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Photochemical C–H activation: generation of indole and carbazole libraries, and first total synthesis of clausenawalline D

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Table of Contents

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H NMR, 13C NMR, IR and ESI-HRMS spectra of 1a S3 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1b S7 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1c S11 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1c’ S15 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1d S19 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1d’ S23 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1e S27 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1e’ S31 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1f S35 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1f’ S39 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1g S43 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1g’ S47 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1h S51 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1h’ S55 1

H NMR and IR spectra of 1i S59 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1j S61 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1k S65 1

H NMR spectrum of 1l S69 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 1m S70 1

H NMR spectrum of 1n S74 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2a S75 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2b S79 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2c S83 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2d S87 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2e S91 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2f S95 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2g S99 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2h S103 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2i S107 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2j S111 1

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S 2 1

H NMR, 13C NMR and IR spectra of 2l S119 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 2m S122 1

H NMR spectrum of 2n S126 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4a S127 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4a’ S131 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4b S135 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4b’ S139 1

H NMR, 13C NMR, IR and MALDI-TOF-HRMS spectra of 4c S143 1

H NMR, 13C NMR, IR and MALDI-TOF-HRMS spectra of 4d S147 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4e S151 1

H NMR, 13C NMR, IR and MALDI-TOF-HRMS spectra of 4f S155 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4g S159 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 4h S163 1

H NMR, 13C NMR, IR and EI-MS spectra of 4i S167 1

H NMR, 13C NMR, IR and EI-MS spectra of 4j S171 1

H NMR, 13C NMR, IR and EI-MS spectra of 4k S175 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 5b S179 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 6 S183 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 7 S187 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 9a S191 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 9b S195 1

H NMR, 13C NMR, IR and ESI-HRMS spectra of 3a S199 1

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