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Accelerated ageing of OLED under different temperature and current conditions: photometric and electrical characterizations and analysis

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HAL Id: hal-03238163

https://hal.archives-ouvertes.fr/hal-03238163

Submitted on 26 May 2021

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Accelerated ageing of OLED under different

temperature and current conditions: photometric and electrical characterizations and analysis

Laurent Canale, P Dupuis, A Zerrouki, G Zissis

To cite this version:

Laurent Canale, P Dupuis, A Zerrouki, G Zissis. Accelerated ageing of OLED under different tem-perature and current conditions: photometric and electrical characterizations and analysis. 9th Inter-national Conference on Organic Electronics (ICOE), Jun 2013, Grenoble, France. �hal-03238163�

(2)

Accelerated ageing of OLED under different temperature

and current conditions: photometric and electrical

characterizations and analysis

LAPLACE Laboratory, UMR5213, CNRS, Paul Sabatier University, 118, route de Narbonne 31062 Toulouse cedex 9, France

Laboratory on Plasma and Conversion of Energy

L. Canale, P. Dupuis, A. Zerrouki, G. Zissis

E-mail :laurent.canale@laplace.univ-tlse.fr

LAPLACE, CNRS - Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex 9, FRANCE

Introduction

OLED are constantly technologicaly evolving. Performances evolve, and

materials also. In a context in permanent revolution, it is necessary to

maintain up to date our knowledge on the most common commercial

products, ageing and failure mechanism. We need to have a deeper

expertise, characterize them and study them to predict their life

expectancy otherwise to anticipate the possible causes of failure.

OLED applications

Schematic view of one unit of the experimental setup

Methodology

Results

Conclusion and Perspectives

Thermal 3D modeling in COMSOL

Simulated temperature distribution from top view of the

thermal conductive gap filler (k= 6 W/m.K) at 40°C and 60°C temperature set point

Foresee the experiments results

Verify the homogeneity of the copper layer

Good thermal homogeneity

40°C

60°C

OLED are operated at two currents, one in the middle of nominal operating range and one producing a small overdrive with respect to the normal operating conditions. At regular intervals, the driver is switched off and the devices returned to ambient temperature. A complete electrical characterization is performed both in the time and frequency domains. To avoid self-heating, short current or voltages pulses are applied with a low on-off ratio. Optical parameters are measured during the pulses: spectrum, chromaticity coordinates, color temperature and color rendering index. An optical setup permits to produce an image of the OLED directly at the spectrometer input slit, avoiding the need to use dark rooms. In parallel, a deep bibliography study has been conducted in order to consolidate our knowledge about many aspects leading to OLED premature failure. 350 500 216 432 0 100 200 300 400 500 600 1 2 3 4 If max If nominal If tested

Currents power supplies output are chosen to be

around nominal and maximum values

The optical system permits to produce an image of the lighting device onto the input fiber of an Ocean Optics HR4000 spectrometer. This device is triggered by the electrical power source, permitting to evaluate spectra in strict synchronism with the voltage pulses. The illustrated figures were obtained with an exposure time of 16 milli-seconds and voltage pulses whose amplitude run from 20 volts up to 26 volts in steps of one volt.

The pulse period is 500 ms, avoiding device heating by self-dissipation. The input fiber is placed in a simple cardboard cylinder, in a room with no special optimization with respect to optical conditions. Daylight and artificial lights were present into the room.

Time resolved spectrum measurements

40 40 40 40 HEATER Thick

Thick Copper Copper holderholder Thermal conductive gap filler OLED

thermocouple PID controller CONTROL & CONTROL & DATALOGGING DATALOGGING 11h00 ‘ON’ ‘OFF’ 1h00

At the time of writing, the full system results from the assembly of a number of functional blocs. Each block has been separately tested and validated:

Thermal measurements corroborates the thermal simulation;

Electrical and optical measurements have been optimized with respect to self-heating & environmental lighting;

The on/off cycles are fully automated, and the whole process is computer monitored.

Various tendencies have been observed on a prototype and are under review with respect to our database of failure and ageing patterns. The measurements performed on the prototype lack the optical part. The new system now covers the whole range of measurements required in order to fully characterize OLED ageing.

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