t a l t o adhesion, but l e a d s d i r e c t l y t o l e a k s (4).

We r e c e n t l y o b s e r v e d in v a r i o u s c a s e s that t h e b a l l a s t m a t e r i a l w a s exposed even a t t h e edges of t h e joint. Such joint edges a r e t o t a l l y u n s a t i s f a c t o r y . T h e y m u s t f i r s t b e smoothed by grinding, o r a t l e a s t levelled off with a high quality p l a s t i c t r o w e l b e f o r e t h e s e a l i n g o p e r a t i o n s a r e begun. We s h a l l h a v e m o r e t o s a y about t h i s in

connection with i n s t a n c e s of damage.

3. P l a s t i c o r e l a s t i c s e a l i n g m a t e r i a l s

Whether an e l a s t i c o r p l a s t i c s e a l i n g m a t e r i a l should be c h o s e n h a s been a m a t t e r of dispute for y e a r s . Any final a n s w e r t o t h i s question i s p r o b a b l y i m p o s s i b l e , b e c a u s e t h e multiplicity and non-uniformity of t h e influences acting on t h e joint a r e n e i t h e r physically nor technologically controllable. T h i s applies p a r t i c u l a r l y t o the p e r i o d i c motions of t h e joints and t h e c l i m a t i c s t r e s s e s , and a l s o t o t h e c o m p l e x i t y of the p r o p e r t i e s of t h e s e a l i n g m a t e r i a l , i. e.

,

mixed p l a s t i c i t y and e l a s t i c i t y , h a r d n e s s , p r o f i l e of t h e joint m a t e r i a l o r deformability.

Once one h a s b e c o m e f a i r l y well acquainted with t h e b a s i c r u l e s by m u c h r e f l e c t i o n and experimenting, it i s then b e t t e r to m a k e u s e of one's e x p e r i e n c e and choose a s e a l i n g m a t e r i a l f o r the m o s t p a r t accordingly. In t h e c o u r s e of t h i s , one will h a v e l e a r n e d that s e a l i n g m a t e r i a l s with q u a s i - e l a s t i c t e r m i n a l p r o p e r t i e s h a v e d e f i - nitely given by f a r the b e t t e r r e s u l t . T h e p r i n c i p a l r e a s o n s for t h i s would s e e m to be t h e r e v e r s i b i l i t y of s t r a i n of t h e e l a s t i c m a t e r i a l in t h e p r e s e n c e of a l t e r n a t i n g s t r e s s e s .

(7)

3. 1 Functional differences between p l a s t i c i t y and e l a s t i c i t y

The scope of t h e p r e s e n t paper does not p e r m i t a detailed exposition of t h e s e important questions, although it would contribute g r e a t l y t o an understanding of t h e problem of joints. However, I should like t o m a k e one o r two brief s t a t e m e n t s on t h e

subject of e l a s t i c i t y v e r s u s plasticity:

a) P l a s t i c m a t e r i a l s , owing to the i r r e v e r s i b i l i t y of t h e i r s t r a i n p r o p e r t i e s tend to form wrinkles a s a consequence of joint motion, and i n the hollows of t h e s e wrinkles incipient f r a c t u r e s m a y appear a s a r e s u l t of f u r t h e r alternating s t r e s s (5).

b) Ln p l a s t i c m a t e r i a l s s t r a i n phenomena a r e concentrated a t t h e n a r r o w e s t point in the joint profile, t h i s can a l s o lead locally t o incipient f r a c t u r e s

( 6 ) .

c) The deformability of p l a s t i c m a t e r i a l s in m o s t c a s e s depends strongly on t h e t e m p e r a t u r e , i. e.

,

t h e m a t e r i a l s become m o r e rigid at low t e m p e r a t u r e s (7).

d) Ln p l a s t i c m a t e r i a l s , slow deformation lead to a relaxation of t h e physi- cally bound molecular entanglements. T h i s , too, l e a d s t o l o c a l f r a c t u r e phenomena.

e) Mixed p l a s t i c - e l a s t i c m a t e r i a l s , owing to the e l a s t i c components exhibit an i n t e r n a l s t a t e of s t r e s s a s a r e s u l t of t h e deformation, which in t h e c o u r s e of t i m e i s t r a n s m i t t e d to the plastic component in t h e f o r m of local expansions. Within a c r i t i c a l region t h e quantity of the plastic component i s too s m a l l t o a b s o r b t h e expan- sions; f r a c t u r e phenomena a r e t h e r e s u l t (8).

4. E l a s t i c sealinn m a t e r i a l s

Among t h e e l a s t i c sealing m a t e r i a l s available on the m a r k e t t h o s e employing a so-called polysulphide b a s e

-

often a l s o known by t h e t r a d e n a m e "Thiokol"

-

hold a dominant position. Polysulphides a r e thickly liquid, organic sulphur compounds which have t h e p r o p e r t y of r e a c t i n g at r o o m t e m p e r a t u r e with s o - c a l l e d peroxide

-

e.

g.

,

lead dioxide

-

to f o r m solid, r u b b e r -like end products. However, t h e d e g r e e of e l a s t i c i t y cannot b e c o m p a r e d with that of vulcanized r u b b e r . On t h e c o n t r a r y , such m a t e r i a l s have a comparatively high p l a s t i c component, which under long t e r m s t r e s s e s r e s u l t s in t h e "cold flow" phenomenon.

4. 1 Various types of sealing m a t e r i a l s

Ln

addition to polysulphide m a t e r i a l s we m a y mention sealing m a t e r i a l s uging a bonding agent b a s e of silicon r u b b e r and urethane r u b b e r and a l s o a b a s e of

(8)

a c r y l a t e r e s i n . At p r e s e n t , a p p l i c a t i o n s of t h e s e t y p e s a r e s t i l l s e v e r e l y l i m i t e d f o r t e c h n i c a l r e a s o n s , and t o s o m e extent f o r economlc r e a s o n s a s well; t h i s i s not t o s a y t h a t t h e y cannot gain a g r e a t e r s h a r e of t h e m a r k e t a f t e r s u i t a b l e modification.

Silicon m a t e r i a l s c o n s i s t of a thickly liquid p a s t e which r e a c t s with t h e a i r t o give a highly e l a s t i c m a t e r i a l . T h e m a t e r i a l t h u s h a s only one component. Depending on t h e r e a c t i o n m e c h a n i s m , i t m u s t a l w a y s b e well s e a l e d in i t s packing in o r d e r t o b e c o n s e r v e d f o r u s e .

I t s adhesion p r o p e r t i e s , even in t h e p r e s e n c e of m o i s t u r e and w a t e r , and i t s s t a b i l i t y with r e s p e c t t o t i m e , t e m p e r a t u r e and c h e m i c a l r e a c t i v i t y a r e e x c e l l e n t . T h e h a r d e n i n g t i m e i s not only long and u n r e s p o n s i v e t o t r e a t m e n t , but a l s o depends on t h e t h i c k n e s s of t h e m a t e r i a l applied. T h e m a i n r e a s o n f o r t h e l i m i t e d application of s i - licon m a t e r i a l s c o n s i s t s , however, in t h e i r high p r i c e , which a t p r e s e n t i s m o r e t h a n

50% g r e a t e r than t h a t of t h e polysulphide m a t e r i a l s , which a r e a l r e a d y v e r y expensive. F o r n a r r o w joints which c o n s u m e l i t t l e m a t e r i a l , e. g. , t h e s e a l i n g of i n s u - lating g l a s s windows o r s a n i t a r y equipment, however, t h e s e m a t e r i a l s a r e finding e v e r i n c r e a s i n g application.

T h e u r e t h a n e m a t e r i a l s , l i k e t h e polysulphide m a t e r i a l s , c o n s i s t of two components which m u s t b e mixed in a p r e d e t e r m i n e d r a t i o p r i o r t o application. Not only do t h e y h a v e advantageous t e r m i n a l p r o p e r t i e s , but t h e y a r e a l s o c h e a p e r t h a n t h e polysulphide m a t e r i a l s . T h e i r l i m i t e d application i s due t o t h e f a c t t h a t d u r i n g r e a c t i o n of t h e c o m p o n e n t s they a r e e x t r e m e l y s e n s i t i v e t o v e r y s m a l l q u a n t i t i e s of m o i s t u r e and t e n d t o bubble s e v e r e l y ( 9 ) . D e s p i t e e x t e n s i v e r e s e a r c h and development work, which h a s been going on m o r e than a decade, t h e s e difficulties h a v e not yet been o v e r c o m e , s o that t h e few p r o d u c t s a v a i l a b l e on t h e m a r k e t h a v e not yet been a b l e t o c a p t u r e a significant p a r t of it.

F i n a l l y , t h e r e a r e t h e a c r y l a t e m a t e r i a l s . T h e s e a r e a c t u a l l y of a p l a s t i c n a t u r e , but h a v e an a p p r e c i a b l e e l a s t i c component. T h e y c o n s i s t of a m i x t u r e of

a c r y l a t e r e s i n s , p l a s t i c i z e r s , s o l v e n t s and f i l l e r s . S i n c e t h e m a t e r i a l s , which c o m e in a s i n g l e component, h a v e a c o n s i s t e n c y a t r o o m t e m p e r a t u r e which i s too stiff f o r p l a c i n g with a caulking gun, t h e y m u s t b e h e a t e d b e f o r e application t o about 60°C.

In t h e i r t e r m i n a l p r o p e r t i e s t h e y show good adhesion (in m o s t c a s e s without t h e u s e of a p r i m e r , ) and good c l i m a t i c aging s t a b i l i t y . A f t e r evaporation of the

6

-

8% content of s o l v e n t , they s t i f f e n t o s o m e extent a f t e r a t i m e . However, t h e y a r e s e n s i t i v e t o m o i s t u r e and w a t e r , e s p e c i a l l y t h e l a t t e r when i t i s alkaline. M o r e o v e r

(9)

in place the m a t e r i a l s a r e unstable with r e s p e c t t o t e m p e r a t u r e , i. e.

,

at low t e m p e r a - t u r e they become very hard. F o r this r e a s o n the Laboratory of t h e Swedish Lightweight Concrete Industry has advised against t h e u s e of a c r y l a t e m a t e r i a l s in conjunction with p a r t s c a s t in a e r a t e d concrete. The basis for t h i s recommendation i s the alternating s t r e s s t e s t whose r e s u l t s a r e shown in F i g u r e 10; it i s found that the a c r y l a t e m a t e r i a l s have excellent p r o p e r t i e s at t e m p e r a t u r e s of 20°C, but fail completely at lower t e m p e r a - t u r e s .

I should not like t o close t h e s e r e m a r k s on t h e different types of sealing m a t e - r i a l s without mentioning again the limited classifiability of chemical industrial products and emphasizing that their development is s t i l l in mid-course.

4. 2 Sealing with rubber o r plastic profiles

The sealing of joints in p r e c a s t construction with sealing m a t e r i a l s that m u s t be placed by hand i s diametrically opposed t o t h e basic idea of this method of c o n s t r u c - tion. Hence, the u s e of profiled sealing s t r i p s which can be i n s e r t e d into the joints

appears obvious. We can d i s c e r n t h r e e different f o r m s of technical solutions h e r e (1 1):

a) A subsequently i n s e r t e d sealing profile equivalent in its effect t o a sealing m a t e r i a l ;

b) A sealing s t r i p that prevents most of the m o i s t u r e f r o m penetrating into the joint, but r e q u i r e s additional sealing behind it;

c ) Sealing profiles which can be poured directly into the edges of the joint during casting of t h e p a r t s and a r e then coupled together during a s s e m b l y of the s t r u c t u r a l units.

None of t h e s e units have a s yet been fully applied. The main r e a s o n for t h i s would appear t o be the fact that t h e requirements with r e s p e c t t o dimensional t o l e r a n c e and accuracy execution of t h e edges of the joint a r e s o high that they a r e no longer

feasible. However, anyone who has studied the publication i s s u e d f r o m the CIB Congress in Oslo in September 1967 will understand that developments of p r a c t i c a l importance in this direction may be expected.

4. 3 The polysulphide or Thiokol m a t e r i a l s

The polysulphide m a t e r i a l s , in most c a s e s , consist of two components, one of which c o m p r i s e s a mixture of polysulphide, r e s i n , p l a s t i c i z e r s and pigments, while the other contains additional p l a s t i c i z e r s a s well a s t h e peroxide. The latter compo- nent is called the h a r d e n e r .

(10)

T h e r e a c t i o n r a t e c a n be c o n t r o l l e d within c e r t a i n l i m i t s by t h e u s e of a c c e l e r

-

ating o r r e t a r d i n g a d d i t i v e s . A f t e r c a r e f u l m i x i n g of t h e c o m p o n e n t s a r e a c t i o n s e t s in and i t i s t h e n n e c e s s a r y t o d i s t i n g u i s h between t h e pot l i f e , within which t h e m a t e r i a l m u s t b e applied, and t h e c u r i n g t i m e , which t e r m i n a t e s with t h e s o l i d i f i c a t i o n of t h e m a t e r i a l . P o t life and c u r i n g t i m e a r e p r o p o r t i o n a l . T h e c u r i n g t i m e i s about 40

-

50 t i m e s a s long a s t h e pot life. T a b l e I s h o w s t h e m e a s u r e d v a l u e s f r o m v a r i o u s c o m m e r

-

cia1 p r o d u c t s .

T h e d e g r e e of e l a s t i c s t r e n g t h o r r e s i s t a n c e t o d e f o r m a t i o n i s m e a s u r e d by d e t e r m i n i n g t h e h a r d n e s s i n S h o r e A - d e g r e e s . S u i t a b l e v a l u e s f o r polysulphide m a t e r i a l s in p r e c a s t c o n s t r u c t i o n a r e 10

-

25 S h o r e A at 2 0 ° C .

T h e h a r d n e s s depends on t e m p e r a t u r e and i n c r e a s e s with d e c r e a s i n g t e m p e r a - t u r e . T h e r e s i s t a n c e t o d e f o r m a t i o n i n c r e a s e s s i m u l t a n e o u s l y . T h i s i s an i m p o r t a n t point, s i n c e t h e g r e a t e s t s t r e s s e s in t h e joint m a y b e expected t o o c c u r at low t e m p e r a - t u r e s . F o r l a r g e expansion v a l u e s in t h e joint, t h e r e f o r e , t h e a p p l i c a t i o n of a m a t e r i a l with a low S h o r e A v a l u e i s r e c o m m e n d e d . Of c o u r s e , g e n e r a l l y s p e a k i n g , t h e p l a s t i c component i n c r e a s e s a c c o r d i n g l y (12). T h e r e s i s t a n c e t o d e f o r m a t i o n b e a r s a n i m p o r t a n t r e l a t i o n s h i p t o t h e a d h e s i o n , i. e . , t h e d e f o r m a t i o n f o r c e f o r m a x i m u m expansion m u s t a l w a y s b e l e s s t h a n t h e a d h e - s i v e f o r c e . O t h e r w i s e , a definite l o s s of a d h e s i o n w i l l o c c u r . F o r r e a s o n s of s a f e t y , t h e r e f o r e , it i s always a d v i s a b l e t o apply a n a d h e s i o n - i m p r o v i n g b a s e c o a t ( o r s o - c a l l e d p r i m e r ) t o t h e e d g e s of t h e joint b e f o r e u n d e r t a k i n g t o s e a l it. At t h e s a m e t i m e , d u s t i s r e m o v e d and i n s u l a t i o n a g a i n s t m o i s t u r e and a l k a l i n e a c t i o n i s a t t a i n e d . Excellent a d h e s i v e c o a t s , s u i t a b l e f o r v a r i o u s jointing m a t e r i a l s , a r e f u r n i s h e d by t h e r e s p e c t i v e m a n u f a c t u r e r s .

5. T h e c o r r e c t p r o f i l e of t h e s e a l i n g m a t e r i a l i n t h e joints

R e l i a b l e functioning of a s e a l depends not only on t h e p r o p e r t i e s of t h e s e a l i n g m a t e r i a l s . T h e p r o f i l e of t h e joint i s a l s o of d e c i s i v e i m p o r t a n c e . T h e a i m h e r e i s t o get a m i n i m u m d e f o r m i n g f o r c e with a m a x i m u m expansion, and m a x i m u m a d h e r i n g s u r f a c e .

On t h e b a s i s of p r a c t i c a l e x p e r i e n c e and e x p e r i m e n t a l i n v e s t i g a t i o n s t h e c o n - c l u s i o n h a s b e e n r e a c h e d t h a t t h e m o s t f a v o u r a b l e r e s u l t s a r e obtained f r o m a double- c o n c a v e p r o f i l e . T h e depth a t t h e e d g e of t h e joint should b e about h a l f t h e s p a n and i n t h e c e n t r e t h e joint p r o f i l e should be r e d u c e d to about 2 / 3 of t h e depth ( 1 3 ) . I n t h e S w e d i s h Building S p e c i f i c a t i o n Bygg

-

AMA 1965 t h i s w a s e x p r e s s e d in t h e f o r m u l a

(11)

( t K = depth of t h e edge of t h e joint; b = span), and f o r p r a c t i c a l r e a s o n s , a s well, i t

w a s s t a t e d a s a l i m i t i n g condition t h a t t h e depth i n t h e c e n t r e should not b e l e s s t h a n 4 m m . In p r a c t i c e t h i s r e q u i r e m e n t i s m e t by injecting a round b a s e filling

-

c o n s i s t i n g for example, of a s t r i p of c e l l u l a r r u b b e r with c l o s e d p o r e s b e f o r e placing the s e a l i n g m a t e r i a l . In t h i s way a round p r o f i l e i s obtained at t h e b a c k of t h e s e a l i n g m a t e r i a l . T h e o u t s i d e f a c e i s molded into t h e p r o p e r f o r m b e f o r e h a r d e n i n g with t h e aid of a s u i t a b l y s h a p e d t r o w e l .

So that t h e s e a l i n g m a t e r i a l c a n p e n e t r a t e deeply into t h e a n g u l a r s p a c e between t h e joint e d g e s and t h e round b a s e filling, in o r d e r t o a c h i e v e t h e r e q u i r e d wetting and

adhesion, it i s a d v i s a b l e t o i n s e r t t h e mouth p i e c e of t h e caulking gun deeply into t h e joint s o t h a t t h e l a t t e r i s f i l l e d with m a t e r i a l t o s o m e extent f r o m below.

6 .

Execution of iointing

P r o p e r jointing i s t h u s c a r r i e d out a s follows:

a ) Cleaning of joint e d g e s . T h e s e m u s t b e f r e e of m o i s t u r e , g r e a s e , o i l and dust;

b) TrowelLingoff of i r r e g u l a r i t i e s , i n j u r i e s o r p o r e s a t t h e e d g e s of t h e joint with a n epoxy t r o w e l ;

c ) P l a c i n g of t h e b a s e f i l l i n g , taking c a r e t o m a i n t a i n a u n i f o r m depth; d) Application of a d h e s i v e ground coat. M a t e r i a l c h o s e n a c c o r d i n g t o r e c o m m e n d a t i o n of t h e s e a l i n g m a t e r i a l s u p p l i e r ;

e) Application of s e a l i n g m a t e r i a l .

f) Smoothing and p r o f i l i n g of t h e s u r f a c e of t h e u n h a r d e n e d m a t e r i a l u s i n g a s p e c i a l t r o w e l m o i s t e n e d with s o a p y w a t e r .

In what follows we s h a l l d e a l with two o t h e r i m p o r t a n t a u x i l i a r y p r o b l e m s of s e a l i n g technique, t h e c o n s i d e r a t i o n of which i s of g r e a t i m p o r t a n c e f o r t h e a c h i e v e m e n t of a s a t i s f a c t o r y f i n a l r e s u l t . Both p r o b l e m s a r e e x t r e m e l y complex: s e v e r a l p r o p e r t i e s and r e q u i r e m e n t s a r e c l o s e l y linked and i t i s n e c e s s a r y t o s t u d y t h e s e q u e s t i o n s i n o r d e r t o get an a c c u r a t e p i c t u r e of t h e conditions.

(12)

7. 1 Adhesion of the sealing m a t e r i a l t o the edge of the ioint

7. 1. 1 Conditions for s e c u r i n g an adhesion

T h e s e c u r i n g and t h e d e g r e e of m e c h a n i c a l adhesion obtained between two solid m a t e r i a l s a s s u m e s not only that t h e m a t e r i a l s have "adhesion affinity" t o each o t h e r , but that a) a t l e a s t one of t h e s u b s t a n c e s c o m e s i n liquid f o r m and b) t h e liquid substance (i. e , t h e sealing m a t e r i a l at the t i m e of application) is capable of wetting t h e solid s u p p o r t (i. e, t h e edge of t h e joint).

Thus adhesion a s s u m e s a wetting p r o c e s s . F o r t h i s t h e following fundamental r u l e s hold:

a) Highly viscous, i. e . , thickly liquid s u b s t a n c e s , h a v e p o o r e r wetting p r o p e r t i e s than thinly liquid s u b s t a n c e s of a s i m i l a r n a t u r e .

b) T h e d e g r e e of wetting depends on the p h y s i c a l c h a r a c t e r of t h e s u r f a c e of t h e solid m a t e r i a l . C o a r s e s u r f a c e s a r e m o r e difficult t o wet.

c ) T h e extent of wetting depends on t h e t i m e , i. e.

,

t h e wetting is i m p r o v e d i f t h e r e i s a long r e a c t i o n t i m e .

7. 1. 2. T h e influence of t h e v i s c o s i t y of t h e s e a l i n g m a t e r i a l on wetting and adhesion

T h e p r o p e r adjustment of t h e v i s c o s i t y ( o r consistency) of a s e a l i n g m a t e r i a l i s d e t e r m i n e d by t h r e e mutually counteracting f a c t o r s :

a) A high wetting capacity r e q u i r e s a low viscosity.

b) In o r d e r t o p r e v e n t running down i n the joint a f t e r placing, t h e v i s c o s i t y m u s t be high.

c) Finally, application with t h e caulking gun r e q u i r e s a not too stiff consistency. T h e r e f o r e , in establishing t h e c o n s i s t e n c y of a s e a l i n g m a t e r i a l one i s f o r c e d t o a c o m p r o m i s e between t h e s e different r e q u i r e m e n t s . S a t i s f a c t o r y solutions t o t h i s p r o b l e m have been found in p r a c t i c e .

T h e v i s c o s i t y of a l l o r g a n i c s u b s t a n c e s depends on t h e t e m p e r a t u r e , i. e.

,

t h e m a t e r i a l stiffens p r o g r e s s i v e l y with d e c r e a s i n g t e m p e r a t u r e . At the s a m e t i m e ,

however, t h e conditions for wetting and adhesion a r e i m p a i r e d . F o r t h i s r e a s o n i t is n e c e s s a r y t o b e v e r y c a r e f u l in placing s e a l i n g m a t e r i a l s a t low t e m p e r a t u r e s and it m u s t b e b o r n e in mind that heating the m a t e r i a l will not help g r e a t l y b e c a u s e on contact

(13)

with t h e edge of t h e joint it i s cooled in,nlediately. T h i s e f f e c t i s p a r t i c u l a r l y c l e a r in t h e c a s e of t h e a c r y l a t e m a t e r i a l s which have t o be applied w a r m , b e c a u s e r a p i d cooling r e s u l t s in s o s t r o n g a stiffening that t h e wetting e f f e c t i s quite c o n s i d e r a b l y i m p a i r e d .

Sealing o p e r a t i o n s have been c a r r i e d out in Sweden a t an o u t s i d e t e m p e r a t u r e of - 3 0 ° C with good r e s u l t s . In doing s o , however, t h e joint edges and t h e i r i m m e d i a t e vicinity w e r e s o s t r o n g l y h e a t e d t h a t t h e conditions of a n o r m a l jointing o p e r a t i o n w e r e s a t i s f i e d . In m y view, and t h a t of m o s t of t h e s p e c i a l i s t s , s e a l i n g o p e r a t i o n s ought not t o b e c a r r i e d out a t t e m p e r a t u r e s below t 5 " C u n l e s s it i s p o s s i b l e t o u n d e r t a k e p r o p e r heating of t h e joint units.

During r e a c t i o n of t h e components t h e v i s c o s i t y i n c r e a s e s s t e a d i l y . T h i s i s of no i m p o r t a n c e w h e r e a caulking gun i s used manually, b e c a u s e t h e a v a i l a b l e f o r c e f i x e s a n a t u r a l l i m i t t o t h e applicability. Where c o m p r e s s e d a i r i n j e c t o r s a r e used, however, c o n s i d e r a b l e caution m u s t b e e x e r c i s e d .

T h e wetting p r o c e s s t a k e s a c e r t a i n t i m e . Where n o r m a l pot l i f e of a few h o u r s i s involved, t h i s i s of no i m p o r t a n c e . H o w e v e r , if v e r y r a p i d l y h a r d e n i n g

polysulphide m a t e r i a l s a r e employed, t h e wetting p r o p e r t i e s at t h e joint edges m u s t b e sufficiently favour a b l e s o that t h e wetting p r o c e s s i s concluded b e f o r e t h e c r i t i c a l stiffening of t h e m a t e r i a l s e t s in.

C a r e f u l o b s e r v a n c e of t h e s e p o i n t s , e s p e c i a l l y a t t h e building s i t e , a p p e a r s e x t r e m e l y n e c e s s a r y if s e t - b a c k s a r e t o b e avoided.

7. 1. 3. T h e effect of t h e c h a r a c t e r of t h e joint e d g e s on t h e a d h e s i o n

Wetting a c t u a l l y m e a n s , of c o u r s e , that a liquid s u b s t a n c e i s a b l e t o s p r e a d out o v e r a s o l i d s u p p o r t and in doing s o p e n e t r a t e s into a l l t h e i r r e g u l a r i t i e s . T h e wetting s u r f a c e i s then equal t o t h e a d h e s i v e s u r f a c e and h e n c e p r o p o r t i o n a l t o t h e a d h e s i v e f o r c e .

If t h e s u r f a c e s a r e s m o o t h then t h e m o s t f a v o u r a b l e conditions a r e p r e s e n t f o r good adhesion. I r r e g u l a r i t i e s at t h e joint e d g e s , h o w e v e r , c a n i n t e r f e r e with t h e wetting t o s u c h a n extent that a s a t i s f a c t o r y adhesion i s just not p o s s i b l e even though t h e m a t e r i a l of t h e joint edge and t h e s e a l i n g m a t e r i a l would l e a d u s t o expect f a v o u r a b l e conditions.

Such s i t u a t i o n s a r e s u b s t a n t i a l l y enhanced, of c o u r s e , by t h e low t e m p e r a t u r e e f f e c t s on t h e v i s c o s i t y a l r e a d y mentioned. I s h a l l r e t u r n t o t h e s e points in t h e d i s - c u s s i o n of i n s t a n c e s of d a m a g e .

(14)

7 . 2 O c c u r r e n c e of c o n d e n s a t i o n behind t h e joint

By s e a l i n g t h e joints t h e a i m i s t o p r o t e c t t h e joint in e v e r y r e s p e c t f r o m m o i s t u r e p e n e t r a t i n g f r o m t h e o u t s i d e . At t h e s a m e t i m e , h o w e v e r , t h e joint i s s e a l e d f r o m t h e i n s i d e . If t h e r e a r e no e f f e c t i v e v a p o u r b a r r i e r s on t h e i n s i d e w a l l t h e m o i s - t u r e a r i s i n g i n t h e i n t e r i o r s p a c e s m i g r a t e s in t h e d i r e c t i o n of t h e c o l d s i d e , i. e . ,

outward, and in t h e event of an u n f a v o u r a b l e t e m p e r a t u r e g r a d i e n t in t h e e x t e r n a l w a l l w i l l p r e c i p i t a t e in t h e f o r m of c o n d e n s a t i o n . F o r t h i s c o n d e n s a t i o n , t h e i n t e r i o r s i d e of t h e joint i s e s p e c i a l l y c r i t i c a l , b e c a u s e h e r e t h e t e m p e r a t u r e in g e n e r a l i s c o n s i d e r - a b l y l o w e r t h a n t h e t e m p e r a t u r e a t t h e i n s i d e of t h e e x t e r n a l w a l l . T h i s i s shown in p r i n c i p l e in F i g u r e 14. When joints h a v e l a t e r b e e n opened up, it h a s often b e e n found t h a t t h e f i l l i n g m a t e r i a l behind t h e m , e. g.

,

f o a m p l a s t i c , i s s o a k e d with w a t e r , a n d i t i s often concluded p r e m a t u r e l y t h a t t h e joint h e r e w a s not s e a l e d . I s h o u l d l i k e t o s u g g e s t e m p h a t i c a l l y t h a t in m o s t c a s e s c o n d e n s a t i o n of i n t e r n a l m o i s t u r e i s a c t u a l l y r e s p o n s i b l e .

T h e d a n g e r f r o m t h i s phenomenon i s not s o m u c h t h e i m p a i r m e n t of t h e s e a l i n g f r o m t h e o u t s i d e , s i n c e a c o r r e c t l y e x e c u t e d s e a l with a polysulphide m a t e r i a l should not b e d a m a g e d by c o n d e n s e d m o i s t u r e . T h i s d o e s not apply, h o w e v e r , t o a c r y l a t e m a t e r i a l s , s i n c e t h e s e a r e known t o b e s e n s i t i v e t o m o i s t u r e . T h e d a m a g e i s done r a t h e r t o t h e i n t e r i o r wall, s i n c e with r i s i n g t e m p e r a t u r e t h e c o n d e n s e d m o i s t u r e a g a i n m i g r a t e s i n w a r d and c a n then a c t in c o n c e n t r a t e d f o r m on t h e i n t e r n a l wall.

T h i s s i t u a t i o n c a n b e c o n s i d e r a b l y i m p r o v e d by u s i n g a b a s e f i l l i n g with c l o s e d p o r e s

-

e. g . , c e l l u l a r r u b b e r o r polyethylene f o a m . S i n c e s u c h m a t e r i a l s do not a b s o r b m o i s t u r e , t h e i r good i n s u l a t i o n p r o p e r t i e s a r e r e t a i n e d , s o t h a t t h e t e m - p e r a t u r e g r a d i e n t in t h e joint b e c o m e s m o r e f a v o u r a b l e . In addition, h o w e v e r , c e r t a i n s t r u c t u r a l m e a s u r e s in t h e f o r m of m o i s t u r e b a r r i e r s o r ventilation of t h e i n t e r n a l c a v i t y behind t h e e x t e r n a l f a c a d e should b e applied.

7. 3 T h e e f f e c t s of bubbles in t h e h a r d e n e d s e a l i n g m a t e r i a l

During m a n u f a c t u r i n g o r packaging, and i n t h e c o u r s e of c a r e l e s s m i x i n g of s e a l i n g m a t e r i a l s , t h e a p p e a r a n c e of bubbles i n t h e joint c a n often be o b s e r v e d , and t h e q u e s t i o n i s r a i s e d a g a i n and a g a i n w h e t h e r t h e s e b u b b l e s a r e d e t r i m e n t a l t o t h e

functioning of t h e joint a s a whole.

In o r d e r t o get a n a n s w e r t o t h i s q u e s t i o n , m o d e l s w e r e p r o d u c e d with a r t i f i c i a l bubbling. Bubbles w e r e exposed and l o c a l d e f o r m a t i o n d u r i n g expansion of

(15)

t h e t e s t body was m e a s u r e d under t h e m i c r o s c o p e . T h e s i z e , f o r m and position of t h e bubble (in r e l a t i o n t o t h e d i r e c t i o n of expansion) w e r e taken into account. T h e r e s u l t s of t h e s e investigations a r e shown in p r i n c i p l e in F i g u r e 15. T h e following i m p o r t a n t conclusions for p r a c t i c a l application m a y b e drawn:

a) Elongated bubbles p a r a l l e l t o t h e d i r e c t i o n of expansion show g r e a t l y i n c r e a s e d expansion at t h e peaks (point B) at which d i r e c t f r a c t u r e phenomena can b e observed.

b) Round bubbles and bubbles that a r e elongated a t right angles t o the direction of expansion exhibit t h i s p r o p e r t y much l e s s strongly.

c ) L a r g e bubbles a r e c o n s i d e r a b l y m o r e c r i t i c a l than s m a l l ones.

d) Mixed p l a s t i c - e l a s t i c m a t e r i a l s ( a c c o r d i n g t o 3. 1 e) show an e s p e c i a l l y s t r o n g tendency t o w a r d s the a p p e a r a n c e of incipient f r a c t u r e s at p l a c e s of e x c e s s i v e s t r e s s .

e) In p l a s t i c m a t e r i a l the joining up of bubbles (and h e n c e e n l a r g e m e n t of t h e bubbles) c a n b e observed.

8. Methods of t e s t i n e s e a l i n e m a t e r i a l

T h e choice of a suitable s e a l i n g m a t e r i a l would b e c o n s i d e r a b l y facilitated by t e s t i n g and by a method of investigation that would r e p r o d u c e t h e p r a c t i c a l conditions. However, t h i s p r o b l e m i s c o n s i d e r a b l y m o r e difficult than one might imagine. T h e m a i n r e a s o n s a r e :

a ) T h e s t r e s s e s in the joint v a r y not only f r o m one s t r u c t u r e t o another, but v a r y in a n e n t i r e l y uncontrollable m a n n e r with t h e c l i m a t i c conditions. In t h e t e s t i n g of p a i n t s , for example, the m e c h a n i s m of which is b a s i c a l l y much s i m p l e r than t h a t of t h e s e a l i n g m a t e r i a l s , i t h a s b e e n found that t h e s a m e paint m a t e r i a l applied exactly under the s a m e conditions m a y give not only completely opposite r e s u l t s when t h e y a r e investigated on w e a t h e r t e s t i n g installations in different geographical situations, but that even on a single t e s t i n g stand t h e y yield a bewildering p a t t e r n a t different t i m e s of t h e y e a r , and

b) T h e p r o f i l e of t h e joint and t h e conditions of t h e placing p r o c e s s c a n v a r y s o g r e a t l y that it a p p e a r s i m p o s s i b l e t o develop a u n i f o r m s t a r t i n g point in t h i s r e s p e c t for a t e s t i n g method t h a t might b e g e n e r a l l y applicable.

(16)

A testing method m a k e s s e n s e , of c o u r s e , only i f i t i s possible either t o r e - produce the p r a c t i c a l conditions o r t o c r e a t e conditions allowing for a r e a l i s t i c c o m p a r i - son with reality.

S t r e s s e s in joints, in p r a c t i c e , a r e c h a r a c t e r i z e d by t h e fact that they generally involve slow alternating motions which come about under varying t e m p e r a t u r e conditions.

It can perhaps be r e g a r d e d a s a typical sign of the t i m e s that we know a g r e a t deal about f a s t motions, but v e r y little about slow ones, b e c a u s e we have forgotten how t o wait for the slow ones t o r u n their c o u r s e . Now, i f it i s t r u e that slow, continuous s t r e s s e s constitute the c r i t e r i a for the quality of sealing m a t e r i a l s , we find o u r s e l v e s on t h e h o r n s of a dilemma, because slow motions cannot be accelerated. Existing methods of investigations in t h e U. S. A.

,

England, Germany, Denmark, Sweden and other countries r e f l e c t t h e s e difficulties. The v e r y aging of t h e t e s t body i s s o poor that it in no way c o r r e s p o n d s t o r e a l i s t i c conditions. Table I1 shows the t e s t conditions for expansion, and i t i s evident that a l l conditions differ s h a r p l y f r o m each other and hardly ever correspond even approximately t o reality. Only t h e U. S. specification r e q u i r e s an expansion t e s t at low t e m p e r a t u r e s and t h e r a t e of expansion at 3 mm/h i s t h e lowest.

All testing methods m u s t be r e g a r d e d a s s e r i o u s a t t e m p t s to solve a v e r y

difficult problem. In my view, however, p r a c t i c a l experience i n t h e choice of a suitable sealing m a t e r i a l must be p r e f e r r e d t o any of the inadequate t e s t i n g methods h i t h e r t o employed. Otherwise, t h e r e i s a danger not only of rejecting altogether suitable m a t e - r i a l s , but a l s o of using m a t e r i a l s that m a y have p a s s e d t h e t e s t , but will give u n s a t i s - f a c t o r y r e s u l t s in practice.

9. Discussion of instances of damage

In closing I should like t o deal with a number of difficult c a s e s of damage and look into their c a u s e s .

9.

1 Inadequate depth of joints

In a v e r y l a r g e building in ~ z l m o t h e joints between p r e c a s t c o n c r e t e p a r t s of room s i z e w e r e sealed with a polysulphide m a t e r i a l which, in m y opinion, was of high quality. T h e climatic and constructional conditions w e r e favourable. After about half a y e a r t h e f i r s t c r a c k s appeared in t h e c e n t r e of the joint p r o f i l e and two y e a r s l a t e r t h e damage had become extensive.

(17)

An o n - s i t e investigation showed t h a t in t h e c e n t r e t h e joint p r o f i l e had a depth of only 1

-

2 m m . It c a n t h e r e f o r e b e p r e s u m e d t h a t t h e p r o f i l e was d e f o r m e d in t h e c e n t r e by continuous a l t e r n a t i n g s t r e s s e s and t h a t t h e d e f o r m a t i o n b e c a m e m o r e and m o r e i r r e v e r s i b l e a s a c o n s e q u e n c e of t h e p l a s t i c component, s o t h a t f r a c t u r i n g g r a d u - ally s e t in. E l s e w h e r e , t h e jointing m a t e r i a l showed no fatigue phenomena o r i m p a i r

-

m e n t of e l a s t i c i t y . Where t h e p r o f i l e was d e e p e r ( t h i s was evident f r o m undamaged p a r t s of t h e d e f o r m a t i o n ) no d a m a g e o c c u r r e d .

9. 2 Inadequate joint width

T h e joints between m a r b l e p a n e l s and 2 m long aluminium window

f r a m e s in a h i g h - r i s e building i n Stockholm w e r e s e a l e d with a polysulphide m a t e r i a l . T h e joint width a v e r a g e d 8 m m .

After two y e a r s e x t e n s i v e d a m a g e a p p e a r e d in t h e upper c o r n e r s of t h e joints. T h i s d a m a g e was c o n c e n t r a t e d on t h e south and w e s t s i d e s being insignificant on t h e north. It was concluded t h a t t h e m a i n c a u s e of t h e d a m a g e w a s t h e g r e a t d i f f e r e n c e between t h e coefficients of t h e r m a l expansion of t h e building m a t e r i a l s . In addition t h e r e was t h e f a c t that t h e joint widths, which on checking a p p e a r e d often t o b e a s l i t t l e a s 4 m m , w e r e m u c h t o o s m a l l .

T h e jointing had b e e n c a r r i e d out i n s p r i n g a t t e m p e r a t u r e s of 5

-

1 0 ° C . T h e c a l c u l a t e d joint d i s p l a c e m e n t s w e r e up t o 3 m m , and w e r e c o n c e n t r a t e d in t h e upper c o r n e r s , b e c a u s e at t h e lower edges t h e position of t h e window w a s s t a b i l i z e d . T h e p e r c e n t a g e o f expansion in t h e joints w a s s o g r e a t that it could not be a b s o r b e d b y t h e jointing m a t e r i a l , s o t h a t u l t i m a t e l y f r a c t u r i n g s e t in. T h i s effect was s m a l l e r on t h e n o r t h s i d e of t h e building.

9. 3. Unfavourable joint edges and i n c o r r e c t choice of m a t e r i a l

In a l a r g e hfi??pital in s o u t h e r n Sweden t h e joints between rough s u r f a c e d c o n c r e t e (Waschbetong) in a l a t e r a l wing w e r e f i l l e d with an a c r y l a t e m a t e r i a l . T h e rough s u r f a c e d c o n c r e t e (Waschbetong) p e n e t r a t e d deeply into t h e e d g e s of t h e joint. T h e work had been c a r r i e d out in s p r i n g at a p p r o x i m a t e l y 1 0 ° C . ABter a s h o r t t i m e

s e v e r e m o i s t u r e d a m a g e a p p e a r e d i n t h e joints and on the i n t e r i o r of t h e w a l l s . It was found that t h e s e a l i n g m a t e r i a l had n e v e r a t t a i n e d adequate adhesion. T h i s w a s due p a r t l y t o t h e v e r y rough s u r f a c e and p a r t l y t o t h e f a c t t h a t t h e m a t e r i a l , which had been h e a t e d t o 6 0 ° C f o r application, b e c a m e s o s t i f f a t t h e t e m p e r a t u r e of t h e

(18)

joint edge t h a t no a d e q u a t e wetting could b e achieved. M o r e o v e r , t h e m a t e r i a l w a s p a r t l y softened by t h e action of a l k a l i n e m o i s t u r e . T h i s i s a c a s e in which t h e c a u s e s of d a m a g e l a y both in t h e d e s i g n , t h e m a t e r i a l p r o p e r t i e s and t h e m a n n e r of application.

F i n a l l y , t h e m a n n e r i n which t h e s e joints w e r e r e p a i r e d i s i n t e r e s t i n g and i n s t r u c t i v e . After r e m o v i n g t h e old jointing m a t e r i a l t h e e d g e s of t h e joint w e r e ground s m o o t h with a high-speed grinding disk, t h e p o r e s and d a m a g e d p l a c e s w e r e s e a l e d with an epoxy t r o w e l , a p r i m e r w a s applied, and f i n a l l y t h e joint was s e a l e d with a polysulphide m a t e r i a l . T h e i n i t i a l jointing had c o s t about 8 c r o w n s p e r m e t r e , while t h e r e j o i n t i n g o p e r a t i o n c a m e t o not l e s s than 80 c r o w n s / m e t r e , i. e . , 10 t i m e s t h e o r i g i n a l p r i c e .

I hope that I h a v e a d e q u a t e l y d e m o n s t r a t e d t h a t t h e s a t i s f a c t o r y solution of t h e jointing p r o b l e m i s s u b s t a n t i a l l y a question of c o o p e r a t i o n between d e s i g n e r s , c h e m i s t s and t h o s e who e x e c u t e t h e joints.

R e f e r e n c e s

1. Norwcglrcllcr Ilauforrchu~~gsinslitul, Rapporl 51 A - C , O r l o (1967 ulld 1968)

2 . A . V a l n u s ~ r . I2ci11hcrld I'ublirl~inl: Corp., NFW York, lYb7

3 . A . Wollcr, A d l l ; ~ s i o ~ ~ . U l l r l c i ~ ~ - V c r l o p 1967 ( I l c l l 9 ) ulld lYb8 ( l l c l l 4)

(19)

T a b l e I C u r i n g t i m e (in days) of v a r i o u s c o m m e r c i a l l y obtained polysulphide m a t e r i a l s Type 100% 9 0 % ' ~ ) 8070 (1) R e m a r k s c u r i n g curing c u r i n g A 12-15

6

-7 5 pot life :

6

h r . B 8-10 4-5 2 - 3 pot l i f e : 50 min. C 10

6

-7 4

-

5 pot life :

6

h r . D

-

-

-

not c u r e d a f t e r 28 days E 1 3 - 1 4 8 4 p o t l i f e : 3 . 5 h r . (1) T i m e a f t e r which 80% o r 90% of t e r m i n a l h a r d n e s s was r e a c h e d

(20)

T a b l e I1 C o m p a r i s o n of t e s t i n g i n s t r u c t i o n s f o r s e a l i n g m a t e r i a l s i n d i f f e r e n t c o u n t r i e s ( e x p a n s i o n t e s t s ) . C o u n t r y I s s u e r Date S t o r a g e t i m e b e f o r e t e s t S i z e of s p e c i m e n R a t e of expansion Expansion t e s t ( d r Y) Expansion t e s t (wet) Expansion t e s t ( a f t e r aging) A p p r a i s a l U. S. A. US - F e d e r a t i o n S p e c i a l T T -S-227b J u n e 1965 10 d. a t 23" C t 4 d a y s i n w a t e r 9 x 2 4 x 4 8 m m 0 , 0 5 m m / m i n 3 c y c l e s 2 4 . /70°C 7h. /water 8h. /-17°C e x p a n s i o n 15070 - 1 7 ° C

-

m a x . 2 s q . in. l o s s of a d h e s i o n D e n m a r k A s s . of D a n i s h s u p p l i e r s of E l a s t i c jointing m a t e r i a l s J u n e 1966 3 d a y s at 5 0 " C t 16 h. at 25°C 2 0 x l 0 x 5 0 m m 5 m m / m i n 3 c y c l e s 4h/-15°C 200% exp.

/

16 h. 4h/25"C r e l a x a t i o n 16 h. /25"C 4d. /water exp. 250%/ 20°C 500 c y c l e s 102 m i n / 6 0 " ~ A t l a s 18 min/2O0 C exp. ZOO%/ 20" C m a x . 2 . 5 m m f r a c t u r e in joint Sweden Bygg-AMA 1965 7 d a y s at 25" C l 0 x l 0 x 5 0 m m 10 m m / m i n 2 5 0 7 0 / 2 5 " ~ 4d. /water exp. ZOO%/ 25°C 4d/70°C exp. Z O O % / 25°C 2 of 3 s p e c i m e n s f l a w l e s s G e r m a n y D e u t s c h e r Betoll- v e r e i n e . V. J u n e 1967 1 4 d a y s a t 20" C 1 5 x l 5 x 5 0 m m 5 m m / m i n 2O0~o/2O0 C 12 c y c l e s 16 h. /water 3 h/-20°C 2 h / t 2 0 " ~ 3 h/-20°C 6 4 h / w a t e r 20070/20" c a s a b o v e + 3 c y c l e s 250%/-20" C -5070/50" c o r v i b r a t i o n f r o m 8 0 - 1 2 0 ~ / 2 0 " ~ 1000 t i m e s / 2 h . max. 5 m m depth of c r a c k s England F e d e r a t i o n of B r i t i s h R u b b e r and Allied M a n u f a c t o r y F e b r u a r y 1964 7 d a y s at 25°C 12, 5 x 1 2 , 5 x 4 8 m m 0, 25 m m / m i n 250%/25"C 4d. /water 250%/24 h. a) 96h/70°C 4 / 2 5 " C 2 0 0 7 0 / 2 5 " ~ b ) 20070/-15°C 4h/25" c C o m p r e s s i o n : 50 yo 16h/25"C s a m e a s Sweden and D e n m a r k

(21)

s p a n

W

u e v e l l e c l j o i n t f a c e . o u t s i d e e d g e s F i g . 1 C o r r e c t d e s i g n o f a j o i n t ; F i g .

3

D i m e n s i o n i n g o f j o i n t s p a n e x p a n s i o n o r c o n t r a c t i o n j o i n t w i t h s h e a r i n g m o t i o n F i g . 2 J o i l - ~ t s f u n c t i o n i n g i n t i i f f e r e n t ways I n c o r r e c t

'r

F i g .

4

C o r r e c t a n d i n c o r r e c t s u r f a c e q u a l i t y o f j o i n t e d g e s

(22)

e l a s t i c p l a s t i c c o m p ~ . e s s i o n e x p a n s i o n c o m p r e s s i o n I / e x p a n s i o n a n d

mq?

p o s s i b l e f r a c - n u l l L c o n t r a c t i o n p o s i t i o n o f p r o f i l e e x p a n s i o n i n c i p i e n t f r a c t u r e t u r e F i g .

5

F i g .

6

S t a r t o f c r a c k i n g i n p l a s t i c S t a r t o f f r a c t u r e i n p l a s t i c m a t e r i a l m a t e r i a l d u e t o a l t e r n a t i n g s t r e s s d u e t o c o n t r a c t i o n o f p r o f i l e E l a s t i c m a t e r i a l w i t h s m a l l p l a s t i c c o m p o n e n t s s h o r e h a r d n e s s A

-

A c r y l a t e m a t e r i a l ( p l a s t i c ) B

-

S i l i c o n m a t e r i a l ( e l a s t i c ) C

-

T h i o k o l m a t e r i a l H ( e l a s t i c ) D

-

T h i o k o l m a t e r i a l W ( e l a s t i c ) E

-

B u t y l m a t e r i a l ( p l a s t i c ) F i g .

7

H a r d n e s s e s o f p l a s t i c a n d e l a s t i c s e a l i n g m a t e r i a l s a s a f u n c t i o n o f t h e t e m p e r a t u r e e x p a n s i o n o/. r e l a x a t i o n o f e l a s t i c component i n c i p i e n t A f r a c t u r e

f

Z

t

ime A

-

E l a s t i c e x p a n s i o n B

-

P l a s t i c e x p a n s i o n F i g .

8

E x p a n d i n g f u n c t i o n o f e l a s t i c m a t e r i a l w i t h s m a l l p l a s t i c component ( r e l a x a t i o n c u r v e )

(23)

F i g .

9

C r o s s - s e c t i o n t h r o u g h

a

u r e t h a n e m a t e r i a l

w i t h b u b b l e s ( m i c r o p h o t o g r a p h )

No. o f c y c l e s

t o f r a c t u r e

p o l y s u l p h i d e m a t e r i a l 18:

s h o r e

---

p o l y s u l p h i d e m a t e r i a l 40

s h o r e

. . .

a c r y l a t e m a t e r i a l

.-.-

s i l i c o n m a t e r i a l

.-.-.-

b u t y l m a t e r i a l

T e s t i n a c c o r d a n c e w i t h Bygg

-

AMA

1 9 6 5 ( 1 5 0 % e x p a n s i o n )

F i g . 1 0

R e p e a t e d e x p a n s i o n t e s t s o f

d i f f e r e n t s e a l i n g m a t e r i a l s

as

a

f u n c t i o n o f t h e t e m p e r a t u r e

( f r o m

a

r e p o r t o f t h e S i p o r e x

C e n t r a l L a b o r a t o r y

) A. S t r i w i t h expanding i n s i i e p r o f i l e B. B a r r i e r s t r i p i n s e r t e d i n j o i n t w i t h s e a l behind i t C. I n t e r l o c k i n g s t r i p s i n t e - g r a t e d w i t h t h e p a r t s d u r i n g t h e i r c a s t i n g

F i g .

11

E x a m p l e s o f some t y p e s o f p r o f i l e d

s e a l i n g s t r i p s f o r j o i n t s b e t w e e n

p r e c a s t p a r t s

(24)

SHORE A T y p e A p o l y s u l p h i d e

B

p o l y s u l p h i d e C p o l y s u l p h i d e

D

p o l y s u l p h i d e

E

p o l y s u l p h i d e F a c r y l a t e S h o r e 20°c S l o p e ') R e m a r k s 30 40 O r e s i n o u s 2

5

25O 3 0 1 l o 2 3 17O

15

8 . 5 O h i g h p l a s t i c i z e r c o n t e n t

o

79O p l a s t i c ')

o 0

h a r d n e s s i n d e p e n d e n t o f t e m p e r a t u r e F i g . 1 2 H a r d n e s s

-

t e m p e r a t u r e c u r v e s D e p t h o f j o i n t i n g m a t e r i a l

t K

-

s p a n o f j o i n t b + mm

5

L i m i t i n g c o n d i t i o n

tmin

>

4

mm F i g . 1 3 P r o f i l i n g o f a n e x p a n s i o n j o i n t a c c o r d i n g t o S w e d i s h B u i l d i n g S p e c i f i c a t i o n s Bygg

-

AMA 1 9 6 5

(25)

f a c a d e p a r t , i n s u l a t i o n

I

I::

g r o u n d f i l l i n g t, = t. c c > n r l e n s a t , i on bet1 i n d t h e j o i n t I - - L Temp. c u r v e Temp. c u r v e i n S e c .

R

i n S e c . A F i g . 11-1 O c c u r r e n c e o f m o i s t u r e c o n d e n s a t i o n b e h i n d t h e j o i n t o w i n g t o p o o r t h e r m a l i n s u l a t i o n

(26)

E l o n g a t e d b u b b l e E l o n g a t e d b u b b l e t r a n s v e r s e t o p a r a l l e l t o d i r - d i r e c t i o n o f Round e c t i o n o f e x p a n - e x p a n s i o n b u b b l e s i o n p o s i t i o n expansion 4 d e f o r m a t i o n o f b u b b l e d u e t o e x p a n s i o n .- - .

-

8 El € 1 1 p a r t i a l e x p a n - I s i o n d i a g r a m E E

-

l o c a l e x p a n s i o n En

-

a v e r a g e e x p a n s i o n F i g . 1 5 P a r t i a l e x p a n s i o n f u n c t i o n o f a b u b b l e e n c l o s e d i n t h e s e a l i n g m a t e r i a l , d e p e n d i n g on t h e s h a p e o f t h e b u b b l e

Références

Documents relatifs

i) The calculated intensities are very close to those obtained by the software CaRIne, ii) There is a difference between the calculated intensities and those given by the base

c Department of Chemical Engineering , Saad Dahlab University of Blida , Blida , Algeria d Laboratory of Environmental Biotechnologies BIOGEP , Ecole Polytechnique d’Alger—10

Par contre si le scénario d’accords agricoles alternatifs a augmenté les prix aux producteurs et l’équité, il a aussi augmenté les dépenses publiques pour le financement

اًﻮْﻀُﻋ ﺔﻴﻧﺪﻤﻟا ﺔﻴﻟوﺆﺴﻤﻟا ﻦﻣ ﻦﻴﻣﺄﺘﻟا ﺠﻟا نﻮﻧﺎﻘﻟا ﻲﻓ روﺮﻤﻟا ثداﻮﺣ جﺎـــــــﺤﻟوأ ﺪـــــــﻨﺤﻣ ﻲـــــــــﻠﻛأ

The nominal result and statistical uncertainty is given in black, while the results of the dominant systematic variations to the nominal model (per Sec. VI ) are given by the

راد ،(ةنراقم ةسارد) كلهتسملا ةيامح دعاوق ءوض يف ةحايسلا دوقع يف ةمالسلا نامضب مازتلالا ،حاتفلا دبع ديلف دباع رهاقلا ،ةيبرعلا ةضهنلا ،ة 2006 ص ، 26..

detection of flooded areas on the 526 MODIS images, chosen to monitor the annual and interannual variations of the flood. The IDL routine automatically computed

the criteria towards design and accepting the latter two as constraints, a proposal for the total form of the campus for 1980 is suggested. The existing