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Electric microfield distribution in multicomponent plasmas
B. Held
To cite this version:
B. Held. Electric microfield distribution in multicomponent plasmas. Journal de Physique, 1984, 45
(11), pp.1731-1750. �10.1051/jphys:0198400450110173100�. �jpa-00209915�
Electric microfield distribution in multicomponent plasmas
B. Held
Laboratoire d’Electricité, Avenue Louis Sallenave, Université de Pau, 64000 Pau, France
(Reçu le 14 mai 1984, accepté le 5 juillet 1984)
Résumé.
2014Un formalisme général est présenté pour les parties Haute Fréquence et Basse Fréquence du micro- champ dans
unplasma à trois composantes (une composante électronique
2014température Te, deux composantes ioniques
2014température Ti). Ce formalisme est présenté sous
uneforme générale permettant des applications
allant des plasmas faiblement corrélés
auxplasmas fortement corrélés, les effets physiques étant introduits explici-
tement par la fonction de corrélation de paire. Les résultats sont présentés pour les deux parties du microchamp et
une attention particulière
aété portée
surles effets rencontrés dans les plasmas de fusion inertielle produits par laser
(corrélation, proportion, température, charge). Ces effets montrent une très grande sensibilité du microchamp
Basse Fréquence vis-à-vis du paramètre plasma A.
Abstract.
2014A general formalism is presented for the High Frequency and the Low Frequency parts of the electric microfield in three component plasmas (one electronic
2014temperature Te, two ionic
2014temperature Ti). This
formalism is presented in
ageneral form allowing extensive applications from weakly to strongly correlated plas-
mas, the physical effects being introduced explicitly by
meansof
atwo-body correlation function. Results
arepre- sented for the two parts of the electric microfield and particular attention has been paid to effects encountered in
plasmas of inertial-confined-fusion produced by laser (correlation, proportion, temperature, charge). These
effects show that the Low Frequency part of the electric microfield is very sensitive to the plasma parameter A.
Classification
Physics Abstracts
52.70
1. Introduction.
In dense and hot plasmas of inertial-confinement- fusion produced by laser, the Stark broadening dia- gnostics of stripped ions immersed in ionic perturbers
appears to be the best method for determining the density-temperature conditions [1-8].
Because, for the Stark broadening calculations
[9-13], it is necessary to know the electric microfield,
the purpose of this paper is to present a general for-
malism for multicomponent plasmas.
The problem of electric microfield distributions was
first solved a long time ago by Holtsmark [14-16] in
the low-density, high-temperature limit (non corre-
lated system). Since then many works have been devoted to these calculations [17-77] and a general
formalism was presented by Baranger and Mozer [27-
28] using the approximation of a weakly correlated
one component plasma, but Hooper et al. [30-32]
were the first to propose an accurate numerical code for multicomponent plasmas.
Further to these theoretical approaches, numerical
methods were developped to predict the microfield
distributions. The Monte Carlo calculations [78]
now give accurate results for two component plas-
mas [79-80] and numerical simulations for the ionic component of the plasma allow the inclusion of the effect of ion dynamics on stark profiles [81-90].
A generalization of the Baranger-Mozer formalism
is presented in this paper for multicomponent plasmas including strong correlation effects by a resummation up to infinity of the most important chain diagrams [92-93].
A comparison between the results presented here
Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphys:0198400450110173100
and other works [80, 91] gives accurate values for a
plasma parameter A less than unity. This theory can
be extended to higher values of A by including into
the model new conditions on the resummation and
on the two body correlation function [91].
The electric field is separated into two parts : the
High Frequency part (H.F.) being relative to electrons
and the Low Frequency part (L.F.) to ions.
For the H.F. part, the model is an electronic gaz with uniform neutralising background, while the L.F.
part corresponds to the time average of the electric
field, the average being taken over times long compared
to electronic relaxation times but short compared to
ionic times. Keeping in mind the Stark broadening application, the electric microfield distribution must be calculated on an emitter; this emitter can be an atom or an ion and we must establish a distinction between the Neutral Point case (N.P.) and the Charged
Point case (C.P.).
Finally, the two time-independent parts of the scalar microfields (H.F. and L.F.) will be calculated
in the two cases (N.P. and C.P.) using the assumption
that the medium is isotropic.
The model developed in this paper is devoted to three component plasmas (one electric and two ionic),
with the assumption of local thermodynamic equili-
brium for electrons (Te) and ions (T;), and the des-
cription of the plasma is given by five parameters : the correlation parameter v (measuring the relative
importance of the energy of interaction compared to
the thermic energy), the proportion coefficient p
(between ions a and b), the temperature rate RT (between electrons and ions) and the number of
charges Za, Zb of the ionic perturbers.
In section 2, the general formalism is developed for (ç) particles, (ç) being electrons or ions.
Section 3 is devoted to applications of the formalism to the H.F. and the L.F. parts of the microfield. Defi- nitions are given for the five parameters and physical
effects are introduced into the theory by means of the two-body correlation function.
In section 4 are presented the results for the H.F.
and the L.F. part of the microfield, in the N.P. and C.P. cases.
Section 5 gives the general conclusions and supple-
ments to the main text are presented in an extensive Appendix.
2. Formalism.
We consider a plasma with two species of particles’
and ç. We call N the total number of particles with
coordinates r,, r2,
...,rN :
where N, and N4 are respectively the number of particles of types and ç.
For a certain spatial repartition of particles, the
total microfield at an arbitrary point 0 is given by :
where EJ(E4) is the microfield produced by the parti-
cle ((j) located at a point Mj(rj) (Mk(rk))’
We wish to calculate the probability distribution
w(E), but it is more convenient to consider the Fourier transform :
If {f(rl’ r2,
...,rN) is the probability of occurrence
of a given configuration of the N particles, we can
write :
It is then possible to replace the exponential by the development :
where qJ) and (p4 k are defined by :
By an integration over all the possible positions, F(k) becomes :
E4 (.E4) being the sum on all particles (ç), (r) the sum on all pairs, etc...
If we take M particles among the N and assume that correlations introduce small corrections, it is possible
to express the probability function 5’(rj, r2l .... rN) by a series containing increasing orders of correlations :
where V is the total volume and gc, g2,
...correlations of first and second order.
The Fourier transform of probability can then be written
It is then simpler to define G(k) functions :
I(I;) being the sum on all possible combinations of p particles, Ip(I;p) on all possible distinct combina- tion of two clusters containing p particles, etc...
If we call n,(n,) the density of particles (ç) and assume that n, and nÇ remain constant when N,, N ç and V
become very large, we can write :
When N, and N4 approach infinity, the Gp(k) functions have a fairly simple expression :
with :
We obtain the probability distribution W(E) by inverting the Fourier transform :
with :
3. General results.
3.1 PARAMETERS. 2013 We assume that the plasma is composed of two ionic components (a, b) and an
electronic one. The description of such a plasma is possible with five parameters (v, p, RT, Za, Zb) :
-
Correlation :
where ro is approximately the mean inter electronic
length and AD. the Debye length for the electrons (appendix A).
-
Proportion :
where Ca(Cb) is the concentration of ions.
-
Temperature rate :
where Te(T;) is the electronic (ionic) temperature.
-
Number of charges on ions a and b :
Starting with these five parameters, the plasma parameter can easily be written (appendix A) :
with :
where AD is the Debye length for the plasma.
3.2 CORRELATION FUNCTION.
-If we call V,,(r) the
interactive potential between particles C and j at a
distance r, the two body correlation function is defined by :
with :
To connect the g,,(r) correlation function with
g 1 (r), g 1 (r) and g’4(r) probability functions, we assume
that there is an C particle, with Z, charges, at the
centre of the system.
The one-body probability functions gc(r) and gi(r) can easily be written starting from the g,,(r)
correlation functions :
- gí (r) represents the correlation between an , particle (coordinate r) and the C particle located at the
centre (coordinate 0) :
-
g4(r) is the correlation between the centre and
a ç particle (coordinate r) :
The two-body correction gj4(r) can be written :
and gÇ(r) is obtained explicitly by a linearization of the g,,(r) function. This approximation is corrected by a resummation over all the orders [92-93] and g%4(r) becomes :
with :
and the reduced length :
The general expressions for the electronic (H.F.)
and the ionic (L.F.) parts are easily deduced :
3. 3 GENERAL EXPRESSIONS.
-Before deducing gene- ral expression for the microfield from the formalism, it is very useful to introduce :
-
the reduced microfield :
with :
-
a new variable for the expression of F(k) :
with :
-
a new variable for functions cp) and (p4 :
with these notations, the general expressions for the
microfield produced at the origine by an electron or
an ion located at Xj (Xk) are given by :
for an electron
If we call H(fl) the probability distribution of the scalar microfield. we can write :
with :
for the first and second orders of correlation.
The functions h2(u) are calculated expanding every factor in the integrant in spherical harmonics (appen-
dix B); h 1 (u) and h2 (u) can then be written :
where the h(Xl’ x2) functions are deduced from the development into spherical harmonics of 0,,(x) (appen-
dix B).
The F(u) function becomes :
with :
and :
3.4 ONE AND TWO-COMPONENT SYSTEMS.
-The one component system is deduced from the general expres-
sions with the condition : p
=0 and it is easy to show that (appendix A) :
The function F(u) is then given by :
For the electronic part (H.F.), , is an electron e with the conditions :
and for the ionic part (L.F.), , is an ion a with :
For two ionic-components systems, we have to introduce the proportion p and functions F(u), t/J l’ ql2, become
__ ,
which verify the one-ionic component limit (p
=0).
3 . S PARTICULAR CASES.
-The microfield distribu- tion can be calculated at a charged point (C.P.) or at a
neutral point (N.P.). In the first case, there is a charged particle with Z, charges at the centre of the system
and in the second case, there are no charged particles
at the centre.
We now consider the N.P. case, deduced from the C.P. situation (section 3. 2) writing :
and we find :
The general results of section 3.4 are also valid in N.P. conditions with :
another particular case is also caused by high tempe-
rature-low density conditions; the system is then equivalent to independent particules without correla- tion :
The general results are then reduced to :
and
The general expressions of section 3. 3 become :
For the electronic part (H.F.) we find (p
=0, nÇ
=0)
the Holtsmark distribution :
with (appendix C) : ie
=1 and for the two ionic part (L.F.) :
with (appendix C) :
The Holtsmark distribution is also the limit of an
ionic microfield with the following conditions :
or
When there is no correlation between particules (v =o),
the functions g/§’ and g/§4 are the same at a neutral or at
a charged point and the results are independent of
the temperature rate RT.
3 . C) ASYMPTOTIC BEHAVIOUR. - We consider first a
correlated system (v # 0) and we establish a distinc-
tion between a neutral point (N.P.) case and a charged point (C.P.) case to take the asymptotic limit.
Let us assume that we are in the N.P. case. With an
appropriate change of variable, we can write (appen-
dix C) :
and
with
FE(a) being the development of F(u) in the vicinity of
a
=0. As it is shown in appendix C, the functions 4/1 and t/J 2 are given by developments of a and if we call
t/J(a) the sum on all these developments :
F£(a) can be written :
For a one component system
with
and for a two-ionic component system :
In each case, the constants A, B, C have to be calcu- lated from functions t/11 and ql2’
After a development of the powers of t/1(a), we find :
If we now consider a charged particle (Z,) at the centre of the system, it is then possible to make the nearest neighbour approximation to obtain the asymptotic development of H(fl). If we assume that the probability of finding microfield fl at the origin is equal to the probability of finding a charged particle at a distance r (appen-
dix C), we can write :
and with the notation :
we find :
with :
The total microfield becomes :
and, as a first approximation, it is possible to replace the exponential integral term by unity if P is sufficiently large.
For a one component system (p
=0, n4
=0) we find :
-
for electrons :
-
for ions :
in the limit of large values of fl.
For a two-ionic component system :
Finally, we should consider a non correlated system (v
=0). In this case (see section 3. ), F(u) is reduced to the first terms oa,, oab . The asymptotic distribution
H(fl) is obtained as a limit case of N.P. calculations, writing :
and
without distinction between N.P. or C.P. cases.
It is obvious that we will find the asymptotic
Holtsmark distribution for electrons (K
=1) and also
for ions if :
or
4. Applications.
Because of the Stark broadening diagnostics of highly stripped heavy ions immersed in dense and hot
plasmas of inertial confinement
-fusion produced by laser, the results presented below are devoted to the
L.F. part of the microfield in the C.P. case (Figs. 1 to 8).
Fig. 1.
-Correlation effects (v) at
acharged point (L.F.)
for
aone component plasma.
Fig. 2.
-Correlation effects (v) at
acharged point (L.F.)
for
atwo component plasma.
Correlation effects are presented in figures 1 and 2 ; when v increases (i.e. for increasing values of the
electronic density ne or decreasing values of the elec- tronic temperature T e), the microfield H(fl) is shifted
towards smaller values of the reduced microfield f
with a pinch effect on the distribution and an enhan- cement of the maximum. The weaker field, produced by charged particules far from the centre, are intro- duced with increasing values of the correlation v, this effect‘ being accentued by the presence of a charged particle at the centre.
This effect is also observed on H.F. part of the microfield in the N.P. case and in the C.P. case [51-52].
In figures 1 and 2 (p
=1, RT
=1, Zb
=1) it is also possible to observe the correlation effects for various values of the central charge Za. When Za increases, a repulsive effect on the perturbers Zb appears and the
microfield is slightly shifted towards weaker fields with a pinch effect on the distribution. When the central charge and the perturbers are the same (p
=0, RT
=1 ), the distance between the perturbers and the
centre increases with Z. (repulsive effect), but the field
being proportional to Za, the maximum of the dis- tribution shifts towards stronger fields and the peak
value of H(f3) decreases.
Composition effects are illustrated by figures 3 and 4
when the charge on the perturbers (Zb = 1 ) are less
than the charge on the central ion (Za). In figure 3 (v
=0,.Zb
=1) a shift towards the weaker fields with
a pinch effect is observed when p increases (progressive
introductions of singley charged ions into the plasma).
In the case of correlated plasma (Fig. 4), the shift towards the weaker fields with increasing values of p
is accentuated by the correlation effect. The correlation
being more important for small values of p, the resul-
tant shift is maximum for p equals zero and minimum for p equal unity : the global composition effect
decreases when correlations increase (Figs. 3, 4).
Fig. 3.
-Proportion effects (p) at
acharged point (L.F.)
for a non correlated plasma.
Fig. 4.
-Proportion effects (p) at
acharged point (L.F.) for
acorrelated plasma.
Temperature effects are presented in figures 5 and 6.
The maximum of the distribution H(P) increases with
RT, this effect growing with Za : the cloud of electrons surrounding each ion is perturbed by a change in RT leading to a modification in the shield effect.
In figures 7 and 8, the effects of the central charge (Za) are shown. In the case of a one component plasma,
when Za increases, there is a competition between
the Coulomb repulsion and the enhancement of Za :
the maximum of H(fl) decreases and the distribution is shifted towards stronger fields. The « correlation shift » towards weaker fields increasing with Z., the global Za charge effect decreases when v increases.
Fig. 5.
-Temperature rate effects (RT) at
acharged point (L.F.) for
aone component plasma.
Fig. 6.
-Temperature rate effects (RT) at
acharged point (L.F.) for
atwo component plasma.
Fig. 7.
-Charge effects (Za) at
acharged point (L.F.) for
a
non correlated plasma.
5. Conclusion.
In this paper, the H.F. part and the L.F. part of the microfield have been introduced as particular cases of
a general formalism valid for a three-component plasma. Physical effects are easily introduced into the
theory by means of the two-body correlation function, allowing extensive studies (such as diffraction and symmetry effects encountered in highly dense and hot plasmas [53-54]).
With the introduction of five parameters (v, p, RT, Za, Zb), it is possible to observe the different effects
on the L.F. part of the microfield in view of application
Fig. 8.
-Charge effects (Za) at
acharged point (L.F.) for
a
correlated plasma.
to the Stark broadening. In practice, the results have been presented for values of the coefficient of correla- tion v encountered in plasmas of current interest in
inertial-confinement-fusion studies (i.e. for high den- sity, high temperature).
A general survey of the curves (Figs. 1 to 8) permits
one to notice the importance of the plasma parameter A for the interpretation of the results; however, particular attention must be paid to density-tempe-
rature effects because a dense plasma is not necessarily
a correlated plasma, the correlation being dependent
on the temperature (A3); in consequence, the Holtsmark limit can be reached in high temperature conditions for the H.F. part or the L.F. part of the microfield.
With the results presented in this paper, it is possible
to deduce a general law for the normalized distribution of the microfield : a shift of H(fl) towards the weaker
fields is always accompanied by a pinch of the distri- bution (and an enhancement of the maximum to
respect the normalisation conditions), this law being
valid for all physical effects.
In summary, this shift appears when the correlation
or the proportion (for Zb Za) increase and when the
charge Za decreases (for a one-ionic component
plasma); the proportion (p) and charge effects (Za)
are reduced by the correlation effects. The temperature effect is responsible for a modification in the electronic shield surrounding each ion and a small shift is also observed when RT increases (this tendency increasing
with the central charge Za).
Finally, keeping in mind the applications of the
Stark broadening, it is important to note that the proportion, temperature or charge effects can some-
times be interpreted as correlation (density-tempe- rature) effects : this is a difficulty for the diagnostic if the plasma caracteristics are insufficiently known.
Appendix A.
-Parameters.
We consider a three component plasma : one electronic
e and two ionic a and b. The description of this plasma
is possible with five parameters : v (correlation), p
(proportion of ions b), RT (temperature rate), Za - Zb (number of charges on ions a and b).
These parameters are fully defined using electronic density ne, electronic and ionic temperatures T,, Ti.
We have first to introduce the mean inter electronic
length defined by :
and the Debye length for the electrons :
kB being the Boltzmann constant.
The coefficient of correlation v is then given by :
and the proportion p by :
where Ca and Cb, the concentrations of ions a and b,
are related to Ce, the concentration of electrons by :
and neutrality :
Introducing the density of particles :
with
it is easy to obtain the rates :
Finally it is useful to introduce RT, the temperature
rate (when electron and ions are at two equilibrium temperatures Te and Ti) :
with these definitions, it is easy to explicit the Debye length and and the plasma parameter A.
The Debye length for a plasma with two tempe-
ratures is given by [94] :
with
From the preceding definitions, the Debye length
for the ions can be written :
and the Debye length for the plasma becomes :
with
It now becomes interesting to express the plasma
parameters from these definitions.
The electronic plasma parameter Ae defined by :
becomes
and the plasma parameter A :
becomes :
Appendix B.
-Correlation function and spherical harmonics developments.
The two-body correction function d24(r) can be written from the two-body correlation function g,ç(r) :
It has been shown [92-93], that it is possible to make a resummation on all the orders of development
for a two-body correlation function :
writing
we find
with
The h2(u) function can then be expressed explicitly with a spherical harmonics development. Field functions
c 4 and correlation functions 0,,(x) can be expanded :
By integration, the functions fC4(X 11 X2) can be found [52] :
with
Appendix C. - Asymptotic behaviour of H (fl).
Cl GENERAL EXPRESSIONS FOR THE FIELDS.
-Before
establishing asymptotic behaviour of H(fl) at a neutral
or at a charged point, we have to express the variables
U j and U4 of the fields.
By definitions, we can write :
For the H.F. part, Eje is the field of one electron at a distance rj :
For the L.F. part, Ej(E:) is the field-screaned by the
electrons
-of an ion a(b) at a distance rj(rk) :
and we find :
with the definitions :
The distribution of H(P) will be expressed from P,
the reduced microfield, defined by :
where Eo is the field of an electron at a distance ro :
ro being approximately the mean inter electronic
length (section 3 .1 ).
Eo can be also expressed explicitly by :
C2 ASYMPTOTIC FORM AT A NEUTRAL POINT (V # 0).
-
We will now examine the neutral point case and it is important to calculate the 04 and 2 functions. The first order functions can easily be found using general
results for the spherical Bessel functions j, [95-96].
Integrating t/Je by parts :
we find, for the H.F. part :
The calculation is a little more complicated for the L.F. part :
In practice, these functions are calculated for small values of the variable a.
After the change of variable :
and the development ofjo(Uf) :
we can write :
with
Integrating by parts, we find, for small values of a :
which verify the non correlated limit (v
=0), given here by :
For the second order functions, it is possible to show [52] that g/gE is proportional to the variable a in the
vicinity of zero. Under these conditions, it is possible to write :
with
and
A, B, C being calculated for each particular case from the corresponding curves.
We have now to perform the calculation of the asymptotic behaviour of H(fl) in the neutral point case when
the system is correlated (v # 0).
After an appropriate change of variable, we can write:
with
in the asymptotic fl limit, and
FE(a) being the approximation of F(u) in the limit of small values of a :
After a development of [I - 41(a)]", we find :
with
and
After integration, HN(fl) becomes [52] :
C3 ASYMPTOTIC FORM AT A CHARGED POINT (V # 0).
-
We now consider a charged particle (Z,) at the
centre of the system and we make the nearest neigh-
bour approximation.
If P(r) is the probability of finding a particle between
0 and r and P’(r) the contrary probability, we can
write :
For r + dr, wL- have :
and noting that the probability P(r) is necessarily
proportional to the length r, this result can be expres-
sed :
where p is the density probability of finding a particle between r and r + dr.
In consequence, P(r) becomes :
If we assume that the probability of finding a micro- field P at the origine 0 is equal to the probability of finding a charged particle at a distance r from 0, we can write :
We must now express the probability p dr.
The definition of the correlation function for two bodies permits one to write :
With one ( particle located at the origine and assuming the hypothesis of isotropy :
this integral shows that 4 Hr’ 9,,(r) dr is the proba- bility of finding a j particle between r and r + dr.
For a system containing N, particles, we find : 1
with
The distribution H(fl) then becomes :
It now useful to introduce a new variable p defined
by :
Using the definition of ro (appendix A), we find :
and
The total distribution is then given by :
The reduced microfield f3 can be expressed starting
from definitions of Ej, Ej and Eo.
For the H.F. part :
and for the L.F. part :
For large values of P, p is approximately zero and the exponential integral term can be replaced by unity.
Therefore, it is possible to write for the ions :
The asymptotic behaviour of the one component
electronic system (H.F.) is then given by :
and for a two component ionic system (L.F.) :
If rigorous treatment is required, it is necessary to compute the exponential integral term.
C4 ASYMPTOTIC FORM FOR A NON CORRELATED PLASMA
(v
=0).
-Since we have no correlation (v
=0), we
return to the neutral point condition (no correlation between the centre of the system and the charged particles) with :
- rB.