Formation of silver nanoparticles by electron transfer in peptides and c‐cytochromes
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(2) . Figure S2. AgNPs formation from AgCl/peptides as described in Figure 4.. .
(3) 1.2. 1. 0.8.
(4) . 0.6. 0.4. 0.2. 0 200. 250. 300. 350. 400. 450. 500. 550. 600. . Figure S3. Addition of 10 eq. AgNO3 to c-cytochrome/Fe2+ for 2 hours. As comparison the UV/Vis of ccytochrome/Fe3+ is also shown.. Figure S4. All traces for the time dependence of the experiments with sulfurreducens in Figure 5. The dashed line corresponds to Gs without AgNO3. The thick red line is the last spectrum. Note: Time between spectras: 15 seconds (except dashed-black).. .
(5) Figure S5. Effect of the silver nitrate addition on the oxidation state of the hemes in Gs as demonstrated by the baseline-corrected absorption of the Q band as function of time (used in Figure 5B). A) Spectra showing the initial decrease of the Fe2+ absorption between 0.5 and 1 minute.Only these two lines are shown at low absorption. B) 2+ Spectra showing the increase of the Fe absorption at the indicated times. The dashed line corresponds to Gs without AgNO3.. .
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