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Undecacarbonyl (μ4-2-thiodithiobenzoato-κ4C, S, S′, S′′)(triphenylphosphine) tetrafe

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Undecacarbonyl

(μ4-2-thiodithiobenzoato-κ4C,

S,

S′,

S′′)(triphenylphosphine) tetrafer

Authors

El Adoui Laifa, Nourredine Benali-Cherif, Fadila Berrah

Publication date

2003/2/1

Journal

Acta Crystallographica Section E: Structure Reports Online

Volume 59 Issue 2 Pages m80-m82 Publisher

International Union of Crystallography

Description

The structure of the title compound, [Fe4(C7H4S3)(C18H15P)(CO)11], obtained by heating the tetranuclear complex Fe4S3C19O12H4 with an excess of triphenylphosphine in acetone at 328 K, shows that PPh3 has replaced one carbonyl on the less hindered Fe atom.

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