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SOME ASPECTS OF STRUCTURE AND LATTICE DYNAMICS OF TOURMALINS AND BORACITES STUDIED BY MÖSSBAUER EFFECT

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HAL Id: jpa-00215755

https://hal.archives-ouvertes.fr/jpa-00215755

Submitted on 1 Jan 1974

HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.

L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

SOME ASPECTS OF STRUCTURE AND LATTICE DYNAMICS OF TOURMALINS AND BORACITES

STUDIED BY MÖSSBAUER EFFECT

I. Zheludev, V. Belov, V. Pilnev, A. Belov

To cite this version:

I. Zheludev, V. Belov, V. Pilnev, A. Belov. SOME ASPECTS OF STRUCTURE AND LATTICE DY- NAMICS OF TOURMALINS AND BORACITES STUDIED BY MÖSSBAUER EFFECT. Journal de Physique Colloques, 1974, 35 (C6), pp.C6-633-C6-633. �10.1051/jphyscol:19746140�. �jpa-00215755�

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CR YS TA L PHASE TRANS/ TION§.

I. G. GUSAKOVSKAYA and V. I. GOLDANSKII Institute of Chemical Physics, Moscou, USSR

ORDER-DISORDER PHENOMENA AND M~~SSBAUER LINE BROADENING

(to appear on Soviet Physics Solid State, October 1974)

INVESTIGATION OF THE PHASE TRANSITION IN PHTHALOCYANINE USING THE MOSSBAUER EFFECT

Dr. B. DUDREVA and Dr. R. PIRINTCHIEVA Institute of Civil Engineering, Dep. of Physics, Sofia, Bulgaria

and Dr. S. GRANDE

Karl-Marx-University, Section Physik, Leipzig, D D R

Resume. - L'effet Mossbauer a 6th utilisk pour Btudier la transition de phase B proximite de la temperature ambiante d'une solution solide de phthalocyanine sans metal (H2Pc) et de phthalo- cyanine contenant du fer (PePc) : 9 H2Pc-1 FePc, transition qui est semblable aux transitions de phase ferroelectriques. La dependance thermique des parametres du spectre Mossbauer entre - 160 et + 160 O C est egalement donnee. Les rtsultats obtenus sont discutCs et compares avec les donnees de la resonance y dans FePc.

Abstract. - The Mossbauer effect has been used for investigation of the phase-transition in the region of the room temperature in a solid solution of metal-free H2Pc and iron phthalocyanine FePc : 9 H2Pc-1 FePc, showing properties, similar to the ferroelectric phase transitions. The temperature dependences of the parameters of the Mossbauer spectrum in the range - 160-

+

160 OC are given as well. The results from the investigation were discussed and compared with the data from y-resonance in FePc.

I. S. ZHELUDEV, V. F. BELOV, V. G. PILNEV and A. F. BELOV Institute of Cristallography, Academy of Sciences, Moscou, USSR

SOME ASPECTS OF STRUCTURE AND LATTICE DYNAMICS OF TOURMALINS AND BORACITES STUDIED BY MOSSBAUER EFFECT

Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyscol:19746140

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