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Microsedimentological investigations in lacustrine sediments from a maar lake: implications for palaeoenvironmental reconstructions.

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70° 24.0' W 51° 57.0' S 70° 21.0' W 51° 59.0' S N 1 km

Aerial photograph by Hugo Corbella

5022-2 24m 27m 18m 5022-2 2A 2B 2C

PASADO cores (HPC, extended nose)

Figure 1: Location of Laguna Potrok Aike in southern Patagonia (blue circle on inset map

of South America). Aerial photograph of the immediate catchment area of Laguna Potrok Aike (kindly provided by Hugo Corbella, Buenos Aires) and bathymetric map of the lake with indicated coring site 5022-2. Red dots indicate the positions of piston cores.

(modified from Ohlendorf et al., 2011)

Microsedimentological investigations in lacustrine sediments from a maar lake:

implications for palaeoenvironmental reconstructions

Guillaume Jouve,

1,2

Pierre Francus (presenting author), Arnaud de Coninck, Frederic Bouchard and the PASADO science team. INRS-ETE (Quebec), GEOTOP (Montreal), CEN (Quebec)

1,2 1 3 1 2 3

1- Introduction and objectives

Collaborators

PASADO is an international and interdisciplinary scientific project with field work in Argentina coordinated at the University of Bremen by GEOPOLAR (Institute of Geography). It is based on a close cooperation of several research institutions distributed all over the world. PASADO is made possible by funding from ICDP and six national funding agencies.

2- Materials:

subsampling the PASADO sedimentary sequence

3- Methods :

image analysis

thin sections

fladbed transparency

scanner

natural and

XP light

image analysis software

Francus and Nobert, 2007

SEM-EDS

grey-scale BSE image

binary image

4- Results

0,005 0,015 0,025 0,035 Si/cps 0,6 0,8 1 1,2 Mn/Ti 30 40 50 60 Fe/Ti 0,6 0,8 1 K/Ti 1 2 3 4 Ca/Ti 92.54 92.56 92.58 92.60 92.62 92.64 92.66 92.68 92.70 0,02 0,06 0,1 Ti/cps a b c e d f g h i j ROIs image depth 0,2 0,3 0,4 0,5 Ca/coh 0,02 0,04 0,06 0,08 K/cps 4 8 12 16 Fe/coh 4 8 12 Ca/Si 0 0,02 0,04 0,06 0,08 0,1 Mn/coh C25 C27 1 2 3 3,5 4,5 5,5 6,5 58.66 58.68 58.70 58.72 58.74 0,060,080,10,12 0,0150,0250,035 0,25 0,35 0,45 0,040,050,060,07 0,6 0,8 1 0,04 0,08 0,12 0,6 1 1,4 8 12 16 35 45 55 ap aq ar as

Si/cps Ca/Ti K/Ti Mn/Ti Fe/Ti

Ti/cps Ca/coh Ca/Si K/cps Mn/coh Fe/coh

C9 C10 d 500 250 125 63 500 250 125 63 aq 500 250 125 63 ar 500 250 125 63 as 500 250 125 63

clay silt sand

0 5 105 1 106 1,5 106 2 106 2,5 106 3 106 1 10 100 particle size (µm) w eigh t 77.86 77.88 77.90 77.92 77.94 77.96 77.98 78.00 78.02 0,02 0,06 0,1 Ti/cps 2 4 6 Ca/Ti 0,005 0,015 0,025 0,035 Si/cps 1 2 3 4 K/Ti 1 2 3 Mn/Ti 40 60 80 Fe/Ti 6 10 14 Ca/Si 0,1 0,3 0,5 0,7 Ca/coh 0,02 0,06 0,1 K/cps 0,05 0,15 0,25 0,35 Mn/cps 2 6 10 Fe/coh C19 C20 C21 aa 500 250 125 63 ab 500 250 125 63 500 250 125 63

clay silt sand

w eigh t 0 5 105 1 106 1,5 106 2 106 2,5 106 3 106 3,5 106 4 106 1 10 100 particle size (µm) clay 65% silt35% 0 1 2 3 4 5 0 5 10 15 20 25 30 35 0,1 1 10 100 particle size (µm) 500 250 125 63 500 250 125 63

6- Conclusions

µ-XRF average 1mm cps = count per second coh = coherent scaterring

BSE images

binary image

Corresponding author Guillaume Jouve PhD earth sciences INRS-ETE Quebec, QC, CANADA guillaume.jouve@ete.inrs.ca 0 2 4 6 8 10 12 14 1 10 100 particle size (µm) per cen tages

clay silt sand

grain size

Fe and Mn: increase gradually in clays (c) and fine laminations (d) K and K/Ti: rich in clays (c) and redeposited layers (i-j)

Ti: low in sands (g) and high in silts (a) Ca and Si: increase in sands (g, j)

Fe and Ti: low in micropumices intervals (t-aa) (Jouve et al., 2012) K: rich in clays (z)

Mn: peak on the top of turbidite (ab)

All ratios are particularly high during micropumices intervals because

of Ti close to the detection limit. Thus, no one is useful for environmental or climatic reconstructions. ROIs image depth ROIs image depth c 500 250 125 63 500 250 125 0 2 104 4 104 6 104 8 104 1 105 1,2 105 1 10 100 particle size (µm)

clay silt sand

w eigh t i 500 250 125 63 500 250 125 63 0 1 106 2 106 3 106 4 106 5 106 6 106 7 106 8 106 1 10 100 particle size (µm)

clay silt sand

w eigh t

5- Interpretations

Top of the remobilized tephra s 500 250 125 63 s 500 250 125 63

clay silt sand

w eigh t 0 5 105 1 106 1,5 106 2 106 2,5 106 3 106 1 10 100 particle size (µm) EDS confirm vivianite concretions

Ti: low in sands (ap)

K: rich in clays (ar) and coarse sediments (sandy silt sediments between

ROIs ar and as)

Mn: peak in vivianite concretions (reddingite) while Fe does not increase

significantly in vivianite (?) (ROI as)

Ca and Si: increase in sands (ap)

Laguna Potrok Aike is a maar lake in Argentina, southeast

of Patagonia, in the Santa Cruz province (51°59.0 'S ; 70°21.0'

W).

- The climate is dominated by strong westerly winds

(Endlicher, 1993)

- Polymictic conditions prevail (Endlicher, 1993)

- No ice cover during the winter (Endlicher, 1993).

- The lake has no outlet, which makes it very sensitive

to changes in the precipitation/evaporation ratio

(Haberzettl et al., 2005; Ohlendorf et al., 2011).

This work investigates how commonly used geochemical

proxies such as Ca, Si, Ti, Fe, Mn, K, Ca/Si, Ca/Ti, Mn/Ti, Fe/Ti

and K/Ti can be used in long lacustrine sedimentary

sequences in the light of detailed microsedimentological

facies analyses.

High-resolution analysis, combining:

- µ-XRF,

- SEM-EDS and

- image analysis,

were conducted on 22 thin sections during the Last Glacial.

Red boxes, and numbers associated, represent all thin sections

subsam-pled. Only eight thin sections are presented in this poster.

Microfacies interpretations

Successive microfacies from silt to very thin laminations (ROIs a-e) are interpreted as progressive elevation of the lake level created by less westerly winds and more eas-terly winds, bringing more precipitations from the Atlantic Ocean. Consequently, less mixing in the water column could have resulted in oxygen depletion in the deep basin, leading to enrichment of Fe and Mn at the oxic-anoxic boundary in the sedi-ments (ROIs d, e).

Signification of elements and ratio of element peaks: • Ca, Ca/Ti and Ca/Si:

o Coarse sediments during the Last Glacial, and

o Autochthonous calcite precipitation during the Holocene. • K and K/Ti: o Clay, or o Redeposited layers • Fe and Fe/Ti: o Clay, or o Silt, or o Vivianite, or

o Low micropumices content, or o Sand event

• Simultaneous Fe, Mn, Mn/Ti and Fe/Ti :

o Dislocation of volcanic rocks (non presented here), or o oxic-anoxic boundary variations, or

o Redeposited layers. • Si and Ti :

o Sand and silt respectively, but only if sediments are not rich in micropumices (Jouve et al., 2012).

Consequently, the behavior of elements, or ratio of elements, could not be used in a unique way for inferring environmental and climatic conditions. This work cautions against the use of many µ-XRF proxies for an entire long lacustrine sedimentary sequence, and warns about their use from a site to another.

C25-27

C19-21

C9-10

*

*

*

*

*

*

*

*

*

C25-27 : very thin laminations during lake level change

C19-21 : Turbidite composed of micropumices

C9-10 : rapid variations of microfacies and vivianite concretions

References

-Endlicher, W., 1993. Klimatische Aspekte der Weidedegradation in Ost-Patagonien. Geographische Gesellschaft Trier: 91-103.

-Francus P., Nobert P., 2007. An integrated computer system to acquire, process, measure and store images of laminated sediments. In: 4th International Limnogeo-logy Congress, Barcelona, Spain, 11-14th July.

-Haberzettl, T., Fey, M., Lücke, A., Maidana, N., Mayr, C., Ohlendorf, C., Schäbitz, F., Schleser, G. H., Wille, M., Zolitschka, B., 2005. Climatically induced lake level changes during the last two millennia as reflected in sediments of Laguna Potrok Aike, southern Patagonia (Santa Cruz, Argentina). Journal of Paleolimnology 33 (3), 283-302. -Jouve G.N., Francus P., Lamoureux S. F., Provencher-Nolet L. , Hahn A., Haberzettl T., Fortin D., Nuttin L., and the PASADO science team, 2012. Microsedimentological characterization using image analysis and XRF as indicators of sedimentary processes and climate changes during Late Glacial at Laguna Potrok Aike, Santa Cruz, Argentina, in press.

-Ohlendorf, C., Gebhardt, C., Hahn, A., Kliem, P., Zolitschka, B., 2011. The PASADO core processing strategy - A proposed new protocol for sediment core treatment in multi disciplinary lake drilling projects. Sedimentary Geology 239 (1-2), 104-115.

Region of interest (ROI) are defined and then investigated at the SEM

laser diffraction analysis

Location of Laguna Potrok Aike in southern Patagonia (blue circle on inset map of South America). Aerial photo-graph of the immediate catchment area of Laguna Potrok Aike (kindly provided by Hugo Corbella, Buenos Aires) and bathymetric map of the lake with indicated coring site 5022-2. Red dots indicate the positions of piston cores.(modified from ohlendorf et al., 2011)

SEM

EDS Image analysis software B789 EGU2013-9500

ROIs

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