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Préparation et caractérisation haut débit de catalyseurs nanostructurés

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Succession d’étapes élémentaires

Réaction de coordination

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Nombre d’échantillons Précision de l’information

CRIBLAGE PRIMAIRE

Découverte de nouveaux catalyseurs

CRIBLAGE

SECONDAIRE

Optimisation des catalyseurs Tests classiques Catalyseurs testés à l’échelle industrielle Eloigné des conditions industrielles

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(23)

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(24)

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Expérimentation Interprétations statistiques Conclusions -Défnition du problème -Choix des réponses -Choix des facteurs -Choix du modèle -Choix du plan -Mise en oeuvre

-Repecter les niveaux des facteurs

-Noter les dérives éventuelles

-Calcul des coefficients -Validation statistiques

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2 !"#$% "#! $ %&'( )'*+,-./& 0,1- 2/13 )'*+/1-4 +-'(40,454 /( *,,-2,((54 /( *,,-2,((5/4 -521.+/4# -56-/44.,( 475*-.-' 8 y = β0+β1X1+β2X2+β3X3+β12X1X2+β13X1X3+β23X2X3+β123X1X2X3+e 9"#:; '</* β0 &' *,(4+'(+/ 21 =,2>&/? βi &/ *,/@*./(+ '44,*.5 A *B'C1/ )'*+/1- i? βij &/ *,/@*./(+ '44,*.5 A &7.(+/-'*+.,( /(+-/ &/ )'*+/1- i /+ &/ )'*+/1- j /+ e &/4 -54.214 21 =,2>&/ 0-52.*+.)# D' ='+-.*/ 21 =,2>&/ /4+ 2,(* 8       I X1 X2 X1X2 X3 X1X3 X2X3 X1X2X3 +1 +1 +1 +1 +1 +1 +1 +1 +1 −1 +1 −1 −1 +1 −1 +1 +1 +1 −1 −1 −1 −1 +1 +1 +1 −1 −1 +1 +1 −1 −1 +1      

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(27)

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