Chiral ferrocenyl diphosphines for asymmetric transfer hydrogenation of acetophenone

Herein, we wish to describe the synthesis, the full analytical and spectroscopic characterization, and the electrochemical behaviour of the three chiral

Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and selectivities in the transfer hydrogenation of

Biphasic glycerol/2-MeTHF ruthenium-catalyzed enantioselective transfer hydrogenation of ketones using sodium hypophosphite as hydrogen donorKeywords: Reduction /

In summary, the mechanism of hydrogenation of enamides by rhodium catalysts with monodentate phosphorous ligands has been computationally investigated by means of

pH-dependent profile of conversion (䊐) and enantiomeric excess (ρ) for transfer hydrogenation of acetophenone (1 mmol) using complex 7 as the catalyst and HCOONa as a hydrogen donor

20 In order to evaluate the efficiency of ferrocene-based P-S ligands 1-12 in the hydrogenation of olefins with different steric demands, we initially tested them in the

the present paper we report the synthesis and the coordination chemistry of a new P,N chiral ferrocenyl ligand, bearing a TosNR fragment (R = H, Me), with ruthenium,

Design of Modified Amine Transfer Reagents Allows the Synthesis of #-Chiral Secondary Amines via CuH-Catalyzed Hydroamination.. The MIT Faculty has made this article