تنقية الماء من الفينول باستعمال الإدمصاص على الفحم النشط

(1)

ﺙﺤﺒﻝﺍ ﻭ ﻲﻝﺎﻌﻝﺍ ﻡﻴﻠﻌﺘﻝﺍ ﺓﺭﺍﺯﻭ ﻲﻤﻠﻌﻝﺍ

Ministère de l’Enseignement Supérieur et de la Recherche Scientifique

ﺔﺒﻠﻁﻝﺍ ﺩﺍﺩﻋﺇ ﻥﻤ :

ﺓﺫﺎﺘﺴﻷﺍ ﻑﺍﺭﺸﺇ

:

ﻰﻤﻠﺴ ﻲﻨﺍﺩ

ﺩﻨﻫ ﻥﺍﺭﻘﻤ

ﻡﻴﺭﻤ ﺔﻠﻬﺴﻭﺒ ﺭﻫﻭﺠﻝﺍ ﺡﺎﺒﺫ

ﺔﻨﺠﻝ ﺔﺸﻗﺎﻨﻤﻝﺍ :

ﺫﺎﺘﺴﻷﺍ ﺓ

: ﺔﻴﺩﺎﻨ ﺱﺎﻴﺭﺩﻭﺒ ...

...

ﺔﺴﻴﺌﺭ

: ﺔﺒﻴﺒﺤ ﺵﺭﻜﻭﺒ ...

...

ﺔﻨﺤﺘﻤﻤ

: ﺩﻨﻫ ﻥﺍﺭﻘﻤ ...

...

ﺔﻓﺭﺸﻤ

ﺔﻴﺴﺍﺭﺩﻝﺍ ﺔﻨﺴﻝﺍ 2014

- 2015

ﺔﻌﻓﺩ ﻥﺍﻭﺠ 2015

ﺓﺫـﺘﺎـﺴﻸﻝ ﺎـﻴﻠـﻌﻝﺍ ﺔـﺴﺭﺩـﻤﻝﺍ

ﺔﻤﻴﺩﻘﻝﺍ ﺔﺒﻘﻝﺍ )

ﺭﺌﺍﺯﺠﻝﺍ (

ﺎﻴﻤﻴﻜﻝﺍ ﻡﺴﻗ ﺀ

ECOLE NORMALE SUPERIEURE Vieux - Kouba (Alger)

Département de chimie

ﻰﻠﻋ ﺹﺎﺼﻤﺩﻹﺍ لﺎﻤﻌﺘﺴﺎﺒ لﻭﻨﻴﻔﻝﺍ ﻥﻤ ﺀﺎﻤﻝﺍ ﺔﻴﻘﻨﺘ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ

(2)

ﺱﺭﻬﻔﻝﺍ

ﺀﺍﺩﻫﻹﺍ ﺭﻜﺸﻝﺍ ﺔﻤﺩﻘﻤﻝﺍ ...

01

لﻭﻷﺍ لﺼﻔﻝﺍ لﻭﻨﻴﻔﻝﺎﺒ ﻩﺎﻴﻤﻝﺍ ﺙﻭﻠﺘ ﺭﺩﺎﺼﻤ :

-I -1 لﻭﺤ ﺕﺎﻴﻤﻭﻤﻋ

لﻭﻨﻴﻔﻝﺍ . ...

...

03

-I 1 -1- لﻭﻨﻴﻔﻝﺍ )

phenol ...(

03

-I -1 2 -

ﺔﻴﺌﺎﻴﺯﻴﻔﻝﺍ ﺹﺍﻭﺨﻝﺍ

ﺔﻴﺌﺎﻴﻤﻴﻜﻝﺍﻭ ...

04

-I -1 3 - ﻡﺍﺩﺨﺘﺴﺍ

لﻭﻨﻴﻔﻝﺍ ...

06

-I -1 4 - ﻡﻫﺃ

ﺍ ﺕﺎﻤﺍﺩﺨﺘﺴ

ﻪﺘﺎﺒﻜﺭﻤ ...

06

-I 1 - 5 -

ﻰﻠﻋ لﻭﻨﻴﻔﻝﺍ ﺓﺭﻭﻁﺨ

ﻥﺎﺴﻨﻹﺍ ...

07

-I 2 -

ﻩﺎﻴﻤﻝﺍ ﺙﻭﻠﺘ

لﻭﻨﻴﻔﻝﺎﺒ ...

08

-I 2 - -1 ﺔﻴﻋﺎﻨﺼﻝﺍ ﻩﺎﻴﻤﻝﺍ ...

08 .

-I 2 - -2 ﺕﺍﺩﻴﺒﻤ

ﺕﺍﺭﺸﺤﻝﺍ ...

11

-I 2 - -3 ﺘﺤﻤ

ﻭ ﻥﻤ ﺕﺎﻴﻔﺸﺘﺴﻤﻝﺍ ﻥﻤ ﺓﺭﺩﺎﺼﻝﺍ ﺕﻼﻀﻔﻝﺍ ﻩﺎﻴﻤ ﻯ

12

-I 2 - 4 - ف أ لو ا ةد Bisphenol A

...

12

-I ﺃ - ﺭﺎﻁﺨﺃ ف أ لو ا ةد

...

ﻝﺍ لﺼﻔﻝﺍ ﻲﻨﺎﺜ

ﺹﺎﺼﻤﺩﻹﺍ لﻭﺤ ﺕﺎﻴﻤﻭﻤﻋ :

1 13

(3)

ﺱﺭﻬﻔﻝﺍ

ﺔﺤﻤﻝ ﺔﻴﺨﻴﺭﺎﺘ

...

14

ﺓﺭﻫﺎﹼﻅﻝﺍ ﺭﻴﺴﻔﺘ ...

...

14

-II - ﻑﻴﺭﻌﺘ ﻹﺍ

ﺹﺎﺼﻤﺩ :

L’Adsorption

...

14

-II 4

لﺤﺍﺭﻤ

-

ﻹﺍ ﺹﺎﺼﻤﺩ

...

....

15

-II 5

ﻉﺍﻭﻨﺃ

-

ﻹﺍ ﺹﺎﺼﻤﺩ

...

16

-II 7 - لﻤﺍﻭﻌﻝﺍ ﻰﻠﻋ ﺓﺭﺜﺅﻤﻝﺍ

ﻹﺍ ﺹﺎﺼﻤﺩ ...

17

-II 4 - ﺯﺍﺯﺘﻨﻹﺍ :

Desorptio ...

...

17 ...

-II 5 - لﻤﺍﻭﻌﻝﺍ ﻰﻠﻋ ﺓﺭﺜﺅﻤﻝﺍ

ﻹﺍ ﺹﺎﺼﻤﺩ ...

18

-II 5 - 1 - ﺏﻠﺼﻝﺍ ﻡﺴﺠﻝﺍ ﺔﻴﻨﺒ ...

18 .

-أ ﺕﺎﻤﺎﺴﻤﻝﺍ ﻡﺠﺤ ...

18

-ب ﺔﻴﻋﻭﻨﻝﺍ ﺢﻁﺴﻝﺍ ﺔﺤﺎﺴﻤ ...

18

-II 5 - 2 -

ﻤﺩﻤﻝﺍ ﺔﻴﻨﺒ ﺹ

...

18

ﺃ - ﺔﻴﺒﻁﻗ ﺹﻤﺩﻤﻝﺍ ...

...

18

ﺏ - ﺯﻴﻜﺭﺘ ﺹﻤﺩﻤﻝﺍ

...

18

-ج ﺔﻴﻨﺎﺒﻭﺫﻝﺍ ...

...

18

-II 5 - 3 - لﻤﺍﻭﻌﻝﺍ

19

(4)

ﺱﺭﻬﻔﻝﺍ

ﺔﻴﺌﺎﻴﺯﻴﻔﻝﺍ ...

...

-أ ﻡﻗﺭﻝﺍ ﻲﻨﻴﺠﻭﺭﺩﻴﻬﻝﺍ ...pH

19 ....

-ب ﺔﺠﺭﺩ

ﺓﺭﺍﺭﺤﻝﺍ ...

...

19

-II 6 - ﻹﺍ ﺕﺎﻘﻴﺒﻁﺘ ﺽﻌﺒ لﻴﻝﺎﺤﻤﻝﺍ ﻲﻓ ﺹﺎﺼﻤﺩ

...

9 1

-II 7 - ﻡﺭﺘﻭﺯﻴﺇ

ﺹﺎﺼﻤﺩﻹﺍ ...

...

19

-II 7 - 1 - ﺹﺎﺼﻤﺩﻹﺍ ﻡﺭﺘﻭﺯﻴﺇ ﻑﺎﻨﺼﺃ ...

19 ..

II 7 - - 2 - ﺹﺎﺼﻤﺩﻹﺍ ﻥﻴﻨﺍﻭﻗ ...

21

-II 7 - 3 - ﻡﺭﺘﻭﺯﻴﺇ ﺝﺫﺎﻤﻨ

ﺹﺎﺼﻤﺩﻹﺍ ...

...

21

-أ

ﺭﻴﻤﺠﻨﻻ ﻡﺭﺘﻭﺯﻴﺇ

:

Langmuir) ...(

...

21

-ب ﻡﺭﺘﻭﺯﻴﺇ

ﺵﻴﻝﺩﻨﻭﺭﻓ ):

freundlich ...(

24

-I ﺃ - ﺭﺎﻁﺨﺃ ف أ لو ا ةد

...

ﻝﺍ لﺼﻔﻝﺍ ﺙﻝﺎﺜ

ﻝﺍ ﻡﺤﻔﻝﺍ ﻰﻠﻋ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ : ﻤ

ﻁﺸﻨ 1

13

ﺔﻤﺩﻘﻤ ...

...

26

-1-III ﺕﺎﺼﻤﺩﻤﻝﺍ

: ) ﻡﺎﺴﺠﻷﺍ

ﺓﺯﺎﻤﻝﺍ ( ...

26

-1-1-III ﻉﺍﻭﻨﺃ

27

(5)

ﺱﺭﻬﻔﻝﺍ

ﺕﺎﺼﻤﺩﻤﻝﺍ .

...

1-1-1-III ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ

: Charbon actif .

...

27 ...

2 - ﻑﻴﺭﻌﺘ ...

28

2 - ﻡﺤﻔﻝﺍ ﺏﻴﻜﺭﺘ

ﻝﺍ ﻤ ﻁﺸﻨ ...

...

28

4 - ﻝﺍ ﻡﺤﻔﻠﻝ ﺢﻁﺴﻝﺍ ﻑﺌﺎﻅﻭ ﻤ

ﻁﺸﻨ ..

...

29

5 - ﺭﻴﻀﺤﺘ ﻝﺍ ﻡﺤﻔﻝﺍ

ﻤ ﻁﺸﻨ ...

30

ﺃ - ﺔﻨﺒﺭﻜﻝﺍ )

Carbonisation (

...

30

ﺏ - ﻁﻴﺸﻨﺘﻝﺍ ^Activation

30

- ﻲﺌﺎﻴﺯﻴﻔﻝﺍ ﻁﻴﺸﻨﺘﻝﺍ :

Activation physique .

...

31

- ﻲﺌﺎﻴﻤﻴﻜﻝﺍ ﻁﻴﺸﻨﺘﻝﺍ :

Activation chimique ...

31

6 - ﻥﻭﺒﺭﻜﻝﺍ ﺩﺠﺍﻭﺘ لﺎﻜﺸﺃ

ﻁﺸﻨﻝﺍ ...

31

7 - ﻝﺍ ﻡﺤﻔﻝﺍ ﺕﺎﻘﻴﺒﻁﺘ ﻤ

ﻁﺸﻨ ...

...

..

...

31

8 - ﻝﺍ ﻡﺤﻔﻝﺍ ﺩﻴﺩﺠﺘ ﻤ

ﻁﺸﻨ ...

..

32 ....

ﺃ - ﺭﻴﺨﺒﺘﻝﺎﺒ ﺩﻴﺩﺠﺘﻝﺍ ...

32

ﺏ - ﺩﻴﺩﺠﺘﻝﺍ

ﻱﺭﺍﺭﺤﻝﺍ ...

...

33

ﺝ - ﻲﺌﺎﻴﻤﻴﻜﻝﺍ ﺩﻴﺩﺠﺘﻝﺍ ...

33

ﺩ - ﻲﺠﻭﻝﻭﻴﺒﻝﺍ ﺩﻴﺩﺠﺘﻝﺍ ...

..

...

33

(6)

ﺱﺭﻬﻔﻝﺍ

2-1-1-III ﺕﻴﻨﻭﺘﻨﺒﻝﺍ

...

33

3-1-1-III ﻥﻴﻁﻝﺍ

: L’Argile ...

33

4-1-1-III ﻁﺸﻨﻝﺍ ﻥﻴﻤﻭﻝﻷﺍ

...

34

5-1-1-III ﺕﻴﻝﻭﻴﺯﻝﺍ ...

34

6-1-1-III ﺎﻜﻴﻠﻴﺴﻝﺍ ﻡﻼﻫ

...

34

-III -2 ﺇ ﻰﻠﻋ ﻪﺘﺎﻘﺘﺸﻤﻭ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩ ﻡﺤﻔﻝﺍ

35

-III

3 -

ﺔﻜﺭﺎﺸﻤﻝﺍ ﺕﻼﻋﺎﻔﺘﻝﺍ ﺔﻌﻴﺒﻁ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ لﻼﺨ

...

35

-4-III لﻭﻨﻴﻔﻠﻝ ﺱﻭﻜﻌﻝﺍ ﺭﻴﻏ ﺹﺎﺼﻤﺩﻹﺍ

...

37

5-III - ﺕﻻﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ

ﺔﻝﺩﺒﺘﺴﻤﻝﺍ ...

37

ﻊﺒﺍﺭﻝﺍ لﺼﻔﻝﺍ :

ﺀﺯﺠﻝﺍ ﻲﻠﻤﻌﻝﺍ

ﻝﺍ ﺔﺴﺍﺭﺩ ﻝﺍ

ﺔﻴﺒﻴﺭﺠﺘ ﺢﻁﺴ ﻰﻠﻋ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﻺﻝ

ﻝﺍ ﻡﺤﻔﻝﺍ ﻤ

ﻁﺸﻨ

-IV 1 - ﻕﺌﺍﺭﻁ ﻭ ﺔﻠﻤﻌﺘﺴﻤﻝﺍ ﺕﺍﻭﺩﻷﺍ

لﻴﻠﺤﺘﻝﺍ ...

. ...

. 39

-IV 1 - -1 ﻤﻝﺍ ﺩﺍﻭ

ﻠﻤﻌﺘﺴﻤﻝﺍ ﺔ

...

39

-IV 1 - 2 - ﺕﺎﻴﺠﺎﺠﺯﻝﺍ

ﺔﻠﻤﻌﺘﺴﻤﻝﺍ ...

...

43

1 - 3 - لﻴﻠﺤﺘﻝﺍ ﻕﺭﻁ

... -IV 44

(7)

ﺱﺭﻬﻔﻝﺍ

1 - ﻕﻭﻓ ﺔﻴﻓﺎﻴﻁﻤ ﺔﻁﺴﺍﻭﺒ لﻭﻨﻴﻔﻠﻝ ﻲﻤﻜﻝﺍ لﻴﻠﺤﺘﻝﺍ

ﺔﻴﺠﺴﻔﻨﺒﻝﺍ ...

44

2-IV – ﺔﻘﻴﺭﻁ لﻭﻨﻴﻔﻝﺍ ﻥﻤ ﻩﺎﻴﻤﻝﺍ ﺔﻴﻘﻨﺘ ﺔﺴﺍﺭﺩ ﺩﻨﻋ لﻤﻌﻝﺍ

ﺹﺎﺼﻤﺩﻹﺍ لﺎﻤﻌﺘﺴﺎﺒ

ﻝﺍ ﻡﺤﻔﻝﺍ ﻰﻠﻋ

ﻤ ﻁﺸﻨ

ﺓﺩﻋ ﺭﻴﺜﺄﺘ ﺔﺴﺍﺭﺩ ﻊﻤ

لﻤﺍﻭﻋ ....

..

...

47

-IV 2 - 1 - ﺭﻴﺜﺄﺘ ﺔﻠﺘﻜ

ﻝﺍ ﻡﺤﻔ ﺔﻴﻠﺒﺎﻗ ﻰﻠﻋ ﻁﺸﻨﻝﺍ ﺇ

لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩ ﻡﺤﻔﻝﺍ

ﻝﺍ ﻤ ﻁﺸﻨ 47 ....

-IV 2 - 2 – ﺭﻴﺜﺄﺘ ﺯﻴﻜﺭﺘﻝﺍ

لﻭﻨﻴﻔﻠﻝ ﻲﺌﺍﺩﺘﺒﻻﺍ ﻰﻠﻋ

ﺇ ﻝﺍ ﺹﺎﺼﻤﺩ ﻡﺤﻔ

48

-IV 1 - 3 - ﻰﻠﻋ ﺓﺭﺍﺭﺤﻝﺍ ﺔﺠﺭﺩ ﺭﻴﺜﺄﺘ ﺇ

لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩ ﺍ ﻰﻠﻋ

ﻡﺤﻔﻝ

48

-IV 1 - 4 - ﺭﻴﺜﺄﺘ ـﻝﺍ ﺔﻴﻠﺒﺎﻗ ﻰﻠﻋ pH

ﺇ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩ ﻡﺤﻔﻝﺍ ﻰﻠﻋ

49

-IV 3 - ﻭ ﺞﺌﺎﺘﻨﻝﺍ ﺎﻬﻠﻴﻠﺤﺘ

...

49

-IV 3 - 1 - ﻝﺍ ﻡﺤﻔﻝﺍ ﺔﻠﺘﻜ ﺭﻴﺜﺄﺘ ﺔﺴﺍﺭﺩ ﻤ

ﺹﺎﺼﻤﺩﺇ ﻰﻠﻋ ﻁﺸﻨ

49

-IV 3 - 1 - 1 - ﻡﺤﻔﻝﺍ ﻰﻠﻋ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﻹ ﻥﺍﺯﺘﻻﺍ ﻥﻤﺯ ﺔﺴﺍﺭﺩ

49

-IV 3 - 1 - 2 - ﻝﺍ ﻡﺤﻔﻝﺍ ﺔﻠﺘﻜ ﺭﻴﺜﺄﺘ ﻤ

لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ ﻰﻠﻋ ﻁﺸﻨ ...

52

-IV 3 - 2 - ﻝﺍ ﻡﺤﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ ﺔﻴﻠﺒﺎﻗ ﻰﻠﻋ لﻭﻨﻴﻔﻠﻝ ﻲﺌﺍﺩﺘﺒﻻﺍ ﺯﻴﻜﺭﺘ ﺭﻴﺜﺄﺘ ﻤ

ﻁﺸﻨ ...

55

-IV 3 - 3 - ﻡﺤﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ ﺔﻴﻠﺒﺎﻗ ﻰﻠﻋ ﺓﺭﺍﺭﺤﻝﺍ ﺔﺠﺭﺩ ﺭﻴﺜﺄﺘ

ﻁﺸﻨﻝﺍ ...

58

-IV 3 - 4 - ﺭﻴﺜﺄﺘ ـﻝﺍ

ﺔﻴﻠﺒﺎﻗ ﻰﻠﻋ pH ﺇ

لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩ ﻡﺤﻔﻝﺍ ﻰﻠﻋ

ﻝﺍ ﻁﺸﻨﻤ ...

61

(8)

ﺱﺭﻬﻔﻝﺍ

-IV 4 - ﻲﺠﺫﻭﻤﻨ ﻕﻴﺒﻁﺘ ﺇ

ﻹﺍ ﻡﺭﺘﻭﺯﻴ ﺹﺎﺼﻤﺩ

) ﻭ ﺵﻴﻝﺩﻨﻭﺭﻓ

ﻨﻻ ﺠ ﺭﻴﻤ ( ...

64

-IV 4 - 1 - ﺩﻴﻬﻤﺘ ...

64

-IV 4 - 2 - ﺝﺫﻭﻤﻨ ﺇ

ﻡﺭﺘﻭﺯﻴ

ﺵﻴﻝﺩﻨﻭﺭﻓ ...

64

-IV 4 - 2 - 1 - ﺔﻴﺭﻅﻨﻝﺍ

64

-IV 4 - 2 - 2 - ﺩﻜﺄﺘﻝﺍ ﺎﻴﺭﻅﻨ ﺵﻴﻝﺩﻨﻭﺭﻓ ﺔﻝﺩﺎﻌﻤ ﻥﻤ ...

...

65

-IV 4 - 2 - 3 - ﻥﻤ ﺩﻜﺄﺘﻝﺍ ﻡﺭﺘﻭﺯﻴﺇ ﺝﺫﻭﻤﻨ ﻕﻴﺒﻁﺘ

ﺵﻴﻝﺩﻨﻭﺭﻓ

ﺎﻴﺒﻴﺭﺠﺘ ...

65

-IV 4 - 3 - ﺝﺫﻭﻤﻨ ﺇ

ﻡﺭﺘﻭﺯﻴ

ﺭﻴﻤﺠﻨﻻ ...

68

-1-3-4-IV ﺔﻴﺭﻅﻨﻝﺍ

68

-IV 4 - 3 - 2 - ﺩﻜﺄﺘﻝﺍ ﺔﻝﺩﺎﻌﻤ ﻥﻤ ﺭﻴﻤﺠﻨﻻ

ﺎﻴﺭﻅﻨ ...

...

68

-IV 4 - 3 - 3 - ﻥﻤ ﺩﻜﺄﺘﻝﺍ

ﺭﻴﻤﺠﻨﻻ ﻡﺭﺘﻭﺯﻴﺇ ﺝﺫﻭﻤﻨ ﻕﻴﺒﻁﺘ

ﺎﻴﺒﻴﺭﺠﺘ ...

68

-IV 5 - ﻡﺎﻌﻝﺍ لﻴﻠﺤﺘﻝﺍ ...

...

70 .

ﺔﻤﺘﺎﺨﻝﺍ ...

...

72

(9)

لﺎﻜﺸﻷﺍ ﺔﻤﺌﺎﻗ

ﺔﺤﻔﺼﻝﺍ لﺎﻜﺸﻷﺍ ﺔﻤﺌﺎﻗ

3 لﻭﻨﻴﻔﻝﺍ ﺔﻴﻨﺒ :(1 -І) لﻜﺸﻝﺍ

5 لﻭﻨﻴﻔﻠﻝ ﺔﻴﺭﻴﻤﻭﺯﻴﻤﻝﺍ لﺎﻜﺸﻷﺍ :(2 -І) لﻜﺸﻝﺍ 15 ﺏﻠﺼﻝﺍ ﻡﺴﺠﻝﺍ ﻕﻭﻓ ﺹﻤﺩﻤﻝﺍ ﺕﺎﺌﻴﺯﺠ ﺹﺎﺼﻤﺩ ﺇ:(1 -II) لﻜﺸﻝﺍ 16 ﺹﺎﺼﻤﺩﻹﺍ ﺔﻴﻠﻤﻋ ﺙﻭﺩﺤ لﺤﺍﺭﻤ :(2 -II) لﻜﺸﻝﺍ 20 ﺯﺎﻐﻝﺍ ﻁﻐﻀ ﺔﻝﻻﺩﺒ ﺔﺼﻤﺩﻤﻝﺍ ﺓﺩﺎﻤﻝﺍ ﺔﻴﻤﻜ ﺭﻴﻐﺘ ﺕﺎﻴﻨﺤﻨﻤ:(3 -II) لﻜﺸﻝﺍ

28 ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ :(1 -III) لﻜﺸﻝﺍ

29 ﺔﻴﺌﺎﻨﺒﻝﺍ ﺓﺩﺤﻭﻝﺍ ﺝﺫﻭﻤﻨ (ﺃ).ﻁﺸﻨﻝﺍ ﻡﺤﻔﻠﻝ ﺔﻴﺭﻬﺠﻤﻝﺍ ﺔﻴﻨﺒﻝﺍ(ﺏ) :(2 -III) لﻜﺸﻝﺍ ﺱﺎﺴﻸﻝ 30 ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﺢﻁﺴﻝ ﺔﻴﻔﻴﻅﻭﻝﺍ ﺕﺎﻋﻭﻤﺠﻤﻝﺍ :(3 -III) لﻜﺸﻝﺍ 37 Garcia-Araya et Coll ﻑﺭﻁ ﻥﻤ ﺔﺴﻭﺭﺩﻤﻝﺍ ﺕﺎﺌﻴﺯﺠﻝﺍ :(4 -III) لﻜﺸﻝﺍ (2003)

40 لﻤﻌﺘﺴﻤﻝﺍ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﺓﺭﻭﺼ :(1 -IV) لﻜﺸﻝﺍ

41 لﻭﻨﻴﻔﻝﺍ ﺓﺩﺎﻤﻝ ﺓﺭﻭﺼ :(2 -IV) لﻜﺸﻝﺍ

42 ﻥﻜﺎﻤﻷﺍ ﺩﺩﻌﺘﻤ ﻲﺴﻴﻁﺎﻨﻐﻤ ﻁﻼﺨ :(3 -IV) لﻜﺸﻝﺍ r

42 ﻲﻨﻭﺭﺘﻜﻝﺇ ﻥﺍﺯﻴﻤﻝ ﺍ:(4 -IV) لﻜﺸﻝﺍ

43 ﺭﺘﻤ ^PH ـﻝﺍ :(5-IV) لﻜﺸﻝﺍ

43 ﺀﺎﻤﻝﺍ ﺭﻴﻁﻘﺘ ﺯﺎﻬﺠ :(6-IV) لﻜﺸﻝﺍ

44 ا ت ا :(7-IV) لﻜﺸﻝﺍ

46 ﺩﻨﻋ لﻭﻨﻴﻔﻝﺍ ﺯﻴﻜﺍﺭﺘﻝﺍ ﺔﻝﻻﺩﺒ ﺔﻴﺼﺎﺼﺘﻤﻼﻝ ﺓﺭﻴﺎﻌﻤﻝﺍ ﻰﻨﺤﻨﻤﻝﺍ :(8 -IV) لﻜﺸﻝﺍ 270 nm 47 لﻤﻌﺘﺴﻤﻝﺍ ﺭﺘﻤﻭﺘﻭﻓﻭﺭﺘﻜﻴﺒﺴ ﺯﺎﻬﺠ لﺜﻤﻴ :(9-IV) لﻜﺸﻝﺍ

48 لﻤﻌﻝﺍ ﺔﻘﻴﺭﻁ :(10-IV) لﻜﺸﻝﺍ

(10)

لﺎﻜﺸﻷﺍ ﺔﻤﺌﺎﻗ 51 ﻭ ^[phe]ﺹﻤﺩﻤﻝﺍ ﺭﻴﻏ لﻭﻨﻴﻔﻝﺍ ﺯﻴﻜﺭﺘ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ :(11 -IV) لﻜﺸﻝﺍ

ﺹﺎﺼﻤﺩﻹﺍ ﺩﻭﺩﺭﻤﻝﺍ R(%)

ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﻰﻠﻋ [phe]= mg/l

،

T=21°^C

، mCa=0.^1g .

53 لﺘﻜ ﺩﻨﻋ ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ لﻭﻨﻴﻔﻝﺍ ﺕﺍﺭﻴﻐﺘ ﻲﻨﺤﻨﻤ:(12-IV) لﻜﺸﻝﺍ ﻁﺸﻨﻤﻝﺍ ﻡﺤﻔﻝﺍ ﻥﻤ ﺔﻔﻠﺘﺨﻤ

[phe]=100^mg/l

، T=21°^C

54 ﺩﻨﻋ ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ ﺭﻴﻏ لﻭﻨﻴﻔﻝﺍ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ :(13-IV) لﻜﺸﻝﺍ ﻡﺤﻔﻝﺍ ﻥﻤ ﺔﻔﻠﺘﺨﻤ لﺘﻜ

[phe]=100^mg/l

، T=21°^C

55 ﻥﻤ ﺔﻔﻠﺘﺨﻤ لﺘﻜ ﺔﻝﻻﺩﺒ ﺹﺎﺼﻤﺩﻹﺍ ﺩﻭﺩﺭﻤ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ :(14 -IV) لﻜﺸﻝﺍ ﻁﺸﻨﻤﻝﺍ ﻡﺤﻔﻝﺍ

[phe]=100^mg/l

، T=21°^C

56 ^ا ^ا ^ا ^ل ^{ا تا} ^! :(15-IV)لﻜﺸﻝﺍ

ل ا " #ا ا m_Ca=0.1^g

، T=21°^C

57 ﺩﻨﻋ ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ لﻭﻨﻴﻔﻝﺍ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ _:(16-_IV₎ $%& ا لﻭﻨﻴﻔﻝﺍ ﻥﻤ ﺔﻔﻠﺘﺨﻤﻝﺍ ﺯﻴﻜﺍﺭﺘﻝﺍ

mCa=0.1^g

، T=21°^C

57 ﺯﻴﻜﺍﺭﺘﻝﺍ ﺔﻝﻻﺩﺒ ﺹﺎﺼﻤﺩﻹﺍ ﺩﻭﺩﺭﻤ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ :(17-IV)لﻜﺸﻝﺍ ﺔﻔﻠﺘﺨﻤﻝﺍ ﺔﻴﺌﺍﺩﺘﺒﻻﺍ

mCa=0.1^g

، T=21°^C

59 ﺩﻨﻋ ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ ﺭﻴﻏ لﻭﻨﻴﻔﻝﺍ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ:(18 -IV) لﻜﺸﻝﺍ ﺔﻔﻠﺘﺨﻤ ﺓﺭﺍﺭﺤ ﺕﺎﺠﺭﺩ [phe]=100^mg/l

، m_Ca=0.1^g

60 ﺩﻨﻋ ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ لﻭﻨﻴﻔﻝﺍ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ:(19 -IV) لﻜﺸﻝﺍ ﺔﻔﻠﺘﺨﻤ ﺓﺭﺍﺭﺤ ﺕﺎﺠﺭﺩ [phe]=100^mg/l

، mCa=0.1^g

60 ﺔﻔﻠﺘﺨﻤ ﺓﺭﺍﺭﺤ ﺕﺎﺠﺭﺩ ﺔﻝﻻﺩﺒ ﺩﻭﺩﺭﻤﻝﺍ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ :(20 -IV) لﻜﺸﻝﺍ [phe]=100^mg/l

، mCa=0.1^g

(11)

لﺎﻜﺸﻷﺍ ﺔﻤﺌﺎﻗ 62 ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ ﺭﻴﻏ لﻭﻨﻴﻔﻝﺍ ﺯﻴﻜﺭﺘ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ:(21 -IV) لﻜﺸﻝﺍ

ﻡﻴﻗ ﺩﻨﻋ ﺔﻔﻠﺘﺨﻤ pH

[phe]=100^mg/l

، mCa=0.1^g

62 ﺩﻨﻋ ﻥﻤﺯﻝﺍ ﺔﻝﻻﺩﺒ ﺹﻤﺩﻤﻝﺍ لﻭﻨﻴﻔﻝﺍ ﺯﻴﻜﺭﺘ ﺕﺍﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ:(22 -IV) لﻜﺸﻝﺍ ﻡﻴﻗ ﺔﻔﻠﺘﺨﻤ pH

[phe]=100^mg/l

، m_Ca=0.1^g

63 ﻰﻠﻏ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ ﺩﻭﺩﺭﻤ ﻰﻠﻋ ^pHـﻝﺍ ﺭﻴﺜﺄﺘ ﻰﻨﺤﻨﻤ :(23 -IV) لﻜﺸﻝﺍ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ [phe]=100^mg/l

، mCa=0.1^g

66 ﺔﻴﺒﻴﺭﺠﺘﻝﺍ ﻥﺍﺯﺘﻻﺍ ﺩﻨﻋ ﺹﺎﺼﻤﺩﻹﺍ ﺔﻌﺴ ﺭﻴﻐﺘ ﻰﻨﺤﻨﻤ :(24 -IV) لﻜﺸﻝﺍ ﺔﻝﻻﺩﺒ ﺹﺎﺼﻤﺩﻺﻝ ﺯﻴﻜﺍﺭﺘ ﻡﻴﻗ

ﺔﻔﻠﺘﺨﻤ

ﻤﺩﻤﻝﺍ ﺭﻴﻏ لﻭﻨﻴﻔﻠﻝ ﻥﺍﺯﺘﻻﺍ ﺩﻨﻋ ﺹ

67 ﺵﻴﻝﺩﻨﺍﺭﻓ ﻡﺭﺘﻭﺯﻴﻹ ﻲﺒﻴﺭﺠﺘﻝﺍ ﻲﻁﺨﻝﺍ ﻥﺎﻴﺒﻝﺍ :(25 -IV)ﻡﻗﺭ $%& ا 69 ﺭﻴﻤﺠﻨﻻ ﻡﺭﺘﻭﺯﻴﺇ ﻲﻁﺨﻝﺍ لﻜﺸﻝﺍ :(26 -IV)ﻡﻗﺭ $%& ا

(12)

لﻭﺍﺩﺠﻝﺍ ﺔﻤﺌﺎﻗ

ﺔﺤﻔﺼﻝﺍ لﻭﺍﺩﺠﻝﺍ ﺔﻤﺌﺎﻗ

5 لﻭﻨﻴﻔﻠﻝ ﺔﻴﺌﺎﻴﻤﻴﻜﻝﺍﻭ ﺔﻴﺌﺎﻴﺯﻴﻔﻝﺍ ﺹﺌﺎﺼﺨﻝﺍ : ( 1 -I) لﻭﺩﺠﻝﺍ 11 ﺭﺼﻋ ﻩﺎﻴﻤﻝ ﺔﻴﺌﺎﻴﻤﻴﻜﻝﺍﻭ ﺔﻴﺌﺎﻴﺯﻴﻔﻝﺍ ﺹﺌﺎﺼﺨﻝﺍ ﺽﻌﺒ :(2-I) لﻭﺩﺠﻝﺍ ﻥﻭﺘﻴﺯﻝﺍ

12 ﺔﻴﻋﺍﺭﺯﻝﺍ ﺕﺍﺩﻴﺒﻤﻝﺍ :(3 -I) لﻭﺩﺠ

17 ﺹﺎﺼﻤﺩﻹﺍ ﻭ ﻲﺌﺎﻴﺯﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﻹﺍ ﻥﻴﺒ ﻕﻭﺭﻔﻝﺍ ﺽﻌﺒ :(1 -II) لﻭﺩﺠﻝﺍ ﻲﺌﺎﻴﻤﻴﻜﻝﺍ

18 ﺏﻠﺼﻝﺍ ﻡﺴﺠﻝﺍ ﺕﺎﻤﺎﺴﻤ ﻑﻴﻨﺼﺘ :(2 -II) لﻭﺩﺠﻝﺍ 26 ﺕﺎﺼﻤﺩﻤﻝﺍ ﺽﻌﺒﻝ ﺔﻴﺌﺎﻴﺯﻴﻔﻝﺍ ﺹﺌﺎﺼﺨﻝﺍ :(1 -III) لﻭﺩﺠﻝﺍ 28 ﻁﺸﻨﻝﺍ ﻡﺤﻔﻠﻝ ﺔﻨﻭﻜﻤﻝﺍ ﺔﻴﺌﺎﻴﻤﻴﻜﻝﺍ ﺭﺼﺎﻨﻌﻝﺍ ﺽﻌﺒ ﺏﺴﻨ :(2 -III) لﻭﺩﺠﻝﺍ ﻊﻨﺼﻤﻝﺍ ﺔﻔﻠﺘﺨﻤ ﺩﺍﻭﻤ ﻥﻤ

39 -

40 لﻤﻌﺘﺴﻤﻝﺍ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﺹﺍﻭﺨ:(1 -IV) لﻭﺩﺠﻝﺍ 41 لﻤﻌﺘﺴﻤﻝﺍ لﻭﻨﻴﻔﻝﺍ ﺹﺍﻭﺨ:(2 -IV) لﻭﺩﺠﻝﺍ 46 لﻭﻨﻴﻔﻝﺍ ﻥﻤ ﺔﻔﻠﺘﺨﻤ ﺯﻴﻜﺍﺭﺘ ﺔﻴﺼﺎﺼﺘﻤﺍ :( -3 IV) لﻭﺩﺠﻝﺍ 50 ^[phe]=100 ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﻰﻠﻋ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ ﺞﺌﺎﺘﻨ :(4 -IV) لﻭﺩﺠﻝﺍ

،mg/l m_Ca=0.^1g

، .^T=21°^C

52 ﻲﻓ ﺕﻤﺩﺨﺘﺴﺍ ﻲﺘﻝﺍ ﺔﺼﻤﺩﻤﻝﺍ ﺩﺍﻭﻤﻝﺍ ﺽﻌﺒﻝ ﻥﺍﺯﺘﻻﺍ ﻥﻤﺯ :(5 - IV)لﻭﺩﺠ لﻭﻨﻴﻔﻝﺍ ﺹﺎﺼﻤﺩﺇ 63

-

64 ﺹﺎﺼﻤﺩﺇ^pHلﻭﺤ ﺔﻘﺒﺎﺴﻝﺍ ﺕﺎﺴﺍﺭﺩﻝﺍ ﺞﺌﺎﺘﻨ ﺽﻌﺒ :(11- IV ) لﻭﺩﺠﻝﺍ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﻰﻠﻋ لﻭﻨﻴﻔﻝﺍ .

67 ﺩﻴﺩﺤﺘﻝﺍ لﻤﺎﻌﻤ ﻭ ﺵﻴﻝﺩﻨﺍﺭﻓ ﺕﺒﺍﻭﺜ ﻡﻴﻗ (13 -IV) :لﻭﺩﺠﻝﺍ

(13)

لﻭﺍﺩﺠﻝﺍ ﺔﻤﺌﺎﻗ

68 ﺔﺼﻤﺩﻤﻝﺍ ﺔﻴﻤﻜﻝﺍ ﻭ ﺹﻤﺩﻤﻝﺍ ﺭﻴﻏ لﻭﻨﻴﻔﻝﺍ ﺯﻴﻜﺭﺘ ﺕﺍﺭﻴﻐﺘ (14 -IV) لﻭﺩﺠﻝﺍ ﺏﻠﺼﻝﺍ ﻡﺴﺠﻝﺍ ﺔﻠﺘﻜ ﺓﺩﺤﻭ ﻲﻓ 70 ﺕﺎﻴﻠﻤﻋ لﻭﺤلﻭﺤ ﺔﻘﺒﺎﺴﻝﺍ ﺕﺎﺴﺍﺭﺩﻝﺍ ﺞﺌﺎﺘﻨ ﺽﻌﺒ :(15 -IV) لﻭﺩﺠﻝﺍ ﺹﺎﺼﻤﺩإ لﻭﻨﻴﻔﻝﺍ

ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﻰﻠﻋ ﺵﻴﻝﺩﻨﻭﺭﻓ ﺝﺫﻭﻤﻨ ﻕﻘﺤﺘ ﻲﺘﻝﺍ

(14)

تا ا لو

ر ا

ﺔﻴﺯﻴﻠﺠﻨﻹﺍ ر ا

EPA Environmental Protection

Agency ﺔﻴﻜﻴﺭﻤﻷﺍ ﺔﺌﻴﺒﻝﺍ ﺔﻴﺎﻤﺤ ﺔﺌﻴﻫ

CAS Chimical Abstracts Service ﺕﺎﺼﻠﺨﺘﺴﻤﻝﺍ ﺕﺎﻤﺩﺨ ﺓﺭﺌﺍﺩ ﺔﻴﺌﺎﻴﻤﻴﻜﻝﺍ IUPAC International union of pure and

applied chemistry ﺔﻓﺭﺼﻝﺍ ﺀﺎﻴﻤﻴﻜﻠﻝ ﻲﻤﻝﺎﻌﻝﺍ ﺩﺎﺤﺘﻻﺍ ﺔﻴﻘﻴﺒﻁﺘﻝﺍ ﻭ BET Brunauer Deming Teller ﺭﻠﻴﺎﺘ ﻎﻨﻴﻤﻴﺩ ﺭﻭﻨﺍﺭﺒ USB Unity Structural Basis ﺱﺎﺴﻸﻝ ﺔﻴﺌﺎﻨﺒﻝﺍ ﺓﺩﺤﻭﻝﺍ

GAC Granular actived carbon ﻲﺒﻴﺒﺤ ﻁﺸﻨ ﻥﻭﺒﺭﻜ

PAC Powder actived carbon ﻕﻭﺤﺴﻤ ﻁﺸﻨ ﻥﻭﺒﺭﻜ

AC Actived carbon ﻁﺸﻨ ﻥﻭﺒﺭﻜ

Omww Olive mille waste water ﺭﺼﺎﻌﻤ ﻥﻋ ﺔﺠﺘﺎﻨﻝﺍ ﻑﺭﺼﻝﺍ ﻩﺎﻴﻤ ﻥﻭﺘﻴﺯﻝﺍ Steam-PAC Steam- Powder actived carbon ﻕﻭﺤﺴﻤ ﻁﺸﻨ ﻥﻭﺒﺭﻜ -ﺭﺎﺨﺒ Chemical-PAC Chemical- Powder actived

carbon

ﻕﻭﺤﺴﻤ ﻁﺸﻨ ﻥﻭﺒﺭﻜ ﻲﺌﺎﻴﻤﻴﻜ

(15)

ﺹﺨﻠﻤﻝﺍ

:

ﻹﺍ ﺔﺴﺍﺭﺩ لﻤﻌﻝﺍ ﺍﺫﻫ لﻼﺨ ﻡﺘ

ﻭﻠﻤﻝﺍ ﻩﺎﻴﻤﻝﺍ ﺔﺠﻝﺎﻌﻤﻝ ﺔﻴﻨﻘﺘﻜ ﺹﺎﺼﻤﺩ لﻭﻨﻴﻔﻝﺎﺒ ﺔﺜ

ﺎﺒ

ﻤﺩﻤﻜ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ لﺎﻤﻌﺘﺴ لﺜﻤ ﺔﻴﻠﻤﻌﻝﺍ ﻩﺫﻫ ﻰﻠﻋ ﺓﺭﺜﺅﻤﻝﺍ لﻤﺍﻭﻌﻝﺍ ﻑﻠﺘﺨﻤ ﺔﻓﺭﻌﻤﻭ ﺹ

:

،ﺓﺭﺍﺭﺤﻝﺍ ﺔﺠﺭﺩ pH

لﻭﻨﻴﻔﻝﺍ ﺯﻴﻜﺭﺘﻭ ﻁﺸﻨﻝﺍ ﻡﺤﻔﻝﺍ ﺔﻠﺘﻜ ،ﻁﺴﻭﻝﺍ .

لﻭﺼﻭﻝﺍ ﻑﺩﻬﺒ ﺇ

ﻰﻝ

ﺔﻴﻝﺎﺜﻤﻝﺍﻭ ﺔﻤﺌﻼﻤﻝﺍ ﻁﻭﺭﺸﻝﺍ ﻪﻴﻠﻋ لﺼﺤﺘﻨ ﻥﺃ ﻥﻜﻤﻴ ﻱﺫﻝﺍ ﺩﻭﺩﺭﻤ ﻰﻠﻋﺃ ﻕﻴﻘﺤﺘﻝ

.

Résumé :

ce travail montre l'adsorption comme un procédé de traitement des eaux polluées par le phénol en utilisant le charbon actif comme absorbant et permis aussi de voir les différents paramètres influençant ce procédé : la température, le pH, la masse de charbon actif, la concentration de phénol afin d’assurer les conditions optimales pour a un bon rendement.

Abstract :

This work shows the adsorption as a process to treat water polluted with phenol using activated carbon as an absorbent. And also allowed to see the various factors effecting this process such as :temperature, pH, activated carbon mass and phenol concentration . In order to have access to ideal conditions to achieve the highest yields that we can get