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The T and CLP families of triply periodic minimal surfaces. Part 3. The properties and computation of

CLP surfaces

Djurdje Cvijović, Jacek Klinowski

To cite this version:

Djurdje Cvijović, Jacek Klinowski. The T and CLP families of triply periodic minimal surfaces. Part

3. The properties and computation of CLP surfaces. Journal de Physique I, EDP Sciences, 1992, 2

(12), pp.2207-2220. �10.1051/jp1:1992102�. �jpa-00246696�

(2)

Classification

Physics

Abstracts

02.40 61.30 68.00

The T and CLP families of triply periodic minimal surfaces.

Part 3. The properties and computation of CLP surfaces

Djurdje Cvijov16

and Jacek Klinowski

Department

of

Chemistry, University

of

Cambridge,

Lensfield Road,

Cambridge

CB2 IEW, G.B.

(Received J7 June J992, accepted 24

August

J992)

Abstract. Parametric

equations

for normalized CLP minimal surfaces

provide

the solution of the

problem

of

finding

the coordinates of the CLP saddle surface inscribed in a

given tetragonal parallelepiped (right tetragonal prism).

This is crucial for the

matching

of

specific

surfaces to real

structures. The geometry of a CLP surface

depends only

on the ratio cla of the

tetragonal

axes, and

can be described in terms of a

single

free parameter. We offer a choice of two such parameters, both related to surface geometry, and derive

analytical expressions

for their

relationships

to the

axes ratio and the norrnalization factor. Parametric equations for norrnalized CLP surfaces enable us, for the first time, to find the surface

corresponding

to any

given

value of the cla ratio.

Straightforward physical applications

are therefore

possible.

A CLP surface is

perfectly

self-

adjoint only

when the free parameter A =0. We list exact coordinates of CLP surfaces

corresponding

to

prescribed

values of the cla ratio.

Introduction.

Previously

of interest

only

as mathematical

objects [1-3], triply periodic

embedded minimal surfaces

(TPEMS)

have been

applied

to real

problems

in many areas of

physical

and

biological

sciences

[4].

In

particular, they

are well suited for the

modelling

of condensed matter, as

suggested by

Scriven

[5], Mackay [6-7], Hyde

and Andersson

[8], Mackay

and Klinowski

[9]

and Sadoc and Charvolin

[10-11]. Rigorous

mathematical

description

of 20 surfaces in terms of the

Enneper-Weierstrass representation [12-17, 26]

will

undoubtedly

lead to further

applications.

The tD

(also

known as

T)

and the CLP families are the

only

TPEMS with known

parametric representations,

derived

by

us in the first paper of the

present

series

[18].

The

second paper

[19]

has

demonstrated,

for the first

time,

the

possibility

of

straightforward applications

of tD surfaces as models

(without adjustable parameters)

for

matching

actual

structural data. We now demonstrate that such

possibility

exists for CLP surfaces.

The CLP

family

of TPEMS.

The CLP surface was first described

by

Schwarz

[I]

and named

by

Schoen

[2].

The name refers to the

graph

of the tunnel network of the surface which is in the form of Crossed

Layers

(3)

2208 JOURNAL Dfi PHYSIQUE I N° 12

of Parallels. CLP surfaces have

tetragonal symmetry,

and can be

generated by using

two non-

congruent

types of skew

straight-edged 6-gons only [20].

One of them is the

6-gon

obtained

by taking

six of the nine

edges

of a

prism

the bases of which are

right-angled triangles (see Fig, la).

The solution of the Plateau Problem for such

6-gon

is a finite minimal surface

piece

of the CLP surface

(see Fig. lb)

which can be used as a

building

block for

constructing

an infinite

minimal surface

(Fig, lc).

We consider the

properties

of a finite minimal surface

piece

of the CLP surface

(referred

to as the CLP saddle

surface)

which can be

thought

of as inscribed in the

right tetragonal prism

with

edges

a, a and c

(see Fig, ld).

The CLP saddle surface is bounded

by

four

straight-line segments (lying

on the

edges

of the

right tetragonal prism)

and four curvelinear

segments (lying

in the bases of the

right tetragonal prism),

and contains two

straight-line

segments which divide it into four congruent parts.

We will show that CLP surfaces make up a one-parameter

family

of

triply periodic

embedded minimal

surfaces,

I.e. can be described in the form

X#X(U, V(p) Y"Y(U,V(p) Z#Z(U, V(p)

where u and v are

parametric

variables with values in a

specific parametric domain,

and p is a free parameter. The semicolon stresses the difference between

parametric

variables and the free parameter. In other

words,

for a

particular

value of p we have

parametric equations

of a

specific

surface. The free parameter is any

quantity

with a one-one

correspondence

to the cla ratio of the

edges

of the

right tetragonal prism

in which the CLP saddle surface is inscribed.

This means that different CLP surfaces

correspond

to different values of the same value of the

free

parameter,

and that surfaces

corresponding

to the same value of the free

parameter (I.e.

with the same cla

ratio)

are identical.

We will offer a choice between two free parameters, and show that both

correspond

to the cla ratio on the one-to-one basis. We will also demonstrate that surfaces with the same cla ratio can be

distinguished by introducing

the

multiplication

constant,

dependent

on the cla ratio, which is referred to as « normalization factor » and denoted

by

K. For different

values of K

(corresponding

to different values of

lengths

a and c but to the same

cla

ratio)

a

multiplicity

of surfaces are

produced,

and the coordinates of these differ

by

the

multiplication

constant K.

The free

parameter

E with 0 ~ E ~

l12,

determines coordinates of the

images

of flat

points

on the unit

sphere

(± E,

±

/$, 0)

and

(± fi,

± E, 0

which are obtained from the Gauss map of a

specific

CLP saddle surface. The free parameter

A

(with

2

~ A

~

2)

appears in the Weierstrass function of CLP saddle surfaces

[12]

R(r)

=

~

~

Since the parameters A and E are related

A

=

16(E~ -E~)

2

E=

~

either of them can be used.

(4)

(a)

~~

(b)

c i

i i

' ,"

,

' ''

' '

'

a

(c) (d)

a

Fig.

I. (a) Skew space

6-gon

(bold lines) made up of

edges

of a tetragonal

prism

based on a

right- angled triangle

; (b) CLP minimal surface

piece spanning

(a) ; (c)

Arrangement

of

prisms leading

to an

infinite CLP surface (d) CLP saddle surface obtained from (c)

by dissecting

the

prisms

with

parallel planes

at

height

c/2 and c/2.

The

parametric representation

of the

family

of CLP saddle surfaces

(see Appendix

and Ref.

[18])

involves a

special

function known as the

incomplete elliptic integral

of the first kind F

(q~, k),

where we assume that the modulus k is real and lies in the interval

[0, 1]

and the

amplitude

q~ is a

complex

number. In what follows we often use the

properties

of

(5)

2210 JOURNAL DE

PHYSIQUE

I N° 12

z

Fig. 2.

-Right-handed

Cartesian coordinate system attached to the CLP saddle surface described by

equations

(1).

F

(q~,

k

)

which were outlined earlier

[18-19].

Detailed

theory

of

elliptic

functions can be found in standard texts

[21-22].

The Cartesian coordinates x, y and z of a

specific

CLP saddle surface are

given by

the

following parametric equations

x(u, v)

=

Kg~Re [F(arcsin ll'~(w ), k~)]

2

z(u,

v

)

=

j

Kg~

K(k~)

Kg~ Re

iF (arctan

~l~~(w

), k~)j

where Re is the real part of the

complex

F (q~,

k)

and

1l'~(w)= ~~°

gxw +1

~'~~~

l +

w~

are the

complex

functions where

w is

complex

w

= u + iv, with w w I. The

multiplication

factors g~ and g~ and the moduli k~ and k~ are defined in table

I,

and K stands for the

complete elliptic integral

of the first

kind, K(k)

=

F

(w/2, k).

All components of

equations (I) depend

on the value of the same free real

parameter,

and such

dependence,

except for the

normalization factor K, is

given

in table1.

(6)

Table I.

-Multiplication

constants g~ and g~ and moduli k~ and k~ used in

parametric equations for

the CLP

surfaces expressed

in terms

of free

parameters E and A. The domains

of

E and A are

(0, l12)

and

(- 2, 2), respectively.

/

2

~~

~/l

+

~/1 4(E~ E~) ~

l 2

~~

l+2

E~ 2+fi

~

i

-Vi -4(E2-E4) 2-Wm

~

l+~/1-4(E~-E~) 2+fi

~

4

Vi

4

(E2 E4)

8

Wm

~

[l

+

~/1 4(E~ E~)]~ [2

+

fil~

Quantitative

characteristics of the CLP

family.

An

analytical expression

for the cla ratio

(which

we

designate by x)

for the CLP surfaces

cannot be derived from the

Enneper-Weierstrass representation

alone. The

parametric

equations (

I

)

show

that,

for any value of free parameter, the

point

A in the

complex plane

with coordinates

(1, 0)

is

mapped

into

point

A on the CLP saddle surface with coordinates

(x,

y,

c/2) (see Fig. 3a). Similarly,

the

point ( l12, l12)

in the

complex plane corresponds

to the

point (a/2, a/2, 0)

on the saddle surface

(see point

A in

Fig. 3b). Thus,

from

(I)

we obtain

a = Kg~ Re F arcsin

~,

k~

g

x ~~~

c = Kg~

K(k~)

Since for any value of the free parameter we have

~~~"~

j~ i

~

~~'~~~~

where

fi(g~)

is some function of the free

parameter

alone

(its

exact

analytical

form is

irrelevant),

the

elliptic integral

in

(2)

can be

expressed

in the form

F

)

+

ifi(g~),

k~)

=

K(kx)

+

if2(gx) (3)

This makes it

possible

to

separate

the real and the

imaginary parts.

From

(2)

and

(3)

we have

~ ~~~

~~~~~

(4)

c = Kgz

K(kz)

and

gz

K(k~

'~ ~ ~

gx

K(k~)

(7)

2212 JOURNAL DE PHYSIQUE I N° 12

(a)

jmjw)

A c

~

Re la)

~ D

(b) Im(w)

B A

Re (W) c

c D

Fig.

3. Construction of characteristic parts of the CLP surfaces.

Using

table I, the ratio

(5)

can be

easily expressed

in terms of either of the parameters E or A, so that

expressions

for x

= x

(E)

and x

= x

(A

are

readily

available. We see therefore that the

tetragonal

axis ratio x is

independent

of the normalization

factor,

and

only depends (in

a continuous

manner)

on the free

parameter

on the one-to-one basis. It follows that

x is

uniquely

characteristic

(an invariant)

of a

specific

CLP surface.

It is

important

to determine the coordinates of a surface for any

prescribed

value of xo. To do that, it is not necessary to find

explicit analytical expressions

E

=

E(x)

and

A

=

A

(x), especially

since such

expressions

are

complicated

and involve Jacobi's

elliptic

functions. It is sufficient to solve the

equation

g~K(k~)

g~K(k~)

~~~

in terms of either of the parameters E or A

by using

table I. The

equation

is transcendental, and

can be solved

only numerically. Equation (6)

can be solved

directly by

numerical methods

altematively

an

approximate equation

can be solved.

(8)

To solve

(6) directly,

we

adopt

the

following procedure.

To shorten the

root-searching

interval, we express x in terms of E. Since there is

always only

one real root

(I.e.

E)

for any value of xo and the interval is

known,

it is not necessary to

employ root-finding

methods which involve derivatives. This is fortunate,

considering

the very

complicated expression

for the derivative of

(5).

To solve

(6)

we have used the Van

Wijngaarden-Dekker-

Brent

algorithm [23].

In most

applications

it is sufficient to

approximate

x

by

a rational function. We use a rational

approximation

of the form

£

4 p~ E'

X ~

~

~

(7)

£

q~ E'

0

where E is the free parameter with 0 ~ E

~

l12,

and the coefficients p~, q~

(I

=

0, 1, 2,

3 and

4)

need to be determined.

By employing

the standard method of rational

interpolation [23]

we have found rational

approximations

for x

(see

Tab.

III)

with a numerical accuracy better than 7

significant figures. Thus,

for a

given

xo, the determination of free parameter is reduced to numerical solution of the

quartic

£

4 ~Pi xo

qi)

E~

= 0

,=o

with coefficients

given

in table III.

Unfortunately,

it is very difficult to

approximate

X for very

large

and very small values of the free parameter, so there is a need for an

asymptotic expansion

of some kind.

Table II.

Limiting

values

of

the various constants

for

E

- 0

(corresponding

to A -

2)

and

for

E

-

l12 (corresponding

to A

-

2).

~x ~z k k X K

E-o I 0 ~x~ 2/w

E -

l12 / 1/2

0 0 0

Table III. Three rational

approximations

in

form (7) for

the ratio

x(E) for different

intervals

of

the

free

parameter E.

0.06£ E < 0.20 o.40 SE £0.63

0

1 lls.9511514706845 820349143156813

2 %73 985950387064 -75.~77308

3 152.7952883144366 103.3426687204758

4 17178 77852003997 -

(9)

2214 JOURNAL DE PHYSIQUE I N° 12

The

expressions (4) readily yield

the

following

relations for the normalization factor

K for CLP saddle surfaces

K = a

(8a)

gx K

(k~)

K = c.

(8b)

gz

K(k~ )

Equations (8a)

and

(8b)

and

expressions

in table I

give analytical

formulae for the normaliz- ation factor

K in terms of the free parameter. It is clear that for

given

values of

a and c,

K is

uniquely

determined so that can be used in either

(8a)

or

(8b).

We will use

(8a) exclusively.

For a

specific

value of the

length

of the

edge

a, K

depends only

on the value of the free parameter and

changes continually

with

it,

with

limiting

values listed in table II. The

family

of CLP saddle surfaces normalized

by (8a)

are related to

right tetragonal prisms

with the

same base

edge

a and different

edges

c. It is therefore

possible

to compare some characteristics for different surfaces

belonging

to the CLP

family.

Parametric

equations

for normalized CLP surfaces.

According

to

(1), (5)

and

(8a),

for any

specific

values of the

length

of

edges

a and

c

(where

we assume that a is the

edge

of square basis and c as the

height

of the

right tetragonal prism)

there is

always exactly

one CLP saddle surface

completely

described

by

the

following

parametric representation

:

y

(r,

b

=

-

/ Re

iF (arcsin ~l~~

(I

w

where k~, k~,

ll'~(w )

and

ll'~(w )

all

depend

on the value of the free parameter, have the same

meanings

as in

(I)

and w

= r cos 0 + ir sin 0 with 0 « r « I and 0 ~ 0 « 2 w.

Unfortunately,

there is no true addition formula for the

elliptic integral

F

(q~, k)

with a

complex amplitude,

so

that F

(u

+ iv,

k)

cannot be

expressed

in terms of F

(u, k)

and F

(iv, k) only.

It is therefore

impossible

to separate the real and

imaginary

parts, and

parametric equations (9)

cannot be

simplified

further.

Parametric

equations (I)

and

(9)

were derived with the

assumption

-2~A~2

(0

~E~

l12),

I,e,

assuming

finite values of

a and c. Two

limiting

cases need to be considered :

(I)

a is finite and c infinite and

(it)

a is infinite and c is finite. It is clear that then

equations (9)

cannot be

applied,

but it is easy to

verify numerically

that for A

= 2 and

cla - ~x~

equations (I)

with K

=

2

give

the well-known

doubly periodic

Scherk's minimal

surface

(«Scherk's

first surface» in Nitsche's

terminology)

z=In

(cos y/cosx) [24].

Similarly,

A

= 2 and cla

- 0

corresponds

to Scherk's

singly periodic

tower of order one

(which

Nitsche calls « Scherk's fifth surface

»),

which also can be

easily

described in terms of

elementary

functions as sin z

=

sinhx sinh y

[24].

Parametric

equations (I)

can therefore be extended to the these

limiting

cases.

It is

interesting

to use our

parametric equations

to

verify

Schoen's claim

[2]

that a

specific

CLP surface is

self-adjoint.

Let S be the CLP saddle surface described

by

the

parametric

(10)

representation (9)

for

particular

values of a and c.

Then,

the surface S* with the Cartesian coordinates

z*(r,

0

=

~ Re

iif (arctan

~l~~(w

), k~)j

is

adjoint

to S. It may seem at first

sight

that S* is rotated in

respect

to the chosen coordinate system shown in the

figure 2,

and that a

straightforward comparison

is not

possible. However,

the

problem

is

easily

resolved

by

the

following

transformation of the coordinates

which,

of

course, cannot affect the surface itself

X*

=

#(X*+y*) Y*=#(X*-y*)

z*~_~*

and

gives

identical coordinate systems for S and S*. The conclusions of detailed

analysis

are as

follows :

I. For the surface S with A

=

2,

its

adjoint

surface S* is identical to the surface with the coordinates determinated

by (9)

and A = 2. This confirms that Scherk's fifth and first surfaces are

adjoint

to one another.

2. For any 2

~ A ~ 2 with the

exception

of A

=

0,

the

adjoint

surface S* is

always

a

member of CLP

family,

but S and S* are not identical. This can be illustrated

by comparing

their cla ratios shown in

figure

4.

4

~

3

W Xs

~

~

x~*

0

0 2

Free

parameter

~

Fig.

4.

Comparison

of the cla ratios, XS and XS* for the CLP surfaces and for their

adjoint

surfaces.

(11)

2216 JOURNAL DE

PHYSIQUE

I N° 12

3. A CLP surface is

perfectly self-adjoint only

when A

= 0. This means that the minimal

surface with the Weierstrass function

~~~~

"

fi

is

completely unique.

Computation

of CLP surfaces.

The main obstacle to a wider

application

of TPEMS in

experimental

science is that most of

them have been described

empirically,

without the

precise

mathematical

specification

necessary for a

quantitative comparison

with

physical systems.

It is therefore essential to

quantify TPEMS,

and to establish

straightforward procedures

to compare such surfaces with actual structures. Even in the case of

mathematically

well-described surfaces

(with

known

Enneper-Weierstrass representations),

such

procedures,

as well as

quantitative computation,

are

missing.

Among published drawings

of CLP saddle surfaces

only

that obtained

by

Terrones

[25]

and based on the

Enneper-Weierstrass representation

can be

regarded

as

quantitative.

In

general,

it is very difficult to

apply

the

Enneper-Weierstrass representation

to match actual structural data to a CLP

surface, mainly because,

without the

knowledge

of K and x, the

Enneper-Weierstrass representation

must be

regarded

as a model with

adjustable

parameters. In other

words,

it does not tell us how to generate a surface which would match

experimental

data. Parametric

equations

for normalized CLP surfaces

(9) provide

the solution of the

problem,

which can be

geometrically

formulated as follows : find the coordinates od the CLP saddle surface

(see Fig. ld)

which is inscribed in the

given right tetragonal prism.

A more

practical

restatement of the

problem

is : match the

given

structural data

belonging

to

tetragonal

symmetry and confined to the volume of a

right tetragonal prism

to a definite CLP surface. This means that we must :

(a)

find the value of the free

parameter

for

given

c and a, I,e. solve

equation (6)

with xo =

cla. The free parameter

fully

determines a

unique

CLP saddle surface

(b) apply (9)

and calculate the coordinates for this value of the free parameter;

(c)

establish the

agreement

between structural data and the coordinates

ofpoints

on the CLP surface to a

prescribed degree

of accuracy.

Table IV. Constants used in the

computation of

the various CLP saddle minimal

surfaces for different

values

of

the cla aXis ratio x.

=2 =0.5

R 1.36726376 0.098205240 1.52487530

K 0.6165553 0.55652108 0.44477396

1.02128444 1.088008572 1.21958182

o.71544904 o.s799s923 o.sis8oo9

0.20741721 0A2867546 0.69812594

kz 0.99907413 0.98297064 0.87319008

(12)

This

procedure,

for the first

time,

enables easy and

straightforward practical applications (minimal

surfaces appear in a

variety

of

physical problems)

and

completely

obviates the need of

using

the

Enneper-Weierstrass representation.

This is not to say that the use of the Weierstrass function, necessary for the calculation of the Gaussian curvature, metric and

topology

can be avoided. However, our

parametric equations completely

avoid the

integration

of the Weierstrass function.

Equations (9)

contain no

adjustable parameters

and allow us to use

« yes-or-no »

modelling.

This means that it is

always possible

to say whether or not

given

data match a

specific

CLP surface to a

prescribed degree

of accuracy.

Table V. Cartesian coordinates

of

three

different

CLP saddle

surfaces.

The columns

differ

in n~ and the rows in no.

a)

x

= 2.0.

b)

x

=

1.0.

c)

x = 0.5.

1 2 3 4 S 6 7 8

o.isioo63 o

1

0.071048284

2 0.029%6423

3

30089514 4

a)

1 2 3 4 S 6 7 8

0.35844771

o o

1

0.40913367

2 0.055915786 0.3075348

0.024101157 0.l1625311 3

049446296 4

b)

(13)

2218 JOURNAL DE PHYSIQUE I N° 12

Table V

(continued).

1 2 3 4 5 6 7 8

o

i o.036417933

2

3

4

C)

Part

(c)

of the above

procedure

will be described elsewhere

using rigorous

mathematical

model

theorey.

Here we use parts

(a)

and

(b)

to compute CLP saddle surfaces for

x =

2,

and 0.5. The

length

of

edge

a is assumed to be I

(c

= x

)

and all

quantifies required

in the calculation are

given

in table IV.

Computational

evaluation F

(w, k)

and

K(k)

has been

described earlier

[19].

Tables Va-c list

only

the coordinates of

1/8

of each saddle surface.

These surface

pieces

are

asymmetric units,

and for each the

computational

domain

(r,

o

)

is a sector of the unit disc with 0 w r w I and 0 w o w arm. The sector is divided

using

a

8 x 5

grid,

where the coordinates of

grid points

are

given by

w

(n~, n~)

= n~ ro cos

(n~ oo)

+

in~

ro sin

(n~ oo)

with ro =

1/8 and

oo

=

ar/16

(n~

=

1,

8 and n~ =

0, 1, 2, 3, 4).

It is clear that the coordinates of a

complete

CLP saddle surface can be obtained

by symmetry

considerations alone. Coordinates of surfaces

corresponding

to the same value of x but to a different value of

a are obtained

by multiplying

the coordinates in tables Va-c

by

a.

Appendix.

For the

parametric equations

of tire CLP saddle surfaces

(Eqs. (9), (10)

and Tab. IV with 2 ~ A

~ 2 in Ref.

[18])

to be

practically useful,

it is necessary to introduce the normalization factor w, examine the

complex

square root function of the

complex

variable which appears in

equations

for the coordinates x and y, and find a suitable coordinate system. It is

clearly

desirable to choose the same branch of

complex

square root for both coordinates on the entire unit disc. We consider

only

that branch of the square root which is I at I. In the

equation

x = xo + wgx Re

IF (w~, k~)j

where g~ and k~ are

given

in table I, the

amplitude

w~ defined

by

~ 2

w

~

Sl~ ~x

g~ w 2 +

(14)

can be

simply expressed

in terms of the inverse sine function

only

p~ =

arcsin °~

gx w +

and then the x coordinate

correctly represents

the CLP saddle surface on the entire unit disc.

However,

in the

equation

y = yo + Ngx Re

jif (w~,

k~

)j

with k~ =

[the expression

for

amplitude

p~ is

(~+fi)w~

sin~wy~

4~~2

2-A+1

which means that the square root function cannot be avoided. With the above

assumption

about the branch of the square root, the

equation

for the y coordinate

gives

a correct

representation

of the CLP saddle surface in the first and the fourth

quadrant

of the

complex plane. Symmetry

considerations

require

that for the y coordinate the surface be

correctly represented

on the upper

(I

and II

quadrant)

part of the unit disc. It is therefore sufficient to

change

the

sign

of the

equation

in order to represent the lower

part

of the unit disc

correctly.

To resolve this

problem

we must «rotate» the solution function for the y coordinate counter-clockwise

by

ar/2. The

required

function for y is found

by using

the

procedure

described in

[18].

The new

equation

for the y coordinate is

= Yo Ngx Re IF

(w~, k~)]

where g~ and k~ are defined in table I and the

amplitude

w~ is

2 wi

w~ = arcsm

gx I ~ w

It is clear that the

relationship

between p~ and p~ is

simply p~(w )

=

p~(iw ).

Finally,

for xo =

0,

yo

= 0 and zo = wg~

K(k~),

we obtain the

right-handed

Cartesian 2

coordinate

system

shown in

figure

2.

References

[i] SCHWARz H. A., Gesammeite Mathematische

Abhandlungen (Veriag

Julius

Springer,

Beriin, 1890), vol. 1.

[2] SCHOEN A. H., Infinite Periodic Minimal Surfaces Without Self-intersections, NASA Technical

Report

No. TN D-05441 (1970).

[3] FISCHER W, and KocH E., J. Phys. Colloq. France 51 (1990) C7-131-147.

[4] ANDERSSON S., HYDE S. T., LARSSON K. and LIDIN S., Chem. Rev. 88 (1988) 221-242 and references therein.

[5] SCRIVEN L. E., Nature 266 (1976) 123.

[6] MACKAY A. L., Nature 314

(1985)

604-606.

[7] MACKAY A. L.,

Physica

131B (1985) 300-305.

(15)

2220 JOURNAL DE

PHYSIQUE

I N° 12

[8] HYDE S. T. and ANDERSSON S., Z.

Kristallogr.

168 (1984) 221-254 170 (1985) 225-239.

[9] MACKAY A, and KLINOWSKI J.,

Computers

and Mathematics with

Applications

12B (1986) 803- 824.

[10] SADOC J. F. and CHARVOLIN J., J.

Phys.

France 47 (1986) 683.

[i ii SADOC J. F, and CHARVOLIN J., J.

Phys.

France 48 (1987) 1559.

[12] LIDIN S. and HYDE S. T., J.

Phys.

France 48 (1987) 1585-1590.

[13] LIDIN S., J. Phys. France 49 (1988) 421-427.

j14] LIDIN S., HYDE S. T. and NINHAM B. W., J.

Phys.

France 51 (1990) 801-813.

jis] LIDIN S. and LARSSON S., J. Chem. Sac.

Faraday

Trans. 86 (1990) 769-775.

j16] FOGDEN A., J.

Phys. Colloq.

France 51(1990) C7-149-156.

[17] FOGDEN A., J. Phys. I France 2 (1992) 233-239.

j18] CvIJovIt D. and KLINOWSKI J., J.

Phys.

I France 2

(1992)

137-147.

[19] CvlJovIt D. and KLINOWSKI J., J. Phys, I France 2 (1992) 2191-2205.

j20] KocH E. and FISCHER W., Z. Krist. 183 (1988) 129-152.

j21] BYRD P. F. and FRIEDMAN M. D., Handbook of

Elliptic Integrals

for

Engineers

and Scientists, 2nd Edition

(Springer-Verlag, Berlin-Heidelberg-New

York, 1971).

j22] MILNE-THOMPSON L. M., Handbook of Mathematical Functions, M. Abramowitz and I. A.

Stegun

Eds. (Dover Publications Inc., New York, 1980) ch, 17.

j23] PRESS W. H., FLANNERY B. P., TEUKOLSKY S. A. and VETTERLING W. T., Numerical

Recepies

:

The Art of Scientific

Computing

(Cambridge

University

(Press, 1986).

j24] NITSCHE J. C. C., Lectures on Minimal Surfaces, vol. I

(Cambridge University

Press, 1989).

j25] TERRONES H., Ph. D. Thesis, Birkbeck

College, University

of London (1992).

j26] FOGDEN A. and HYDE S. T., Acta

Cryst.

A 48 (1992) 442 and 575.

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