BASTIN Stéphanie
Chargée de recherche CNRS
Laboratoire de Chimie de Coordination du CNRS 205 Route de Narbonne 31077 Toulouse Cedex 04
France
Born 14/09/1974 in Valenciennes (France) Tel : 05 61 33 31 72
[email protected] ACADEMIC AND PROFESSIONAL BACKGROUND
2012- Research assistant - Chargée de recherche CNRS
“Molecular design of transition metal pre-catalysts” research group Laboratoire de chimie de coordination (LCC) du CNRS (Toulouse) 2004-2012 Research assistant - Chargée de recherche CNRS
“Heteroelements and Transition Metals for Catalysis and Electronic Transfer”
research group
Laboratoire de chimie de coordination (LCC) du CNRS (Toulouse) 2003-2004 Post-doctoral associate
Laboratoire de chimie de coordination (LCC) du CNRS (Toulouse) Supervisor: Dr Jean-Pierre MAJORAL
“Synthesis of polycationic dendrimers”
2001-2003 Post-doctoral associate
University of Warwick (Coventry – UK) Supervisor: Prof. Martin WILLS
“Synthesis of chiral polymer-supported ligands. Use in asymmetric transfer hydrogenation of ketones.”
2000-2001 Teaching and research assistant
University Institute of Technology of Chemistry (Béthune – France) Supervisor: Pr. Jacques Brocard
“Synthesis of ferrocenyl analogues of norephedrine and their use as ligands in the enantioselective alkylation of benzaldehyde with diethylzinc.”
1997-2000 PhD in chemistry (defended the 29/11/2000) Université des Sciences et Technologies de Lille I Supervisor: Pr. Jacques Brocard
“Synthesis of optically pure ferrocenyl amino alcohols and diamines. Use in asymmetric homogeneous catalysis.”
1997 DEA (≡ Master) in Organic and Macromolecular Chemistry Université des Sciences et Technologies de Lille I
Supervisor: Pr. Jacques Brocard
“Synthesis of optically pure ferrocenyl amino alcohols. Use in asymmetric homogeneous catalysis.”
SUPERVISION AND FUNDINGS
- ANR HEL-NHC (Coordinator: J. Crassous, Rennes). 2016-2020
- ANR GOLDWAR (Coordinator: V. Michelet, Chimie ParisTech). 2016-2019
- French-Polish exchange program “Polonium” (Coordinator: Vincent César, Toulouse). 2016 - 3 PhD students, 1 post-doc associate, 8 M2R students, 4 BTS students, 1 M1.
RESEARCH INTERESTS
Organometallic chemistry, catalysis, N-Heterocyclic carbenes, phosphorus ligands, chiral ligands, asymmetric catalysis.
SCIENTIFIC RECORD
18 publications, 11 oral communications in meetings.
LIST OF PUBLICATIONS
18. Ruthenium Catalysts Supported by Amino-Substituted N-Heterocyclic Carbene Ligands for Olefin Metathesis of Challenging Substrates.
Vincent César, Yin Zhang, Wioletta Kosnik, Adam Zielinski, Adam A. Rajkiewicz, Mirko Ruamps, Stéphanie Bastin, Noël Lugan, Guy Lavigne, Karol Grela.
Chem. Eur. J., 2017, 23, 1950-1955.
17. Anionic N-Heterocyclic Carbene Complexes of Gold(I) as Precatalysts for Silver- Free Cycloisomerization of Enynes.
Stéphanie Bastin, Cécile Barthes, Noël Lugan, Guy Lavigne, Vincent César.
Eur. J. Inorg. Chem., 2015, 2216-2221.
16. Tethered η5-Oxocyclohexadienyl Piano-Stool Ruthenium(II) Complexes: A New Class of Catalysts?
Manel Kechaou-Perrot, Laure Vendier, Stéphanie Bastin, Jean-Marc Sotiropoulos, Karinne Miqueu, Lucia Menendez-Rodriguez, Pascale Crochet, Victorio Cadierno, Alain Igau.
Organometallics, 2014, 33, 6294-6297.
15. Metal-assisted conversion of an N-ylide mesomeric betaine into its carbenic tautomer: generation of N-(fluoren-9-yl)imidazol-2-ylidene complexes.
Laure Benhamou, Stéphanie Bastin, Noël Lugan, Guy Lavigne, Vincent César.
Dalton Trans., 2014, 43, 4474-4482.
14. A Direct, Modular, and Efficient Construction of the P-C-P Structural Motif through Coupling of Manganese Carbyne Complexes with Phosphines.
Dmitry A. Valyaev, Stéphanie Bastin, Kamil I. Utegenov, Noël Lugan, Guy Lavigne, Nikolai A. Ustynyuk.
Chem. Eur. J., 2014, 20, 2175-2178.
13. Can a functionalized phosphine ligand promote room temperature luminescence of the [Ru(bpy)(tpy)]2+ core ?
Emilie Lebon, Stéphanie Bastin, Pierre Sutra, Laure Vendier, Rémi E. Piau, Isabelle M.
Dixon, Martial Boggio-Pasqua, Fabienne Alary, Jean-Louis Heully, Alain Igau, Alberto Juris.
Chem. Commun., 2012, 48, 741-743.
12. Multi-site coordination N-phosphanylamidine ligands as stabilizers for the synthesis of ruthenium nanoparticles.
Raymond Bronger, Thanh D. Le, Stéphanie Bastin, Jordi Garcia-Anton, Cécilia Citadelle, Bruno Chaudret, Pierre Lecante, Alain Igau, Karine Philippot.
New J. Chem., 2011, 35, 2653-2660.
11. N-phosphanylamidine ligands and their catalytic activity in the hydroformylation of 1-octene and styrene.
Régis Maura, Jennifer Steele, Laure Vendier, Damien Arquier, Stéphanie Bastin, Martine Urrutigoïty, Philippe Kalck, Alain Igau.
J. Organomet. Chem., 2011, 696, 897-904.
10. N-phosphonio formamidine derivatives: synthesis, characterization, X-ray crystal structures, and deprotonation reactions.
Thanh Dung Le, Damien Arquier, Laure Vendier, Stéphanie Bastin, Thi Kieu Xuan Huynh, Alain Igau.
C. R. Chimie, 2010, 13, 1233-1240.
9. Crucial role of the amidine moiety in methylenamino phosphine-type ligands for the synthesis of tethered η6-Arene-η1-P ruthenium(II) complexes: experimental and theoretical studies.
Damien Arquier, Laure Vendier, Karinne Miqueu, Jean-Marc Sotiropoulos, Stéphanie Bastin, Alain Igau.
Organometallics, 2009, 28, 4945-4957.
8. Unprecedented rearrangement during the formation of P–P homoatomic N- phosphino formamidine complexes.
Thanh D. Le, Damien Arquier, Karinne Miqueu, Jean-Marc Sotiropoulos, Yannick Coppel, Stéphanie Bastin, Alain Igau.
J. Organomet. Chem., 2009, 694, 229-236.
7. N-Phosphanylformamidines (phosfam) R2N–C(H)=N–PR2: one-pot synthesis and versatile protonation reaction.
Thanh Dung Le, Marie-Christine Weyland, Yamna El-Harouch, Damien Arquier, Laure Vendier, Karinne Miqueu, Jean-Marc Sotiropoulos, Stéphanie Bastin and Alain Igau.
Eur. J. Inorg. Chem., 2008, 2577-2583.
6. A soluble-polymer system for the asymmetric transfer hydrogenation of ketones.
Stéphanie Bastin, Richard J. Eaves, Christopher W. Edwards, Osamu Ichihara, Mark Whittaker and Martin Wills.
J. Org. Chem., 2004, 69, 5405-5412.
5. Chiral ferrocenyl amino alcohols for enantioselective addition of diethylzinc to aldehydes.
Stéphanie Bastin, Mihaela Ginj, Jacques Brocard, Lydie Pélinski, Guy Novogrocki.
Tetrahedron: Asymmetry, 2003, 14, 1701-1708.
4. Chiral ferrocenyl amino alcohols as catalysts for the enantioselective borane reduction of ketones.
Thierry Brunin, Jérôme Cabou, Stéphanie Bastin, Jacques Brocard and Lydie Pélinski.
Tetrahedron : Asymmetry, 2002, 13, 1241-1243.
3. Enantioselective alkylation of benzaldehyde with diethylzinc catalyzed by 1,1’ and 1,2-disubstituted ferrocenyl amino alcohols.
Stéphanie Bastin, Francine Agbossou-Niedercorn, Jacques Brocard and Lydie Pélinski.
Tetrahedron: Asymmetry, 2001, 12, 2399-2408.
2. Chiral ferrocenyl amino alcohols as analogues of noréphédrine catalysts for enantioselective addition of diethylzinc to benzaldehyde.
Stéphanie Bastin, Jacques Brocard and Lydie Pélinski.
Tetrahedron Lett., 2000, 41, 7303-7307.
1. Synthesis of C2-symmetrical 1,1’-disubstituted ferrocenyl amino alcohols and use in catalytic asymmetric addition of diethylzinc to benzaldehyde.
Stéphanie Bastin, Nathalie Delebecque, Francine Agbossou, Jacques Brocard and Lydie Pélinski.
Tetrahedron: Asymmetry, 1999, 10, 1647-1651.
