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Experimental arguments for a non-zero transition temperature in RKKY Heisenberg spin glasses without
anisotropy
A. Fert, N. de Courtenay, H. Bouchiat
To cite this version:
A. Fert, N. de Courtenay, H. Bouchiat. Experimental arguments for a non-zero transition temperature in RKKY Heisenberg spin glasses without anisotropy. Journal de Physique, 1988, 49 (7), pp.1173-1178.
�10.1051/jphys:019880049070117300�. �jpa-00210799�
Experimental arguments for a non-zero transition temperature in RKKY Heisenberg spin glasses without anisotropy
A. Fert, N. de Courtenay and H. Bouchiat
Laboratoire de Physique des Solides, Université de Paris Sud, 91405 Orsay, France (Reçu le 17 novembre 1987, accepté sous forme définitive le 23 fivrier 1988)
Résumé.
2014Alors que l’existence d’une transition de phase à température non nulle est bien admise pour les
verres de spin de type Ising à 3 dimensions, des travaux théoriques récents suggèrent que Tc est nul pour des
verres de spin Heisenberg sans anisotropie et que le Tc non nul des systèmes réels est dû à l’anisotropie. Pour
éclaircir ce problème, nous analysons l’influence de l’anisotropie
surle comportement critique et la température de transition de phase d’alliages CuMn et AgMn dopés avec des impuretés d’or ou de platine.
Cette analyse suggère plutôt un Tc fini pour les verres de spin Heisenberg RKKY dans la limite d’anisotropie
nulle.
Abstract.
2014While the existence of
aphase transition at finite Tc is well admitted for Ising spin glasses in 3- dimensions, recent theoretical studies have proposed that Tc is zero in Heisenberg spin glasses and that the finite Tc of real systems is induced by the anisotropy. To clear up this question,
weanalyse the influence of the
anisotropy
onthe critical behaviour and the transition temperature of CuMn and AgMn alloys doped with Au
or
Pt. This analysis rather suggests
afinite Tc for RKKY Heisenberg spin glasses in the limit of
zeroanisotropy.
Classification
Physics Abstracts
75.30 - 75.30G - 75.30H - 75.40
1. Introduction.
There is now a strong experimental evidence for a
phase transition at finite T, in spin glass alloys [1].
On the theoretical side, it seems well admitted that, in three-dimensional systems, a phase transition
takes place in Ising spin glasses [2] but not in short
range Heisenberg spin glasses [3]. The case of
RKKY Heisenberg spin glasses is not completely
clear. On the basis of scaling arguments, Bray et al.
[4] have proposed that a RKKY spin glass in 3d is at
its lower critical dimension, so that the transition at finite Tc observed in metallic spin glasses should be
due to the existence of anisotropy. Bray et al. [4]
predict for the variation of 7c with the anisotropy in
a RKKY vector spin glass with Dzyaloshinsky- Moriya (DM) or dipolar anisotropy:
which gives :
J and dJ =- D are the exchange and anisotropy strengths respectively (A is a constant of order unity
and yD = 3/2 for 3-dimensional systems). As d tends
to zero, Tc tends to zero but the logarithmic depen-
dence of equations (1) can explain that T, does not change very much in the experimental range of d.
Computer simulations on RKKY Heisenberg sys- tems have been recently published [5]. They are compatible with the predictions of Bray et al. [4] but
cannot rule out completely the possibility of a non-
zero Tc. In this paper we present some arguments for
a non-zero Tc in RKKY Heisenberg spin glasses.
These arguments are derived from experimental
data on CuMn and AgMn alloys in which the DM anisotropy is made to vary by adding Au or Pt impurities [6]. More precisely our arguments are based on :
(a) our previously published analysis of the influ-
ence of anisotropy on the critical behaviour [7] ; (b) an analysis of experimental data for Tc(d) [8],
with T, (d) extrapolated in the limit d --+ O.
We discuss the two preceding points in sections 2 and 3 respectively.
2. Influence of anisotropy on the critical behaviour.
de Courtenay et al. [7] have studied the critical
behaviour of the non-linear susceptibility for series
Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphys:019880049070117300
1174
of CuMn and AgMn alloys doped with Au impuri-
ties. We show in figure la an example of the
influence of the DM anisotropy strength (fixed by
the concentration of Au) on the non-linear suscepti- bility KNL at T = T,, : two different regimes, corre- sponding to exponents 8 I = 3.1 ± 0.2 and 8 H =
4.5 ± 0.2, are observed in the low and high field
limits and the field of the cross-over between the two
regimes increases with the concentration of Au, i.e.
with the DM anisotropy strength (1). A similar anisotropy dependent cross-over between two differ- ent values, y I and y H, of the exponent y is also
Fig. 1.2013(a) Non-linear susceptibility KNL
versusH at r==7e for CuMnO.2 at% alloys doped with Au [7].
KNL is defined by M
=XH(1 - KNL). With KNL ~ H2/6,
the slopes at low and high fields correspond to 5j
=3.1 ± 0.2 and 8 H
=4.5 ± 0.2. Similar results have been found in AgMnAu alloys [7] ; (b) K NL/ a * (d)
versusH/H*(d) for series of CuMnAu and AgMnAu alloys at T - Tc, with a * (d ) and H* (d ) varying
asd1.7 and dO.9 respectively [7]. This scaling expresses equation (2b).
(I) Notation : KNL
=(X - M/H)/X with X
=(M/ H)H -+0’ KNL - h2/s for T h2, KNL - h2/T y for
h2 Tlp, with
T =r/7, - 1, h
=gJ-LB H/kB Tc, CPA
=anisotropy cross-over exponent, cp H
=ï’ H s H/ ( s H -1 ).
observed in the temperature dependence of the non-
linear susceptibility at low fields above Tc (see Ref.
[7] for a detailed report).
These experimental results, which show an ani- sotropy induced cross-over between two critical
regimes [9], are accounted for in reference [7] by using a three-parameter scaling function (1) :
with values of the reduced anisotropy d calculated as a function of the concentration of gold [7]. For example, we show in figure Ib how all the data at
Tc for series of CuMnAu and AgMnAu can be gathered on a unique curve by plotting KNL/ a * (d ) (with a * - d0.9 versus H/H* (d ) (with H* - dl-1),
in agreement with the limit of equation (2a) foi
T - 0 :
with
This analysis has given the exponent of the
anisotropy induced cross-over, (P A =z 0. 8 -t 0. 1 for
both the CuMn and AgMn systems, and two sets of exponents (cp I, 8I, yI) and (cp H, 03B4H, yH) characteriz-
ing the scalin function in the
two limits, d >
T I’P A, d> , (PA ’OH and d « T, d .r. h’,"PA qH re-
spectively [7]. We note that one value Of 0 A
accounts for the dependence of both a* and
H* on d, which checks the selfconsistency of the picture.
Obviously, if a scaling function in the form of
equations (2) exists and if its low anisotropy limit for
d much smaller than T 1/’PA and h 1/’OA ’OH is well
established, this means that, in the limit of zero
anisotropy, RKKY Heisenberg spin glasses present
a transition at Tc =F 0 with the set of exponents 03B4H, YH9 ’PH’ etc. The experiments of reference [7]
have convincingly shown the existence of an ani- sotropy dependent scaling and the d ---> 0 limit of the critical behaviour appears to be clearly observed, see
e.g., the right side of figure 1. However, even for the sample with the lowest anisotropy, CuMn without
Au (d
=0.036), the Heisenberg regime is observed only for h > 2 x 10- 2, 7 > 0.1. This range of
Tcorresponds to a correlation length smaller than
100 A. In this length range deviations from the
RKKY behaviour (R - 2 instead of R - 3) 4re-expected
[10] and this could be a plausible explanation for a
critical behaviour different from that expected by Bray Moore and Young [4] for RKKY Heisenberg spin glasses. Whence we infer that the analysis of the
influence of the anisotropy on the critical behaviour suggests the existence of a transition at finite
Tc for zero anisotropy Heisenberg systems but
cannot be absolutely conclusive (of course, the
existence of an Heisenberg regime would be proved
more strongly if there would exist a spin glass with a
lower anisotropy and Heisenberg regime extending
to smaller values of h and T).
3. Shift of the transition temperature induced by the anisotropy.
The most direct way to see if Tc (d = 0 ) has a zero or
non-zero value is to analyse the variation Tc(d) and
to extrapolate to d
=0. A difficulty arises from the additional variation of Tc due to the reduction of the
isotropic exchange by mean free path effects. Fortu- nately Vier and Schultz [8] (VS) have studied the variation of Tc in very extensive series of CuNin and
AgM alloys doped with several types of impurity,
Au and Pt giving rise to anisotropy-induced positive shifts, and In, Sn, Sb giving rise to negative mean free-path effects. Moreover VS have used their data
on alloys doped with In, Sn or Sb to derive an empirical law describing accurately the variation of
Tc due to mean free path (MFP) effects [11] :
where p is the resistivity of the alloy at low tempera-
tures and
This empirical law can be used to correct the data of VS on CuMn and AgMn doped with Au or Pt for the
mean free path effects.
In figure 2 we show the variation of Tc measured by VS in CuMn4 at% and AgMn5.5 at% alloys doped with Au or Pt. From equation (3) the shift of T, due only to the reduction of the mean free path by
the Au or Pt impurities can be written :
We have calculated A Trp by using the values of po and [Tc(p
=0 ) - Tc (p
=oo )] quoted above and
Fig. 2. - Tc versus y for C_uMn4 at%Pty%, CuMn4 at%Auy% and AgMn5.5 at%Auy% alloys : (0 ) experimental Tc found by Vier and Schultz [8] ; (.) Tc corrected for mean free path effects (see text).
p (CuMn4%Auy% ) =10.8 + 0.49 y [14] ,
p ( AgMn5.5% )
=8.63 03BC03A9cm [8] ,
p (AgMn5.5%Auy% )
=8. b3 + 0.38 y [13] .
The data of VS corrected for the mean free path
effects are represented by black symbols in figure 2.
For the CuMnPt and AgMnAu series the corrections for mean free path effects are relatively small, whereas, for CuMnAu, the experimental shift and
the correction have approximately the same magni-
tude. We will therefore limit our analysis to the
CuMnPt and AgMnAu systems for which the exper- imental data cannot be significantly affected by an
error in the calculation of the mean free path
contribution [14].
We now calculate the anisotropy d as a function of
the concentration of Au or Pt. For, say CuMnPt, we write [15, 7] :
where Vrn and Vr are the DM coefficients associat- ed with Mn-Mn-Mn and Mn-Mn-Pt triangles respect-
ively, Vo is the RKKY coefficient, yAu and xmn are the concentrations of Au and Mn and Rc = 42 A,
ro
=2.55 A (in AgMn, Rc
=39 A, ro
=2.89 A) [15, 7]. The values of the ratios V1/Vo have been derived
in previous works by combining ab initio calculations and experimental data [6, 7, 16, 17] and are listed in
table I. One can rely on this set of values which
appeared to account consistently for several spin-
orbit induced properties, from ESR shifts to changes
in the critical behaviour. The corresponding values
1176
Table I. - Relative strengths of the DM and RKKY
interactions in CuMn or AgMn alloys doped with Au
or Pt : (a) from ab initio calculations of the spin-orbit scattering by Pt, see reference [6] : (b) obtained from
( v 1 N by comparing the macroscopic ani-
( 0 CuMn
sotropy energy of CuMnPt with that of CuMn, see reference [16], or that of CuMnAu, see reference [13] ; (c) obtained from ( ( v0 v 1 Mn by cumn comparing
the ESR shift of CuMn and AgMn alloys, see reference [7].
-
of d derived from equation (5) range from 0.0036
(CuMn) to 0.33 (AgMn5.5%Au5%), see table II.
We now compare the variation of Tc induced by
Au or Pt impurities in CuMn or AgMn with the
variation expected in several models :
.
(a) the variation expected by Bray, Moore and Young [4] (BMY) for RKKY vector spin glasses can
be derived from equation (1a). We have calculated
Tc for the CuMnPt and AgMnAu series of VS [8] by using the values of d
=DIJ calculated above, A =1, YD
=3/2 and by choosing J to obtain Tc = 24 K for CuMn4 at% (d
=0.036) and T, =
18.5 K for AgMn5.5 at% (d
=0.095). The values of
Tc calculated for the series CuMn,Pty are shown in figure 3, see curve BMY, and can be compared with the corrected experimental Tc (i.e. the experimental Tc of VS corrected for the mean free path effects, as explained above). It turns out that equation (1)
Fig. 3.
-T,
versusy for CuMn4 at%Pty% alloys. VS : experimental values of Viers and Schultz [8] corrected for
mean
free path effects. BMY : T,, calculated from equation (1). MCMB : Tc calculated from equation (6). KS : Tc calculated from equation (7).
predicts too large shifts of Tc. We can lower the
calculated shifts by lowering the values of d uni- formly. When we lower the factors of d by about an
order of magnitude, the calculated Tc come closer to
the experimental Tc but it is hard to obtain a good fit throughout the whole concentration range. This can be clearly understood from figure 4 where j2 ITC’ 2 is
Fig. 4. - J2/ T;
versusIn (dJ / Tc). The straight line is the variation predicted by equation (1). The experimental T,
arethose obtained by Vier and Schultz [8] corrected for
mean free path effects. In order to fit the experimental
curve with the calculated line in the left side of the figure,
we
have taken values of d lowered by
afactor of 8 (with respect to their values of Tab. II), and J
=63 K for
CuMn4 at% or J
=44.6 K for AgMn5.5 at%.
Table II.
-The transition temperature Tc measured by VS, reference [8], the transition temperature corrected
for mean free path effects, T§", and the anisotropy parameter d calculated from equation (5) with the
parameters V1/Vo of table I for series of CuMnPt and AgMnAu alloys.
°