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Chiral-at-Metal BODIPY-Based Iridium(III) Complexes: Synthesis and Luminescence Properties

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Academic year: 2021

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Figure

Figure 1. Previously studied Fischer metal carbene BODIPYs push-pull systems (I, II) and   BODIPYs having remote half-sandwich Ir(III) and Rh(III) (III)
Figure  2.  X-ray  structure  of  complex  7b  depicted  at  a  30%  thermal  ellipsoid  level
Figure 3. Circular dichroism (CD) spectra of compounds 5a, 6a, and 7a (10 µM solutions  in MeCN, T= 25⁰ C)
Figure 4. Absorption spectra (MeCN) of compounds 5 and 6 and complexes 7.
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