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Luminescent molecular switches based on dicationic P-doped Polycyclic Aromatic Hydrocarbons

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Academic year: 2021

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Figure

Fig. 3 UV-Vis absorption (top) and normalized emission spectra (bottom) of 2[OTf] and 4ad[OTf] 2 in CH 2 Cl 2 (c = 5  10 6 M).
Fig. 4 Cyclic voltammograms of 2[OTf] and 4a–d[OTf] 2 (c = 10 3 M) in DCM (Bu 4 NPF 6 (0.2 M), 200 mV s 1 , potentials vs
Fig. 6 EPR spectra of the chemically generated 4a + (a), 4b + (b), 6 + (c) and 8 + (d) in DCM.
Fig. 8 Representation of the spin density difference in the radical cation of 4a + , 4b + , 6 + and 8 + (at their minimal radical cation geometry)

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