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Biological Routes to Gold Nanoplates

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Biological Routes to Gold Nanoplates

Jianping XIE

1

, Jim Yang Lee

*1,2

, Yen Peng Ting

2

1

Singapore-MIT Alliance, 4 Engineering Drive 3, National University of Singapore, Singapore

117576.

2

Department of Chemical and Biomolecular Engineering, National University of Singapore, 10 Kent

Ridge Crescent, Singapore 119260. Fax: 65 67791936; Tel: 65 6874 2899; E-mail:

cheleejy@nus.edu.sg.

Abstract – Much effort has been devoted to the

synthesis of gold nanoparticles with different shapes, including the zero-dimensional nanospheres, one dimensional nanorods, and two-dimensional nanoplates. Compared to zero or one dimensional nanostructures, the synthesis of two-dimensional nanostructures in high yield has always been more involved, often requiring complex and time-consuming steps such as morphology transformation from the nanospheres, or the seeded growth process. Herein we report a high yield method for gold nanoplate synthesis using the extract of unicellular green alga Chlorella vulgaris, which can be carried out under ambient conditions. More than 90% of the total nanoparticle population is of the platelet morphology, surpassing the previously reported value of 45%. The control of the anisotropic growth of different planes; as well as the lateral size, has also been partially optimized.

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