5 EXPERIMENTAL RESULTS
5.3 Isolator characterization tests
5.3.3 EQSB isolator
- Otimizar as condições de síntese utilizando como emulsificante Tween 80, a fim de obter microcápsulas com maiores diâmetros e maior taxa de encapsulamento.
- Utilizar como agente encapsulado outro tipo de monômero epóxi tal como éter diglicidil de bisfenol F (DGEBF).
- Utilizar as microcápsulas de epóxi com casca de epóxi-amina em materiais compósitos a fim de investigar o processo de autorreparo por meio de testes mecânicos.
REFERÊNCIAS
1 ZHANG, M. Q., ZHU, D. Y.,RONG,M.Z., Self-healing polymeric materials based
on microencapsulated healing agents: From design to preparation. Progress in Polymer Science 49–50,175–220- 2015.
2 WU, DY, MEURE, S., SOLOMON, D., Self-healing polymeric materials: areview
of recent developments. ProgPolymSci, 33:479–522, 2008.
3 WOOL, R. P., Self-healing materials: a review. Soft Matter, 4:400–18, 2008. 4 MURPHY, E. B., WUDL, F., The world of smart healable
materials.ProgPolymSci, 35:223–51, 2010.
5 HAGER MD., GREIL P., LEYENS, C., VAN, S.,SCHUBERT, US.Self-healing
materials.Adv Mater, 22:5424–30, 2010.
6 YANG Y.,URBAN, M. W., Self-healing polymeric materials. ChemSoc Rev;
42:7446–67, 2013.
7 VAIYAPURI, R., GREENLAND,BW., COLQUHOUN, HM, ELLIOTT, JM.,
HAYES, W., Evolution of supramolecular healable composites: a minireview.PolymInt, 63:933–42, 2014.
8 HILLEWAERE, X. K.D.,PREZ, F. E. D., Fifteen chemistries for autonomous
external self-healing polymers and composites. Progress in Polymer Science 49– 50 ,121–153, 2015.
9 SAMADZADEH, M., BOURA, S. H., PEIKARIA, M., KASIRIHA, S.M., ASHRAFI,
A., A review on self-healing coatings based on micro/nanocapsules. Progress in Organic Coatings 68, 159–164, 2010.
10 IONOV, L., SYNYTSKA, A., Self-healing superhydrophobic materials. Phys.
Chem. Chem. Phys., 14, 10497–10502, 2012.
11 WHITE, S. R., SOTTOS, N.R., GEUBELLE, P.H, MOORE, J.S., KESSLER,
M.R., SRIRAM, S.R., BROWN, E. N., VISWANATHAN, S., Autonomic healing of polymer composites.Nature;409:794–7, 2001.
12 YUAN, L., LIANG, G.Z., XIE, J.Q.,HE, S.B., Colloid Polym. Sci. 285, 781-2007. 13 SURYANARAYANA, C., K. CHOWDOJI, R., KUMAR, D., Prog. Org. Coat. 63,
72, 2008.
14 LEE, J. K., HONG, S. J., LIU X., Characterization of Dicyclopentadiene and 5-
Ethylidene-2-norbornene as Self-healing. Agents for Polymer Composite and Its Microcapsules.Macromolecular Research, Vol. 12, No. 5, pp 478-483, 2004.
15 COSCO, S., AMBROGI, V., MUSTO P., CARFAGNA, C.,Macromol. Symp.234
(2006) 184, 2006.
16 LIÃOL.P., ZHANG, W., Chin. Sci. Bull. 56, 439, 2011.
17 LIU, X., ZHANG, H., WANG, J., WANG, Z., WANG, S., Preparation of epoxy
microcapsule based self-healing coatings and their behavior. Surface & Coatings Technology 206, 4976–4980, 2012.
18 LEE, H., NEVILLE, K., Handbook of Epoxy Resin, McGraw Hill, New York,
1967.
19 RICCARD, C.C., ADABBO H.E., WILLIAMS, R.J.J., Appl. Polym. Sci. 29, 2481,
1984.
20 ELLIS, B., Chemistry and Technology of Epoxy Resins, Blackie Academic and
Professional,London, 1993.
21 WANG, D.Z., Production and Applications of Epoxy Resins, Chemical
IndustryPress, China, 2002.
22 LIANG, G.-Z., YUAN,L.,XIE, J.Q.,GUO, J.,LI, L., Thermal stability of
microencapsulated epoxy resins withpoly(urea-formaldehyde). Polymer Degradation and Stability 91, 2300 e 2306, 2006.
23 YUAN, L., GU, A., LIANG, G., Preparation and properties of poly(urea–
formaldehyde) microcapsules filled with epoxy resins. Materials Chemistry and Physics 110, 417–425, 2008.
24 WHITE, N. R., JIN, H., MANGUN, C. L.,STRADLEY, D.S.,MOORE, J. S.,
SOTTOS,Self-healing thermoset using encapsulated epoxy-amine healing chemistry.Polymer 53, 581e 587, 2012.
25 YUAN, Y. C., YIN, T., RONG, M. Z., ZHANG, M. Q., Self-healing in polymers
and polymer composites. Concepts, realization and outlook: a review. Express PolymLett, 2:238e50, 2008.
26 TONG, X.M., ZHANG, T., YANG, M.Z., ZHANG, Q., Colloids Surf. A:
Physicochem. Eng. Aspects, 371, 91,2010.
27 SOTTOS, N.R., BLAISZIK, B.J., CARUSO, M.M., MCLLROYC, D.A.,
MOOREB, J., WHITE, S.R., Microcapsules filled with reactive solutions for self- healing materials.Polymer 50, 990–997, 2009.
28 KHOEE,S., PAYANDEH, S. H., JAFARZADEH, P., ASADI,H., Size and core
content optimization of epoxy nanocapsules by response surfacemethodology for use in self-healing coatings. Smart Mater.Struct.25 084014 (13pp), 2016.
29 GIAMBERINI, M., PASCU, O., VALLS-GARCIA, R., Interfacial polymerization
of an epoxy resin and carboxylic acids for the synthesis of microcapsules. Polym Int 57:995–1006, 2008.
30 PONCELET, D., PERIGNON, C., ONGMAYEB, G., NEUFELD, R., FRERE, Y.,
Microencapsulation by interfacial polymerisation: membrane formation and structure. J Microencapsul, 32(1): 1–15, 2015.
31GASSAN, J., DIETZ, T., Compos.Sci.Technol., 61, 157, 2001. 32LI, M. C., GE, X., CHO, U. R., Macromol. Res., 21, 519, 2013. 33LI, M. C., ZHANG, Y. H., CHO, U. R.,Mater.Des., 63, 565, 2014.
34 MA, W., ZHANG, W., ZHAO, Y., YU, H., Preparation and assessment of a self-
healing material based on microcapsules filled with ethyl phenylacetate. J. APPL. POLYM. SCI. 2016.
35 SKORB, E. V., ANDREEVA, D. V. Layer-by-layer approaches for formation of
36 WEI, Z., YANG, J. H., ZHOU, J., XU, F., ZRÍNVI, M., DUSSAULT, P.H., et al.
Self-healing gels based on constitutional dynamic chemistry and their potential applications. Chem Soc Ver,43:8 114 e 31, 2014.
37 MAULDIN, T. C., KESSLER, M. R., Self-healing polymers and composites.
Int. Mater. Rev.,55:317 e 46, 2010.
38 WU, X. F., YARIN, A. L. Recent progress in interfacial toughening and damage
selfhealingof polymer composites based on electrospun and solution- blownnanofibers: an overview. J. Appl. Polym. Sci, 130:2225e37, 2013.
39 WILLIAMS, K. A., DREYER, D.R., BIELAWSKI, C.W., The underlying
chemistry of self-healing materials. MRS Bull, 33:759 e 65, 2008.
40 BENIGHT, S. J., WANG, C., TOK, J. B. H., BAO, Z., Stretchable and self-
healing polymers and devices for electronic skin. Prog.Polym.Sci.; 38:1961 e 77, 2013.
41 GHOSH, S. K., Self-healing materials: fundamentals, design strategies, and
applications.In: Ghosh SK, editor. Self-Heal. Mater. Wiley-VCH Verlag GmbH & Co. KGaA; p. 1 e 28., 2008.
42 KIIL, S., NESTEROVA,T., JOHANSEN, K.D., Synthesis of durable
microcapsules for self-healing anticorrosive coatings: A comparison of selected methods, Progress in Organic Coatings 70, 342–352, 2011.
43 WANG, Y., PHAM, D. T., Self-healing composites: A review. Cogent
Engineering, 2: 1075686, 2015.
44 VIJAYAN, P., ALMAADEED, M. A., Containers for self-healing epoxy
composites and coating:Trends and advances. Express Polymer Letters Vol.10, No.6 506–524, 2016.
45 CRESPY, D., LANDFESTER K., Miniemulsion polymerization as a versatile
tool for the synthesis of functionalized polymers.Beilstein J Org Chem; 6:1132– 48, 2010.
46 UGELSTAD, J., El-ASSER, M.S., VANDERHOFF, J.W., Emulsion
Polymerization:initiation of polymerization in monomer droplets. J PolymSci: PolymLett Ed;11:503–13, 1973.
47 FICKERT, J., MAKOWSKI, M., KAPPL, M., LANDFESTER, K., CRESPY,
D.,Efficient encapsulation of self-healing agents in polymer nanocontainers functionalized by orthogonal reactions. Macromolecules;45:6324–32, 2012.
48 LANDFESTER, K.,TIARKS, F., ANTONIETTI, M., Preparation of Polymeric
Nanocapsules by MiniemulsionPolymerization.Langmuir, 17, 908-918, 2001.
49 AVEYARD, R., BINKS, B. P., CLINT, J. H., Emulsions stabilised solely by
coloidal particles. Adv Colloid Interface Sci ;100–102:503–46, 2003.
50 GANDER, B., FREITAS, S., MER KLE, H. P., Microencapsulation by solvent
extraction/evaporation: reviewing the state of the art of microsphere preparation process technology. Journal of Controlled Release 102,313–332, 2005.
51 THIES, C. In Drugs and the Pharmaceutical Sciences; Benita, S., Ed.;Marcel
Dekker: New York, Vol. 73, pp 1-19, 1996.
52 (a) BAKHSHAEE, M.; PETHRICK, R. A.; RASHID, H.; SHERRINGTON, D.
C.Polym.Commun., 26, 185-192,1985. (b) GREEN, B. K.; SCHLEICHER,L. U.S. Patent 2800457,Chem. Abstr.1957,51, 87338, 1957. (c) SCHER,H. B.; RODSON, M.; LEE, K.-S.Pest.Sci.,54, 394-400, 1998. (d) CHANG,T. M. S.Artificial Cells; Charles C. Thomas: Springfield, 1972.(e)TSUJIi, K. InMicrospheres Microcapsules & Liposomes; Arshady, R.,Ed.; Citus Books: London, Vol. 1, pp 349-371, 1999.
53 ARSHADY, R. InMicrospheres Microcapsules & Liposomes; Arshady,R., Ed.;
Citus Books: London, Vol. 1, pp 93-96, 1999.
54 MCQUADE, D. T., KOBASLIJA, M., Polyurea Microcapsules from Oil-in-Oil
Emulsions via Interfacial Polymerization. Macromolecules,39,6371-6375, 2006.
55 ICHIURA,H.,MORIKAWA,M., NINOMIYA, J., Preparation of smart paper part
I—formation of nylon microcapsules on paper surface using interfacial polymerization. J Mater Sci,41:7019–7024, 2006.
56 LI, Q., HE, Z., SHUAI, J., WANG, J., ZHAO, Y., Facile and cost-effective
synthesis of isocyanate microcapsules via polyvinyl alcohol-mediated interfacial polymerization and their application in self-healing. Composites Science and Technology 138, 15 e 23, 2017.
57 BROWN, EN, SOTTOS, NR, WHITE, SR. Fracture testing of a self-healing
polymer composite. ExpMech, 42:372–9, 2002.
58 YANG, J, KELLER, MW., MOORE, JS., WHITE, SR., SOTTOS, NR.
Microencapsulation of isocyanates for self-healing polymers. Macromolecules,41: 9650–5, 2008.
59 MCLLROY, DA., BLAISZIK, BJ., CARUSO, MM., WHITE, SR., MOORE, JR.,
SOTTOS, NR. Microencapsulation of a reactive liquid-phase amine for self- healing epoxy composites. Macromolecules, 43:1855–9, 2010.
60 KELLER, MW., SOTTOS, NR. Mechanical properties of microcapsules used in
a self-healing polymer. ExpMech, 46:725–33, 2006.
61 ODEGARD, G. M., BANDYOPADHYAY, A., Molecular Modeling of Physical
Aging in Epoxy Polymers, J. APPL. POLYM. SCI. 2013.
62 WANG,R., HU, H., LIU, W.,HE, X.,GUO, Q. ,The Effect of Synthesis Condition
on Physical Properties of Epoxy-Containing Microcapsules. Journal of Applied Polymer Science, Vol. 124, 1866–1879, 2012.
63 WANG, H.,HU, S.,CAI, S.,YU, F. Preparation and properties of bisphenol A
epoxy resinmicrocapsules coated with melamine–formaldehyde resin. Polym. Bull. 71:2407–2419, 2014.
64 ZHANG, M. Q., YIN, T., RONG, M. Z., YANG, G. C.,Self-healing epoxy
composites – Preparation and effect of the healant consisting of microencapsulated epoxy and latent curing agent. Composites Science and Technology 67, 201–212, 2007.
65 HOSUR, M. V ,CHOWDHURY, R. A., NURUDDINA, Md., TCHERBI-
composites: preparation, characterization and healing performance j materrest
technol,,4(1):33–43, 2015.
66 PASCAULT, J-P., WILLIAMS, R. J. J.: Epoxy polymers: New materials and
innovations. Wiley-VCH,Weinheim, 2010.
67 PASCAULT, J.P.,SAUTEREAU, H., VERDU,
J.,WILLIAMS,R.J.J,Thermosetting Polymers, Marcel Dekker , New York, 2002.
68 MATEJKA , L. , CHABANNE, P. , TIGHZERT , L. ,and PASCAULT, J.P. J.
Polym. Sci.,Part A: Polym. Chem. ,32, 1447, 1994.
69 LIANG, G. YUAN, L.,XIE, J.Q., LI,L., GUO,J., Preparation and characterization
of poly(urea-formaldehyde) microcapsules filled with epoxy resins, Polymer 47 5338–5349, 2006.
70 COSCO, S., AMBROGI, V., MUSTO, P., CARFAGNA, C., Properties of
Poly(urea-formaldheyde) Microcapsules Containing an Epoxy Resin. JournalofAppliedPolymerScience, Vol. 105, 1400–1411, 2007.
71 YUAN, L., GU, A., LIANG, G., Preparation and properties of poly(urea–
formaldehyde) microcapsules filled with epoxy resins. Materials Chemistry and Physics 110, 417–425, 2008.
72 YUAN, Y. C., RONG, M. Z.,ZHANG, M. Q., CHEN, J., YANG, G. C.,LI, X. M.,
Self-Healing Polymeric Materials Using Epoxy/Mercaptan as the Healant.Macromolecules, 41, 5197-5202, 2008.
73 SOTTOS N. R., MCLLROY, D. A., BLAISZIK B. J., CARUSO, M. M.,WHITE,
S.R.,MOOREJ.S., Microencapsulation of a Reactive Liquid-Phase Amine for Self-Healing Epoxy Composites. Macromolecules, 43, 1855–1859, 2010.
74 LEE, J., ZHANG, M., BHATTACHARYYA, D., YUAN,Y. C., JAYARAMAN, K.,
MAI, Y. W.,Micromechanical behavior of self-healing epoxy and hardener-loaded microcapsules by nanoindentation. Materials Letters 76, 62–65, 2012.
75 WANG, J., ZHANG, H., LIU, X., WANG, Z., WANG, S., High Performance Self-
Healing Epoxy/Polyamide Protective Coating Containing Epoxy Microcapsules and Polyaniline Nanofibers for Mild Carbon Steel.Ind. Eng. Chem. Res., 52, 10172−10180, 2013.
76 XIULAN, C. A. I., DATIAN, F. U., AILAN,Q. U, Effects of Processing Conditions
on the Properties of Epoxy Resin Microcapsule. Journal of Wuhan University of Technology-Mater.Sci., Aug.2015.
77 HALDER, S., KHAN, N. I., GOVAT, M. S., Effect of epoxy resin and hardener
containing microcapsules on healing efficiency of epoxy adhesive based metal joints. Materials Chemistry and Physics, 171 267e275, 2016.
78 ROY, P.K., TRIPATHI, M., KUMAR, D., Microencapsulation of reactive amine
by interfacially engineered epoxy microcapsules for smart applications, Iran Polym. J., 26:489–497, 2017.
79 OLLIER, R. P., ALVAREZ, V. A., Synthesis of epoxy-loaded poly(melamine-
formaldehyde) microcapsules: Effect of pH regulation method and emulsifier selection, Colloids and Surfaces A: Physico chem. Eng. Aspects 520, 872–882 2017.
80 ROSSI, C.G.F.T. Inibição à corrosão do aço AISI 1020, em meios ácidos e
salino, por tensoativos e substâncias nitrogenadas microemulsionados. 2007. 162p. Tese (Doutorado em Química), Programas de Pós-Graduação em Química, Universidade Federal do Rio Grande do Norte, Natal, 2007a. Disponível em: < http://ftp.ufrn.br/pub/biblioteca/ext/bdtd/CatiaGFTR.pdf>. Acesso em: 10 deabril 2017.
81 KUMAR, A., STEPHENSON, L.D., MURRAY, J.N., Prog. Org. Coat. 55, 244,
2006.
82 FERRARI, V. C. G. M.,LOURENÇO, V. L., DUTRA, R. C. L., DINIZ, M.
F.,AZEVEDO, M. F. P.,DAVID, L. H., Caracterização de um pré-impregnado aeronáutico por FTIR e análise térmica.Polímeros vol.22 no.4, 2012.
83 CHALMERS, J. M., Mid-Infrared Spectroscopy: Anomalies, Artifacts and
Common Errors. Handbook of vibrational spectroscopy, 2006.
84 SILVERSTEIN, R. M., WEBSTER, F. X., KIEMLE,D. J., Spectrometric
85 MIJOVIC, J., ANDJELIC, S., YEE, C.F.W., BELLUCCI, F., NICOLAIS, L., A
study of reaction kinetics by near infrared spectroscopy 2.Comparison with dielectric spectroscopy of model and multifunctional epoxy/amine. Macromolecules.Vol.28, No.8, pp. 2797-2806, ISSN 0024-9297, 1995.
86 PELOUX, J., TIGHZERT, L., PASCAULT, JP., MALINGE, J., SILLION, B.
Polymer Bulletin (Berlin); 20(2):207–13, 1988.
87 WANG, M. S.; PNNAVAIA, T. J, Chem Mater, 6, 468, 1994.
88 EDWARDS, H. G. M. In Handbook of Vibrational Spectroscopy; Chalmers, J.
M.; Griffiths, P. E., Eds.; Wiley: New York, 2002; Vol. 3, p 1838.