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THE EFFECT OF HYDROGEN DURING STRESS CORROSION CRACKING AND CORROSION FATIGUE OF Al-Li-Cu ALLOYS IN 3.5 % NaCl
SOLUTIONS
T. Magnin, M. Rebière
To cite this version:
T. Magnin, M. Rebière. THE EFFECT OF HYDROGEN DURING STRESS CORROSION CRACK-
ING AND CORROSION FATIGUE OF Al-Li-Cu ALLOYS IN 3.5 % NaCl SOLUTIONS. Journal de
Physique Colloques, 1987, 48 (C3), pp.C3-835-C3-841. �10.1051/jphyscol:1987398�. �jpa-00226630�
JOURNAL DE PHYSIQUE
Colloque C3, supplgment au n09, Tome 48, septembre 1987
THE EFFECT OF HYDROGEN DURING STRESS CORROSION CRACKING AND CORROSION FATIGUE OF Al-Li-Cu ALLOYS IN 3.5 % NaCl SOLUTIONS
T. MAGNIN and M. R E B I ~ R E
E c o l e des M i n e s , 158, C o u r s F a u r i e l , F-42023 S a i n t - E t i e m e C e d e x , France
SYNOPSIS
S t r e s s c o r r o s i o n c r a c k i n g and c o r r o s i o n f a t i g u e t e s t s a t imposed s t r a i n r a t e a r e conducted on a n i n d u s t r i a l Al-Li-Cu a l l o y i n a 3 . 5 % NaCl s o l u i i o n a t imposed poten- t i a l . I n t h e c o n d i t i o n o f t h e t e s t s and f o r s h o r t f a t i g u e l i f e t i m e s , t h e a n o d i c d i s - s o l u t i o n i s shown t o p l a y t h e predominant r o l e d u r i n g c o r r o s i o n - f a t i g u e a t f r e e c o r - r o s i o n p o t e n t i a l . N e v e r t h e l e s s a marked hydrogen e m b r i t t l e m e n t i s o b s e r v e d a t c a t h o - d i c p o t e n t i a l s d u r i n g c o r r o s i o n f a t i g u e of specimens c o n t a i n i n g s u p e r f i c i a l micro- c r a c k s . These o b s e r v a t i o n s a r e d i s c u s s e d t o compare t h e s u s c e p t i b i l i t y t o hydrogen e m b r i t t l e m e n t . o f t h e Al-Li-Cu a l l o y s and o f c o n v e n t i o n a l Al-Zn-Mg a l l o y s d u r i n g s t r e s s c o r r o s i o n and c o r r o s i o n - f a t i g u e t e s t s .
INTRODUCTION
The damaging e f f e c t o f hydrogen i s known t o h e o f p r i o r i m p o r t a n c e t o e x p l a i n t h e s t r e s s c o r r o s i o n c r a c k i n g (SCC) and t h e c o r r o s i o n f a t i g u e (CF) p r o p e r t i e s o f conven- t i o n a l Al-Zn-Mg a l l o y s u s e d i n t h e a e r o s p a c e i n d u s t r i e s C1,2,33. N e v e r t h e l e s s t h e r e i s l i m i t e d knowledge a v a i l a b l e on t h e e n v i r o n m e n t a l e f f e c t s on t h e mechanical ro- p e r t i e s o f t h e v e r y p r o m i s i n g A1-Li a l l o y s [ 4 , 5 , 6 , 7 1 . Up t o d a t e , a n o d i c d i s s o f u t i o n i s e x p e c t e d t o b e t h e main damaging mechanism d u r i n g SCC i n A1-Li a l l o y r 7 1 . I n f a c t , n o t h i n g i s known a b o u t t h e i n f l u e n c e o f hydrogen d u r i n g SCC and CF of t h e s e a l l o y s , even i f hydrogen e m b r i t t l e m e n t h a s b e e n r e c e n t l y s u g g e s t e d t o b e a p o s s i b l e SCC f r a c - t u r e mechanism C61. Moreover l i t t l e a t t e n t i o n h a s b e e n p a i d , a s y e t , t o t h e i n t e r - f a c i a l r e g i o n between CF and SCC, and t o t h e r e s p e c t i v e p a r t s of t h e m e c h a n i c a l dama- ge on t h e SCC and CF p r o p e r t i e s of A1-Li a l l o y s .
Thus t h e aim of t h i s p a p e r i s t o a n a l y s e and compare t h e s t r e s s c o r r o s i o n c r a c k i n g and t h e c o r r o s i o n f a t i g u e b e h a v i o u r o f smooth specimens o f an i n d u s t r i a l Al-Li-Cu a l l o y (CP271) deformed a t imposed s t r a i n r a t e i n a 3 . 5 % NaCl s o l u t i o n , p a y i n g a par- t i c u l a r a t t e n t i o n t o t h e r e s p e c t i v e p a r t of the a n o d i c d i s s o l u t i o n and t h e hydrogen e m b r i t t l e m e n t on t h e damaging p r o c e s s e s .
EXPERIMENTAL PETHOD
Experiments were conducted on an i n d u s t r i a l Al-Li-Cu CP271 a l l o y ( s u p p l i e d b y P e c h i n e y ) c o n t a i n i n g ( i n w e i g h t p e r c e n t ) 2.5 L i , 1 . 3 Cu, 1.0 Mg, 0.09 Z r , 0 . 0 2 Fe and (C 0.25) Zn. The e x t r u d e d p l a t e s have been s o l u t i o n t r e a t e d a t 53S°C, t h e n quen- ched i n c o l d w a t e r , s t r e t c h e d by 2 % and a r t i f i c i a l l y aged f o r 12h a t 190°C. T h i s c o r r e s p o n d s t o t h e peak aged c o n d i t i o n s (T651).
The c o r r e s p o n d i n g m i c r o s t r u c t u r e s have been d e s c r i b e d e l s e w h e r e ( t h i s c o n f e r e n c e CBI). Smooth specimens (15 m gauge l e n g t h , 5 mm d i a m e t e r ) were machined from t h e e x t r u d e d p l a t e s on two d i r e c t i o n s : t h e L and TL d i r e c t i o n s a s d e s c r i b e d i n d e t a i l s i n C81.
The o b s e r v e d p r e c i p i t a t e s f o r t h e T651 h e a t t r e a t m e n t a r e t h e 6 ' (A13Li) p r e c i - p i t a t e s i n t h e m a t r i x , t h e 6 ( ~ l L i ) p r e c i p i t a t e s a t g r a i n b o u n d a r i e s , t h e S' (AlzCuMg) and 6' (Al3Zr) p r e c i p i t a t e s i n t h e m a t r i x . The T I (AlnCuLi) p r e c i p i t a t e s seem t o b e v e r y r a r e . They have been shown t o ~ r e c i p i t a t e a t g r a i n b o u n d a r i e s C71.
SCC
te
t s l w e r e performed u s i n g t h e s l o w s t r a i n r a t e method i n the s t r a i n r a t e range 10 's- < b < 1 0 - ~ s - ' a s d e s c r i b e d e l s e w h e r e r f l . CF t e s t s were c o n d u c t e d i n t e n s i o n - c o m p r e s s i o n under s y m m e t r i c a l p l a s t i c s t r a i n c o n t r o l (AE / 2 ) , a t c o n s t a n tP
Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyscol:1987398
C3-836 J O U R N A L D E PHYSIQUE
s t r a i n r a t e E , u s i n g a s e r v o h y d r a u l i c machine [ 3 1 .
A l l t h e e x p e r i m e n t s a r e made i n r e p l e n i s h e d 3.5 % NaCl s o l u t i o n s a t pH 6 ( a e r a t e d o r d e s a e r a t e d ) and u n d e r p o t e n t i o s t a t i c c o n t r o l . T e s t s a r e performed e i t h e r a t f r e e c o r r o s i o n p o t e n t i a l o r a t imposed c a t h o d i c p o t e n t i a l . The b e h a v i o u r i n t h e c o r r o s i v e s o l u t i o n s i s compared t o t h e b e h a v i o u r i n a i r ( w i t h 60 % h u m i d i t y ) and u n d e r vacuum ( 2 . T o r r )
.
The s e n s i t i v i t y t o SCC and t o CF i s q u a n t i t a t i v e l y d e f i n e d by t h e r a t i o s A(NaCl)/
A ( a i r ) and N.(NaC1)/Ni(air) r e s p e c t i v e l y . A i s t h e e l o n g a t i o n t o f r a c t u r e and N . t h e number o f c y i l e s t o c r a c k i n i t i a t i o n ( c o r r e s p o n d i n g t o a 1 % r a p i d d e c r e a s e of *he s a t u r a t i o n peak s t r e s s ) . N. h a s been shown t o b e a q u i t e r e l e v a n t p a r a m e t e r t o cha- r a c t e r i s e t h e i n i t i a t i o n o!C c r a c k s l e a d i n g t o p r o p a g a t i o n i n volume ( f o r more d e t a i l s , s e e C91).
EXPERIMENTAL RESULTS T e n s i l e p r o p e r t i e s i n a i r
The y i e l d s t r e n g t h (Y.S.), u l t i m a t e t e n s i l e s t r e n g t h (U.T.S.) and t h e e l o n g a t i o n t o f r a c t u r e (A ) o f t h e CP271 T651 a l l o y a r e shown on t a b l e 1 . A comparison i s e s t a - b l i s h e d w i t h c o n v e n t i o n a l Al-Zn-Mg a l l o y s .
E l e c t r o c h e m i c a l b e h a v i o u r
The p o l a r i z a t i o n c u r v e s o f t h e Al-Li-Cu CP271 a l l o y i n t h e a e r a t e d and d e s a e r a t e d 3.5 % NaCl s o l u t i o n a t pH 6 a r e g i v e n on F i g . 1. The f r e e c o r r o s i o n p o t e n t i a l s ( i n r e f e r e n c e w i t h t h e s a t u r a t e d c a l o m e l e l e c t r o d e (SCE)) a r e i n f a c t Eo =
-
740 ~ V / S C E f o r t h e a e r a t e d s o l u t i o n and-
950 4 Eo <-
900 mV/SCE f o r t h e d e s a e r a t e d s o l u t i o n . The f r e e c o r r o s i o n p o t e n t i a l s a r e c l o s e d t o t h e p i t t i n g p o t e n t i a l . A c c o r d i n g t o t h e b e h a v i o u r i n t h e c a t h o d i c r e g i o n , t e s t s a t imposed c a t h o d i c p o t e n t i a l n e e d a v e r y r e p r o d u c t i b l e method b e f o r e SCC o r CF e x p e r i m e n t s : t h e p o t e n t i a l i s s l o w l y d e c r e a s e d from E = E t o E = - 1400 mV and t h e n s l o w l y p u t t o t h e a p p r o p r i a t e v a l u e-
1400 mV< E < Eo. gelow E =
-
1400 mV, a d a r k l a y e r a p p e a r s o n t h e CP271 s p e c i m e n s . No t e s t s have b e e n made below - 1400 mV/SCE. F i n a l l y , b e f o r e SCC o r CF e x p e r i m e n t s t h e s y s t e m i s s t a b i l i z e d d u r i n g 12h.SCC p r o p e r t i e s a t f r e e c o r r o s i o n p o t e n t i a l
F i g . 2 shows t h e e f f e c t o f s t r a i n r a t e on t h e e l o n g a t i o n t o f r a c t u r e A o f t h e CP271 a l l o y i n t h e a e r a t e d NaCl s o l u t i o n a t E = E
.
A comparison 2 s e s t a b l i s h e d w i t h t h e c o n v e n t i o n a l 7020 a l l o y f o r peak aned c o g d i t i o n s T6DR ( f o r more d e t a i l s on A l l o y nameCP271 T651
-
t h i s a l l o y , s e e C33). No e f f e c t o f s t r a i n r a t e h a s b e e n e n c o u n t e r e d i n a i r f o r t h e d i f f e r e n t a l l o y s .
On F i g . 2 , i t can b e shown t h a t t h e CP271 a l l o y i n t h e L and TL d i r e c t i o n s e x h i b i t s a good SCC r e s i s t s $ c e compared t o t h e 7020 a l l o y . The c r i t i c a l s t r a i n r a t e t f o r SCC i s a b o u t 3.10 s-' f o r t h e CP271 a l l o y and I O - ~ S - ' f o r t h e 7020 a l l o y .
& = 2 . 1 0 - ~ s - ' , A i s r e d u c e d by a f a c t o r 2 f o r t h e CP271 a l l o y and h y a f a c t o r 3 f o r t h e 7020 a l l o y . I t can b e n o t i c e d t h a t A i s t w i c e h i g h e r f o r t h e L o r i e n t a t i o n t h a n f o r t h e TL o r i e n t a t i o n w h a t e v e r 6 .
0.2% Y.S. ( m a ) 47 1 413 S e c t i o n
l o n g i t u d i n a l L l o n g t r a n s v e r s e TL
CF p r o p e r t i e s of smooth specimens a t f r e e c o r r o s i o n p o t e n t i a l
The i n f l u e n c e o f t h e e n v i r o n m e n ~ ~ o n t h e f a t i g u e b e h a v i o u r of t h e CP271 a l l o y i s shown on F i g . 3 f o r AE / 2 = 3 . 3 . 1 0 and a t h i g h s t r a i n r a t e E? = IO-~S-'. It c a n b e o b s e r v e d t h a t : ( i ) FO!? t h e CP271 L a l l o y t h e f a t i g u e l i f e i s r e d u c e d o n l y by a f a c - t o r 1 . 5 i n a i r i n comparison t o vacuum b u t by a f a c t o r 3.5 i n t h e a e r a t e d NaCl s o l u - t i o n . These r e d u c t i o n s a r e l o w e r t h a n f o r t h e 7020 a l l o y ( f a c t o r 5 f o r N a C l / a i r ) b u t f a t i g u e l i f e t i m e s a r e always l o n g e r f o r t h e 7020 a l l o y .
( i i ) The CP271 TL a l l o y i s n o t s e n s i t i v e t o t h e NaCl s o l u t i o n b e c a u s e o f a v e r y redu- ced f a t i g u e l i f e i n a i r .
UTS ( m a ) 535 476
A
( x )
8 4
( i i i ) The e f f e c t of t h e o r i e n t a t i o n of t h e specimen i s s e n s i t i v e : t h e peak s t r e s s Au/2 of t h e L o r i e n t a t i o n i s h i g h e r than f o r t h e TL o r i e n t a t i o n .
Moreover, no r e d u c t i o n (NaCl/air) of t h e f a t i g u e l i f e t i m e s has been observed on the CP271 L and TL a l l o y s a t AE 12 >, l o d 3 , c o g t r a r i l y t o the behaviour of the 7020 a l l o y ( r e d u c t i o n by a f a c t o r 5 g t A& /2 = 10 C31). The e f f e c t of s t r a i n r a t e on t h e CF p r o p e r t i e s t h e CP271 L a l l o y
ig
t h e a e r a t e d s o l u t i o n i s shown on F i g . 4. For AE 12 = 3.3.10,
i t can be ~ b s e r v e c l ~ t h g t :' ( i ) At h i g h s t r a i n r a t e s ( k 3 10 s ), t h e r e i s no e f f e c t of 6 on t h e f a t i g u e l i f e t i m e s of t h e CP271 TL a l l o y but a marked r ~ d u c t i o n f o r t h e CP271 L a l l o y .
( i i ) A t i n t e r m e d i a t e s t r a i n r a t e s (5. 1 0 - ~ s - < t < 5 . 1 0 - ~ s - ' ) t h e r e i s no CF wha- t e v e r the o r i e n t a t i o n of t h e specimen.
( i i i ) A t low s t r a i n r a t e s a new r e d u c t i o n of t h e f a t i g u e l i f e can be observed.
To analyse t h i s l a s t phenomenon, t h e microcracking process h a s been observed.
CF cracks a r e t r a n s g r a n u l a r under vacuum and a i r whatever t h e s t r a i n r a t e (Fig.
5 a ) , mix ( t r a n s + i n t e r ) i n t h e NaCl s o l u t i o n a t h i g h s t r a i n r a t e s ( F i g . 5b) which emphasizes a d i s s o l u t i o n e f f e c t a t g r a i n boundaries, and i n t e r g r a n u l a r a t low s t r a i n r a t e s (Fig. 5c) i n t h e c o r r o s i v e s o l u t i o m a s f o r SCC. Moreover, only t h i s l a s t case, microcracks form a t the f i r s t 114 c y c l e . I t can be concluded t h a t CF occurs by SCC a t low s t r a i n r a t e s and t r u e CF occurs a t high s t r a i n r a t e s .
To analyse the i n f l u e n c e o f hydrogen on the CF behaviour, t e s t s have been p e r f o r - med on the CP271 L a l l o y i n t h e d e s a e r a t e d s o l u t i o n a t E = E and a t a p p l i e d c a t h o d i c p o t e n t i a l s i n the a e r a t e d s o l u t i o n . The o b t a i n e d r e s u l t s a r e O s u m a r i z e d on Fig. 6 . It can be observed t h a t :
( i ) a t high s t r a i n r a t e s ( t = 10-')s-') t h e r e i s no d i f f e r e n c e between t h e CF beha- v i o u r i n t h e a e r a t e d and i n t h e d e s a e r a t e d s o l u t i o n a t E = E
.
( i i ) a t i n t e r m e d i a t e s t r a i n r a t e s (6 = 2 . 1 0 ~ ~ s - ' ) no CF ogcurs i n t h e a e r a t e d solu- t i o n a t E = E b u t a small r e d u c t i o n ( f a c t o r 1.5) i s observed a t E = E =-1230mV/
c a t h SCE (which cogresponds t o a b a s i c c a t h o d i c c u r r e n t J = 15 1 . ~ ~ / c m 2 ) .
This small r e d u c t i o n i s n o t s i g n i f i c a n t enough tooconclude t h a t hydrogen e m b r i t t l e - ment can take p l a c e i n t h e CP27J a l l o y .
CF p r o p e r t i e s of precycled smooth specimens
It has been shown i n a previous s t u d y on the Al-Zn-Mg a l l o y s C31 t h a t hydrogen embrittlement takes p l a c e d u r i n g CF on t h e s e a l l o y s only when microcracks a r e i n i - t i a t e d mechanically o r by d i s s o l u t i o n . So, CF t e s t s have been done on CP271 L spe- cimens p r e c y c l e d i n a i r d u r i n g 50 c y c l e s a t AE / 2 = t o o b t a i n a d e n s i t y of s u r f a c e rnicroc_r$cks = 18/mm2 a t t h e beginning of thePcF experiments, CF t e s t s a t AE /2 = 3.3.10 and 6 = 2 . 1 0 ~ ~ ~ - ' a r e then conducted on t h e precycled specimens fo! d i f f e - r e n t a p p l i e d p o t e n t i a l s (E = E
,
E = E cath,
corresponding t o d i f f e r e n t v a l u e s of t h e b a s i c c u r r e n t J measured g u s t b e f o r e t h e CF t e s t ) . The s e n s i t i v i t y of t h e pre- cycled specimens t o ° C ~ i s q u a n t i t a t i v e l y d e f i n e d by t h e r a t i o N . ( ~ a C l ) / N i ( a i Z , ) r where N (NaC1) i s t h e f a t i g u e l i f e t i m e i n the NaCl s o l u t i o n akP& /2 = 3.5.10 ofi p P
t h e p r e c y c l e d specimens and N . ( a i r ) t h e corresponding f a t i g u e - l i f e t i m e i n a i r . The i n f l u e n c e of t h e b a s i c L g a t h o d i c c u r r y t J on t h e r a t i o N . (NaCl)/N. ( a i r ) i s c l e a r l y shown on F i g . 7. For AE / 2 = 3.3.10 an8 k = 2 . 1 0 ' ~ s ' ~ , ~ ~ i t e x i s t i p a marked t h r e s h o l d Joc. A t J 3 Joc a marked r e d u c t i o n of t h e f a t i g u e l i f e of P t h e precycled specimens i s observgd. At J i J , no CF i s observed. These r e s u l t s emphasizes t h e r o l e of t h e hydrogen embrit?leme% which can occur i n t h e CP271 a l l o y f o r a p p l i e d c a t h o d i c p o t e n t i a l s i n t h e c o n d i t i o n s of our-tes:s. F i n a l l y i t must be n o t i c e d t h a t the same t e s t s a t h i g h e r s t r a i n r a t e (6 = 10 s ) i n d i c a t e s no CF e f f e c t whatever J
.
This r e s u l t emphasizes t h e r o l e of t h e d u r s t i o n of the t e s t t o d e t e c t CF and tRe hydrogen embrittlement.
DISCUSSION AND CONCLUSIONS
From t h e experimental r e s u l t s r e p o r t e d i n t h e p r e s e n t paper, 1t can b e pointed o u t t h a t :
I
-
A t f r e e c o r r o s i o n p o t e n t i a l , t h e anodic d i s s o l u t i o n p l a y s t h e main r o l e i n t h e CF damage of t h e CP271 a l l o y a s ohown by t h e i n t e r g r a n u l a r a t t a c k of t h e c o r r o s i v e s o l u t i o n which promctes crack i n i t i a t i o n (Fig. 5 ) . Moreover, i n t h e s t r a i n r a t e range I O - ~ S - ~ t o 10 's-l, the lower the s t r a i n r a t e t h e longer t h e c o r r o s i o n f a t i g u e l i f e (Fig. 4 ) . This o b s e r v a t i o n confirms t h e r o l e of t h e d i s s o l u t i o n e f f e c t . A t high s t r a i n r a t e t h e d e p a s s i v a t i o n i s more important than a t i n t e r m e d i a t e s t r a i nC3-838 JOURNAL DE PHYSIQUE
r a t e and t h e c o r r e s p o n d i n g d i s s o l u t i o n i s t h e n more pronounced.
2
-
A t f r e e c o r r o s i o n p o t e n t i a l , i t e x i s t s a s t r a i n r a t e r a n g e ( c a l l e d " i n t e r m e d i a t e s t r a i n r a t e " ,-
IO-'s- ) f o r which no CF can o c c u r , t h e d e p a s s i v a t i o n b e i n g n o t s u f f i - c e n t . Moreover, i t h a s been n o t i c e d t h a t , whatever t h e s t r a i n r a t e , no CF o c c u r s a t s t r a i n a m p l i t u d e s A s 1 2 >, f o r t h e CP271 a l l o y , c o n t r a r i l y t o t h e b e h a v i o u r o f t h e 7020 a l l o y f o r i R s t a n c e . T h i s o b s e r v a t i o n c a n be r e l a t e d t o t h e d u r a t i o n o f t h e CF t e s t s i n t h i s c a s e which a r e t o o s h o r t e r t o a l l o w a n e f f e c t o f c o r r o s i o n . 3-
Hydrogen e m b r i t t l e m e n t h a s been observed a t a p p l i e d c a t h o d i c p o t e n t i a l s , mainly f o r specimens c o n t a i n i n g s u p e r f i c i a l m i c r o c r a c k s formed d u r i n g f a t i g u e i n a i r . T h i s o b s e r v a t i o n emphasizes t h e i n t e r a c t i o n between t h e m i c r o c r a c k s and t h e hydrogen e m b r i t t l e m e n t a s i t was p o i n t e d o u t i n a p r e v i o u s s t u d y on Al-Zn-Mg a l l o y s C31. When m i c r o c r a c k s a r e formed ( m e c h a n i c a l l y on by d i s s o l u t i o n ) t h e l o c a l i z a t i o n of t h e hydro- gen r e d u c t i o n f a v o u r s hydrogen e m b r i t t l e m e n t . N e v e r t h e l e s s , hydrogen e m b r i t t l e m e n t d u r i n g t r u e CF of t h e CP271 a l l o y h a s been observed o n l y f o r c a t h o d i c c u r r e n t s h i g h e r t h a n a c r i t i c a l v a l u e J.
Thus, i n t h e c o n d i t i o n s o f o u r t r u e CF t e s t s , t h e hydrogen e m b r i t t l e m e n t does n o t ?$ke p l a c e a t f r e e c o r r o s i o n p o t e n t i a l f o r t h e CP271 a l l o y , a s shown on F i g . 7.-However, f o r l o n g e r CF t e s t s , i t w i l l be p a r t i c u l a r l y i n t e r e s t i n g t o s t u d y t h e e v o l u t i o n o f J a s a f u n c t i o n of t h e d u r a t i o n o f t h e t e s t s . It can b e imagined f o r i n s t a n c e a decggase o f J when t h e s t r a i n amplitude a p p l i e d on precy-0 C
c l e d specimens d e c r e a s e s .
Thus, i t can b e s u g g e s t e d t h a t , when m i c r o c r a c k s a r e formed i n CF o f i n SCC by a n o d i c d i s s o l u t i o n f o r i n s t a n c e , hydrogen e m b r i t t l e m e n t c a n be a ~ o s s i b l e damaging mechanism when t h e t e s t s a r e l o n g enough. Hydrogen e m b r i t t l e m e n t could be o p e r a t i v e w i t h d i s s o l u t i o n d u r i n g SCC t e s t s even a t f r e e c o r r o s i o n p o t e n t i a l . I n t h e same way, when CF o c c u r s by SCC a t v e r y low s t r a i n r a t e , hydrogen e m b r i t t l e m e n t c o u l d b e a l s o o p e r a t i v e f o r CF a t f r e e c o r r o s i o n p o t e n t i a l . T h i s i s t h e s u b j e c t o f f u r t h e r s t u d i e s .
F i n a l l y , i t must b e emphasized t h a t t h e Al-Li-Cu CP271 a l l o y i n t h e NaCl s o l u t i o n seems t o be l e s s s u s c e p t i b l e t o hydrogen e m b r i t t l e m e n t t h a n t h e c o n v e n t i o n a l Al-Zn-Mg a l l o y s i n t h e peak aged c o n d i t i o n s .
REFERENCES
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C11 M.O. S p e i d e l , Met. Trans. A . , v o l . 6A, 1975, p. 631.r 2 1 N . J . H . Holroyd and D . H a r d i e , Environment-Sensitive F r a c t u r e , ASTM STP 821, S. Dean, E. Pugh and G. Ugiansky, E d s . , P h i l a d e l p h i a , 1984, p . 534.
1 3 1 T. Magnin, C. Dubessy and P. Rieux, Aluminum a l l o y s : t h e i r p h y s i c a l and mechani- c a l p r o p e r t i e s , E.A. S t a r k e and T.H. Sanders Eds., EMAS, 1986, p. 1177.
C41 L. C h r i s t o d o u l o u , L. S t r u b l e and J . R . P i c k e n s , Aluminium-Lithium 11, E.A. S t a r k e and T.H. Sanders E d s . , THS-AIM., 1984, p. 561.
r 5 1 P . P i z z o , R. Galvin and H. Nelson, i b i d , p . 627.
C61 N . J . Holroyd, A. Gray, G. Scamans and R. Herman, Aluminium-Lithium 111, Baker, Gregson, H a r r i s and P e e l Eds., The I n s t i t u t e o f M e t a l s , London, 1986, p. 310.
171 E . I . M e l e t i s , J . M . S a t e r and T.H. S a n d e r s , Aluminium a l l o y s : t h e l r p h y s i c a l and mechanical p r o p e r t i e s , E.A. S t a r k e and T.H. Sanders E d s . , EMAS, 1986, p . 1157.
C81 T. Magnin, P. Rieux, C. L e s p i n a s s e and C . B a t h i a s , 1987, T h i s c o n f e r e n c e . [9] T . Magnin, L. Coudreuse and J . M . Lardon, S c r i p t a Met., v o l . 1 9 , 1985, p. 1487.
FIG. I.. P o l a r i z a t i o n curves of t h e Al-Li-Cu CP271 (T651) a l l o y i n t h e a e r a t e d and d e s a e r a t e d 3 . 5 % NaCl s o l u t i o n s a t pH 6 .
FIG. 2. SCC s u s c e p t i b i l i t y of t h e CP271 (L and TL) and t h e 7020 L a l l o y s a t f r e e corro- s i o n p o t e n t i a l f o r peak aged c o n d i t i o n s
.
FIG. 3 . I n f l u e n c e of t h e environment on t h e e v o l u t i o n with the number of c y c l e s N of t h e peak s t r e s s Ao/2 a t AE /2=3.3.10-'
- 3 - 1 P
and t = 18 s
.
Comparison with t h e 7020 a l l o y i n peak aged condi- t i o n s .JOURNAL DE PHYSIQUE
FIG. 4. E f f e c t of the s t r a i n r a t e k c on t h e CF s u s c e p t i b i l i t y of t h e CP271 L and TL a l l o y s a t A& / 2 = 3.3.10 i n t h e a e r a t e d s o l u t i o n .
P
( a ) h i g h s t r a i n r a t e i n vacuum ( L = I O - ~ S - ~ )
( b ) h i g h s t r a i n r a t e i n t h e NaCl s o l u t i o n ( t = I O - ~ S - ~ )
FIG. 5 . Crack i n i t i a t i o n modes i n t h e CP271 L a l l o y a t AE / 2 = 3 . 3 . 1 0 ~ ' .
P
( c ) Low s t r a i n r a t e i n t h e NaCl
- 7 -1
s o l u t i o n (t = 2.10 s ) a f t e r 1 / 4 c y c l e .
FIG. 6. I n f l u e n c e of t h e a p p l i e d p o t e n t i a l on t h e CF b e h a v i o u r of t h e CP271 L a l l o y a t AE / 2 = 3.3.10-' i n t h e a e r a t e d and d e s a e r a t e d s o l u t i o n . (Ecath = - 7260 mV/SCE c o r r e s p o n d i n g t o a b a s i c c a t h o d i c c u r r e n t Jo = 15 p ~ / c m ~ ) .
FIG. 7 . I n f l u e n c e of a p p l i e d c a t h o d i c p o t e n t i a l s and c o r r e s p o n $ i n f b a s i c c a t h o d i c c u r r e n t J on t h e f a t i g u e l i f e t i m e s a t AE / 2 = 3.3.10 and E = Z . I O - ~ ~ - '
P i n t h e 3.5 % NaCl s o l u t i o n o f p r e c y c l e d specimens.