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Frost durability of Canadian clay bricks
Kung, J. H.
https://publications-cnrc.canada.ca/fra/droits
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Ser
Trn
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5 5 - , &
N21d
no.
1317
National ResearchConsel
nationalc . 2
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Council Canadad.
recherchesCanada
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Division of Division desBuilding Research recherches en biltiment
Frost Durability of Canadian Clay Bricks
by J.H. Kung
Reprinted from
Proceedings of the 7th International Brick Masonry Conference
Melbourne, Australia, 17 -20 February 1985 Vol. 1, p. 245
-
251(DBR Paper No. 1317)
Price $2.00 NRCC 24947
On a Bvaluk p a r d i v e r s e s mkthodes l a d u r a b i l i t k d e s b r i q u e s d ' a r g i l e exposges au g e l . L ' e s s a i d ' e x p a n s i o n p a r l e g e l de b r i q u e s s a t u r g e s permet d ' g v a l u e r prkciskment l e u r d u r a b i l i t g . Bien que l e s c r i t 2 r e s bas& s u r l e c o e f f i c i e n t de s a t u r a t i o n e t l ' a i r e de s u r f a c e s p k c i f i q u e s o i e n t u t i l e s , i l s dgpendent d e s m a t g r i a u x c o n s t i t u t i f s e t d e s prockdks de f a b r i c a t i o n . Les c o n d i t i o n s de c u i s s o n o p t i m a l e s peuvent t t r e d k d u i t e s d'une s 6 r i e de p o i n t s r e p r k s e n t a n t l e c o e f f i c i e n t d e s a t u r a t i o n
en
f o n c t i o n de l ' a i r e de s u r f a c e s p g c i f i q u e . Le c o n t r b l e de l a q u a l i t k p e u t S t r e amkliork s i on u t i l i s e simultangment l e c o e f f i c i e n t d ' a b s o r p t i o n e t c e l u i de s a t u r a t i o n . La d u d e de l ' e s s a i de c o n t r b l e de l a q u a l i t k , a c t u e l l e m e n t de 48 h e u r e s , p e u t d t r e r g d u i t e 3 1 h e u r e ou moins e n procgdant aux e s s a i sFROST DURARILITY OF CANADIAN CLAY BRICKS
J.H.
KUNG R e s e a r c h O f f i c e rD i v i s i o n of B u i l d i n g R e s e a r c h , N a t i o n a l R e s e a r c h C o u n c i l Canada, Ottawa, Canada, KIA OR6
ABSTRACT Some methods were used t o a s s e s s t h e f r o s t d u r a b i l i t y of c l a y
b r i c k s . Expansion on f r e e z i n g of s a t u r a t e d b r i c k s p r o v i d e s a v a l i d t e s t f o r t h e a s s e s s m e n t of t h e i r d u r a b i l i t y . Although c r i t e r i a b a s e d on s a t u r a t i o n c o e f f i c i e n t and s p e c i f i c s u r f a c e a r e a a r e u s e f u l , t h e y depend on t h e raw m a t e r i a l s and t h e m a n u f a c t u r i n g p r o c e s s e s . The optimum f i r i n g c o n d i t i o n can b e e s t i m a t e d from a p l o t of s a t u r a t i o n c o e f f i c i e n t a g a i n s t s p e c i f i c s u r f a c e a r e a . Q u a l i t y c o n t r o l can b e improved i f b o t h a b s o r p t i o n and s a t u r a t i o n c o e f f i c i e n t a r e used t o g e t h e r . The c u r r e n t q u a l i t y c o n t r o l t e s t i n v o l v i n g 48 h o u r s can b e reduced t o one h o u r o r less u s i n g s h o r t - t e r m a b s o r p t i o n t e s t s .
1. INTRODUCTION
I n Canada, t h e p r i n c i p a l c a u s e of masonry d e t e r i o r a t i o n i s t h e f r e e z i n g and thawing of c l a y b r i c k s . Although c u r r e n t b r i c k s p e c i f i c a t i o n s c o f i t a i n d u r a b i l i t y c r i t e r i a , t h e tests a r e time-consuming and t h e r e s u l t s a r e n o t r e l i a b l e . An I n d u s t r i a l R e s e a r c h F e l l o w s h i p Program was s p o n s o r e d j o i n t l y by t h e Clay B r i c k A s s o c i a t i o n of Canada and t h e D i v i s i o n of B u i l d i n g R e s e a r c h of t h e N a t i o n a l R e s e a r c h C o u n c i l of Canada, i n 1978. The purpose of t h e program was t o i d e n t i f y t h e p e r t i n e n t p h y s i c a l and m i n e r a l o g i c a l p r o p e r t i e s t h a t a r e r e s p o n s i b l e f o r f a i l u r e i n o r d e r t o e s t a b l i s h c r i t e r i a f o r p r o d u c t
improvement, t o improve q u a l i t y c o n t r o l and t o p r o v i d e a b e t t e r and f a s t e r t e s t f o r t h e f r o s t d u r a b i l i t y of c l a y b r i c k s . Nine t y p e s of commercially marketed b r i c k s manufactured by s i x p l a n t s were s t u d i e d . The program i n c l u d e d a s t u d y of t h e e f f e c t s of raw m a t e r i a l s , forming methods and h e a t g r a d i e n t i n k i l n s . The h i g h l i g h t s of t h e program from 1978 t o 1982, and i n f o r m a t i o n p e r t i n e n t t o m a n u f a c t u r e r s , a r e p r e s e n t e d h e r e .
2. MICROSTRUCTURAL CHARACTERISTICS AND DURABILITY
The m i c r o s t r u c t u r a l p r o p e r t i e s t h a t may b e r e l e v a n t t o t h e d u r a b i l i t y of c l a y b r i c k s , i.e. s a t u r a t i o n c o e f f i c i e n t , s p e c i f i c s u r f a c e a r e a and p o r e s t r u c t u r e , a r e d e s c r i b e d below. 2.1 S a t u r a t i o n C o e f f i c i e n t S a t u r a t i o n c o e f f i c i e n t i s t h e r a t i o of t h e twenty-four h o u r s c o l d w a t e r a b s o r p t i o n v a l u e t o t h e f i v e h o u r s b ~ i l i n g a b s o r p t i o n v a l u e of a b r i c k . It i s an approximate i n d i c a t i o n of t h e s p a c e a v a i l a b l e i n t h e b r i c k t o accommodate t h e e x p a n s i v e p r e s s u r e of f r e e z i n g water. The lower t h e s a t u r a t i o n
c o e f f i c i e n t , t h e more s p a c e t h e r e i s f o r t h e f r e e z i n g p r e s s u r e t o b e r e l i e v e d ; t h u s i t i s less l i k e l y t h a t t h e b r i c k w i l l b e damaged. The s a t u r a t i o n
c o e f f i c i e n t i s t r a d i t i o n a l l y used as a measure of d u r a b i l i t y i n b r i c k
s p e c i f i c a t i o n s and q u a l i t y c o n t r o l . The development of s a t u r a t i o n c o e f f i c i e n t
i
w i t h r e s p e c t t o h e a t work (combined e f f e c t of peak t e m p e r a t u r e and s o a k i n gt i m e ) , a s measured by t h e s h r i n k a g e of f i r e c h e k k e y s ( I ) , e x p r e s s e d i n t h e a r b i t r a r y B R I u n i t , i s shown i n F i g u r e 1 f o r v a r i o u s Canadian brickmaking m a t e r i a l s and i n F i g u r e 2 f o r b r i c k s made of t h e same raw m a t e r i a l b u t by d i f f e r e n t forming methods. These f i g u r e s i n d i c a t e t h a t t h e c r i t i c a l s a t u r a t i o n c o e f f i c i e n t r e q u i r e d f o r f r o s t r e s i s t a n c e depends on t h e raw m a t e r i a l s and t h e m a n u f a c t u r i n g p r o c e s s and v a r i e s from b r i c k t o b r i c k .
0 . 1
-
0 - - 2 + 4 0 1 - 0 W H I T E M U D 0 Q U E E N S T O N H I G H L l M E - Q U E E N S T O N - L O W L l M t O U N D A S - 9 P E N N S Y L V A N I A N 0 . 1 ' \ 0 1 0 2 0 3 0 4 0 5 0 0 0 7 0 8 0 9 0 H E A T W O R K . B R I U n l l r F I G U R E 1 S A T U R A T I O N C O E F F I C I E N T O F B R I C K S M A D E O F V A R I O U S C A N A D I A N B R I C K M A K I N G M A T E R I A L S A S A F U N C T I O N O F H E A T W O R K H E A T W O R K B R I U n i l i F I G U R E 2 S A T U R A T I O N C O E F F I C I E N T O F B R I C K S M A D E O F T H E S A M E R A W M A T E R I A L B U T B Y D I F F E R E N T F O R M I N G M E T H O D A S A F U N C T I O N O F H E A T W O R K.
P E N N S Y L V A N I A N.
Q U E E N S T O N L O W L l M E a Q U E E N S T O N H l G H L I M E 0 O U N D A S 0 W H I T E M U D 1 0 2 0 3 0 4 0 5 0 6 0 1 0 8 0 90 1 0 0 H E A T W O R K B R I U n l l l F I G U R E 3 S P E C I F I C S U R F A C E A R E A O F B R l C K S M A D E O F V A R I O U S C A N A D I A N B R I C K M A K I N G M A T E R I A L S A S A F U N C T I O N 0 1 H E A T W O R KAlthough the saturation coefficient criterion
has some merit, it fails, by itself, to take
this variation into account. As can be seen
from these results, Canadian Standard CSA A82.1
is of questionable value since five out of the
nine products studied achieved a saturation
coefficient of 0.88 when fired to about 900°C.
These underfired bricks have the specified
saturation coefficient and will pass the CSA
Standard but they do not possess adequate
durability characteristics to withstand either
laboratory freeze-thaw tests or natural
weathering.
2.2 S~ecific
Surface Area
Typically, the specific surface area value of
burnt Canadian clay bricks is between 0.5 and
3.0
/g. Litvan (2) found that the specific
surface areas of twenty-seven bricks collected
from different masonry structures correlated
well with their field performance. Further
results from the Fellowship research indicate
that durability can be assessed on the basis of
specific surface area measurement. But the
effect of raw materials and manufacturing
processes must be considered. Figure 3 shows
the variation of specific surface area of
extruded bricks made from different raw
materials with respect to heat work. The region
of heat work between 35 and 70 BRI units
corresponds to peak firing temperatures between
1030°C and 1080°C. This is where the durability
of the five bricks develops. It can be seen
that the curves are apart and do not cross in
this region. Thus, Figure 3 reveals that the
critical surface area corresponding to the
durable limit of each product may vary.
Similarly, Figure
4
indicates that different
manufacturing processes may also result in
different critical surface areas for equal
durability, even though the same raw materials
were used. Thus the relative durability of
bricks manufactured from raw materials of
different composition and by different processes
cannot be predicted solely on the basis of a
direct comparison of the absolute value of the
specific surface area. Specific surface area is
useful for quality control purposes only when
applied to a particular raw material formed by
the same process.
2.3 Pore Structure
References in the literature suggest that the
existence of coarse pores (greater than
1 micron) result in an enhancement of durability
whereas the intermediate pore sizes (say,
o S T I F F E X T R U S I O N
.
D R Y P R E S S H E A T W O R K , B R I U n l l r F I G U R E 4 S P E C I F I C S U R F A C E A R E A O F B R I C K S M A O E O F T H E S A M E R A W M A T E R I A L B U T B Y D I F F E R E N T F O R M I N G M E T H O D A S A F U N C T I O N O F H E A T W O R K S A T U R A T I O N C O E F F I C I E N T F I G U R E 5 R E L A T I O N S H I P B E T W E E N T H E A M O U N T O F I N T E R M E D I A T E S I Z E P O R E S A N D S A T U R A T I O N C O E F F I C I E N T O F B R I C K S F R O M P R O J E C T B P m U N B U R N E D Bbetween
0 . 1and
1micron) have a lower
frost resista~ce
(2,3,4).
In natural
weathering conditions, coarse pores are
rarely filled with water because, although
they are easily filled with water, it
dries out quickly. Small pores do not
fill or dry easily. Since water in small
pores does not freeze until very low
temperatures are reached, it has very
little effect on the frost susceptibility
of bricks. Intermediate pores are most
susceptible to freeze-thaw action since
they are most frequently filled with water
and the water dries more slowly than in
larger pores. This detrimental effect is
illustrated in Figure 5, which shows that
the saturation coefficient is proportional
to the amount of intermediate-sized pores
in bricks, as determined by mercury
intrusion porosimetry. In general, large
pores lower the saturation coefficient,
whereas small pores increase it. It is
perhaps feasible to use pore structure as
a durability test, but more analysis is
needed.
During the firing of a brick, its
durability is improved because the total
porosity is reduced by grain growth and
particle fusing. Also, as the firing
temperature increases, coarsening of the
pores takes place, as shown in Figure
6 .By comparing water absorption results and
the total theoretical porosity determined
by mercury intrusion porosimetry, the
following important conclusions can be
drawn: a) Some bricks are easier to
saturate than others. For example, after
soaking for one hour in water, bricks from
projects BP and NW achieved~the
highest
level of saturation, i.e.
80%,whereas
HC
and VD bricks had the lowest degree of
saturation, i.e. below
60%.b) Bricks
fired at higher temperatures (thus with
greater frost resistance) are more
difficult or slower to saturate by soaking
in water than those fired at lower
temperatures. Such different rates of
saturation have an important practical
significance in considering the
weatherability of bricks in service.
P O R E O I I M i T E Q n l c r o n l
l l b 1 1 9 t h
3. FREEZING EXPANSION AS A FROST
E W C ~ or F I W I U L r t m ~ r ~ ~ ~ u i l ~ s nu vnrt r ~ z t o a r r a r s u r ~ o a
DURABILITY TEST
It is desirable to establish a test
method that is fast and reliable. One
promising method is to measure expansion
of a wet brick specimen during freezing. The method involves measuring the
expansion of a small (8 mm in diameter
x 13 mmin length) vacuum-saturated
brick specimen during one cycle of freezing and thawing that could be carried
out in a few hours. It is based on the concept that expansion is caused by
the stress developed when the water freezes, and that there is a relation
between the difference in freezing expansion and thawing shrinkage (called
residual expansion) and the damage suffered (Figure 7).
The results obtained
rated samples of known relative durability in the proper order. Figure 8
presents the residual expansion plotted against the total expansion on
freezing of seventy-seven bricks. Higher freezing expansion is accompanied by
larger residual expansion in general. This behaviour becomes more pronounced
as the freezing expansion exceeds the
0.15%level. Using
0.10%expansion as
the threshold, the prediction is
100%accurate with
15%rejection of possibly
durable products. Taking
0.15%as the threshold value, the prediction of
non-durable products is
93%correct with a 2% rejection of possibly durable
products. Since there is a reasonable correlation between the freezing
expansion and the residual expansion, the method can be simplified by
measuring the residual expansion after freeze-thaw tests. This correlation
improves with specimens of larger size.
The freezing expansion test also provides information on the effect of
the manufacturing process on the frost resistance of bricks. There is an
indication that beyond a critical saturation level, which lies between
75and
80%,
extruded clay bricks show a marked increase in freezing expansion,
whereas bricks made from dry-press and soft mud methods do not, as can be seen
in Figure
9.This behaviour in extruded bricks may be related to the pore
structure.
4.
OPTIMIZATION OF BRICK FIRING
Where frost durability is concerned, firing is the most important process
in the production of clay bricks. Since frost resistance increases with
greater heat work, it is advantageous for the industry to optimize the firing
conditions.
Anempirical laboratory procedure was developed that estimates
the optimum heat work for a given brick, based on saturation coefficient,
specific surface area and the heat work. The specific surface areas of fired
samples at different heat works are plotted against the corresponding
saturation coefficients, as shown in Figure
10.The result could be described
' l ' l ' I ' I k
1
- 4 0 - 2 0 0 2 0 40 T E M P E R A T U R E . " C F I G U R E 7 T Y P I C A L E X P E R I M E N T A L L E N G T H C H A N G E R E S U L T S F R O M T H E R M O M E C H A N I C A L M E A S U R E M E N T o N O N - F R O S T R E S I S I A N T:
:::::::.
]
F R O S T R E S I S T A N . 0 H A N D M O L O 0 = F R E E Z I N G E X P A N S I O N . % F I G U R E 8 R E L A T I O N S H I P B E T W E E N R E S I D U A L E X P A N S I O N A N D F R E E Z I N G E X P A N S I O N O F F R O S T R E S I S T A N T A N D N O N - F R O S T R E S I S T A N T B R I C K SE X T R U D E D B R I C K S D. 1. G 0 5 H A N D M O L D B R I C K , DEGREE OF S A T U R A T I O N , % F I G U R E 9 EFFECT OF M A N U F A C T U R I N G M E T H O D S O N F R E E Z I N G B E H A V I O R OF C L A Y B R I C K S S A T U R A T I O N C O E F F I C I E N T F I G U R E 1 0 E S T I M f l T I O N OF O P T I M U M F I R I N G C O N D I T I O N FOR P R O J E C T V D B A S E D O N S P E C I F I C S U R F A C E AREA A N 0 S A T U R A T I O N C O E F F I C I E N I
by two intersecting lines. The optimum heat work and firing condition are
approximately those corresponding to the intersection of the two lines. This
optimum value can be more clearly defined by the derivative of the curve of
specific surface area with respect to saturation coefficient. This method
could also be used to assess the intrinsic tolerance of a brickmaking material
to frost action or to indicate how much improvement could be achieved in a
product by modifying the present process.
5.
QUALITY CONTROL
The procedures for the present quality control tests have limitations,
since they are based on tests for absorption characteristics and saturation
coefficients which are time-consuming and depend on the variation in raw
materials. Thus, the maximum allowable and the optimum values of absorption
and saturation coefficients must be established for each product.
5.1 Short-Term Absorption Tests
Correlation between the short-term absorption and the saturation
coefficient has been found, as shown in Figures 11 and 12. The degree of
correlation is a function of the mixing or homogeneity of the raw materials:
it is best when only one source of consistent raw material is used (Figures 13
and 14) and is poor when different materials are blended (Figure 15).
Thus,
the standard quality control tests could be shortened considerably from the
usual forty-eight hours (required in the case of saturation coefficient) to
within an hour by using short-term absorptions, such as one minute or one hour
cold absorptions. In order to ensure best correlation, the short-term
absorption tests should be done with half bricks or a fraction of a whole
brick in order to avoid the "tight-skin effect" which increases the scattering
of data. Although the initial rate of absorption could be measured in a
minute, it has a poorer correlation than the one hour absorption tests and is
more affected by surface texture.
5.2 Absorption and Saturation Coefficient
Cold absorption and saturation coefficients have been used separately for
quality control, but their values vary depending on the raw material. The
inadequacy of using either one independently for quality control can be seen
L O 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 9.2
-
- Z 8.4-
z - 0 1.6 - + L - 2 6.8- w - 6 0 - 0 - " 5.2--.
w 3 - p 4.4-
- 1 6 -.
- 2.8-
. I I I I I I I I I - 2.0 I I I I I I I I I I 0.54 0.58 a 6 2 O.M o m 0.14 0.16 0.8 0.1 0.90 0.91 S A T U R A T I O N C O E F F I C I E N T F I G U R E 1 1C O R R E L A T I O N BETWEEN ONE HOUR COLD A B S O R P T I O N A N D S A T U R A T I O N C O E F F I C I E N T FOR B U R N T B R I C K S F R O M P R O J E C T R I I I 1 , - 0 5 0 0.58 0 . 6 6 0.14 0 . 8 2 0 . 9 0 S A T U R A T I O N C O E F F I C I E N T F I G U R E 1 3 R E L A T I O N S H I P BETWEEN S A T U R A T I O N C O E F F I C I E N T A N D A B S O R P T I O N OF B R I C K S MADE F R O M A S I N G L E S O U R C E OF RAW M A T E R I A L F I G U R E I 2 C O R R E L A T I O N BETWEEN ONE M I N U T E C O L D A B S O R P T I O N A N D S A T U R A T I O N C O E F F I C I E N T FOR B U R N T B R I C K S F R O M PROJECT R S A T U R A T I O N C O E F F I C I E N T F I G U R E 1 4 R E L A T I O N S H I P BETWEEN S A T U R A T I O N C O E F F l C I L N T A N 0 A B S O R P T I O N OF B R I C K S M A D E W I T H A D D I T I V E S I N T R O D U C E D I N S L U R R Y I I I I I I I 8 . 0 8.5 9.0 9 5 1 0 0 10.5 1 1 . 0 C O L D A B S O R P T I O N . 5 F I G U R E 15 R E L A T I O N S H I P B E T l E E N S A T U R A T I O N C O E F F I C I E N T A N 0 A B S O R P T I O N OF B R I C K S M A D E F R O M B L E N D I N G A SHALE A N 0 A C L A Y F I G U R E 1 6 P R O P E R T I E S OF B R I C K S PROOUCED I N A P L A N T OVER A P E R I O D OF THREE M O N T H S
13
-
I I I I * 13 - z 0 5 - LIMESTONE CONTfNl - E > D > C > B > A 3-
I I I I 0 . 6 0 0 6 8 0 . 1 6 0 . 8 4 0 P Z 1 0 0in Figure 16. In a production plant, bricks of
similar saturation coefficient but different
absorption values, and similar absorption but
different saturation coefficient values are both
produced. These bricks have different properties.
Thus, it is recommended that absorption and
saturation coefficients be used in conjunction,
since this composite relationship not only reveals
the quality of the particular brick produced but
also the "history" of the brick, such as the
original raw material composition and the resulting
firing condition, as shown in Figure 17.
S A T U R A T I O N C O E F F I C I E N T
~ I G U R ~ 17
6. CONCLUSIONS
V A R I A T I O N I N RAW M A T E R I A L S E L U C I D A T E D B Y P L O T T I N G C O L D A B S O R P T I O N V S S A T U R A T I O N C O E F F I C I E N T
Present Canadian durability standards for clay
bricks are questionable. Evaluation criteria based
on saturation coefficient and specific surf
ace area must be established for
each product because they vary according to the different raw materials and
manufacturing processes. The optimum firing condition can be estimated by
plotting the specific surface area against saturation coefficient at different
degrees of firing. Freezing expansion seems to provide a valid durability
test for clay bricks independent of the composition and process variables. In
the absence of the criteria mentioned above, quality control should be based
on both absorption and saturation coefficient. Current quality control tests
based on saturation coefficient can be shortened by the dne minute or one hour
absorption test.
7. ACKNOWLEDGEMENT
The author would like to thank Drs. V.S. Ramachandran and P.J. Sereda for
their helpful guidance in this work; the technical officers of the DBR
Building Materials Section for their assistance in the experiments; and the
workers at Canada Brick, Domtar Inc., I-XL Industries Ltd., L.E. Shaw Ltd.,
and Toronto Brick for their participation and cooperation. This Program was
sponsored by the CBACIDBR Industrial Research Fellowship.
This paper is a contribution from the Division of Building Research,
National Research Council Canada, and is published with the approval of the
Director of the Division.
8. REFERENCES
(1) Newman, H.B., Direct and Indirect Methods of Measuring Body Maturity.
Bull. Amer. Ceram. Soc. 58 (6) 580-586, 1979.
( 2 )
Litvan, G.G., Testing t h r ~ r o s t
Susceptibility of Bricks. ASTM STP 589,
123-132, 1975.
(3) Robinson, G.C., The Relationship Between Pore Structure and Durability of
Brick. Bull. Amer. Ceram. Soc. 63 (2) 295-300, 1984.
(4) Vincenzini, P., Some Laboratory Tests Used to Foresee the Frost Behaviour
T h i s paper, w h i l e being d i s t r i b u t e d i n r e p r i n t form by t h e D i v i s i o n of B u i l d i n g Research, remains t h e c o p y r i g h t of t h e o r i g i n a l p u b l i s h e r . It s h o u l d n o t be reproduced i n whole o r i n p a r t w i t h o u t t h e p e r m i s s i o n of t h e p u b l i s h e r . A l i s t of a l l p u b l i c a t i o n s a v a i l a b l e from t h e D i v i s i o n may be o b t a i n e d by w r i t i n g t o t h e P u b l i c a t i o n s S e c t i o n , D i v i s i o n of B u i l d i n g R e s e a r c h , N a t i o n a l R e s e a r c h C o u n c i l of C a n a d a , O t t a w a , O n t a r i o , K l A OR6.
C e document est d i s t r i b u g s o u s f orme de tiri5-a-part par l a D i v i s i o n d e s r e c h e r c h e s e n bztiment. Les d r o i t s de r e p r o d u c t i o n s o n t t o u t e f o i s l a proprii5tC de 1 ' C d i t e u r o r i g i n a l . C e document n e p e u t G t r e r e p r o d u i t en t o t a l i t i 5 ou en p a r t i e s a n s l e consentement de l v 6 d i t e u r . Une l i s t e d e s p u b l i c a t i o n s d e l a D i v i s i o n p e u t S t r e obtenue en i5crivant