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REDUCE NOX

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(1)

Brice Piednoir, Jean-Michel Commandré, Anthony Benoist, Sarah El Fassi, Gilles Vaitilingom

Research Unit BioWooEB, Doctoral School

BIOMASS BLENDING AS A WAY TO

REDUCE NO

X

EMISSIONS DURING THE

COMBUSTION OF BIOMASS RESIDUES

(2)

Concerns regarding

greenhouse gas emissions

 Bioenergy

Growing pressure on wood

Valorization of agricultural residues

Slagging, fouling,

(3)

Approach

Which compounds contained in biomass can

influence NO

x

emissions ?

Can synergies be implemented by biomass blending

to reduce NO emissions ?

Procedure

Selection of

biomass residues

Lab scale

pelletization

Combustion

experiments

(4)

NO emissions: blending strategy

Influence of N

Combustion

of « pure »

samples

Blend: extremal

N-content samples

Pine Bark &

Grape Marc

Influence of Ca

Ca CST

N

CST

Ca/N

CST

Rice Husk &

Rape Straw

Rice Husk &

Olive Pomace

(5)

Combustion setup

N2: 79% O2: 21%

Total flow rate: 3,8 Nl.min-1

T = 800 °C To exhaust Gas Analyser N2 O2 TR2 = 650 °C T = 10 °C NO O2 CO2 CO Heated zone Cold zone T = 30 °C (1) (2) (3) (4) (5) (6) (8) (9) (7) mpellet = 500mg (10)

(6)

Typical emission profiles: CO and CO

2

Low CO concentration:

• < 1 000 ppm (0,1%vol)

Efficient combustion:

𝐶𝑂+𝐶𝑂2 𝐹𝑢𝑒𝑙−𝐶 > 90%

𝐶𝑂 𝐶𝑂+𝐶𝑂2

<

1,5%

(7)
(8)

Blending strategy

Influence of N

Combustion

of « pure »

(9)

NO emissions and N-content for the

fuels selected in this study

Criterion : grams of NO emitted for 100 g of biomass

(dry basis)

(10)

Blending strategy

Influence of N

Combustion

of « pure »

samples

Blend: extremal

N-content samples

Pine Bark &

Grape Marc

(11)
(12)

NO emissions: Pine Bark & Grape Marc

0,9%N

(13)

NO emissions: Pine Bark & Grape Marc

Gap between theoretical and

experimental results

(14)

Blending strategy

Influence of Ca

Ca CST

N

CST

Ca/N

CST

Rice Husk &

Rape Straw

(15)

Gap between theoretical and

experimental results : fixed %N

(16)

Blending strategy

Influence of Ca

Ca CST

N

CST

Ca/N

CST

Rice Husk &

Olive Pomace

(17)

Gap between theoretical and

experimental results : fixed Ca/N

(18)

Conclusions on NO emissions

Influence of N

Correlation

on « pure »

samples

Non linearity for

blends

Influence of Ca

Ca CST

N

CST

Ca/N

CST Vol-NO ? Low nonlin. No effect Char-NO Low nonlin. Nonlin Global NO No effect Reduc-tion

(19)

Thank you for your

attention

Contact:

brice.piednoir@cirad.fr

Work fully financed by:

CIRAD

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