• Aucun résultat trouvé

The aqueous extraction of sunflower oil from whole plant in twin-screw extruder, a first step for the manufacturing of biodegradable agromaterials by thermo-pressing

N/A
N/A
Protected

Academic year: 2021

Partager "The aqueous extraction of sunflower oil from whole plant in twin-screw extruder, a first step for the manufacturing of biodegradable agromaterials by thermo-pressing"

Copied!
29
0
0

Texte intégral

(1)

Any correspondence concerning this service should be sent to the repository administrator:

[email protected]

This is an author-deposited version published in: http://oatao.univ-toulouse.fr/

Eprints ID: 11953

To cite this version:

Evon, Philippe and Vandenbossche, Virginie and Pontalier, Pierre-Yves and Rigal, Luc The aqueous extraction of sunflower oil from whole plant in

twin-screw extruder, a first step for the manufacturing of biodegradable agromaterials by thermo-pressing. (2011) In: World Conference on Oilseed

Processing, Fats & Oils Processing, Biofuels & Applications, 21 June 2011 - 23 June 2011 (Izmir, Turkey). (Unpublished)

O

pen

A

rchive

T

oulouse

A

rchive

O

uverte (

OATAO

)

OATAO is an open access repository that collects the work of Toulouse researchers and makes it freely available over the web where possible.

(2)

- Topic: “By-products and utilization”.

The aqueous extraction of sunflower oil from whole plant

in twin-screw extruder, a first step for the manufacturing

of biodegradable agromaterials by thermo-pressing

Ph. Evon*, 1, 2, V. Vandenbossche1, 2, P.Y. Pontalier1, 2, L. Rigal1, 2

1

Université de Toulouse; INP; LCA (Laboratoire de Chimie Agro-industrielle); ENSIACET, 4 Allée Emile Monso, 31030 Toulouse Cedex 4, France

2

INRA; LCA (Laboratoire de Chimie Agro-industrielle); 31030 Toulouse Cedex 4, France

Keywords: Sunflower whole plant, twin-screw extruder, aqueous extraction process, oil and

extraction, proteins and extraction, thermo-pressing, biodegradable agromaterials.

Twin-screw extrusion is an original solution for the biorefinery of sunflower whole plant according to an aqueous extraction process. In best operating conditions, oil yield is 57% and residual oil content in the cake meal is 14%. Oil is extracted in the form of two oil-in-water emulsions stabilized by phospholipids and proteins at interface.

The cake meal would be suitable for use in animal feeds and for energy production in pellets burning furnaces. As a mixture of fibers and proteins, it is also considered as a natural composite. It can be processed into biodegradable agromaterials by thermo-pressing.

During molding, part of residual oil is expressed (until 41% of oil from whole plant), leading to the increase of the total oil extraction yield (aqueous extraction in twin-screw extruder and expression during thermo-pressing): until 81% of oil from whole plant.

Panels have promising mechanical properties in bending (until 12MPa for stress at break). They are usable as inter-layer sheets for pallets, for their sound and heat insulation properties or for the manufacturing of containers by assembly of panels. Their hydrophobic character (8% for residual oil content in the panels) makes them resistant to water.

__________

* Corresponding author. Tel.: + 33 (0)5 62 44 60 80; fax: + 33 (0)5 62 44 60 82. E-mail address: [email protected] (Ph. Evon).

(3)

!

" #

$

%

" & '&'

( #" )

*

+

,

(4)

!"

"

!"

"

+- -

*

*

.

/

* 0

-+-+-

.

/

* 0

-&- -

/

*

/ 1

(

*

// *

*2

*

*

.

.

/

"

2

-&-+-

/

*

/

*

*

*

.

.

(5)

-#$

% & '#(

) %

)

* '

!"

#

$

$ %

&$

'

#

(

)

*

+

$

, '

+

+

-

, '

&

+

+

-

+

*

% &

% #

$

.

/

0

( )

/

0

+

1 ( )

/

0

%

+

(2)

( ) ( ) (2) ( ) ' #" + ," " - ." !" 3' + $ # 32 % * * 2 !/ 012 4 & 4 , 556-( ) 3 + " 4 4" + +"5" ' " !" # $ $ $ % . 3 & $ # $ $ 45 6 ! % 7 (. !7 8 9 : ' 9 , 44;-( ) 3 + " 4 4" + +"5" ' " < # $ $ $ % ' % & % # & " # + . $ ' ' $ $ + . * 61 072 2 & 25 , 44;-( ) 3 + " 4 4" + +"5" ' " !" # $ $ $ % + 1 % & % # . $ ' ' . * 6/ 06 72 22& 62 , 445-(2) 3 + " 4 4" + +"5" ' " = % & % # ' + % $ $ $ ' $ $ % % + 6 (" . 7 . !8 012 4 & ; , 4

(6)

4-' %

%

)

9

9 ':

: (9#

(#

)'#(

#

) %

)

* ' *9

+ #

;!<

#+

%

%

#

>

2 ,?

-&+

&

% &

% #

,@4A $

+

-, 2

&

- ,

=

: :

?

-.

& @

B $

&

6 @B

'

$

&

4 ;B

'

$ +

&

4 5B

'

$ $

,

-&&- 8

2

/

*

"

-& ; 4B

'

$ +

& #

$

+

+

$$

%

%

$

%

+

(7)

' %

%

)

9

9 ':

: (9#

(#

)'#(

#

) %

)

* ' *9

+ #

;6<

( = > > ! / 9 9 . : ) ( * , //

!$

$

+

+.

! 6 7 ;-5 0 < +'-; 0 < ;-; 0 < '-5 0 < !!= &# . !% = 4>-; :- <0 !!" * 9 . !% " . * / * * * 2-? 2 . * . ?2 . * . 9 2 . * . < '

C

#

$

$

$ $ &

$ %

1 ,

@4B-!

#

,$

-

$$

,

1

-

+

'

(8)

#++

(#

%

)

9

$

, +9#% %

) '

, % ' #

+' , ( %

=

+

+ %

$

$

$

&

$

$ %

%

+

.

!

!

=

#

$

,

& &%

'

+ &

+

-

'

++

$

+

.

( 9 9 3 ?

(9)

, %(' +

)

9 (#. : #

"

"

*

+

1

B

'

=

1

$

, 42A

-1

,D 2B $

$

'

-*

#

$

$

0

2

1

* %

$

.

/

$

/

' +

+

$

(10)

9 (#. : #

#

#

'#

( :+ %

!

#

$ $

+

1

+

>

$

&

&+

+

+

$

$

$

(2 6)

#

#

(6) (2) 3 + " 4 4" + +"5" ' " = % & % # ' + % $ $ $ ' $ $ % % + 6 (" . 7 . !8 012 4 & ; , 4 4-(6) 3 + " 4 4" + +"5" ' " = & $ $$ $ " #& $ $ % % + % & % # . $ $ ' + * % , * !!6 6 &; , 4 4-(2)

(11)

9 ':

: (9#

(#

'# %) ':#

)

9 (#. : #

, '

@ :

,

@

=

$$

$ +

+

$ +

=

3

$

%

$

E

=

$

1

$

$

(12)

%

%

*

6" :

"

6" :

"

&

'

'!

(

'

&

'

'!

(

'

+-+-

.

/

* 0

-&- -

/

*

/ 1

(

*

// *

*2

*

*

.

.

/

"

2

-&-+-

/

*

/

*

*

*

.

.

(13)

-(9 : (# ( :+ %

)

9 (#. : #

?

$$

1

%

+

$$

$ "

#

$$

'

% &

% #

#

'

% &

%

#

,B-1

,

- ,B

'

-*

+

'

64B ,2;B

$

$

$

-

1

B

'

0 10 20 30 40 50 60 70 80 13 14 15 16 17 18 19 20 21 22 LC1 (% dry matter) R L 1 ( % )

4 4

4

±

4

24 4

6 ; ± 4

2

4

6

±

4 4

64

±

4

'

!

0A2

(!

0A ,:2

6 @&@ ;B <

$ +

4& 6B <

$ $

&

,

-@%" 2

(14)

-*

6" :

"

6" :

"

+- -

*

*

.

/

* 0

-'

'

)

)

!

!

(

(

'

'

&- -

/

*

/ 1

(

*

// *

*2

*

*

.

.

/

"

2

-&-+-

/

*

/

*

*

*

.

.

(15)

-9 ':

+' %%

@

)

9 (#. : #

F

'

+

$

&

+

.

/

.

! ! 24 ,

* ?

-/

?

. 244 1G ,24

-/

#

+

.

5;

=

&+

.

/

$

1

.

2

/

=

+

$

% +

.

44A

/

++

.

4 1 $H

+

.

24

I

24

:#+# BC

'

+

,

' " +

-$ +

,64B

F

2A -

% &

1

$

(16)

*

+- -

*

*

.

/

* 0

-+-+-

.

/

* 0

-7" '

"

7" '

"

*

+

,

'

*

+

,

'

)

)

!

!

'

-!

!

'

-&-+-

/

*

/

*

*

*

.

.

(17)

-)

(

) #$

% & '#(

)) ( (5

:

(9#

(# +' + '

%

? ,

@

)

9 #@' :# ' #

!

+

+

+

&

,

G?

G

4-.

$

1

0 5 10 15 20 25 13 14 15 16 17 18 19 20 21 22 LC1 (% dry matter) F le x u ra l s tr e n g th a t b re a k ( M P a ) 0,0 0,5 1,0 1,5 2,0 2,5 E la s ti c m o d u lu s ( G P a )

Flexural strength at break Elastic modulus

; 5 ±

6

; ; ±

4 ±

; 2 ±

) 0 2

±

4

5 ± 4

6 ± 4

2 ± 4 4

0@+ 2

±

4

5

±

4 ;

@ 2 ± 4 @

5

±

4 ;

σ

σ

σ

σ

0:+ 2

4

±

4

6 ; ± 4

6

±

4 4

±

4

(!

0A

2

)" 0 &' / . * 9 7 '' / . . σ/" / ( 0 /" *

->

1 ,

-%

1

+

&

$ +

, 4B <

$

#+

-*

&

,

J

$

-6"! ±

±

±

±

C"!

!6"6 ±

±

±

±

C"6

D8"/ ±

±

±

±

6"1

6C"D ±

±

±

±

C"!

(18)

) ':

#% ) '

5 ,% (# (

#

#+

'

,

+

+

1

-

,B-K

#+

'

,

+

+

$ %

%

+

-

,B-=

'

,

#

% &

%

#

#+

-

,B-!CC

'

!CC

'

E

'

6 6 !

×

×

×

×

=

=

=

=

=

=

=

=

+

+

+

+

=

=

=

=

+

+

+

+

×

×

×

×

!CC

'

!CC

'

'

E

'

'

'

! 6 ! 6 ! 6 6 !

'

!CC

'

!CC

'

'

=

=

=

=

×

×

×

×

+

+

+

+

(19)

)

(

) #$

% & '#(

)) ( (5

#

5 , ;!<

<

6;B

$

$

1

#+

,

4B $

$

%

+

-%

,@B

'

&

-

%

1

"

"

LC2, residual oil content inside the

agromaterial

RL2, oil expression

yield during molding (in proportion to the oil that the cake

meal contains) 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 LC1 (% dry matter) LC 2 ( % d ry m a tt e r) 0 10 20 30 40 50 60 70 80 RL 2 ( % )

@

±

4 4

@ @ ± 4 4

@ 5 ± 4 4

4 5 ± 4 4

(6

0A

2

6;

22 2

2

5 5

'

6

0A2

4

±

4

6 ; ± 4

6

±

4 4

±

4

(!

0A

2

18"7

F"! ±

±

±

±

C"C

6C"D ±

±

±

±

C"!

(20)

)

(

) #$

% & '#(

)) ( (5

#

5 , ;6<

#

#

7

#+

$

'

,

=

-.

"

#

% &

%

#

,

-

#+

&+

,

K-L

@4B

$

$

%

+

$

=

,

$

&

1

&

-RL1, oil extraction yield in twin-screw

extruder RL2', oil expression

yield during molding (in proportion to the

oil that the sunflower whole

plant contains)

RLT, total oil yield

(oil extracted in twin-screw extruder, and oil expressed during

molding) 0 20 40 60 80 100 13 14 15 16 17 18 19 20 21 22 23 LC1 (% dry matter) O il y ie ld s ( % )

Oil extraction yield Oil expression yield Total oil yield

4

4 4

4

@4

±

4

;; @

; @

24 4

6 ; ± 4

;; 6

6

2

4

6

±

4 4

;

5

64

±

4

'

0A2

'

6

G

0A2

'

!

0A2

(!

0A

2

6C"D ±

±

±

±

C"!

DC"C

DC"D

FC"D

(21)

$

$

*

+- -

*

*

.

/

* 0

-+-+-

.

/

* 0

-7" '

"

7" '

"

&- -

/

*

/ 1

(

*

// *

*2

*

*

.

.

/

"

2

-*

'

*

'

'

!

!

'

!

!

(22)

)

(

)

9 #@' :# ' #

(

,

@

% : (9#

(# +' + '

%

? ,

@ ;!<

%

%

=

&+

.

/

1

$

'.

1

,

-/

$

1

.

2

/

=

+

$

% +

.

44A

/

++

.

4 1 $H

+

.

24

I

24

0 4 8 12 16 20 0,0 0,1 0,2 0,3 0,4 0,5 0,6 0,7 0,8 0,9 1,0 Water activity (aW) W a te r u p ta k e ( % d ry m a tt e r)

Experimental Dynamic Vapor Sorption (DVS) measurement

, 2A

-%

1

$

$$

+

.

/

2 4B

F

/

2B

F

/

2

2B

F

/

64 4B

F

/

;2 4B

F

%

+

1

A

/

/ 9

.

.

B 9 ) 9 ?2 / . / * -) / 2 2

(23)

-)

(

)

9 #@' :# ' #

(

,

@

% : (9#

(# +' + '

%

? ,

@ ;6<

+

+

$

&

' %

3

;2 4B

F

%

+

3

$

(; @)

9.8% moisture 6.2% moisture 5.0% moisture 3.2% moisture 0.6% moisture 0 2 4 6 8 10 12 14 0,0 0,1 0,2 0,3 0,4 0,5 0,6 0,7 0,8 0,9 1,0 Water activity (aW) F le x u ra l s tr e n g th a t b re a k (M P a ) 0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 E la s ti c m o d u lu s ( G P a )

Flexural strength at break (MPa) Elastic modulus (GPa)

5 ± 4

5 ± 4

±

64 4B

F

4 ± 4

±

4

4 ± 4

4 ± 4

0@+ 2

6 5 ± 4 4

4 ± 4 2

; ± 4

±

4 6

σ

σ

σ

σ

0:+ 2

; 6 ± 4

6

±

±

4 @

5 2 ±

@

) 0 2

;2 4B

F

2

2B

F

2B

F

2 4B

F

(

)" 0 &' / . * 9 7 '' / . . σ/" / ( 0 /" *

-8

1

' ;

;2 4B

F

$

&

$

8

'

%

(;) ' #" " % 3 )" ' " <8 ' + + $ $ % + % 2 D6 0612 4 & 4 ; , 44 -(@) ' #" " % 3 )" ' " = & $ $ % % * * * 7/F 0! 62 52& 4 , 44

-!"C ±

±

±

±

C"!

1"/ ±

±

±

±

C"C

68"1 ±

±

±

±

C"7

8B"CA '9

(24)

*

+- -

*

*

.

/

* 0

-+-+-

.

/

* 0

-&- -

/

*

/ 1

(

*

// *

*2

*

*

.

.

/

"

2

-&-+-

/

*

/

*

*

*

.

.

-D" (

"

D" (

"

(25)

(

(

%

;!<

'

$

$

$ %

%

+

8

+

$

+ $

$

$

!

#

$ $

+

1

*

+

'

<

+

$

#+

$

'

.

@4B

$

$

%

+

,

+

-=

'

+

$

,

@B

'

$

-

1

%

(26)

(

(

%

;6<

!

+

+

+

&

+

%

$

,*

M

0-

#+

,

$

0-

.

/

L

$

1

/

L

J

$

/

4

$

+

'

:#+# DCC

'

+

,

" +

-=

$

$

, - %

, - %

&

+

+

+

%

'

+

.

/

.

! !

44 ,

* ?

-/

?

.

444 1G , 44

-/

#

+

.

;4

/

+

.

@44

I @44

(27)

+

#

% %

)

9

?

, @'#,#? #@' :# ' # %

.

/

*

& '

$

+

'

/

8

+

,

%

54

4

CH

N $

'

2A -

0

%

$

$

$ +

,

-,

' $ +

-.

/

+

/

$

0

,

-.

, -

%

, -

+

2 / .

(28)

H

"

(29)

!

" #

$

%

" & '&'

( #" )

*

+

,

Références

Documents relatifs

This study aimed to evaluate the in fl uence of thermo-pressing conditions (cake quantity, pressure, time) on mechanical ( fl exural properties, Charpy impact strength, Shore D

As a second important operating parameter for twin- screw extrusion, the effect of the pressing temperature on the oil extraction efficiency was assessed for

This study aimed to evaluate the influence of thermo-pressing conditions (cake quantity, pressure, time) on mechanical (flexural properties, Charpy impact strength, Shore D

This study aimed to evaluate the influence of thermo-pressing conditions (pressure applied during molding, molding time, and cake quantity) on oil expression

When twin-screw extruder is used to extract the oil from whole seeds according to an aqueous extraction process, liquid/solid separation requires the addition of

From alfalfa whole plant, the highest protein yield in the aqueous extract (called green juice) is 25% when water is added in the extruder. Water-soluble

Thus, it is possible to predict the evolution of mean residence times of liquid and solid in the three zones of twin-screw extruder with the main operating variables: screw