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HAL Id: jpa-00221676

https://hal.archives-ouvertes.fr/jpa-00221676

Submitted on 1 Jan 1981

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THE MULTIVALUED DISTRIBUTION OF

ELECTRONS BETWEEN EQUIVALENT VALLEYS

M. Asche, H. Kostial, O. Sarbey

To cite this version:

M. Asche, H. Kostial, O. Sarbey. THE MULTIVALUED DISTRIBUTION OF ELECTRONS BE-

TWEEN EQUIVALENT VALLEYS. Journal de Physique Colloques, 1981, 42 (C7), pp.C7-323-C7-

328. �10.1051/jphyscol:1981739�. �jpa-00221676�

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Colloque C7, supplément au n°10, Tome 42, octobre 1981 page C7-323

Résumé.- Dans le Si-n la distribution multiforme d'électrons chauds entre des vallées équivalentes conduit à. la formation de domaines de haut champ en vertu de la conductivité négative dif- férentielle du type N et de la formation de structure des couches avec des champs opposés de Sasaki pour des températures au-des- sous de 50 K.

THE MULTIVALUED DISTRIBUTION OF ELECTRONS BETWEEN EQUIVALENT VALLEYS

M. Asche, H. Kostial and O.G. Sarbey*

Zentralinstitut fur Elektronenphysik dev AdW der DDR, Berlin, Germany.

*Institut fiziki AN USSR, Kiev, USSR.

Abstract. - In n-Si the multivalued distribution of hot electrons among the valleys (mde) leads to static high field domains on account of N-type ndc and to layers of opposite Sasaki fields for temperatures below 50 K.

1. Introduction. - The subject of the present investigations can be described in the following way: when in a finite sample the current j is directed according to Fig. 1, on account of the conductivity

f 1S

anisotropy in the single valleys there are opposite currents 1

v

'

and j y x

v

' besides the contributions of both pairs of valleys to i . When there appears a field F* by fluctuation it originates par-

allel currents j * ' ' and i'v

2

) but opposite components j'^ ' and

(2\ y y *

j'

v

'. Because of these fluctuations, in a heating field the elec-

trons of the second pair of valleys gain more energy and those of the first one will be cooled. In the case of intervalley transitions

Fig. 1: Fields and currents for the equivalent valleys

Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyscol:1981739

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C7-324 JOURNAL DE PHYSIQUE

o f t h e e l e c t r o n s w i t h t h e a s s i s t a n c e o f phonons t h i s l e a d s t o a h i g h e r p o p u l a t i o n o f t h e p a i r o f v a l l e y s 1 i n comparison t o t h e v a l l e y s 2. T h e r e f o r e a l l c u r r e n t c o n t r i b u t i o n o f t h e v a l l e y s 1 a r e i n c r e a s e d , b u t t h o s e o f v a l l e y s 2 a r e decreased.

~f j

('1 -

(2)< j a + j a ( 2 ) t h e f l u c t u a t i o n becomes d i m i n i s h e d ,

Y

( 1 ) j y f o r J

Y

-

jy(2)>l;(1) i t r i s e s . T h i s means t h a t a new + j y

asymmetric s t a t e o f t h e semiconductor becomes r e a l i z e d , which i s c h a r a c t e r i z e d by t h e presence o f an e l e c t r i c f i e l d t r a n s v e r s e t o jx

( S a s a k i - f i e l d ) . Of course, i n t h e same way a f l u c t u a t i o n o f t h e o p p o s i t e s i g n has t o be regarded. T h e r e f o r e i n t h e case o f j y ( l )

-

j Y (2)> jl(')

+

j;(2) a symmetric s t a t e w i t h e q u a l e l e c t r o n d e n s i t i e s i n b o t h t h e p a i r s o f v a l l e y s i s u n s t a b l e , and t h e s t a b l e Y s o l u t i o n on t h e o t h e r hand i s d e t e r m i n e d by t h e boundary c o n d i t i o n s . The t h e o r y /1/ p r e d i c t s t h a t b o t h p o s s i b l e asymmetric s t a t e s ( w i t h d o m i n a t i n g p o p u l a t i o n i n t h e f i r s t o r second p a i r o f v a l l e y s , r e s p e c t i v e l y ) c o e x i s t i f i n t e r v a l l e y s c a t t e r i n g on t h e s u r f a c e i s l a c k i n g ; t h e sample decays i n t o two l a y e r s w i t h o p p o s i t e s i g n o f t h e t r a n s v e r s e f i e l d and t h e w a l l between them extends a l o n g t h e c u r r e n t d i r e c t i o n and l i e s i n t h e m i d d l e o f t h e sample i f t h e l a t t e r i s p e r f e c t l y homogeneous and e x a c t l y o r i e n t a t e d .

2. R e s u l t s .

-

Our experiments were performed w i t h quadershaped samples of n - S i w i t h 5 x 1013< ND<5 x 1014 cme3 and NA< 2 x

loi3

cm3 w i t h t h e l o n g a x i s p a r a l l e l t o <.110>. The measurements were p e r - formed f o r temperatures between 20 and 77 K. The e x i s t e n c e o f mde was observed f r o m 20 K u p t o 5 0 K.

As a f i r s t e f f e c t of mde (Fig. 2a) t h e c u r r e n t v o l t a g e c h a r a c t e r - i s t i c s e x h i b i t r e g i o n s o f c u r r e n t s a t u r a t i o n f o r T 5 5 0 K. They a r e c r e a t e d by domains of a h i g h s t a t i c e l e c t r i c f i e l d f o r F > F c which appear on account of N-type ndc f o r t h e c o n d i t i o n of mde + ) and can be e x h i b i t e d by t h e p o t e n t i a l d i s t r i b u t i o n a l o n g t h e sample. The v a l u e s o f t h e e l e c t r i c f i e l d s i n t h e domains depend on t h e l a t t i c e

+)

r e a l p i c t u r e o f mde f o r n - S i w i t h j a l o n g (110) d i f f e r s from t h e s c e t c h o f F i g . 1 by t h e t h i r d p a i r o f v a l l e y s on t h e < 0 0 1 ) a x i s . I n o r d e r t o demonstrate t h a t t h e ndc observed i s n o t connected w i t h a r e d i s t r i b u t i o n o f c a r r i e r s f r o m these v a l l e y s i n t o b o t h t h e o t h e r p a i r s experiments w i t h u n i a x i a l p r e s s u r e were performed /2/ as w e l l as Monte C a r l o c a l c u l a t i o n s /3/.

(4)

s t r e n g t h s Fc m a r k e d b y a r r o w s ( t h e c u r r e n t d e n s i t i e s f o r 27 K a r e m u l t i p l i e d by 1 0 )

F i g . 2 b r V o l t a g e d i f f e r e n c e b e t w e e n o p p o s i t e p r o b e s on ( i 1 0 ) - s u r - f a c e s ( d i s t a n c e 0,19 cm) v e r s u s m a g n e t i c i n d u c t i o n a p p l i e d a l o n g (001)

t e m p e r a t u r e c h o s e n a n d f o r 27 K f o r i n s t a n c e t h e y a r e a b o u t 70

-

80 V/cm I n t h e h i g h f i e l d d o m a i n a n d a b o u r 4 0 V/cm i n t h e l o w f i e l d r e g i o n . F u r t h e r o n a s t o be s e e n f r o m F i g . 2 a t h e c r i t i c a l f i e l d Fc n e c e s s a r y f o r t h e a p p e a r a n c e o f mde r i s e s w i t h T. From t h e v a l u e of F c o n c l u s i o n s w i t h r e s p e c t t o t h e i n t e r v a l l e y s c a t t e r i n g p r o c e s s e s

C

can b e d r a w n /3/.

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C7-326 JOURNAL DE PHYSIQUE

A n o t h e r e f f e c t observed f o r mde i s t h e decay o f t h e samples i n t o two l a y e r s w i t h o p p o s i t e s i g n s o f t h e t r a n s v e r s e e l e c t r i c f i e l d . T h i s was i n v e s t i g a t e d by a r r a n g i n g s e v e r a l probes on t h e (001)-surfaces p e r - p e n d i c u l a r t o t h e c u r r e n t d i r e c t i o n a l l o w i n g t o observe t h e p o s i t i o n o f t h e w a l l between t h e l a y e r s . As a consequence o f t h e l a y e r e d s t r u c t u r e t h e r e can appear a t r a n s v e r s e v o l t a g e d i f f e r e n c e between o p p o s i t e probes on t h e (310)-surfaces /4/.

W h i l e t h e c u r r e n t s a t u r a t e s i n a c e r t a i n r e g i o n o f F f o r a l l samples t h e t r a n s v e r s e v o l t a g e d i f f e r e n c e between b o t h t h e probes on (TIo) s u r f a c e s can n o t always be observed: t h e r e a r e samples i n which i t does n o t appear a t a l l i n t h e whole r e g i o n o f f i e l d s t r e n g t h s i n v e s - t i g a t e d , o t h e r s f o r which i t was measured a l r e a d y f o r F about F and

C

a t h i r d group where i t shows up f o r some f i e l d s t r e n g t h above F c These t y p e s o f b e h a v i o u r a r e caused by t h e p o s i t i o n o f t h e w a l l i n t h e r e g i o n o f t h e probes. I n t h e presence o f any inhomogeneity which d i s t u r b e s t h e symmetry t h e w a l l i s s h i f t e d f r o m t h e m i d d l e o f t h e sample towards one o f t h e s u r f a c e s and t h e n a v o l t a g e d i f f e r e n c e can be measured between b o t h t h e (x10) s u r f a c e s .

Another e f f e c t o f t h e mde i s t h e pronounced i n f l u e n c e o f t r a n s v e r s e magnetic f i e l d s on t h e c u r r e n t v o l t a g e c h a r a c t e r i s t i c s and t h e S a s a k i - f i e l d s .

F o r F> Fc t h e m a g n e t o c o n d u c t i v i t y o f t h e sample depends on t h e p o l a r i t y o f B when i n t h e absence o f t h e magnetic f i e l d t h e w a l l was n o t s i t u a t e d i n t h e m i d d l e o f t h e sample and i s n o t s h i f t e d symmetri- c a l l y by b o t h t h e p o L a r i t i e s o f B.

The f l e l d s t r e n g t h measured as t h e d r o p o f t h e p o t e n t i a l between an end c o n t a c t and probes on ( T l 0 ) - s u r f a c e s d i v i d e d by t h e d i s t a n c e e x h i b i t s s i g n i f i c a n t changes i n t h e r e g i o n o f weak magnetic f i e l d s

(Fig. 3 ) d e m o n s t r a t i n g how t h e H a l l f i e l d s w i t c h e s t h e w a l l between b o t h s i d e s o f t h e sample. T h e r e f o r e t h e p o t e n t i a l d i f f e r e n c e between o p p o s i t e probes r i s e s s t r o n g l y when i t was o n l y weakly pronounced i n t h e absence o f B. I n samples f o r which t h e r e was a l r e a d y a remarkable d i f f e r e n c e between t h e probes t h e magnetic f i e l d o f one p o l a r i t y changes i t o n l y a l i t t l e , b u t f o r t h e o t h e r p o l a r i t y t h e magnetic f i e l d s w i t c h e s t h e t r a n s v e r s e v o l t a g e d i f f e r e n c e t o one o f t h e o p p o s i t e s i g n and almost t h e same amount.

-

T h i s s h i f t was examined i n d e t a i l a g a i n by experiments w i t h a d d i t i o n a l probes on (001)- s u r f aces.

The dependence o f t h e t r a n s v e r s e v o l t a g e d i f f e r e n c e on magnetic f i e l d s t r e n g t h i s shown i n F i g . 2 b f o r s e v e r a l temperatures a t a

(6)

a l o n g < 1 1 0 ) i n d e p e n d e n c e on a m a g n e t i c i n d u c t i o n p a r a l l e l t o

<

0 0 1 )

h e a t i n g e l e c t r i c f i e l d o f 1 0 6 V/cm. I n s t e a d o f t h e l i n e a r d e p e n d e n c e on B o b s e r v e d f o r weak e l e c t r i c f i e l d s , i n t h e p r e s e n c e o f mde t h e r e a r e two r e g i o n s t o b e s e e n : f o r s m a l l B t h e r e i s a s t e e p r i s e o f t h e v o l t a g e d i f f e r e n c e i n c o n t r a s t t o b i g B, f o r w h i c h t h e t r a n s v e r s e v o l t a g e d i f f e r e n c e i n c r e a s e s o n l y s l o w l y a s o b s e r v e d i n t h e common H a l l e f f e c t . When mde i s r e a l i z e d i n t h e w h o l e s a m p l e + ) t h e s l o p e o f t h e s t e e p r i s e is p r a c t i c a l l y i n d e p e n d e n t o f t h e f i e l d a n d t h e t e m p e r a t u r e . F o r T> 5 0 K o r

FZ

2 0 0 V/cm t h e s l o p e d i m i n i s h s a g a i n b e c a u s e t h e r e e x i s t s n o mde a n y m o r e b u t o n l y a n a n o m a l e o u s H a l l e f f e c t r e m a i n s i n a c c o r d a n c e w i t h t h e o r y /I/.

-

') F o r F j u s t a b o v e Fc t h e s l o p e h a s n o t g a i n e d i t s m a x i m a l v a l u e b e c a u s e t h e l a y e r e d s t r u c t u r e o n l y e x i s t s i n t h e h i g h f i e l d d o m a i n , w h i c h s t i l l d o e s n o t e x t e n d t o t h e s p a c e b e t w e e n t h e p r o b e s .

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C7-328 JOURNAL DE PHYSIQUE

3. C o n c l u s i o n .

-

The i n v e s t i g a t i o n o f t h i s s t r o n g l y n o n l i n e a r s y s t e m ( t h e dependence o f t h e v a l l e y p o p u l a t i o n on t h e h e a t i n g e l e c t r i c f i e l d ) d e m o n s t r a t e s t h e s p o n t a n e o u s symmetry b r e a k i n g c o n n e c t e d w i t h t h e m u l t i v a l u e d e l e c t r o n d i s t r i b u t i o n between e q u i v a l e n t v a l l e y s . B e s i d e s t h e Gunn e f f e c t t h e r e a l i z a t i o n o f s t a b l e a s y m m e t r i c s t a t e s on a c c o u n t o f mde i s a n o t h e r example f o r s y n e r g e t i c phenomena.

The a u t h o r s acknowledge t h e p a r t i c i p a t i o n o f L.F.Kurtenok i n a p a r t o f t h e e x p e r i m e n t s .

/1/ Z. S. G r i b n i k o v , V. A. Kochelap, V. V. M i t i n , Zh. Eksper. Teor.

F i z .

59,

1828 (1970)

/2/ M. Asche, H. K o s t i a l , 0. G, Sarbey, J. Phys. C

13,

L 645 (1980) /3/ 2. S. G r i b n i k o v , V. M, Iwashenko, V. V. M i t i n , 0. G. S a r b e y ,

C h i s l e n n i i r a s c h e t mnogoznachnykh r a s p r e d e l e n i i e l e c t r o n o v po d o l i n a m v S i , p r e p r i n t 8, akademia nauk USSR, i n s t i t u t f i z i k i , K i e v (1981)

/4/ M. Asche, H. K o s t i a l , S o l . S t a t e Commun. ( 1 9 8 1 )

.

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