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Understanding the kinetics of the ClO dimer cycle

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Academic year: 2021

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Table 2. Standard reaction enthalpies ∆ r H ◦ for Reaction (R1) and corresponding heat of for- for-mation ∆ f H ◦ for Cl 2 O 2 at 0 K deduced from laboratory and theoretical studies.
Table 4. Overview of parameters used or calculated in Eq. (4) for M=N 2 . Except for β c , errors given arise mainly from uncertainties in Cl 2 O 2 vibrational frequencies (Table 1).
Table 6. MPIC cross section data.
Fig. 2. Temperature dependence of k diss,0 . For the theoretical values (Eq. 4), solid lines show k diss,0sc , long dashed, short dashed and dotted lines k diss,0wc with β c (300 K) of 0.60, 0.45 and 0.30 respectively.
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