Unusual trinuclear complex of copper(II) containing a 4′-(3-methyl-2-thienyl)-4,2′:6′,4″-terpyridine ligand. Structural, spectroscopic, electrochemical and magnetic properties

(1)

HAL Id: hal-01544454

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01544454

Submitted on 7 Jul 2017

HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.

L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

Unusual trinuclear complex of copper(II) containing a 4’-(3-methyl-2-thienyl)-4,2’:6’,4�-terpyridine ligand.

Structural, spectroscopic, electrochemical and magnetic properties

D. Toledo, G. Ahumada, C. Manzur, T. Roisnel, O. Peña, J.-R. Hamon, J.-Y.

Pivan, Y. Moreno

To cite this version:

D. Toledo, G. Ahumada, C. Manzur, T. Roisnel, O. Peña, et al.. Unusual trinuclear complex of copper(II) containing a 4’-(3-methyl-2-thienyl)-4,2’:6’,4�-terpyridine ligand. Structural, spectroscopic, electrochemical and magnetic properties. Journal of Molecular Structure, Elsevier, 2017, 1146, pp.213- 221. �10.1016/j.molstruc.2017.05.108�. �hal-01544454�

(2)

1

!"#$%&!&

'()*+,-./0)1,2334-567./8-5+(0*+*+9:;<=,>=(*(,(/?<:@ABCDB@:BB<(/)7E)*?*+/.*90+?@F0=>//+

=E+(F/=*G/?0+?=(),-(,)0..E-F0)0-(/)*G/?>EH<)0E-)E=(0..59)07FEIJF/*)=7/-()5=-57*-@

/./-()5-F/6*-0.0+?609+/(*->/F0K*5)F0=>//+/=(0>.*=F/?I

(3)

(4)

(5)

(6)

(7)

(8)

(9)

(10)

(11)

(12)

(13)

(14)

(15)

(16)

(17)

(18)

(19)

(20)

(21)

(22)

(23)

(24)