A NNALES DE L ’I. H. P., SECTION A
U LRICH W ÜLLER
Existence of the time evolution for Schrödinger operators with time dependent singular potentials
Annales de l’I. H. P., section A, tome 44, n
o2 (1986), p. 155-171
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155
Existence of the Time Evolution for Schrodinger Operators
with Time Dependent Singular Potentials
Ulrich
WÜLLER
Freie Universitat Berlin, Institut fur Mathematik I 1000 Berlin 33, FR Germany
Vol. 44, n° 2, 1986, Physique theorique
ABSTRACT. 2014 Let N
particles
movealong
fixedpaths Yj(t)
and causea time
dependent potential.
Thequantum
mechanicaldescription
for anadditional
particle
isgiven by
theSchrodinger equation
For a class of
trajectories
the propagator is constructed for the Coulombpotential v(x) _ 1 (x
E andstronger singularities.
Ixl
RESUME. 2014 Soit N
particules
sedeplagant
sur destrajectoires
fixeeset
produisant
unpotentiel dependant
du temps. Ladescription quantique
d’une
particule supplementaire
est donnee par1’equation
deSchrodinger
Pour une classe de
trajectoires
on construit Iepropagateur
corres-pondant
aupotentiel
de Coulombv(x)
=1/|x|(x
E(R3)
et a despotentiels plus singuliers.
Annales de l’Institut Henri Poincaré - Physique theorique - 0246-0211
Vol. 44/86/02/ 155/ 17/$ Gauthier-Villars
1. INTRODUCTION
There are several
possibilities
to describe a multiparticle
system. Often allparticles
were treated quantummechanically,
which leads to alarge
number of coordinates. The
advantage thereby
is a timeindependent
andself-adjoint
Hamiltonian andconsequently
there are noproblems
to find theunique
time evolution for the systemby using
the functional calculusIn this paper
contrarily only
such systems areregarded
which have N classical andonly
one quantum mechanicalpartical,
i. e. the first N shouldmove
along
fixedtrajectories
=1, ... , N;
andengender
a timedependent potential
which influences the motion of the last one. So the
Schrodinger equation
foronly
oneparticle
has to besolved,
but with a timedependent
Hamiltonian(see [7L [2], [7~])
For this reason the time evolution 2014 if it exists 2014 is
given by
afamily
of
operators { U(t, s) }~,
called propagator,through
the formulaThe
following properties
aresatisfied,
if the Hamiltonian isself-adjoint.
(1) U(t, s)
isunitary
andstrongly
continuous in t and s(2)
= I for all t(3) U(t, s)
=U(t, r) U(r, s)
forall t,
r and sBut the
self-adjointness of H(t)
for all t is not sufficient to show the existence of the time evolution. One needs also somesupplementary
conditionsabout the smoothness of
H(t).
Kato[4]- [7]
was the first to formulateconditions for the
unique
existence of solutions in thegeneral
case ofBanach spaces. Furthermore there are some results of Yosida
[7J]-[77] ]
and Tanabe
[12 ]. Using quadratic
forms Simon[77] has
obtained a wider class ofpotentials
for which he can solve theSchrodinger equation.
ButAnnales de I’Institut Henri Poincaré - Physique theorique
singularities
like those in Coulomb and Yukawapotentials
for dimensionv = 3 are not included. So here
potentials
which have the formwill be
treated,
where is a suitable bounded function. Thesingular part
of thepotential v(x)
should behomogeneous
ofdegree
a2},
so that it is
possible
to take timedependent
scalars out of this term as acoefficient. In
particular
thephysically important
Coulomb and Yukawa forces are included.2. RESULTS
First we
forget
about thequantum
mechanicalparticle
and look at theN others. We assume that their
trajectories
aregiven by
Here should be the matrix of the rotation in a fixed
plane
withangle
~p. Without loss ofgenerality
we later take theplane spanned by
thedirections of the two first coordinates. The functions
l(t)
and have to betwice
continuously
differentiable within the chosen set oftimes,
whichcan be taken as the whole real line or
only
as an interval. In addition weconsider
only
those times for which no collisions occur. If one examines thepermitted trajectories,
it seems to be a strong restriction that and shouldby independent of j
and the rotation is around a fixed axis. For N greater than 2 it isreally
not thedescription
of thegeneral
situation. But if one has two classicalparticles,
allsystems
areadmitted;
where no externalforces act on the
particles.
Afterseparation
of the free motion of thecenter
of mass it is of the form(2.1).
Inparticular
is admissible in this sense. For
example
the whole model describes the transi- tion of an electron from oneproton
toanother,
if the influence of the electronon the nuclei of the
hydrogen
canby neglected.
Now we state the main result.THEOREM. 2014 Let t;2 ~ be a bounded function with bounded first derivatives and
Ov2
E + for some p E[2, oo) n ~ /v -, oo .
Thenfor
v(x)
=1/J x Ja
+v2(x) ~ ~
Vol.
is
self-adjoint
onD(H(t))
= for all t if 0 a minv , 2
2and
is
given
as in(2.1).
Moreover there exists aunique
propagatorU(t, s)
such that
, The statement of
self-adjointness
is acorollary
of Theorem XIII 96 in[10 ],
since 1 |x|a I
x1(%
is inLp(Rv) | L~(Rv) with p
= 2 for v ~3andpE (V -,- V)
2 a for v ~ 4.The
proof
of the rest of this theorem isgiven
in the next sections.Regarding
the
uniqueness
of the solution it is no restriction to take a compact time interval[tl, t2 ].
The propagatorcorresponding
to v2 - 0 will be obtained with the timedependent
transformationL a generator of
rotation, revolving
andblowing
up the space in accor-dance with the motion of the N
particles.
The transformedequation
hasa new Hamiltonian with a
dependence
ontime,
which is moreappropriate
for
finding
a solution inspite
of theproblems
ofvarying
domains. After- wards it is shown how to add the boundedperturbation
v2. For the sake ofsimplicity
we take m =1/2
from here on.3. SOME SELF-ADJOINT OPERATORS -
In this section we introduce some
self-adjoint
operators, which are needed forsolving
the transformedequation.
The operatorgenerating
the rotation in the two first coordinates is denotedby
which is the third component of the
angular
momentum, if we are in thephysical
three dimensional space.Analogously
we have for the dilatation thesymmetrized
scalarproduct
ofposition
and momentumBoth operators are contained in the new
(modified)
Hamiltonianwhich results from the transformation with
W(t) (2 . 3).
Theonly
timedepen-
Annales de I’Institut Poincaré - Physique theorique
dence is in the real coefficients
f (t), k(t)
andh(t).
Thepotential
haschanged
toLater we will see that the domain
ofHM(t) depends
on t. So the smoothness of isgiven by
means of anauxiliary operator
valued functionHs(t)
with a constant domain
Since we
only
want to prove theself-adjointness
of these operators for any fixed t in thissection,
we will omit the time here for convenience.The
potential VM
should be an operator boundedperturbation
of the other terms. So we first set its coefficient hequal
to zero.LEMMA. 2014 For all
f , k
the operatorH o
+f D
+ kL isessentially self-adjoint
onProof
2014 Webegin by showing
the statement the Schwartz space of functions ofrapid
decrease. Theunitary
group of L can becomputed
Because the
self-adjoint
operator Dgenerates
the dilatationwe see that e - iSL commutes with e - ~tD for all sand t. With
we have a
strongly
continuous one parameterunitary
group which leaves invariant and isstrongly continuously
differentiable on the same set. Thus the generatorf D
+ kL isessentially self-adjoint
on(Theorem
VIII 10 in[8 ]).
Since the Fourier transform of Lgenerates
thesame rotation in momentum space, the above argument works also for the sum
Ho
+ kL. Forf ~ 0
we calculate onand we have shown the lemma for because
The
only
reason,why
thisproof
doesn’t work with is that ingeneral (see [3 n.
Tocomplete
theproof
we use the harmonic oscillator Hamiltonian
Ho + x2,
which has the domainD(Ho
+x2)
=D(Ho)
nD(x2)
and isessentially self-adjoint
onThe
following
lemma shows thatHo
+f D
+ kL is operator bounded with respect toHo + x2
and so is also a core for the first one.LEMMA.
Suppose 03C8 ~ C~0(Rv)
and ThenProof. 2014 By expanding
the square ofHo + x2 = . (PJ
+x2
in thescalar
product
we getusing
the canonicalcommutation relations
Applying
theinequality | y|
j=I
1I s 0 I y|I
in /R’ we can estimatev
and
We are finished with the
proof
sinceAnnales de l’Institut Henri Physique - theorique -
LEMMA. - For
all f, k E (F8, s
=(v
+2) ( f 2 + k2
+1)
the operatorHo
+fD
+ kL+sx2
isself-adjoint
on D(Ho)
and is a core.Proof.
2014 We check on that41n
~DSince the
unitary
transformatione
does notchange
the operators D and L or the domain ofHo
+x2,
the last lemmaimplies.
The coefficient max
f |f L ! k } v + 2
is smaller than 1 and thus we canapply
the Kato-Rellich theorem. D-
The next step is the addition of the
potential hVM.
To avoid any relation between thecoefficients f, k
andh,
we will show that the operator bound ofVM
isarbitrarily
small.LEMMA. 2014 For
all f,
the operatorsHM
=Ho f D
+ kL +hVM
and
HS
=Ho
+f D
+ kL +hVM
+sx2
areself-adjoint
on domains inde-pendent
of h.Proof. 2014 Ho
is operator bounded withrespect
toHo
+f D
+ kL +sx2.
The
relativeHo-bound
ofVM
is zero, because for amin -, 2
thereis some p E
[2, oo) n (2 ’ ~)
withVM
ELp(Rv)
+(Theorem
XIII 96in
[10 ]).
Thus for all a > 0 there exists a b > 0 such thatAgain
the statedproperties
forHS
follow from the Kato-Rellich theorem.Regarding
the other operator a little more work must be done. We have touse that the
potential VM
is bounded outside a ballBa.
Therefore we choose~p E with
~p(x)
= 1 for x EBa, ~p(x)
= 0 forx 1100
= 1 and~P(x) _ ~P( I x D.
.+
IIvM(1 - Using
the first part of theproof
weonly
have to showThe
compact
support of ~p can be utilized here to estimateAfterwards we want to eliminate the
function by commuting
it withHo
+f D
+ kL andapplying
The commutators
[D,~]
and[L,~]
arebounded,
butSince is bounded it remains to estimate
We define
~(~):=~(2 "~)
whichimplies
= 1 on the supportof 03C6n and ~ ~ ~xj 03C6n~~
=2 "~ ~xj 03C6~~
. ThusThe same
procedure
as above leads toThe
coefficient t/J "
is based on the factthat ~sx203C6n+1~~ ~ 22n.
Wecan
employ
theinequality (3.5) iteratively
inestimating
The limit n -+ oo exists and shows
(3 . 4) .
0While
D(HS)
=D(Ho)
nD(x2),
we do notgive
the domain ofHM.
Evenfor k = h = 0 the domain
D(Ho
+f D)
varies with thecoupling
constantf.
For 0 the operator
Ho
+f D
can be studied with thefollowing unitary
transformation
from to x For~6~(M~
the momentum space wave
function given by
Fourier transform should be taken inpolar
coordinates to defineSo we obtain the
(Ho
+/D)-space representation,
i. e. under the trans- Annales de l’lnstitut Henri Poincaré - Physique theoriqueformation -~ ~
a function of this operator becomes amultiplication operator
with this function of b. As acorollary
we get that thespectrum
ofHo
+f D
isabsolutely
continuous on the whole real line.Assume that for some
f ~
0 the domain ofHo
+f D
isequal
to thatof
Ho.
One could conclude that D = -(Ho
+f D - Ho)
is defined onD(Ho)
and therefore operator bounded w.r.t.Ho.
So for some smallfl
one could
apply
the Kato-Rellich theorem toHo
andfiD.
We could obtainHo
+f1D
as an operator defined onD(Ho)
and bounded from below sinceHo
>_0,
which is a contradiction to the result above. Indeed one canprove for an
arbitrary pair
of differentcoupling
constants that the corres-ponding
domains are notequal.
The details can be found in[13 ].
4. SOLUTION OF THE
EQUATION
WITH A HOMOGENEOUS POTENTIAL
After the
self-adjointness problems
are settled we turn to solutions of theSchrodinger equation.
First we want to treatwith
continuously
differentiablefunctions f, k
and h. Thefollowing
resultsare contained in Theorems 4 . 4 .1 and 4 . 4 . 2 of Tanabe
[12 ].
His formulation is based upon two Banach spaces X and Y with therespective norms 11.11 and
The space Y isdensely
contained in X and there is some constantc
with ~v~~c~v~Y
for all v~Y. Furthermore he needs thefollowing assumptions.
i) {A(t)}t~[0,T]
is afamily
ofgenerators
ofstrongly
continuous semi- groups inX,
which is stable withstability
constants M and{3.
ii)
There exists a ofisomorphic mappings
from Y to X.S(t)
isstrongly continuously
differentiable on[0,T] ]
as a function with values inB(Y, X) (the
set of all bounded operators from Y toX).
Thereexists a
strongly
continuous functionB(t)
with values inB(X, X),
such thatiii)
Y cD(A(t))
for each t E[0,T],
so thatA(t) E B(Y, X).
The func-tion
A(t)
of t is continuous in the norm ofB(Y, X).
Under these conditions there exists a
unique bounded-operator-valued
function
U(t, s)
EB(X, X)
for 0 s t Thaving
theproperties
a) U(t, s)
isstrongly
continuous ins and t, U(s, s)
= I andd) U(t, s)
Y cY; U(t, s)
isstrongly
continuous in Y.e)
For all v~Y and s E[0,T], U(t, s) v
iscontinuously
differentiable with respect to t in[s, T ] ;
In our
application
the Banach space X isgiven
as but Y must bechosen
appropriately.
We will see thatis a suitable choice.
Regarding (4.1)
we have to takeThe
self-adjointness of HM(t)
for all t is stronger thani),
so that the defini- tion of a stablefamily
can be omited here. From thepreceding
section itis clear that Y c
D(HM(t)).
SinceD,
LandVM
are bounded operators from Y toX,
we getusing
the smoothnessof f,
k and h thatHM(t)
is continuous in the norm. Hence the conditioniii)
is satisfied.Finally
thefamily
of opera- torsS(t)
has to be defined. For that reason we have introduced the self-adjoint
operator which has the domainD(Ho
+x2).
It is evident thatgives
anisomorphic mapping
from Y to X for all t(bounded
with boundedinverse).
The timedependence
ofS(t) (see (3 .1 ), (3 . 3))
is contained in thecoefficients /(~), k(t),
ands(t),
which arecontinuously
differentiable.Thus
S(t)
is differentiable even in the norm ofB(Y, X).
We have tocheck,
whether
[S(t), is
bounded from Y to X(compare
with(4 . 2)). Suppose
03C6 E
and 03C8
EL2(Rv).
With the definitions(3 .1), (3 . 3)
we can computewhere
B(t) _ ~ 4s(t)
D +(HS(t)
+i)-1
is abounded-operator-
valued function
of t,
which is continuous in the norm ofB(X, X). (Tanabe
has
proved
that is continuous in the normof B(X, Y)
under the assump-tions). If 03C8
ED(HM(t)),
then the aboveequality gives
Annales de Henri Physique , theorique ,
Since
Cü(IRV)
is a core forHs(t)
one hasHM(t) (Hs(t)+
D(Hs(t)).
Similarly
the latterimplies 03C8
ED(HM(t)).
Forthose 03C8
weget
It is not hard to extend the result of Tanabe in the case of
self adj oint
operators in Hilbert spaces. One obtains a
unitary
propagator for all s, tE[0,T] and a)-e)
holdscorrespondingly
for all times. We will denote this propagator forA(t)
as in(4. 3) by { UM(t, s)
The next
step
to prove the main theorem of the second section is to usethe
unitary
transformationW(t) (see (2 . 3)).
We consider the timedependent potential
without the bounded part v2, which is amultiplication
operator with the functionwhere denotes a
permitted family
oftrajectories, i,
e.E
~)
andl(t)
# 0 for all t in an interval[tl, t2 ].
We assumel(t)
>0,
because otherwise we turn tol (t)
= 2014and yj
= 2014 Yj.By using
theexplicit
construction of the groupsgenerated by
D and Lwe can compute on Y
At this
point,
where the timedependence
has to beseparated,
wecrucially
use thehomogeneity
of thepotential.
In the same way we getThus,
tocompensate
the factor~2 1 t ’
we introduce thefollowing
trans-formation of the time 1
(t)
which is a
diffeomorphism
from[ti, t2 ] to [0, T ];
T :=t2 t1
dr. We candefine
J’i’M
It is an additional
advantage
of the set Y =D(Ho)
nD(x2)
that it is leftinvariant
by W(t).
Hence " we have " noproblems
to differentiate "for all and 0
We have used that
UM(g(t),g(s))
maps Y into Yby
propertyd).
For thetwice
continuously
differentiable functions land 03C6 we choose the diffe- rentiablefunctions f, k
and h on[0, T] by
( g -1
denotes the inverse functionof g).
With(4 . 6)
and(4 . 7)
In the next theorem we will summarize some characteristics of this propagator. We will denote the
self-adjoint
operatorHo
+Vt(t)
onD(Ho) byH,(t).
THEOREM. 2014 There exists an
unique
operator valued functions) (defined by (4 . 8)
for all t, s E] with
thefollowing properties
a) s)
isunitary
andstrongly
continuous in and t,U 1 (s, s)
= I.b) s)
=r) U 1 (r, s)
for all s, E[t 1, t2 ] ;
inparticular [U,(~)r=U,(~).
a
c) as
= is) for t, s
Eand t/J
E Y.d) U 1 (t, s) [Y] ==
isstrongly
continuous in Y.a
e)
-U 1 (t, s) ~ _ -
iH 1 (t) for t, s
E[t 1,
t2and t/J
E Y.at
Proof.
2014 SinceH 1 (t)
is asymmetric operator
on Y forall t,
every solutionAnnales de l’Institut Henri Poincaré - Physique theorique
= 2014 is norm
preserving.
Thus the difference of two~
-
solutions
Ui(t,
and which is also asolution,
has normIt is sufficient for the
uniqueness
ofU1(t, s)
tota 03C8
in the dense set Y.The
properties a)
andb)
are obviousby
the definition and theproof
ofc)
issimilar to that of
e)
which we have done above. Theequality
ind)
is a direct consequence of
UM(t, s)
Y cY, s)
Y =UM(s, t)
Y c YFor any
operator M,
which is bounded in and leaves Yinvariant,
,one can define
My
=(Ho + X2
+i)
M(Ho + x2
+ as a closed opera-tor on
By
the closedgraph
theoremMy
is bounded. Thus M is bounded as anoperator
from Y to Y.Employing
this toW-1(t), UM(g(t), g(s))
and
W(s)
weget
theproperty d),
if we can show that the threeoperators
are
strongly
continuous in Y. ForUM(g(t), g(s))
we refer to the theorem ofTanabe,
which hasprovided
thepropagator. Suppose ~
EY,
thenTherefore {ei03BBD}03BB and
arestrongly
continuous groups in Y.Hence
W -1(t)
andW(s)
arestrongly
continuous in Y. D 5. THE BOUNDED PERTURBATIONOF THE POTENTIAL
In the
preceding
sections we have solved theSchrodinger equation with
the Hamiltonian
We now consider the operator
H(t)
=Hl(t)
+V2(t)
with some appro-priate
boundedmultiplication operator V2(t)
for all t. The interactionrepresentation
allows the treatment of thisperturbation.
For this we fixsome to E
[t 1, t2] and
defineSuppose
there exists asatisfying
Then we
apply
the time evolutionto) again
and getIf we
formally
differentiate this transformed propagator, we obtainThe next theorem
gives
some conditionsguaranteeing
the existence ofU(t, s)
and its derivative.THEOREM. -
~ V2(t)
be afamily
of bounded functionsfrom
[R"to R with ’
i) V2(t) [D(Ho)] = D(Ho)
for all tii) V2(t)
isstrongly
continuous in t as amultiplication
operator inL2(f~’’).
iii)
forall 03C8
E Y the function t ~[Ho, V2(t)] 03C8
is continuous inL2(Rv).
Then there exists a
unitary strongly
continuouspropagator U(t, s),
which satisfies
U(t, s) :
Y -+Y,
andU(t, s) t/1
iscontinuously
differentiable in forall 03C8 ~ Y
withProof
2014 Since = the operatorV(t)
defined in(5.1)
is
self-adjoint
and bounded on Moreoverby continuity
ofV2(t) (condition ii))
and ofs)
in the strongtopology
of bounded operators in the operatorV(t)
is alsostrongly
continuous in Thuswe can define
This propagator is
unitary, strongly
continuous and it satisfies(5.2).
A solution constructed in this manner is called a
Dyson expansion (see
Theorem X 69 in
[9 ]).
Because we want to differentiate defined in(5 . 3) for 03C8
EY,
we have toverify U(t, s) s) 03C8
E Y. Thepropagator
s
leaves Yinvariant,
thus it remains to showBy
thehypothesis i)
and thefact,
that the domainD(x2)
isobviously
left invariant
by
themultiplication
operatorV2(t),
it followsfor 03C8
E Y thatE Y. Hence
V(t)
also maps Y into Y. Now we cantry
toregard (5 . 5)
l’Institut Poincaré - Physique theorique
as a definition in the Hilbert space Y. E Y and
(Ho
+x2) ~,
then
is continuous in
L2(~V) by
theassumptions.
ThusV2(t)
andconsequently V(t)
isstrongly
continuous in Y. The sum in(5 . 5)
converges on Y as well.This
yields (5.6).
DAs an
application
of this theorem we will examine the caseso that the full Hamiltonian
H(t)
has the form(2.2).
Thefollowing
lemmacompletes
theproof
of the main theorem of Section 2.LEMMA.
Suppose
v2 : [RV -~ ~ is bounded and(The
derivations are taken in the sence ofdistributions).
ThenV2 (t)
definedin
(5. 7)
satisfies the conditionsi)-iii)
of thepreceding
theorem.Proof
2014 Fixsome ~
ED(Ho),
i. e. E(in
the sence of distri-butions).
Then and we can consider the distributionBy
theassumptions A(t~)
EL 2(~v)
if andonly
if(Ai~) ~ ~ L2(~V);
more-over there exist two functions M E and W E with M + W =
Since 1/1
ED(Ho), by
Theorem IX 28 in[9], 1/1
E nL2(Rv) for q
=2p
~ - 2
(
~ q E2, 201420142014 )
for v ~ 4 and 1 = ~only
if v ~3 ).
Therefore the Höl- derinequality (Theorem
III 1 in[8])
shows thatand
So v2 as a
multiplication
operator mapsD(Ho)
intoD(Ho). Regarding
we get the same for
VZ (t)
and haveproved i).
With therepresentation (5 . 9)
of
V2 (t)
we getimmediately
also the conditionii).
For the conditioniii)
v
we compute with
(5.8)
thatv 2 ~
- - u - w - 2i,
a v 2 P k and
therefore
¿ ~xk
k=1
Since
(Ho
+i)-1
maps into and themultiplication
operator with the function u maps into the operatoru(Ho
+i)-1
isbounded in and thus
[Ho,
is continuous. DWe remark that in the
proof
of this lemma we do not need any restric- tions for thetrajectories
except for theircontinuity.
It isobviously sufficient,
if v2 E but we have chosen this weaker condition to includewhere
f E C2((0, 00), [R) with f, f ’
andf "
bounded on(0, 00).
For v >_ 3one can show that the derivatives of v2 as defined in
(5.10)
meet therequire-
ments of the lemma. Therefore we also have proven the existence of the time evolution in the case of the Yukawa
potential
ACKNOWLEDGMENTS
I am indebted to Prof. Dr. V. Enss for his constant
encouragement,
for valuablesuggestions
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(Manuscrit reçu le 15 juillet 1985)
Vol. 44, n° 2-1986.