HAL Id: hal-01544469
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01544469
Submitted on 21 Jun 2017
HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.
L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.
Comparitive study on structural, magnetic and spectroscopic properties of four new copper(II) coordination polymers with 4’-substituted terpyridine
ligands
D. Toledo, A. Vega, N. Pizarro, R. Baggio, O. Peña, T. Roisnel, J.-Y. Pivan, Y. Moreno
To cite this version:
D. Toledo, A. Vega, N. Pizarro, R. Baggio, O. Peña, et al.. Comparitive study on struc- tural, magnetic and spectroscopic properties of four new copper(II) coordination polymers with 4’- substituted terpyridine ligands. Journal of Solid State Chemistry, Elsevier, 2017, 253, pp.78-88.
�10.1016/j.jssc.2017.05.017�. �hal-01544469�
ÿ 0ÿ
234567689ÿ8ÿ3ÿ872876ÿ46892ÿ6ÿ5287323592ÿ5735789ÿ
3ÿ 37ÿ ÿ 2355799ÿ 233796893ÿ 5347ÿ 98ÿ 8988ÿ
875799ÿ96ÿ
ÿ
!"!#$%ÿ&'%()0ÿ*"(+,-ÿ.%/0)1ÿ20"34ÿ5!60++)1ÿ7!30+(ÿ80//!)9ÿ:3;0<!ÿ5%=0)>ÿ&?!%++4ÿ7!-"%')>ÿ@%0"A B<%-ÿ5!<0")>)CÿB0"DÿE+%"F1ÿ
ÿ
0ÿG"!<%+-!(0(ÿ(%ÿH"3%I3!J")ÿK03$';0(ÿ(%ÿH!%"3!0-ÿL$M !30-)ÿ%I0+;0 %";ÿ(%ÿL$M !30ÿ*"0'M;!30ÿ%ÿ N"+/O"!30)ÿH"3%I3!J")ÿH?!'%Pÿ
1ÿG"!<%+-!(0(ÿ*"(+%-ÿ8%'')ÿI;PÿH!%"3!0-ÿL$M !30)ÿK03PÿH!%"3!0-ÿQR03;0-PÿHP5Pÿ1C1SSSS)ÿ.!=0ÿ(%'ÿE0+)ÿ H?!'%Pÿ
9ÿT%+%"3!0ÿ(%ÿN"<%-;!/03!J"ÿ4ÿ*I'!303!"%-)ÿH%";+ÿ*;J !3ÿH"-;!;$4%";%-)ÿH !-!J"ÿ203!"0'ÿ(%ÿQ"%+/M0ÿ
*;J !30)ÿ8$%"-ÿ*!+%-)ÿ*+/%";!"0ÿ
>ÿN"-;!;$;ÿ(%-ÿU3!%"3%-ÿH?! !#$%-ÿ(%ÿ7%""%-)ÿGE7ÿV11V)ÿG"!<%+-!;,ÿ(%ÿ7%""%-A0)ÿ7%""%-)ÿK+0"3%Pÿ
CÿW3'%ÿ20;!"0'%ÿU$I,+!%$+%ÿ(%ÿH?! !%ÿ(%ÿ7%""%-)ÿ7%""%-)ÿK+0"3%ÿ FÿH++%-I"(!"/ÿ0$;?+Xÿ40"DP +%"Y$"0ZP3'ÿ
ÿ
[\]^_`a^ÿ
&?%ÿ-4";?%-!-ÿ0"(ÿ3?0+03;%+!60;!"ÿcÿc$+ÿ3II%+dNNeÿ3 I'%R%-ÿf!;?ÿ(!cc%+%";ÿ;%+I4+!(4'ÿ'!/0"(-ÿ?0<%ÿZ%%"ÿ 30++!%(ÿ$;)ÿ;?%!+ÿ3+4-;0'ÿ0"(ÿ '%3$'0+ÿ-;+$3;$+%-ÿ(%;%+ !"%(ÿ0"(ÿ;?%!+ÿ 0/"%;!3ÿ0"(ÿ'$ !"%-3%";ÿI+I%+;!%-ÿ 0"0'46%(Pÿÿ&?%ÿ'!/0"(-ÿ$-%(ÿ!"ÿ;?%ÿ3+(!"0;!"ÿ+%03;!"-ÿf%+%ÿ>gAd9A %;?4'A1A;?!%"4'eA>)1gXVg)>ggA;%+I4+!(!"%ÿdhi jklme)ÿ A>gAd>A#$!"'!"4'eA>)1gXVg)>ggA;%+I4+!(!"%ÿ dhinklme)ÿ >gAd>A#$!"'!"4'eA9)1gXVg)9ggA;%+I4+!(!"%ÿ doinklmpÿ
$"+%I+;%(ÿ-ÿc0+eÿ0"(ÿ>gAd>A340"I?%"4'eA>)1gXVg)>ggA;%+I4+!(!"%ÿdhirsklmetÿ;?%ÿ+%03;!"ÿcÿ;?%-%ÿ'!/0"(-ÿf!;?ÿ H$dNNeA?%R0c'$+03%;4'03%;"%ÿduvwxyzrzr{|eÿ/!<%-ÿ+!-%ÿ;ÿ3+(!"0;!"ÿI'4 %+-ÿH$d>A-;I4ed?c0303e1ÿd}e)ÿ H$d>A#;I4ed?c0303e1ÿd}}e)ÿH$d9A#;I4ed?c0303e1ÿd}}}eÿ0"(ÿH$d>A3";I4ed?c0303e1ÿd}~ePÿ&?%ÿ(!cc%+%";ÿ'30;!"ÿcÿ;?%ÿ
"!;+/%"ÿ0; ÿcÿ;?%ÿ$;%+ÿ+!"/ÿ!-ÿ+%-I"-!Z'%ÿc+ÿ;?%ÿ(!cc%+%";ÿ3+(!"0;!"ÿ (%-Pÿ
&?%ÿ% !--!"ÿ-I%3;+0ÿcÿ(!3?'+ %;?0"%ÿ-'$;!"-ÿ0+%ÿ3"-!-;%";ÿf!;?ÿ(!--3!0;!"ÿcÿ;?%ÿ3 I'%R%-tÿ;?%ÿ
% !--!"ÿ 0R! 0ÿ-! $'0;%ÿ;?-%ÿcÿ;?%ÿc+%%ÿ'!/0"(-Pÿ&?%ÿ% !--!"ÿcÿ})ÿ}}}ÿ0"(ÿ}~ÿ!"ÿ;?%ÿ-'!(ÿ-;0;%ÿ!-ÿ%--%";!0''4ÿ
#$%"3?%(ÿ$I"ÿ3 I'%R0;!"ÿf!;?ÿH$dNNe)ÿf?%+%0-ÿc+ÿ3 I$"(ÿ}}ÿ0"ÿ% !--!"ÿ0;ÿ>1Sÿ" ÿ!-ÿZ-%+<%(Pÿÿ
&?%ÿ!";%+03;!"ÿZ%;f%%"ÿ3II%+ÿ3%";%+-ÿ?0-ÿZ%%"ÿ+%'0;%(ÿf!;?ÿ;?%ÿ3I'0"0+!;4ÿcÿ;%+I4+!(!"%ÿ+!"/-PÿH I'%R%-ÿ}
}}}ÿ%R?!Z!;ÿ0ÿI0+0 0/"%;!3ÿZ%?0<!$+)ÿf?!'%ÿ3 I$"(ÿ}~)ÿf!;?ÿ;?%ÿ- 0''%-;ÿ;+-!"ÿ0"/'%ÿZ%;f%%"ÿI4+!(!"%ÿ !%;!%-)ÿ-?f-ÿ0"ÿ0";!c%++ 0/"%;!3ÿZ%?0<!$+ÿ(%-3+!Z%(ÿZ4ÿ0ÿ(! %+!3ÿ (%')ÿf!;?ÿÿA>P9ÿ3 A0)ÿÿ ÿ1PSVÿ0"(ÿ
ÿ ÿSPSPÿ