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Nano-sampling of metals with ultra-short laser pulses

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HAL Id: cea-02434550

https://hal-cea.archives-ouvertes.fr/cea-02434550

Submitted on 10 Jan 2020

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Nano-sampling of metals with ultra-short laser pulses

A. Semerok, Sv. Fomichev

To cite this version:

A. Semerok, Sv. Fomichev. Nano-sampling of metals with ultra-short laser pulses. EMSLIBS 2017

- Colloquium Spectroscopicum Internationale XL 9th Euro-Mediterranean Symposium on LIBS, Jun

2017, Pise, Italy. �cea-02434550�

(2)

Nano-sampling of metals with ultra-short laser pulses

Alexandre Semerok *

A

, Sergey V. Fomichev

B, C

A

DEN-Service d’Etudes Analytiques et de Réactivité des Surfaces, CEA, Université Paris-Saclay,

F-91191 Gif-sur-Yvette, France;

B

National Research Center “Kurchatov Institute”, 123182 Moscow, Russia;

C

Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia.

*alexandre.semerok@cea.fr

ABSTRACT: In sample microanalysis by laser ablation (LA), spatial resolution is determined by laser beam diffraction lim-its (of the order of a laser wavelength) and thermal diffusion of a deposited heating energy during laser pulse (proportional to the square root of pulse duration and matter diffusivity). Being limited by these laser beam features and those of heating en-ergy, spatial resolution (a crater diameter) of ∼1 µm was obtained with 4 ns laser pulses on 266 nm wavelength 1-2. To

im-prove spatial resolution of microanalysis, the application of lasers with the pulses of shorter durations (ps and fs) may be advised 3-5. As another way to improve spatial resolution of microanalysis up to ∼100 nm, one may advise LA with a highly localized laser field created by a tip near-field enhancement 6. The experiments with ns laser pulses were made along with multi-parametric theoretical studies 7 based on one-temperature heating model.

In this work, the theoretical studies were extended on ultra-short laser pulses (ps or fs) to analyze the effect of pulse duration and matter properties (absorption coefficient, thermal conductivity and capacity) on the resulting temperature field spatial distribution T (t, x, y, z). A two-temperature model was applied for T (t, x, y, z) calculations. The results of these simulations are compared to temperature distributions for ns laser pulses. Discussion on advantagesof ultra-short pulses application for LA with a tip near-field enhancement for consecutive chemical analysis with nanometric resolution will be presented.

References:

1. D. Menut, P. Fichet, J.-L. Lacour, A. Rivoallan and P. Mauchien, Applied Optics. 42 (2003) 6063-6071.

2. P. Mauchien, J.-L. Lacour, N. Caron, EMSLIBS 2011, Izmir, Turkey, oral presentation “LIBS for microanalysis and chemical imaging”.

3. V. Zobra, X. Mao, R.E. Russo, Spectrochimica Acta Part B, 66 (2011) 189-192.

4. Y. Lu, V. Zorba, X. Mao, R. Zheng and R. E. Russo, J. Anal. At. Spectrom., 28 (2013) 743–748. 5. R.E. Russo, X. Mao, J.J. Gonzales, V. Zobra, J. Yoo, Analytical Chemistry, 85 (2013) 6162-6177.

6. C. Jabbour, J.-L. Lacour, M Tabarant, A. Semerok, F. Chartier, J. Anal. At. Spectrom., 31 (2016) 1534–1541.

7. A. Semerok, C. Jabbour, S.V. Fomichev, J-L Lacour, M Tabarant, F. Chartier, LIBS 2016, Chamonix, France, oral presentation “Multi-parametric modeling of solid sample heating by nanosecond laser pulses in application for nano-ablation”.

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