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Source Rocks and Related Petroleum System of Chelif
Basin, (Western Tellian Domain, Algeria)
Mohamed Arab, Rabah Bracène, François Roure, Réda Samy Zazoun, Yamina
Mahdjoub, Rabi Badji
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1
Source Rocks and Related Petroleum System of Chelif Basin,
1 2 3 2 4 5 6 7 3
(Western Tellian Domain, Algeria)
s
4 Mohamed Arab a, b , Rabah Bracène a , François Roure c, d , Réda Samy Zazoun e, ·,9 10 11 12 5 13
6
14 15 16 17 18 19 7 8Yamina Mahdjoub b and Rabi Badji a
(3) Sonatrach-Division Exploration, Avenue du 1er Novembre Bat 'C' BP 68M,
Boumerdès, Algeria.
2o 9 E-mail adress : Mohamed.arab@ep.sonatrach.dz
21 22 10
23
24
(b) Faculté des Sciences de la Terre, de la Géographie et de l'Aménagement du 25 11 Territoire, USTHB, BP 32, Bab Ez Zouar, Algiers 16111, Algeria.
26
27 12
28 29
(c) Geosciences Department, IFPEN-Institut Français du Pétrole Energies Nouvelles, 30 13 Rueil Malmaison, France.
31 32 14 33 34 35 15 36 37 16 38 39 17 40 41 42 18 43 44 19 45 46 47 20 48 49 21 50 51 52 22 53 54 23 55 56 57 24 58 59 25
(d) Tectonic Group, Utrecht University, the Netherlands.
(e *) Corresponding author: Sonatrach-Division Technologies et Développement, Avenue du 1er Novembre, Boumerdès, Algeria.
26
1. Introduction1
2
27
3 The study area lies in the external zone of the Rif-Tell or Maghrebides fold-and-thrust
4
5
28
belt, the southernmost segment of the Alpine orogeny (Durand-Delga et al., 1980; 67
29
Bracene and Frizon de Lamotte, 2002; Roure et al., 2012), which trends roughly8 9
30
10 east-west in northern Algeria (Fig. 1 ). The Chelif Basin is a dominantly Neogene
11
12
31
trans-tensional basin located within the Northern Algerian foothills, southwest of the 1314
32
15 Kabylian ridge, which constitutes the surface expression of the paleo-suture between 16
17
33
(1) exotic terra nes of European affinities (Kabylides Crystalline Massifs and 1819
34
20 associated Mesozoic to Eocene sedimentary caver), and (2) the Tellian allochthon, 21
22
35
made up of Mesozoic basinal units derived from the former passive margin of North 2324
36
25 Africa (Benaouali-Mebarek et al., 2006, and references therein). The Neogene
26
37
27 sedimentary infill of the Chelif Basin rests on top of the allochthonous basinal 28
29
38
Mesozoic to Paleogene carbonates and sandstones units of the southern Tellian 3031
39
32 allochthon.
33
34
40
Since the discovery of the small oil fields of Ain zeft and Tliouanet in the Chelif Basin 3536
41
37 in 1872, followed by Oued Gueterini in 1948 in the Hodna area, Northern Algeria 38
39
42
constitutes an interesting zone for explorationists. Besides, many oil and gas shows 4041
43
42 exist either in the Saharan Atlas, south of the Alpine thrust front, or within the Tellian
43
44
44
domain itself. The potential plays relate to Miocene compressional structures in the45
46
45
partially inverted foreland, in subthrust units and intra-mountain basins, as weil as in47
48
46
49 Triassic to Jurassic extensional structures still preserved in the foreland autochthon. 50
51
47
The aim of this paper is to (1) identify potential source rocks in the Neogene Chelif 5253
48
54 Basin, in its allochthonous Tellian substratum, as weil as in the underlying
55
51 origin of the ails in the fields, (4) assess the timing of HC migration and trapping, and
1
2 52 (5) define the main petroleum systems.
3 4 5 53 6 7 54 2. Geological setting 8
1
~
55 The intra-mountain Chelif Basin (Perrodon, 1957) is located in the western part of the11
12 56 Tellian Atlas lt is elongated in the east-west direction, with steep border faults
13
~: 57 delineating individual pull-apart basins filled by Miocene to Pliocene series (Fig. 1 ).
16
17 58 lts structure developed following the last phases of the Alpine orogeny (Alfa et al.,
18
~~ 59 1992). For instance, during the Neogene, the plate boundary between the Western
21 22 60 23 24 61 25
~~
62 28 29 63 30 31 64 32 33 34 65 35 36 66 37 38 39 67 40 41 68 42 43 44 69 45 46 70 47Mediterranean and the Kabylides in the north and Africa in the south was a dominantly transform boundary, slab detachment and strike-slip faulting accounting for the lateral escape of the Gibraltar arc and Alboran black towards the west and Tyrrhenian-Calabrian arc towards the east (Hsü, 1971; Olivier, 1984; Thomas, 1985; Carminati et al., 1998; Spakman and Wortel, 2004, and references therein). Due to strain partitioning, numerous episodes of transpression and transtension were then recorded in the Chelif area, bath in the Tellian allochthon and underlying underthrust foreland. The tectonic studies show that the present deformation is mainly compressive with a NNW-SSE direction of shortening (Philip and Thomas, 1977; Meghraoui, 1982; Philip and Meghraoui, 1983; Meghraoui, 1988; Meghraoui and
Doumaz, 1996; fVleghraoui et al., 1996; Boudiaf et al., 1998; Domzig et al., 2006;
:~
71 Yelles-Chaouche et al., 2006; Guemache, 2010). According to Rebaï (1993), the50
51 72 present state of regional stresses suggests that the Maghreb is subjects to a N-S
52
53 73 compression and acts as an indenter in its central Algerian part, the western and
54 55
56 74 eastern parts (Morocco and Tunisia) being allowed to experience a lateral escape
57
58 75 (Piqué et al., 1998a & b ). Furthermore, based on paleomagnetic measurements, the
76 relative convergence motion between the Africa and Eurasia plates could be 1 2 77 3 4 5 78 6 7
79
8interpreted as a transpressional tectonic deformation model with block rotations along
the Algerian continental margin (Derder et al., 2013).
1
~
80 2.1. Geodynamic evolution and tectonic agenda11
12 81 After the opening of the Tethys Ocean and coeval development of the northern
13 14
82
15 16 17 83 18 19 84 20 21 22 85 23 2486
25 26 87 27 28passive margin of Africa during the Triassic and Liassic, the rotation of the African plate as compared to Eurasia induced since the Upper Jurassic a slow convergence between the two plates. This led to a progressive closure of the former ocean, and to
the formation of the circum-Mediterranean Alpine mountains (Thomas, 1985). During
the Late Cretaceous until the Eocene, foreland inversions developed in the former rift basins of the Saharan Atlas, due to a good coupling between the plate boundary and
2 9 88 the African lithosphere, at a ti me wh en the oceanic domain was not yet tully
30
~~
89 subducted (Frizon de Lamotte et al., 2006; Bracène and Frizon de Lamotte, 2002;33
34 90 Roure et al., 2012).
35
~~ 91 Surprisingly enough, the Tellian allochthon is made up of Upper Cretaceous to
38
39 92 Eocene basinal units derived from the distal portion of the former passive margin of
40 41 93 42 43 44
94
45North Africa, with a basal decollement located in Triassic evaporites, with no evidence of Lower Cretaceous nor Jurassic series in between. The best interpretation
4 6 95 he re is to assume, as wh at has already be en described for the Eastern Algerian and
47 48
96
49 50 5197
52 53 98 54 55 5699
57Tunisian Tell, that salt canopies made up of Triassic series were already
interstratified within the Cretaceous series of the passive margin (Vila et al., 1993;
Masrouhi and Koyi, 2012, and references therein), thus allowing a localisation of the
101 the distal portion of the African margin and on top of the southward propagating 1
2 102 Tellian tectonic wedge.
3
4
5 103 The paroxysmal phase of thin-skinned deformation resulted in the overthrusting in the 6
7 104 Tellian allochthon during the Lower Miocene. As a result, Langhian series are 8
1
~
105 currently located in three distinct tectonic positions in the vicinity of the Chelif Basin 1112 106 (Fig. 2): (1) in the autochthonous flexural basin, where the Lower Miocene deep
13
~~ 107 water turbidites rest directly on top of Upper Cretaceous blackshales in Tiaret, (2) in
16 17 108 18 19 109 20 21 22 110 23 24 111 25 26 27 112 28 29 113 30
the footwall of the Tellian allochthon, where the Lower Miocene series still constitute a potential seal for the Mesozoic reservoirs of the subthrust prospects, and (3) on top of the Tellian allochthon, in a piggyback position.
After the final emplacement of the Tellian allochthon on top of its foreland domain, an episode of trans-tension occurred along the plate boundary during the Tortonian and Messinian, accounting for the formation of thrust-top pull-apart basins in the Chelif
;~
114 area (Ghazli, 2001; Roure, 2008; Roure et al., 2012), in a similar way as what has 3334 115 been described for the Vienna Basin at the junction between the Alps and the
35
;~ 116 Carpathians (Sauer et al., 1992; Seifert, 1996), or in the Gulf of Paria between the
38
39 117 Serrania del lnterior in Eastern Venezuela in the west, and Trinidad in the east
40 41 118 42 43 44 119 45 46 120 47 (Lingrey, 2007).
Since the Pliocene, there is again a good coupling between the plate boundary and the African foreland, accounting for the transpressional inversion of former normal
:~
121 faults inherited from the Tethyan rifting in the underthrust African foreland. This new50
51 122 compressional episode has resulted in the formation of subthrust anticlines involving
52
~~ 123 the Mesozoic parautochthonous series and in the refolding of the sole thrust of the
55
56 124 overlying Tellian allochthon beneath the Chelif Basin, in a similar way as in the 57
58 125 Tempa Rossa and Monte Alpi fields of the Southern Apennines and ether nappes
126
1 2127
3 4 5128
6 7129
8 9 10 11130
12131
13anticlines described in Northern Sicily (Casera et al., 1991; Roure et al., 2012), in the
eastern part of the Algerian Tell near Constantine (Vila et al., 1994), as weil as in the
tectonic windows of the Bibans and Ouarsenis Mountains (Mattauer, 1958), where
the lower plate is currently exposed to the surface due to the large a mount of tectonic
uplift and erosion.
i~
132
2.2. Neogene sedimentary infill of the Chelif Basin16
17
133
Due to the complex tectonic evolution of the Chelif Basin, its Neogene sedimentary 1819
134
20 21infill can be subdivided into 3 distinct tectonostratigraphic assemblages
(Neurdin-22
135
Trescartes, 1992 and 1995; Fig. 3): 2324
136
At the base, the marine Lower Miocene megasequence (MSI) was still deposited 2526
27
137
during a compressional episode, in a piggyback position on top of the still moving 2829
138
Tellian. During the Lower Miocene, the sedimentary deposits preserved on top of the 3031
139
32 Tellian units, and especially in the western sub-basin of the Chelif, record the 33
34
140
influence of arc-related alkaline and calc-alkaline volcanism.35 36
141
37 The thicker Tortonian-Messinian megasequence (MSII) was deposited during the 38
39
142
formation of the trust-top pull-apart basin, during the episode of transtension. lt still 4041
143
42 comprises dominantly marine siliciclastic deposits at the base, grading into mari, 43
44
144
continental siliciclastic deposits and intense volcanism, like cinerites, that are 4546
145
47 considered as a chronologie marker at the base of Messinian (Kieken, 197 4 and 48
146
49 1975).
50
51
147
The Plio-Quaternary sequence (MS Ill) was deposited during the reactivation and52 53
148
54 inversion of the border faults of the Chelif Basin, coeval with the formation of 55
151
1
2 152 3. Results
3
4
5 153 3.1. Source rocks characterization
6
7 154 At the scale of the Circum-Mediterranean basins and thrust-belts, numerous
8
1; 155 stratigraphie intervals have been recognized since a long time as potential source
11
12 156 rocks for hydrocarbons. This is the case for Upper Triassic bituminous limestones in
13
~: 157 Sicily and the Adriatic domain (Southern Alps, Dinarides and Albanides; Ziegler and
16
17 158 Roure, 1996, and references therein), Liassic blackshale in the Saharan Atlas in
18
~; 159 Algeria (Vi ally et al., 1994 ), in the lonian zone in the Albanides, in Epi rus in the
21
22 160 Hellenides (Karakitzios, 2013, and references therein), Cenomanian-Turonian euxinic
23
24 161
25 facies in the Apennines, Eocene blackshale in the Eastern Tell in Algeria, Oligocene
26
27 162 Numidian flysch in Tunisia and Sicily, as weil as Messinian series.
28
29 163 ln the Chelif area, only the Cretaceous and Cenozoic rocks of the Tellian allochthon
30
~~
164 and Neogene pull-apart basin have been investigated here, due to the current lack of33
34 165 deep weil that would be required to document potential source rocks in the lower
35
~~ 166 plate (underthrust foreland).
38 39 167 40 41 168 42 43 44 169 45 46 170 47 48 4 9 171 50 51 172 52 53 54 173 55 56 174 57 58 59 175
3.1.1. Upper Cretaceous (Cenomanian to Campanian)
As is most of North Algeria, Upper Cretaceous series of the Tellian allochthon
cropping out in the vicinity of the Chelif Basin are locally preserved around the main
Neogene depocenters, either is the form of weil stratified Campanian outcrops, or as
hard blacks of Cenomanian limestones reworked in the shaley matrix of tectonic
mélanges along the sole thrust of the allochthon (Fig. 2). These Upper Cretaceous
series have been sam pied in outcrops of the northern and southern borders (Fig. 1 ).
176
mean to good. TOC varies from 1.5 to 7 % (Roure et al., 2006). TOC values varies 12
177
3 from 0.56 to 3% Relizane and Beni Chograne mountain, near Tliouant field the
4
5
178
southeast, in the Dahra Mountains it ranges from 0.9 to 8.2 %. The present day6 7
179
8 maturity shows a frozen oil window in the basin borders (outcrops) and instead a gas 9
10
180
window in wells drilled in the central part of the Neogene basin (Fig. 3). Sorne 1112
181
13 outcrop's samples display high residual potential with Hl varying from102 to 480 mg/g
14
15
182
TOC (Fig. 4 and Tab. 1 ), they are in oil window (Tmax= 438- 443 oc), the lower Hl 1617
183
18
(5- 12 mg He/TOC) indicate a gas window, the Tmax is higher (574- 599 oc) (Tab.1 ). 19
20
184
2122
185
23 3.1.2. Oligocene Numidian series
24
186
25 The Oligocene Numidian flysch crops out also in the Tellian allochthon on both sides 26
27
187
of the Neogene depocenters, but it may be entirely lacking beneath the whole basin28
29
188
30 as due to the geometry of the Miocene normal faults. lt consists of grey to black 31
32
189
maris (Fig. 3) deposited in a deep water environment. lts thickness reaches up to 500 3334
35
190
m. TOC varies from 2 to 4%, which gives an equivalent of 10 to 30 % in carbonate 3637
191
composition. The Hl/01 diagram (Fig. 5) shows a type-Ill kerogen. However, the38
39
192
40 optical observation reveals amorphous sapropelic organic matter. This low potential 41
42
193
at lower maturity indicates a poor preservation of the organic matter due to oxidation 4344
194
(Fig. 5). Whole samples display low to fair TOC, ranging from 0.4 to 0.9 % and low45
46
195
47 maturity. ln the central part of the basin, the organic matter reached the oil window at 48
49
196
about 2100 m and a wet gas window at about 3,500 m. The environment of 5051
197
52 deposition, mainly controlled by the geometry of the Maghrebides-Apenninic flexural 53
54
198
basin, was probably not in direct communication with the Atlantic Ocean where up-5556
199
201 1 2 202 3 4 5 203 6 7 204 8 9 10 205 11 12 206 13 14 207 15 16 17 208 18 19 209 20 21 22 210 23 2 4 211 25 26 212 27 28 29 213 30 31 214 32 33 34 215 35
3.1.3. Lower to Middle Miocene
Their thick series of blue maris are characterized by a weakness of organic matter;
the TOC is generally lower than 0.5 % (Figs. 6 and 7), this is due mainly to a dilution
which is related to a high sedimentation rates (1 000/my) . Nevertheless, they contain
thin (decimeter-thick) layers which are limited in space with the TOCs ranging from
0.8 to 1%, like in EI-Biod and Ain Zeft area (Fig. 6 and 7). The organic matter is from
type Il marine with probably inclusion of terrestrial material (Fig. 8), regarding the
proximity of the land to the deep basin. Although the lower potential could be the
result of the thermal maturation process (Figs. 5 and 8), the high oxygen index (10=
200- 400mg C02/g COT) (Figs. 5 and 7) traduces an oxidation and thus a bad
preservation of the organic matter (Fig. 8). ln terms of maturity the deepest layers are
in gas window (Figs. 5 and 8), in the central part of the basin (EI-Biod, Nador, Akboub
and Belkheir) and in oil window in shallower areas, such as Noisy and Fornaka.
~~ 216 3.1.4. Upper Miocene series
38
39 217 The Upper Miocene series have been sampled in the northeastern (EI-Biod and Aïn
40
41 218 Zeft) and southwestern parts (Belkhir and Fornaka) of the basin (Fig. 1) at depths
42 43
44 219 varying from 500 to 750 m. Apart of the Tripoli member of the Messinian where TOC
45
4 6 220 values can rea ch up to 10% or more, he average TOC values of ether Miocene
47
:
~
221 intervals range from less th an 0.5% to 1% (Fig. 5).50
51 222 The majority of the samples in Aïn Zeft (Fig. 7), Akboub and Hellil areas display high
52
;~ 223 oxygen and lower hydrogen proportion in the organic matter (Fig. 5). The hydrogen
55
5 6 224 index is around 1 00 mg HC/g TOC (Fig.5). ln the El Bied a rea, the basal part of the
57
58 225 Upper Miocene presents a fair quality of organic matter (fig. 4 and 7). There, the
226 Hydrogen index (Hl) ranges from 100 to 150 mg HC/g TOC, the sample actually
1
2 227 recording a maturity grade at the beginning of oil window (Figs. 6 and 7). Besides,
3
4
5 228 close to the northern border of the basin near Ain Zeft and Dahra Mountain outcrop
6
7 229 samples have been analysed, they show a good organic richness, with a TOC of
8
1
~
230 1.18- 2.31% (Fig. 4 and Ta b. 1 ). However, even though the thermal indicators Tmax11
12 231 (<430 oc) and TAI= 1.5) (Tab. 1) traduces an immaturity of the organic matter, only
13
Î~ 232 two samples display fair to excellent potential (Hl= 211 and 566 mg hc/g TOC).The
16
17 233 rest of the samples are characterized by low hydrogen indices, this is due probably to
18
~~ 234 a bad preservation or oxidation of the organic matter. Nevertheless, the oil shows
21
22 235 and the Ain Zeft accumulation is an indication that there is an efficient kitchen zone in
23
24 236 the vicinity of the area, the lack of the reliable samples does not allow establishing a
25 26
27 237 thermal maturity map. 28
29 238
30
~~
239 3.2. Oil-source rocks correlations33
34 240 The normalized percentage compositions of the aliphatic, aromatic and NSO
35
~~ 241 fractions of each sample of rock extracts and oils are plotted in a ternary diagram
38
39 242 (Fig. 9). According to Tissot and Welte (1984), the grey area in the figure represents
40
41 243 typical conventional petroleum composition. The samples present a lower proportion
42
43
44 244 of aromatics hydrocarbons (HCA) and polar products (NSO) and high saturated 45
4 6 245 hydrocarbons (HCS) (Fig. 9).
47
48
4 9 246 The graph PRfnC17 - PHfnC18 (Lumbach, 1975, in Chaouche, 1992) is used for
50
~~
247 defining the maturity and the type of organic matter of the source rock which has53
54 248 generated oils and extracts that are analyzed by chromatography in the framework of 55
251 after the graph and humic type zone for the third sample from 1584 m (Fig. 9). At El-1
2 252 Biod weil the diagram shows a type-Il kerogen and lower maturity as compared to
3 4
5 253 Akboub oils in the western area (Fig. 9). 6
7 254 An oil sample issued from Ain Zeft field (weil W3) and a hydrocarbon extract of
8
9
10 255 Messinian maris ( outcrops) have been analysed with gas chromatography and the
11
12 256 chromatograms of C14+ saturates are compared for a correlation need.The
13
~:
257 Messinian extract is characterized by a predominance of even number components16
17 258 and a low Pr/Ph fraction (0.5) (Fig. 1 0), this is an indication of a source rock that has
18
19 259 been deposited in a highly reduced evaporitic environment. Besides, as indicated
20 21
22 260 above, the samples are totally immature, C21-C35 being still present in high
23
24 261 proportion. The Ain Zeft oil sample displays the same distribution with also a low 25
~~
262 Pr/Ph fraction (0.16) (Fig. 10). Moreover, the sulphur content in the present oil is28
2 9 263 higher than 2%, meaning th at this oil was most probably generated from a type-liS
30
~~
264 organic matter. The chromatogram of Messinian extract (shows a high concentration33
34 265 of biomarkers (Fig. 11 a). Although the oil sample is slightly mature than the extract,
35
~~ 266 the two samples seems to be similar. The absence of gas spectrometry data (GCMS) 38
39 267 could not allow a complete correlation.
40
4 1 268 The oils from Tliouanet field are very mature because they contain a higher 42
43
4 4 269 proportion of C14-C21 components (Fig. 11 c), the regular decreasing of the pick 45
4 6 270 heights, from C19 to +C30 compone nt is an indication of a marine environ ment of 47
!~
271 the organic matter, from which these oils have been generated (Fig. 11 c ).The Pr/Ph 5051 272 fraction is 1.6; it is an indication of a highly reduced environment (Fig. 11 c).The 52
53 273 distribution of the extract component is the same as the one of the Tliouanet oil; the
54 55
56 274 predomainance of nC15-nC21 components traduces the relatively higher maturity of
57
276
1 2 277 3 4 52
78
6 7279
8 9 10280
11 12281
13 14282
15 16 172
8
3
18 19284
20 21 2228
5
23 24286
25 262
87
27 28 29288
30 31289
32 33 34290
35 36291
37 38 39292
40 41293
42 43 442
94
45 46295
47 48296
49 50 51297
52 532
98
54 55 56299
57reservoir in Tliounat field (basal Tortonian sandstones) comparing to the Cretaceous allochton source rock which belongs to the substratum of the Neogene Chelif basin, the migration pathways of this ail came from this Cretaceous level (Fig. 2). According to its geochemical signature, this ail is quite similar to the ails of the Oued Gueterini field farther east in the Hodna Basin, with strong affinities with extracts from Cretaceous source rocks. Because of the geometry of the Chelif Basin and their close association with the main border fault of the basin, these ails were probably generated from a deeper structural unit, with a dismigration from the subthrust parautochthous units or underthrust foreland, in a similar way as the Jurassic-sourced ails found in the Neogene reservoirs of the Vienna Basin in Austria, which were actually generated in the lower plate, thus accounting for subsequent vertical migration a cross the sole thrust of the T ellian allochthon.
3.3. Thermal modelling and hydrocarbon generation history
3.3.1. Geothermal boundary conditions
300 Another problem with 1 D models is that they can hardly account for tectonic
1
2 301 duplication, the Tellian allochthon recording a completely different thermal evolution
3
4
5 302 as compared to the underthrust foreland until the Langhian, when the two demains
6
7 303 were ultimately superposed with only miner subsequent tectonic contraction.
8
9
10 304 ln this paper, the ai ms of the 1 D petroleum modelling with the Genex software was to
11
12 305 reconstruct the thermal, source rock maturation and petroleum generation in the 13
~~ 306 Neogene depocenter, with a focus on the evolution of the Neogene source rocks 16
17 307 from the post-nappe pull-apart basin. Further coupled 20 kinematic and petroleum 18
19 308 Thrustpack modelling has also been attempted in the past in the Chelif Basin to
20
21
22 309 address the thermal evolution of the lower plate and exploration risk of subthrust
23
24 310 prospects (Sassi et al., 2006), but these results will not be detailed here, because of
25 26
2 7 311 strong uncertainties wh en reconstructing the pre-Miocene thermal evolution of both
28
2 9 312 the Tel lian allochthon and underthrust foreland.
30
~~
313 ln any case, the North Algerian Tellian Atlas presently displays a normal crust which 3334 314 thickness ranges from 30 to 40 km (Marillier and Mueller, 1982; Thomas, 1985).
35 36 315 37 38 3 9 316 3.3.2. Geothermal history 40
41 317 Acccording to Louni-Hacini et al. (1995), Neogene volcanic rocks from the
42 43
4 4 318 northwestern coast of Algeria include calc-alkaline to shoshonitic andesites and
45
4 6 319 dacites (Sahel of Oran and M'Sirda areas) and alkaline basalts (Tafna valley). 47
!~
320 Seventeen new 4°K-40Ar ages indicate that these volcanics were emplaced during 5051 321 two distinct periods, from 11.7 to 7.2 Ma and 4 Ma, respectively. Ali the andesites
52
53
322 and dacites were emplaced during the first period, and their trace element 54
55
56 323 characteristics are typical of subduction- and/or collision-related magmas. Du ring the 57
58
324 Late Pliocene and Quaternary, the volcanic activity occurred in the Moroccan Middle
1
2 325 Atlas and in Oran area in Algeria (Fig. 1 ).
3 4
5 326 ln the Tellian thrust belt the heat flow increases rapidly towards the Mediterranean
6
7 327 Sea. lts overall pattern is comparable to that measured in the other Tertiary belts 8
9
10 328 (Takherist and Lesquer, 1989). According to these authors the present day heat flow
11
12 329 varies from 80 mW/m2 to more than 100 mW/m2 near the offshore. At the present day
13
î:
330 the geothermal gradient varies from 30-35°C/km (Normal Geothermie Gradient) to16
17 331 more than 50°C/km (Fig. 12), two hyperthermie zones being localized in the central
18
19
332 part of the Chelif Basin, where it may be due to the local occurrence of Neogene
20 21
22 333 diapirs remobilizing the Triassic salt of the Tellian allocthon, (Fig. 2) and the coastal
23
2 4 334 zone near the Gulf of Mostaganem (i.e. in the vicinity of the neoformed Neogene
25
26
27 335 oceanic lithosphere of the offshore Algerian Basin.
28
29 336 ln the eastern part of the basin, the deduced heat flow varies from 50 mW/m2 to 85
30
;; 337 mW/m2 (Fig. 13a). For obvious geodynamic reasons, the heat flow model used in the
33
34 338 present study has been considered variable through the geological time. From the 35
;~ 339 Upper Cretaceous to the Lower Miocene (main episodes of tectonic contraction), the
38
39 340 mean flow value is estimated to 50-55 mW/m2
• However, related to geodynamic and
40
41 341 volcanic activity of the basin, we assume a larger heat flow value since the onset of
42
43
44 342 slab detachment and Tortonian-Messinian episode of accelerated subsidence in the
45
46 343 basin (Fenet, 1975; Bellon and Brousse, 1977; Aït Hamou, 1987; Maury et al., 2000).
47
!
~
344 Ultimately, the present day heat flow has been deduced from the geothermal gradient50
51 345 and thermal conductivities of the sediments. The BHT corrected temperatures
52
~~
346 calibrated the present day heat flow at 85 mW/m2 (Fig. 13a), as estimated by55
56 347 Takherist and Lesquer (1989).
349 3.3.3. Reconstruction of the bu rial history
1
2 350 At eastern part of the study area, the Neogene series of the Chelif Basin were
3 4
5 351 deposited on top of the Oligocene and Cretaceous Tellian allochthon (Figs. 1 and 2).
6
7 352 The Late Oligocene and Burdigalian being still characterized by deep water turbidites
8
9
10 353 along the Tellian allochthonous units underlying the Neogene depocenters of the
11
12 354 Chelif, only miner erosion occurred in this formerly basinal domain until the onset of
13
~~
355 uplift and tectonic accretion.16
17 356 During the development of the Lower Miocene syn-compressional piggyback basin 18
~ ~ 357 (Langhian-Serravallian) and subsequent transtensional opening of the thrust-top
pull-21
22 358 apart basin (Tortonian-Messinian), the sedimentation rate was very high 250 m/Ma
23
2 4 359 (Fig. 13b ). Be cause of renewed trans pression al foreland inversion in post-Miocene 25
26
27 360 times, the sedimentation rate was lower than 100m/Ma (Fig. 13b) during both the
28
29 361 Pliocene and Quaternary in the relict depocenters, most of the basin being instead
30
;~
362 impacted by inversion-related uplift and erosion.33
34 363 ln the western area (W1 0 weil), the sedimentation rate recorded during the Upper
35
;~ 364 Cretaceous- Eocene period) is 30 m/Ma (Fig. 14 a). However, during Upper
Miocene-38
39 365 Pliocene period, this parameter reaches 80 m/Ma; this is related to the transtensional
40
4 1 366 extension of the basin (Fig. 14 a). 42
43
44 367 45
4 6 368 3.3.4. Hydrocarbon generation and expulsion histories
47
!
~
369 1 D thermal modelling has been undertaken with the Genex software on the W5 Weil50
51 370 in the EI-Biod area and W10 to the West (Fig. 1 ). The thermal calibration of the 52
53
371 thermal model is established thanks to the measured temperatures in the weil and
54 55
5 6 372 the maturity mesurements (Ro converted values) (Fig. 13b). ln the former area, the 57
58 373 oil generation from the Middle Miocene formations (supposed source rocks) occurred
374 from 12 to 10 Ma and gas during 10- present day with a burial of 4000- 5200 m,
1
2 375 whereas, the Messenia is still immature (Fig. 13c). Besides, the Langhian supposed
3
4
5 376 source expelled oil between 8 and 5 Ma after that period only gas expulsion occurred
6
7 377 in this deeper part of the basin (Fig. 13 d).
8 9
10 378 ln the western area, there are two picks of oil expulsion, the first pick happens
11
12 379 between 12 and 8 Ma while the second one between happens at 4- 2 Ma (Piiocene)
13
~:
380 (Fig. 14b).16
17 381 Besides, the formation of structural traps relate to the Pliocene and Quaternary
18
19 382 inversion, thus post-dating the Messinian episode of maximum burial. Considering 20
21
22 383 type-li kerogen in this model, the Messinian which is the source rock of the Ain Zeft 23
24 384 oil field was not buried enough there (at 1,000 m depth) to generate hydrocarbons.
25
26
27 385 Alternatively, in the case of type-liS kerogen as is shown by the n alcanes and
28
29 386 biomarkers distribution in the rock extracts, it could generate commercial amounts of
30
~~
387 oil at lower temperatures (<50°C). A kinetic model of this organic matter would be33
34 388 required in order to confirm such scenario. 35
~~ 389 The Upper Cretaceous series are considered as the main source rock for the Upper
38
39 390 Miocene reservoir in Tliouanet. They are probably also the source of the gas and oil 40
!~ 391 shows documented elsewhere in the Chelif Basin (Fig. 1 ). The Middle Miocene series
43
4 4 392 display sorne HC potential in the EI-Biod a rea where the Miocene reservoirs might
45
4 6 393 have been sourced from. The Ain Zeft he avy oil is originated from the Upper Miocene
47
48
4 9 394 source rock which has a Iso a good generation potential in this a rea (Figs. 1, 3 and
50
51 395 Tab. 1 ). There are three types of traps, anticlines, roll-over structures and those 52
53
54 396 associated to diapirs. Their age extend from Middle Miocene to Pliocene and even to 55
56 397 present day. The early charge is most likely oil whereas the most recent traps could
399 1
2 400 4. Discussion
3 4
5 401 4.1. Petroleum systems analysis
6
7 402 4.1.1. Upper Cretaceous 1 basal Tortonian sandstone
8
9
10 403 ln the Tellian allochthon, the Upper Cretaceous (Cenomanian to Campanian) source
11
12 404 rocks extend only away from the Neogene depocenters, i.e. mainly south of the 13
~~ 405 Tliouanet- Relizane fields in the south (Fig. 1 a), and north of the Ain Zeft field in the
16
17 406 north, making it difficult to contribute in any way to the petroleum potential of the 18
19 407 basin. Axtually, due to the Tortonian-Messinian extension, Neogene series rest 20
21
22 408 almost directly above the sole thrust of the Tellian allochthon in the central part of the
23
2 4 409 basin (Fig. 2), where coeval Upper Cretaceous source rocks are instead likely to be 25
;~
410 found at appropriate depth for HC generation in the underthrust foreland and28
2 9 411 parautochthonous subthrust prospects. 30
;~
412 Although the presence of a thick Miocene sandstones package (200 m) in Djebel33
34 413 Djira area, to the west, there is no petroleum perspective because of the absence of
35
;~ 414 the source rocks (Fig. 15).
38
39 415 The zone B (Fig. 15) is the most prospective thanks to the presence of reservoirs at
40
41 416 the base of the Upper Miocene and the presence of both Upper Cretaceous and
42
43
44 417 Upper Miocene source rocks. However, as far as the exploration results are 45
46 418 concerned, and with the exception of the Ain Zeft accumulation, there have been only
47
~~
419 dry heles and hydrocarbon shows. The deficient parameter of the petroleum system50
51 420 in the whole Neogene sedimentary infill of the Chelif Basin is the timing of the trap 52
53 421 formation as compared to hydrocarbon migration. This is the case for instance for 54
55
56 422 Pliocene and Quaternary structures. The presence of the sm ali accumulation in 57
424 structuration or from a remigration from a deeper accumulation. Such accumulation is
1
2 425 not commercial.
3
4
5 426 ln Ain Zeft, Akboub and Hellil areas, the presence of the light oils, more mature than
6
7 427 the rock extracts of the nearby source intervals, clearly require the occurrence of a
8 9
10 428 deeper kitchen and both long range lateral and vertical migration, either from deepest 11
12 429 parts of the pull-apart basin, or from the lower plate, using the main border faults of
13
i:
430 the basin to migrate from the underthrust units towards the Neogene pull-apart.16
17 431 The zone C (Fig. 15) is the deepest part of the basin, it is characterized by a high
18
19 432 sedimentation rate, varying from 100 to 1000
mima
(Fig. 13b) during the Miocene. 2021
22 433 This might have caused dilution of the organic matter. Such sedimentological
23
24 434 conditions and probably the absence of upwelling streams could not favor a
25
~
~
435 development of anoxie conditions during Miocene time.28 29 436 30
;~
437 4.1.2. Messinian (source rock)/ Upper Miocene/Piiocene reservoirs33
34 438 The Upper Miocene (Messinian) source rock extends along central part of the basin,
35
;~ 439 Dahra Mountain and Ai Zeft area (Fig. 15). To be effective, this petroleum system
38
39 440 would require the presence of Upper Miocene reservoirs, i.e. the basal Tortonian
40
41 441 sandstone and Pliocene algallimestones (Lithotamnium limestone) and relatively old
42
43
44 442 (pre-Piiocene) structures. The generation of the hydrocarbon from Messinian source 45
4 6 443 rock is a Iso conditioned by the thickness of the Pliocene sediments (bu rial).
47
:: 444 Besides, the hydrocarbon charge of the Upper Miocene reservoirs could relate from
50
51 445 deep Neogene kitchens or again, from a vertical migration across the sole thrust of
52
~~ 446 the Tellian allochthon, from Upper Cretaceous source rocks from the lower plate.
55
449
1 24
50
3 4 5451
6 7452
8 9 10453
11 12454
13 1445
5
15 16 17456
18 19457
20 21 224
58
23 2 4459
25 264
60
27 28 29461
30 31462
32 33 34463
35 36464
37 38 394
6
5
40 41466
42 43 44467
45 46468
47 48469
49 50 51470
52 53471
54 55 564
72
57 58473
59developing any commercial hydrocarbon accumulation in relationship with this play,
because of the lack of source rocks therein. Elsewhere, the Pliocene series are
thinner (because mainly of Quaternary erosion), ranging from 0 to 50 m, which is
clearly insufficient to expect any sealed reservoir there.
5. Conclusions
The Oligocene Numidian series display locally high organic contents in Sicily and
Tunisia, where they are known to account for effective petroleum systems (El Heuchi
et al., 2004; Gran ath and Casera, 2004 ). Despite the fact that no hydrocarbon field
has yet been discovered in Oligocene Numidian sandstones in Northern Algeria, the
Oligocene series of the Tellian allochthon in the vicinity of the Chelif Basin shows the
same overall characteristics, and could still constitute a target for the exploration.
ln the more than 4 km-thick pre-Messinian Miocene series, there are intervals with a
mean organic rich ness (TOC) comprised between 0.5 and 1%, but their generative
potential still remains law because of the bad preservation of the organic matter,
which is marine with slight continental contribution. The optical observation and the
law residual potential (Hl) show that there is an effect of oxidation. ln contrast, the
Tripoli member of the Messinian series displays a very high organic content, with
TOC values up to 10% or more, but law maturities (Tmax < 430°C). However, its
kerogene is of the type-liS, which could generate hydrocarbon even at law
temperatures (<50°C). Alternatively, the Upper Miocene is more buried in the main
depocenters of the Chelif Basin than in the modelled wells, implying that it could be
already in the ail window in the deepest, not yet inverted parts of the basin. The 1 D
basin modeling shows that the timing of ail generation from the Middle Miocene
474
1 2475
3 4 5476
6 7 477 8 9 10478
11 12479
13 14480
15 16 17481
18 19482
20 21 22483
23 2 4484
25 26 27485
28 29486
30 31487
32 33 34488
35 36489
37 38 39490
40 41491
42 43 44492
45 46493
47 48494
49 50 51495
52 53496
54 55 56497
57richest levels of the Middle Miocene source rocks, the ail expulsion began at 8 Ma. From 5 Ma to the Present day, mainly gas expulsion occurred. ln any case, the GC/GCMS analysis confirms the correlation between Ain Zeft ails, which contain oleanane, and Upper Miocene extracts. However, the main exploration risk for Neogene hydrocarbon systems relates to the scarcity of clastic reservoirs in the sedimentary infill of the pull-apart basin, most anticlinal structures being controlled by salt dames, with dominantly fine grain growth strata. Stratigraphie traps and sandy paleo-chanels would rather occur along the flanks of the structures or in intervening lows, but they can hardly be identified here due to the lack of 3D seismic. Plia-Quaternary anticlines related to the recent inversion of the basin are likely to post-date the episodes of maximum burial in the Miocene depocenters, even if they could host remigrated ails from aider structures, or ail escaping vertically from the substhrust units along vertical conduits such as the main border fault of the basin. Similar modes of petroleum charge is known to occur in the Vienna Basin in Austria for instance, were the ail generated in Jurassic source rocks from the lower plate have migrated upward across the Alpine nappes before to be trapped in Neogene clastics of the trust-top pull-apart basin (Sauer et al., 1992; Seifert, 1996).
499 parautochthonous structures which formed during the Plio-Quatenary episode of 1
2 500 transpression, making the subthrust plays a potential target. The main exploration 3
4
5 501 risk here would relate to the possible erosion of Cretaceous platform carbonate
6
7 502 reservoirs and Albian sands of subthrust prospects prier to the development of the
8
9
10 503 Neogene foreland flexure and deposition of deep water seals, due to Late
11
12 504 Cretaceous to Eocene episodes offoreland inversion (Roure et al., 2012). 13 14 505 15 16 17 506 Acknowledgements 18
19 507 This work was undertaken as part of a Master Il research work realized at USTHB 20
21
22 508 University (Aigiers). The authors wish to thank Sonatrach and Alnaft for giving us 23
24 509 access to weil data. We acknowledge M. Kaced and N. Yahi for reviewing an early
25 26
2 7 510 draft of the manuscript. We greatly benefited from discussions with A. Lassai and H. 28 29 511 Benali. 30 31 512 32 33 34 513 References 35
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30
~~
709 A., 1994. Basin inversion along the North African margin: The Saharan Atlas (Aigeria).33
34 710 ln: Roure F.(Eds.), PeriTethyan Platforms, Editions Technip, Paris, 1994, pp. 79-117.
35 36 711
37 38
39 712 Vila, J. M., 1994. Mise au point des données nouvelles sur les terrains triasiques des
40
41 713 confins algéro-tunisiens: Trias allochtone, "glacier de sel" sous-marins et vrais diapirs.
42
43
44 714 ln : Dercourt J., Tefiani M. and Vila J.M. (Eds.), Trias 93, Mémoire du Service
45 4 6 715 Géologique de l'Algérie, 6, 1994, pp. 105-152. 47 48 716 49 50
51 717 Vila, J. M., Sigal, J., Lahondère, J. C., 1993. Position en fenêtre de la série néritique
52
53 718 constantinoise sous la nappe de Djemila: Observations nouvelles du Djebel Mazela
54 55
56 719 (massif du Djebel Oum Settas, Algérie du Nord-Est), Comptes Rendus de l'
57
58 720 Académie des Sciences, Série Il, 317, 395-401.
721 1
2 722 Yelles-Chaouche, A., Boudiaf, A., Djellit, H., Bracène, R., 2006. La tectonique active
3
4
5 723 de la région nord algérienne. Comptes Rendus Géoscience 338, 126-139.
6
7 724
8 9
10 725 Ziegler, P., Roure, F., 1996. Architecture and petroleum systems of the Alpine orogen
11
12 726 and associated basins. ln: Ziegler P. and Horvath F. (Eds.), PeriTethys, Mémoire. 2,
13
~: 727 Museum de l' Histoire Naturelle, Paris, 1996, pp. 15-46.
1 Figures captions
2 Figure 1. (a) Geological setting of Chelif Basin and weil location map and petroleum
3 results (b ).
4
5 Figure 2. Regional structural cross-section of the Chelif Basin, outlining the Neogene
6 flexural basin, the Langhian and Mesozoic series of the underthrust foreland, the
7 Tellian allochthon, and the Tortonian-Messinian series of the thrust-top pull-apart
8 basin and the main hydrocarbon kitchens and petroleum plays.
9
10 Figure 3. Typical Neogene stratigraphie and lithological section of the Chelif Basin
11 and its substratum.
12
13 Figure 4. Geochemicallog (Rock-Eval data) of Miocene section (El Biod , Weil W5).
14
15 Figure 5. Geochemical log (Rock-Eval data) of Miocene section (Ain Zeft field , Weil
16 W3).
17
18 Figure 6. Maturity indication: S2/TOC diagram of different source rocks.
19
20 Figure 7. Hl Vs. 01 diagram of Miocene organic matter, Akboub, Hellil areas and
21 outcrops samples.
22
23 Figure 8. Hl Vs. Tmax diagram of Miocene organic matter (Weil W6 and outcrops
24 samples ).
26 Figure 9. Ternary diagram HCS-HCA-NSO for oils and rock extracts.
27
28 Figure 10. Pr/nC17 Vs. Ph/nC18 graph of oil indices and rock extracts of Oligocene
29 and Miocene stratigraphie levels.
30
31 Figure 11. Gas chromatogram traces of nC14+ saturates in the source rock extracts
32 and oils.
33 (a) Oil fraction from Upper Miocene reservoir (Weil W3; Ain Zeft field).
34 (b) Messinian hydrocarbon extract (Mesinian maris from outcrops of Ain Zeft area). 35 (c) Oil fraction from Upper Miocene reservoir (Tiiouanet field).
36 (d) Upper Cretaceous hydrocarbon extract (Western Tellian domain).
37
38 Figure 12. Geothermical gradient map (°C/Km) of Chelif basin.
39
40 Figure 13. (a, b, c and d) Results of 10 Genex modelling of the bu rial history and
41 hydrocarbon generation in EI-Biod area (Weil W5).
42
43 Figure 14. (a and b) Results of 10 Genex modelling of the burial history and
44 hydrocarbon generation in Akboub a rea (Weil W1 0). 45
46 Figure 15. Extension of upper Cretaceous source rock and zonation in terms of
47 prospectivity of Upper Cretaceous (SR)/basal Tortonian (reservoir) petroleum
48 system.