INTERNATIONAL HYDROLOGICAL PROGRAMME
Present state and future trends of Karst studies
Proceedings of the
gfh International Symposium and Field Seminar Marmaris, Turkey, 17-26 September 2000
Volume I
Edited by Gi.iltekin Giinay
UKAM, Hacettepe University, Ankara, Turkey Kenneth S. Johnson
Oklahoma Geological Survey, Norman, Oklahoma, USA Derek Ford
School of Geography and Geology, McMaster University, Hamilton, Canada A. Ivan Johnson
A.I. J. Water and Soils Engineering Consulting, Arvada, Colorado, USA Assisted by
Hiiseyin Karakq Sinan Akilli
UKA M, Hate ttepe University, Ankara, Turkey
IHP-V 1 Technical Documents in Hydrology 1 No. 49, Vol. I UNESCO, Paris, 2001
(SC-2OOlAVS/41)
The designations employed and the presentation of material throughout the publication do not imply the expression of any opinion whatsoever on the part of UNESCO concerning the legal
status of any country, territory, city or of its authorities, or concerning the delimitation of its frontiers or boundaries.
TABLE OF CONTENTS
Opening speech of Karst 2000 Symposium Organization
1. KEYNOTES
Karst in Evaporite Rocks of the United States Kenneth S. Johnson
Characteristics of Porosity and Permeability Enhancement in Unconfined Carbonate Aquifers due to the Development of Dissolutional Channel Systems
Stephen R. H. Worthington, Derek C. Ford, Patricia A. Beddows Exploration Techniques for Karst Groundwater Resources Michel Bakalowicz
The Special Problems of Engineering in Karst Petar MilanoviC
Tracer Technology- An Important Tool for the Improvement of Karst Water Resources Management in Semiarid Regions with Special Regard to the Mediterranean
Hans Zojer
2. EVAPORITE KARST
Karst Geomorphology and Hydrogeology of the Bear Rock Formation, a Remarkable Dolostone and Gypsum Megabreccia in the Continuous Permafrost Zone of Northwest Territories, Canada
Jim Hamilton, Derek Ford
Gypsum Karst in the Western Ukraine: Hydrochemistry and Solution Rates Alexander B. Klimchouk, SD. Aksem
Evaporite Karst and Resultant Geohazards in China
Lu Yaoru, Zhang Feng ‘e, Qi Jixiang, Xu Jiaming, Guo Xiuhong
McCauley Sinks: A Compound Breccia Pipe in Evaporite Karst, Holbrook Basin, Arizona, U.S.A.
James T. Neal. Kenneth S. Johnson
Paleosubsidence and Active Subsidence Due to Evaporite Dissolution in Spain
F. Gutierrez, F. Orti, M. Gutierrez, A. Perez-Gonzalez, G. Benito, F.J. Gracia, J.J. Duran Sinkholes Initiated by Salt Dissolution, Dead Sea Basin, Israel
Amos Frumkin, Eli Raz
Gypsum Karst in the Betic Cordillera (Southern Spain) J. M. Calaforra, A. Pulido-Bosch, M. Lopez-Chicano
Speleogy of Gypsum Caves in Oklahoma John Bozeman. Susan Bozeman
Environmental Problems Caused by Gypsum Karst and Salt Karst in Great Britain Anthony H. Cooper
V VII
3
13
31
45
57
61 63
67
81
91
103
121
145
155
165
Human-Induced Activation of Gypsum Karst in the Southern Priangaria (East Siberia, Russia) Yu. B. Trzhtsinsky
3. CARBON CYCLE IN KARST AND ENVIRONMENT, KARST HYDROCHEMISTRY
Spatial Variability of Groundwater Chemistry within a Karst Aquifer- the Milandre Test Site, Swiss Jura
J&ome Perrin, Pierre- Yves Jeannin, Franqois Zwahlen
Nitrate Transport Through Karstic Soil and Unsaturated Karstic Rock Barbara ten&u Curk, Marina Pintar, Matej KarahodiiE, Miran Veselic
Mixture of Deep and Meteoric Waters in a Karst Spring: An Analytical Study Using Hydrochemical, Isotopic and Radioactive Techniques
M. Vallejo, J.J. Dur&
Hydrogeochemical Study of Ildu-i and Halkapmar Karstic Springs, Cesme, Izmir, Turkey
$evki Filiz, G.‘l k T u te in arcan, unsal Gemici
Seawater Intrusion in Coastal Aquifers of Cegme Peninsula, Izmir, Turkey iinsal Gemici, $evki Filiz
Heavy Metal Contamination of Groundwater due to the Solid Wastes of Kemerkoy (Mugla-Turkey) Thermal Power Plant
Alper Baba, Y&se1 K. Birsoy
4. KARST AND SUSTAINABLE DEVELOPMENT, KARST ECOSYSTEMS, SUSTAINABILITY OF KARST WATERS, QUALITY AND POLLUTION IN KARST
A Direct Applicability of Karstology and Motorway Construction on Slovene Karst Tadej Slabe
Particulate Pollution of Karst Groundwaters from Marble Quarrying, Alpi Apuane, Italy Russell Drysdale, Lisa Pierotti, Leonardo Piccini, Francesco Baldacci
Environmental Impact of Yatagan Karstic Springs 7Alper Baba, Yiiksel K. Birsoy
Land Use Planning in Karst Environments Madjid Ownegh
Management Issues and Regulatory Framework for Forestry Operations on Karst in Tasmania Kevin Kiernan
5. ENGINEERING PROBLEMS IN KARST
Water-tightness of Dams and Reservoirs: A Classification of Greek Cases Paul G. Marinos, N. Kazilis
Human-Induced Sinkholes in the Mantled Karst Region of West-Central Florida, USA Ann B. Tihansky, Devin L. Galloway
173
179
181
191
197
205
213
223
231
233
239
249
259
265
271 273
279
Exploitation Potential and Conditions for Underground Storage at Perucac Spring, Serbia Petar Milanovic. Sasa Milanovic
289
Engineering-Geological Investigations of Karst Terrain (Karlovac-Rijeka Highway, Croatia) Davor Pollak
295
Facing with Karst in Kouhrang III Tunnel Project Aref Sadr, Esmail Baradaran
307
Berke Arch Dam, Turkey: Hydrogeology, Karstification and Treatment of Limestone Foundation Saydm Altug, Zeki Sattcroglu
315
Engineering Karst Study in Kowsar Dam Site Madjid Ebrahimi Saati
325
Some Possibilities, of Groundwater Regime in Karst Research by the Analysis both Water Level Diagrams
Tomislav Ivankovic
331
Genetic Model of the Karst-Collapse Structures on the East Coast, Mallorca, Spain Pedro Robledo Ardila, Luis Pomar
6. EXPLORATION TECHNIQUES
Characterising Karst Aquifer Function by Inverse Modelling of Natural Tracers M. Bakalowicz, J-L Pinault, V. Plagnes
Karstic Groundwater Flow Patterns due to Tectonic and Geomorphic Evolution in Mountainous Regions
Th. Herold, P. Jordan, F. Zwahlen,
Evaluation of Hard Rock Aquifers Using Analytical Models and Pumping Test Data N. Samani, J. Doulati
Geophysics in Karst Groundwater Exploration Zoran Timotijevic, Snezana Komatina
Seismic Tomography in Carbonate Rocks (Applications at the Kowsar Dam. Iran) Amir H. Radjaee, Mohammad R. Dawoodi-rad, Yaghoub Miandji
Karst Water Resources Investigations in Kazerun Area, Southwest Iran Mohammad-Taghi Rezaei
A New Application of Square Array for Groundwater Exploration M.K. Hajizi, M. Aiobi Rezamahale
339
345 347
355
363
369
375
381
385
Opening Speech of Karst 2000 Symposium Good afternoon World Delegates and Guests:
I welcome you to the Sixth International Symposium on Karst Waters, convened here in this beautiful setting of the Mares Hotel at Marmaris, Turkey. I speak first as the representative of the International Association of Hydrological Sciences, where I have served in various offices of the International Commissions on Groundwater and on Remote Sensing and in offices in the IAHS Bureau and now as Honorary President. As such I acknowledge the IAHS and its two commissions as co-operating organizations for this symposium and as publisher of several of our past symposia proceedings.
In addition, as a member of the U.S. National Committee for Scientific Hydrology, I acknowledge their co- operation and also financial assistance for this symposium. Finally as one of the Honorary Chairmen of this symposium I welcome you to Turkey - a place that I like to call my “Second Home”.
But let me explain why I feel “at home” here. While I was Chief of the U.S. Geological Survey National Hydrologic Laboratory, I started month-long groundwater training courses for international attendees, convened 3 times per year from 1960 to 1968. During that time period we had around 70 young personnel from Turkey attend some of these sessions. In 1966 one of the class attendees is well known to most of you- Dr. Gultekin Giinay. In 1968 I developed the “U.S. Geological Survey National Training Center” where we offered two 24 week hydrologic training courses per year for internationals, as well as for new USGS employees. This training continued until 1971 when I was transferred to the USGS Washington, D.C.
headquarters. During those years from 1968 to 1971 various management personnel from Turkey toured the center.
But let us go back to my other contacts with Turkey. In 1965 I was sent to Turkey as a UNESCO consultant to assist the new Middle East Technical University in developing their hydraulic and arid zone research laboratories. I also was asked to work with the Turkish President’s Science Advisor in developing Turkey’s program for UNESCO’s International Hydrological Decade. Several years later I had a visit to the Hydrologic Laboratory of the Engineer- in- Charge of the Dams Division of the Hydroelectric Power Plants Department of the Turkish State Hydraulic Works (DSI). Later I was requested by UNDP for an assignment to DSI, where the same man was Director General for all of DSI - his name was Siileyman Demirel - later the most recent President of Turkey. Following that assignment, UNDP requested that I work with Dr.
Giinay in developing the laboratories and archive on karst water research that later become UKAM at Hacettepe University. I also was requested to make recommendations for developing one of the earliest multi -disciplinary curriculums - one that become the Hydrogeological Engineering degree of Hacettepe University. The activities for UKAM facilities required that I come to Turkey several more times to see to installation and calibration of the various new equipment.
Then of course there were the many times that I came to Turkey to work with Dr. Giinay and others of UKAM’s excellent staff in the organization of the six International Symposia on Karst Waters that were convened at a variety of locations in Turkey at about 5 year intervals. Field trips usually were organized to follow each symposium. The first symposium was convened at Oymapinar in 1977 and papers were published in limited quantities by the State Hydraulic Works of Turkey and by UNDP. The Second International Symposium was convened at Oymapmar in 1979 and was published at 1980 by the State Hydraulic Works and UNDP. The Third International Symposium was convened in 1985 at Ankara and Antalya and resulted in IAHS publication 161. The Forth International Symposium was convened in 1990 at Beldibi and resulted in IAHS publication 207. The Fifth International Symposium was convened in 1995 at Kemer and resulted in publication by A.A. Balkema Books. The Sixth International Symposium is this one at Marmaris in 2000 and will be published by UNESCO.
So here I am for the 19” time here in Turkey welcoming you all to also feel at home here in Turkey as you attend this symposium and its great collection of international papers and its field trip. Enjoy it all!
Arnold Ivan Johnson
KARST SYMPOSIA (UKAM)
SEMP. SEMP. PUBL.
NR. YEAR YEAR SEM. PLACE PUBLISHER NAME OF THE
PUBLICATION
1 1977 1978 Oymapmar DSi-UNDP Karst Hydrogeology
Symposium
2 1979 1980 Oymapinar DSi-UNDP Int. Seminar on Karst
Hydrogeology
3 1985 1986
4 1990 1993
(National Library) Ankara
Kemer
IAHS Publ. 16 1 Karst Water Resources Hydrogeological
IAHS Publ. 207 Processes in Karst Terranes
5 1995 1997 Kemer A.A. Balkema Karst Waters and
Environmental Impacts
6 2000 2001 Marmaris UNESCO Present State and Future
Trends of Karst Studies
ORGANIZATION
Hacettepe University
International Research and Application Center for Karst Water Resources (UKAM)
Supported by
UNESCO - Division of Water Sciences United Nations Development Program (UNDP) United Nations Environmental Program (UNEP)
United Nations Natural Resources and Environmental Planning and‘Management Branch (NREPMB) International Association of Hydrogeologists (IAH) - Karst Commission
International Association of Hydrological Sciences (IAHS) International Commission of Groundwater
International Atomic Energy Agency (IAEA)
International Society for Photogrammetry and Remote Sensing (ISPRS) Scientific and Technical Research Council of Ttirkiye (TUBITAK) U.S. National Committee of Scientific Hydrology
Association of Geoscientists for International Development American Society of Testing and Materials
General Directorate of Mineral Research and Exploration (MTA) General Directorate of State Hydraulic Works (DSI)
General Directorate of Electrical Power Resources Survey and Development Administration (EIEI) International Association for Engineering Geology (IAEG)
Organizing committee
Stileyman Saglam, TURKIYE (Honorary Chairman)
A. Ivan Johnson, USA (Honorary Chairman) Gtiltekin Giinay, TURKIYE (Chairman)
Andras Szijlliisi-Nagy, UNESCO Heinz Hoetzl, IAH
Klaus Froehlich, IAEA Yiicel Yurtsever, IAEA Derek Ford, CANADA Philip E. LaMoreaux, USA Petar Milanovic, YUGOSLAVIA
Technical program committee Giiltekin Gtinay, TURKIYE A. Ivan Johnson, USA (Chairmen)
Derek Ford, CANADA Kenneth S. Johnson, USA Yiicel Yurtsever, IAEA Paul G. Marinos, GREECE Michel Bakalowicz, FRANCE Emilio Custodio, SPAIN
Field trip committee Giiltekin Giinay Sakir Simsek Giiksel &ii1 Erkin Turgut Sinan Akilli Fatih Akdeniz
Yuan Daoxian, P.R. CHINA Hans Zojer, AUSTRIA Sakir Simgek, TURKIYE Gijksel biil, TURKIYE Hatip El Hatip, TijRKiYE Fakhri Salim, TURKIYE
Philip LaMoreaux, USA Hans Zojer, AUSTRIA
John Gunn, UNITED KINGDOM Arie Issar, ISRAEL
Petar Milanovic, YUGOSLAVIA Nurkan Karahanoglu, TURKIYE Hasan Yaziclgil, TI.&KIYE
Alexander B. Klimchouk, UKRAINE
Nuri Giildalt Hatem Elhatip Li.itfi Nazik Kenan Tiifekci
&al Akman Koray T&k
1. Keynotes
Present State and Future Trends of Karst Studies; Giinay, Ford, Johnson&Johnson, 2001~UNESCO
KARST IN EVAPORITE ROCKS OF THE UNITED STATES
Kenneth S. Johnson
Oklahoma Geological Survey, 100 E. Boyd, Room N-131, Norman, Oklahoma 73019, U.S.A
ABSTRACT
Evaporites are the most soluble of common rocks; they are dissolved readily to form the same range of karst features that typically are found in limestones and dolomites. Evaporites, including gypsum (or anhydrite) and salt, are present in 32 of the 48 contiguous United States, and they underlie about 3540% of the land area.
Evaporite outcrops typically contain sinkholes, caves, disappearing streams, and springs. Other evidence of active karst in evaporites includes surface-collapse features and saline springs or saline plumes that result from dissolution of salt. Many evaporites, including some in the deeper subsurface, also contain evidence of paleokarst that is no longer active; this evidence includes dissolution breccias, breccia pipes, slumped beds, and collapse structures. Evaporites occur in 24 separate structural basins or geographic districts in the United States, and either local or extensive evaporite karst is known in almost all of these basins or districts. Human activities also have caused development of evaporite karst, primarily in salt deposits. Boreholes or underground mines may enable (either intentionally or inadvertently) unsaturated water to flow through or against salt deposits, thus allowing development of small to large dissolution cavities. If the dissolution cavity is large enough and shallow enough, successive roof failures can cause land subsidence or catastrophic. collapse. Evaporite karst, both natural and human-induced, is far more prevalent than commonly believed.
1. INTRODUCTION
Evaporite deposits are those sediments that form due to precipitation of various salts out of evaporating water, mainly sea water. Principal evaporite rocks are gypsum (or anhydrite) and salt (halite), although potash salts and other rarer salts also are locally important. With continued replenishment of the seawater from which these salts were precipitated originally, it is possible for evaporite layers to accumulate to considerable thicknesses, even tens to hundreds of meters thick. These evaporites are widely distributed in the United States and they contain evidence of karst in most areas (Figure 1). Evaporite rocks are the most soluble of the common rocks throughout the world. Gypsum and salt are dissolved readily to form the same types of karst features that typically are found in limestones and dolomites. The principal difference is that evaporite-karst features can form rapidly, in a matter of days, weeks, or years, whereas carbonate-karst features typically take years, decades, or centuries to form.
The current report is condensed from an article on “Evaporite Karst in the United States,” published in Carbonates and Evuporites (Johnson 1997), which was based largely upon earlier studies by Johnson and Gonzales (1978), Dean and Johnson (1989), and Quinlan et al. (1986). Other recent comprehensive studies of gypsum and/or salt deposits in the United States were published by Withington and Jaster (1960) Pierce and Rich (1962) Withington (1962), Lefond (1969), Smith et al. (1973), Ege (1985) and Kostick (1994).
Publication of this report is approved by the Director of the Oklahoma Geological Survey.
2. EVAPORITE-KARST PROCESSES
The processes for development of karst features in evaporite rocks are identical to those that form karst features in limestone and dolomite, except that the processes are much more rapid. Water percolates over or through gypsum or salt and dissolves the highly soluble rock; typically, this causes formation of a series of sinkholes, caves, natural bridges, disappearing streams, and springs. Once a through-flowing passage is created in the evaporite rock, enlargement results from further dissolution and from abrasion, as water-borne particles are transported through the cavity.
The process for dissolution of evaporites was described earlier by Johnson (198 I), with particular reference to salt; but it clearly applies to dissolution of gypsum as well. He pointed out that ground water in contact with an evaporite deposit will dissolve some of the rock, providing the water is not already saturated with
EXPLANATION Principal evaporiie basin or prWinca
& Cnharareas undedaln byevapodtes .-.--.;
I._._... Indefinite border embracing scattered deposits
EXPLANATION
& Area underlain by gypsumlsnhydtite Area underlain by aall and gypsumfanhydrite Hachures show appoximale areas of waporite karsl. ei!her In outcrops or in subsurtace
Figure 1. Maps of the conterminous United States: (above) evaporite basins and districts; (below) distribution of gypsumanhydrite, salt, and evaporite karst. Modified from Johnson and Gonzales (1978) and Dean and Johnson (1989).
CaS04 (or NaCl). For extensive dissolution to occur, it is necessary for the aqueous solution (or brine) thus formed to be removed from the evaporite deposit; otherwise, the water becomes saturated, and the process of dissolution stops. The four basic requirements for dissolution of gypsum (or salt) are: (1) a deposit of gypsum (or salt) against which, or through which, water can flow; (2) a supply of water unsaturated with CaS04 (or NaCl); (3) an outlet whereby the resulting solution (or brine) can escape; and (4) energy (such as a hydrostatic head or density gradient) to cause the flow of water through the system. When all four of these requirements are met, dissolution of gypsum (or salt) can be quite rapid, in terms of geologic time.
Evaporite karst is rarely seen at the land surface in eastern United States, where the precipitation is fairly high, but gypsum karst is fairly common in the semi-arid to arid regions of the west. Owing to rapid dissolution of gypsum and (especially) salt, most would-be outcrops in the humid east are quickly destroyed, and the rock and its dissolution features are observable only in excavations, mines, tunnels, and boreholes. Abrupt thinning or termination of an evaporite unit, particularly where overlying strata are brecciated, commonly marks a dissolution front (either ancient or modem) where karst processes are, or have been, occurring.
2.1. Gypsum-karst processes
Gypsum karst develops rapidly because gypsum is highly soluble in water. Karst features may be present in gypsum deposits m all parts of the United States, whether the gypsum crops out or is in the deep subsurface;
the karst may result from climatic and hydrologic conditions of today, or it may be a relict from an earlier, wetter climate and/or hydrogeologic regime of the Pleistocene or pre-Pleistocene epochs.
In the eastern United States, where average annual precipitation commonly is greater than 75 cm, gypsum deposits generally are eroded or dissolved to depths of at least several meters or tens of meters below the land surface. In the west, however, in areas where the average annual precipitation commonly is less than about 75 cm, gypsum tends to resist erosion and typically caps ridges, mesas, and buttes; in spite of its resistance to erosion in the west, gypsum commonly contains karst features, such as cavities, caves, and sinkholes, attesting the importance of ground-water movement, even in low-rainfall areas.
Evidence of gypsum karst includes surface and shallow-subsurface features, such as caves, sinkholes (dolines), karren, disappearing streams (swallow holes), springs, collapse structures, and the dropping of drill bits and/or loss of drilling fluids while drilling through gypsum beds. All these karst features, and many more, are identical in character and genesis to those found in carbonate rocks. In fact, paleokarst, becciated zones, and other karst features found in some carbonates may, in fact, have been initiated by earlier dissolution and karst development in gypsum that is interbedded with the carbonates; Sando (1988). and Friedman ( 1997) provide examples and a summary of this carbonate/sulfate relationship.
2.2. Salt-karst processes
Salt is extremely soluble in ground water. Salt-karst features can be present in all parts of the United States that are underlain by salt. The mechanisms for salt dissolution and the development of interstratal karst are described by Johnson (1981) and are illustrated in Figure 2. Fresh ground water can be recharged through sandstone, gypsum, carbonates, alluvium, or other permeable and/or karstic units at or near the land surface (Figure 2). This water migrates downward and/or laterally to the salt beds, and dissolves the salt to form a brine. The resulting brine is then forced through, and away from, the salt to make room for additional unsaturated ground water. Brine can migrate into an aquifer, or it can be forced back to the land surface in brine springs or salt flats. These mechanisms involve the four basic requirements for the dissolution of salt, as described above.
Salt is so soluble that it survives at the land surface only in arid areas. The two sites in the United States with salt recently at the surface are Sevier Valley, Utah (where salt is being quarried), and Virgin Valley. in
Nevada and Arizona (where the salt outcrops are now inundated by Lake Mead). Elsewhere, salt has been dissolved to depths ranging from tens to hundreds of meters below the present land surface. In many places, it is not easy (or possible) to distinguish between modem dissolution/karst and paleodissolution/paleokarst:
some of the salt karst may be remnant from an earlier hydrogeologic regime (perhaps as early as shortly after original deposition of the salt unit).
Evidence of salt karst includes collapse structures, sinkholes, subsidence features, brine springs, salt flats, brecciated zones (in salt beds and overlying rocks), and the dropping of drill bits and loss of drilling fluids while drilling through salt beds. Many salt-karst features are similar to those in carbonate rocks, but there are only a few places in the world with extensive salt outcrops (e.g., Mount Sedom in the Dead Sea Depression of Israel, and Forrat Mica near Cardona in eastern Spain), where typical karst features, such as caves, sinkholes, shafts, and karren, can be documented (White 1988).
3. DISTRIBUTION OF EVAPORITE KARST
Gypsum and salt are present in 32 of the 48 contiguous states, and they underlie about 3540 percent of the land area (Figure 1). These evaporites occur in 24 separate structural basins or geographic districts in the United States, and are reported in rocks of every geologic system from the Precambrian through the Quaternary. Local or extensive evaporite karst is known in almost all of these basins or districts. Below is a discussion of the distribution and selected examples of gypsum karst and of salt karst.
3.1. Distribution of gypsum karst
Gypsum deposits are more widespread than salt and are a significant part of all evaporite United States (Figure 1). Gypsum crops out or is in the subsurface in 32 of the 48 contiguous
deposits in the states.
Fresh water BtilK and cavities
Figure 2. Schematic block diagram of interstratal salt karst in western Oklahoma (from Johnson 1981). The horizontal dimension is 1-15 km; the vertical dimension is 30-300 m.
Generally, in areas where gypsum crops out, or is less than 30 m below the land surface, karst features are present (at least locally). The most widespread and pronounced examples of gypsum karst are in the
Permian basin of southwestern United States. Other significant examples are in the Illinois basin, Michigan basin, Forest City basin, the Black Hills area of South Dakota, and parts of Texas, Wyoming, and other western states.
The Permian basin contains a thick sequence of Permian evaporites and red beds that extend from west Texas and southeast New Mexico into western Oklahoma, western Kansas, and southeast Colorado (Figure 1). Individual gypsum beds typically are 3-10 m thick in most Permian basin formations, but are 20-200 m thick in the Castile Formation of the Delaware basin part of the Permian basin (Dean and Johnson 1989).
Low rainfall in the region permits extensive outcrops of gypsum; particularly in the Delaware basin, to the south, and along the Permian basin’s west flank (eastern New Mexico) and east flank (north-central Texas and western Oklahoma). In these areas, typical gypsum-karst features abound. Quinlan et al. (1986) report that there are more than 500 gypsum caves in the United States, and that most of them are in the Permian basin. The Delaware basin gypsum deposits contain abundant sinkholes, caves, closed depressions, collapse sinks, and underground drainage; an excellent summary is provided by Hill (1996). Much of the area has also been affected by subsurface dissolution of some of the salt layers. Gypsum sinkholes, a few meters to 100 m across, are active collapse features in much of the area, and generally they are related to shallow, underground caverns less than 100 m deep.
Another major gypsum-karst area of the Permian basin is along its east flank, in north-central Texas and western Oklahoma. Principal gypsum beds are 3-30 m thick. Among the more important gypsum-karst features of the region are two well-known caves and a major fresh-water aquifer. The J. C. Jester Cave of southwestern Oklahoma has a main passage that is 2,413 m long (Bozeman et al. 1987; Johnson 1992) but, along with the side passages, the total length is 10,065 m, making it the longest reported gypsum cave in the western world. The cave has passageways that typically are l-5 m in diameter, and locally are up to 20 m wide. Alabaster Cavern of northwestern Oklahoma, now developed as a tourist cave, has a main passage about 700 m long; it has a maximum width of 18 m and a maximum height of 15 m (Myers et al. 1969;
Johnson 1992). A major fresh-water aquifer is developed in gypsum beds of southwestern Oklahoma and north-central ‘Texas (Johnson 1990, 1992). Water is produced from the karstic and cavernous gypsum and dolomite beds of the Blaine aquifer. The aquifer is 50-65 m thick and consists of 9 thick gypsum beds (each 3-8 m thick) interbedded with thinner dolomite beds (0.1-1.5 m thick) and shale beds (0.3-8.0 m thick).
Irrigation wells typically are 15-100 m deep and commonly yield l,OOO-8,000 L/min. The water is a calcium-sulfate type. Total dissolved solids average about 3,100 mg/L (of which about 90% is CaS04); the water is suitable for irrigation, but generally is unsuitable for drinking.
Gypsum karst is indicated, indirectly, along the east and west sides of the Illinois basin in Illinois, Indiana, and Kentucky. Gypsum does not crop out in the area, however, because interstratal karstification is dissolving the evaporites and producing ground water with a high concentration of dissolved sulfates along the eastern boundary of the subsurface gypsum deposits (George 1977). Chemical analyses of springs and well water shows a sulfate concentration of up to 1,350 mg/L, and a low chloride concentration, usually less than 30 mg/L. Westward (downdip) advance of the gypsum-dissolution front in this region generates the sulfate-rich water and the collapse of overlying carbonate rocks into cavities. Saxby and Lamar (1957) also recorded the presence of breccia and the absence of gypsum in outcrops on the west (Illinois) side of the Illinois basin, and they felt this may have resulted from dissolution of the gypsum.
The Michigan basin contains gypsum karst in the Mississippian Michigan Formation in the central part of the State (Elowski and Ostrander 1977). Gypsum caves, sinkholes, and collapse features are described in the Grand Rapids area of Kent County (in the west), and also in parts of Iosco and Arenac Counties (in the east) (Elowski and Ostrander 1977). The Forest City basin area of Iowa contains evidence of gypsum karst in Devonian and Jurassic strata. Devonian strata contain numerous gypsumanhydrite beds in the subsurface of central and southern Iowa (Witzke et al. 1988). Devonian gypsum does not crop out in Iowa; it is thought that the present limits of ‘some of the evaporite units are dissolutional, and that some of the overlying breccia beds are interpreted as having formed by gypsum dissolution and collapse shortly after evaporite deposition (Witzke et al. 1988). Jurassic gypsum present in central Iowa has an upper surface that is quite irregular, due to partial dissolution before deposition of an overlying Pleistocene till (Cody et al. 1996). The principal karst features are joint-controlled dissolution channels, about 1 m wide and l-3 m deep, incised
into the upper surface of the gypsum. Other examples of gypsum karst are noted in central Texas, South Dakota, and Wyoming (Johnson 1996, 1997).
3.2. Distribution of salt karst
Salt deposits underlie a portion of 25 of the 48 contiguous states (Figure 1). Some of the deposits are extensive, such as the Salina Group salts of the Michigan and Appalachian basins, the Permian salts of the Permian basin, and the Louann salt and salt domes of the Gulf Coast basin. These deposits rank among the greatest salt deposits of the world. Evidence of modern dissolution or paleodissolution of salt has been found in almost every one of the states and districts, and therefore salt karst is much more widespread than commonly suspected.
The Delaware basin area of west Texas and southeast New Mexico contains a great thickness of Permian salt and anhydrite interbeds, and much of the salt has been dissolved from the western half of the basin;
hence the stratigraphic position of the salt is marked by brecciated zones of anhydrite that result from collapse and lowering of overlying units (Anderson et al. 1972, 1978). Salt dissolution, resulting m subsidence and increased basin-fill sedimentation, has been observed in various parts of the Delaware basin:
most of the dissolution and subsidence occurred during the Cenozoic Era (Maley and Huffington 1953;
Bachman 1976, 1984; Lambert 1983), but some of the dissolution occurred during or shortly after deposition of the Permian salts (Powers and Hassinger 1985; Johnson 1993). Salt dissolution is still going on in the Delaware basin area, as attested by the presence of saline seeps along Malaga Bend of the Pecos River in southeast New Mexico. Hill (1996) has provided a good summary of salt-dissolution processes in the Delaware basin, along with discussion of lateral and vertical dissolution features, subsidence troughs, breccia pipes, sinks, and other disturbed zones related to salt karst.
Permian salt beds are being dissolved at shallow to moderate depths in western Oklahoma and the Texas Panhandle. Conspicuous results of this process are collapse and subsidence features that reach to the land surface. Salt dissolution in the area is also accompanied by sediment-filled subsidence basins and fractured rock at the surface (Simpkins et al. 1981; Gustavson and Finley 1985; Johnson 1989). Salt dissolution has also caused formation of a series of breccia pipes in the Lake Meredith area of the Texas Panhandle (Eck and Redfield 1965). Another result of modem salt dissolution is the presence of large, salt-encrusted salt plains that form where high-salinity brines are emitted at the surface (Johnson 1981, 1992); emission of these NaCl-rich brines attests to ongoing salt dissolution and karst development.
The Holbrook basin of northeast Arizona is the site of more than 500 sinkholes, fissures, depressions, and other karst features that result from ongoing dissolution of salt in the Permian Schnebly Hill Formation (Neal et al. 1997). Salt dissolution on the southwest side of the basin, in the vicinity of the Holbrook anticline, has been recognized for many years (Johnson and Gonzales 1978; Neal 1995), and the relationship of the dissolution front to the surface karst features is now well documented. The salt-dissolution front is migrating downdip to the northeast, and collapse of overlying strata has enabled karst to develop in such areas as The Sinks, Dry Lake Valley, and McCauley Sinks (Neal et al. 1997).
Salt deposits of central and southeast Utah have undergone diapiric movement and dissolution. In the Paradox basin of southeast Utah and adjacent southwest Colorado, thick salts have flowed into a series of long and narrow salt anticlines. Past and/or present dissolution of salt in the Paradox basin apparently is limited to the western and southeastern edges of the salt basin, and to the crestal areas of the salt anticlines (Hite and Lohman 1973). Hite and Lohman (1973) point out that rivers draining the Paradox basin increase their load of dissolved sodium chloride by about 610 metric tons per day, while passing through the basin;
they also estimate that the present-day 33-m-thick cap rock in the anticlines represents the residue, after dissolution, of about 900 m of halite-bearing rock from the central cores of the anticlines.
Salt dissolution has been documented at several places in the Wyoming basins and the Williston basin.
Parker (1967) described dissolution of salt beds of Middle Devonian and Permian age in the deep subsurface of Wyoming, North Dakota, and Montana. Salt removal caused overlying rocks to subside and collapse into
the depressions thus formed, with subsidence occurring at various times between the Late Devonian and Late Jurassic. The Michigan basin contains several examples of salt karst. Dissolution of Silurian and Devonian salts on the northern edge of the Michigan basin occurred by Middle Devonian time; this created a broad area of brecciated and collapsed rocks, referred to as the Mackinac Breccia (Black 1984). In addition, Black (1984, 1997) has shown that a number of modem sinks in the area, and subsurface zones where drilling fluids are lost, are due to paleodissolution and to ongoing dissolution of subsurface salts by ground water circulating in open fault systems.
The Gulf Coast basin is one of the most significant salt-dome provinces in the world (LeFond, 1969:
Johnson and Gonzales 1978). The Jurassic Louann Salt has flowed (and continues to move) into diapiric structures; more than 260 domes are either known or inferred in the onshore portion of this region. The processes by which salt-dome cap rock forms is a special type of interstratal salt karst; as salt rises in diapirs, ground water dissolves the upper surface of the salt and there is an accumulation of residual, relatively insoluble anhydrite and calcite as the cap rock (Kreitler and Dutton 1983). About half of the known domes have a cap rock, and thus attest salt dissolution.
4. HUMAN-INDUCED EVAPORITE KARST
Human activities can play a special role in inducing or enhancing karst processes in evaporite rocks, and the results can be catastrophic. Owing to the rapid dissolution of gypsum, and the extremely rapid dissolution of salt, small to large dissolution cavities can be developed in subsurface evaporites by allowing unsaturated water to flow through or against the rock. Human activity that can cause such cavity development typically involves: (1) construction upon, or directing water into or above, outcropping or shallow gypsum deposits;
or (2) the drilling of boreholes into or through subsurface salt deposits. Human-induced karst problems in gypsum areas are very much like those that are well known in carbonate-karst areas, but human-induced salt karst can have catastrophic effects locally (Walters 1978, 1991; Dunrud and Nevins 1982; Baumgardner et al. 1982; Ege 1984; Coates et al. 1985; Johnson 1987, 1997, 1998). Drilling of boreholes into or through the salt can enable (either intentionally or inadvertently) unsaturated water to enter the borehole and dissolve the salt. If the dissolution cavity is large enough and shallow enough, successive roof failures can cause the water-filled void to migrate upward; this can result in land subsidence or catastrophic collapse, and the creation of surface sinks up to 100 m wide and tens of meters deep. Two industries associated with local salt dissolution and collapse are the solution-mining and petroleum industries, and the references cited above provide some examples of this human-induced collapse.
Solution mining is the process of extracting soluble minerals, such as salt or potash, by (1) introducing a dissolving fluid (i.e., water) into the subsurface, (2) dissolving the mineral (or rock) and forming a brine, (3) recovering the brine, and (4) extracting the mineral from the brine (usually by evaporation) (Johnson 1997, 1998). Solution mining typically entails creating one or several large underground cavities that are filled with brine; the cavities may be in bedded salts, salt domes, or salt anticlines. Cavities typically are lo- 100 m in diameter and are IO-600 m high, both dimensions based largely on the thickness of the salt and the depth to the top of the cavity. At some sites, unfortunately, the cavity becomes too large and the roof collapses. Dunrud and Nevins (198 1) reported 10 areas of solution mining and collapse in the United States.
Most solution-mining collapses result from cavities formed SO-100 years ago, before modem-day engineering safeguards were developed. Proper, modem design has virtually eliminated this problem in new facilities. Four well-documented subsidence/collapse features resulting from solution mining are Cargill sink (Kansas), Grand Saline sink (Texas), Grosse Ile (Michigan), and Tully Valley (New York) (Johnson 1997, 1998).
Petroleum-industry activities that can produce unintentional dissolution cavities include the drilling of exploration, production, or disposal boreholes into, or through, subsurface salt units (Johnson 1997, 1998).
Unintentional dissolution of the salt can create a cavity that is as large and shallow as those created in solution-mining activities. And if the cavity becomes too large for the roof to be self-supporting, successive roof failures may cause a collapse feature to migrate upward and perhaps reach the land surface. The few collapses related to petroleum activity involve boreholes drilled long ago, before development of proper
engineering safeguards pertaining to drilling-mud design, casing placement, and salt-tolerant cements.
Three well-documented subsidence/collapse features resulting from petroleum activities are the Wink sink (Texas), Panning sink (Kansas), and the Gorham oil field (Kansas) (Johnson 1997, 1998).
5. CONCLUSIONS
This report provides a brief overview of the processes and distribution of evaporite karst in the United States. Caves, sinkholes, disappearing streams, and other features typical of karst terranes are present in evaporite deposits throughout the nation. Evaporites are present in 32 of the 48 contiguous states, and karst is known at least locally in almost all of these areas. Evaporite karst is, in most respects, identical to karst in carbonate rocks, except that the process is much more rapid. It is much more widespread than is commonly believed. Human-induced karst results chiefly from mining of, or drilling into, subsurface evaporite deposits. The most conspicuous problems have developed in salt deposits due to solution mining or petroleum activity. Deep-seated dissolution cavities can result in land subsidence or catastrophic collapse, with surface sinks being up to 100 m wide and tens of meters deep.
REFERENCES
Anderson, R.Y., Dean, W.E., Jr., Kirkland, D. W., and Snider, H.I., 1972, Permian Castile varved evaporite sequence, west Texas and New Mexico: Geological Society of America Bulletin, v. 83, p. 59- 87.
Anderson, R.Y., Kietzke, K.K., and Rhodes, D.J., 1978, Development of dissolution breccias, northern Delaware basin, New Mexico and Texas, in Austin, G.S. (compiler), Geology and mineral deposits of Ochoan rocks in Delaware basin and adjacent areas: New Mexico Bureau of Mines and Mineral Resources Circular 159, p. 47-52.
Bachman, G.O., 1976, Cenozoic deposits of southeastern New Mexico and an outline of the history of evaporite dissolution: U.S. Geological Survey Journal of Research, v. 4, no.2, p. 135-149.
Bachman, G.O., 1984, Regional geology of Ochoan evaporites, northern part of the Delaware basin: New Mexico Bureau of Mines and Mineral Resources Circular 184, 22 p.
Baumgardner, R.W., Jr., Hoadley, A.D., and Goldstein, A.G., 1982, Formation of the Wink Sink, a salt dissolution and collapse feature, Winkler County, Texas: Texas Bureau of Economic Geology Report of Investigations No. 114, 38 p.
Black, T.J., 1984, Tectonics and geology in karst development of northern Lower Michigan, in Beck, B.F.
(ed.), Sinkholes: their geology, engineering and environmental impact, Proceedings of the first multidisciplinary conference on sinkholes. Balkema, Rotterdam, p. 87-91.
Black, T.J., 1997, Evaporite karst of the northern Lower Peninsula of Michigan: Carbonates and Evaporites, v. 12, no. 1, p. 81-83.
Bozeman, S., and 9 others, 1987, The D.C. Jester Cave system: Central Oklahoma Grotto, Oklahoma Underground, v. 14, 56 P.
Coates, G.K., Lee, C.A., Mcclain, W.C., and Senseny, P.E., 1985, Closure and collapse of man-made cavities in salt, in Schreiber, B.C., and Hamer, H.L. (eds.), Sixth international symposium on salt. Alexandria, Virginia, The Salt Institute, v. 2, p. 139-157.
Cody, R.D., Anderson, R.R., and Mckay, R.M., 1996, Geology of the Fort Dodge Formation (Upper Jurassic) Webster County, Iowa: Iowa Geological Survey Bureau Guidebook Series No. 19, 74 p.
Dean, W.E., and Johnson, KS. (eds.), 1989, Anhydrite deposits of the United States and characteristics of anhydrite important for storage of radioactive wastes: U.S. Geological Survey Professional Paper 1794, 132 p.
Dunrud, C.R., and Nevins, B.B., 1981, Solution mining and subsidence in evaporite rocks in the United States: U.S. Geological Survey Miscellaneous Investigation Series Map I-1298, 2 sheets.
Eck, W., and Redfield, R.C., 1965, Engineering geology problems at Sanford Dam, Borger, Texas:
Engineering Geology, v. 2, no. 1, p. 15-25.
10
Ege, J.R., 1984, Mechanisms of surface subsidence resulting from solution extraction of salt, in Holzer, T.L, (ed.), Man-induced land subsidence: Geological Society of America, Reviews in Engineering, v. 6, p. Geology 203-22 1.
Elowski, R.C., and Ostrander, A.C., 1977, Gypsum karst and related features in the Michigan basin, in Official 1977 guidebook, Alpena, Michigan: National Speleological Society, p. 3 1-4 1,
Friedman, G.M., 1997, Solution-collapse breccias and paleokarst resulting from dissolution of evaporite rocks, especially sulfates: Carbonates and Evaporites, v. 12, no. 1, p. 53-63.
George, A.I., 1977, Evaluation of sulfate water quality in north-central Kentucky karst, in Dilamarter, R.R.
and Csallany, S.C. (eds.), Hydrologic problems in karst regions. Western Kentucky University, Bowling Green, Kentucky, p. 340-356.
Gustavson, T.C., and Finley, R.J., 1985, Late Cenozoic geomorphic evolution of the Texas Panhandle and northeastern New Mexico-case studies of structural controls on regional drainage development: Texas Bureau of Economic Geology Report of Investigations 148, 42 p.
Hill, C.A., 1996, Geology of the Delaware basin, Guadalupe, Apache, and Glass Mountains, New Mexico and West Texas: Permian Basin Section-SEPM Publication 96-39, 480 p.
Hite, R.J., and Lohman, S.W., 1973, Geologic appraisal of Paradox basin salt deposits for waste emplacement: U.S. Geological Survey Open-File Report 4339-6, 75 p.
Johnson, K.S., 1981, Dissolution of salt on the east flank of the Permian basin in the southwestern USA:
Journal of Hydrology, v. 54, p. 75-93.
Johnson, K.S., 1987, Development of the Wink sink in west Texas due to salt dissolution and collapse, ill BECK, B.F. and Wilson, W.L. (eds.), Karst hydrogeology: Proceedings of 2nd multidisciplinary conference on sinkholes. Balkema, Rotterdam, p. 127-l 36. Also published in 1989: Environmental Geology and Water Science, v. 14, p. 81-92.
Johnson, K.S., 1989, Salt dissolution, interstratal karst, and ground subsidence in the northern part of the Texas Panhandle, in Beck, B.F. (ed.), Proceedings of the 3rd multidisciplinary conference on sinkholes. Ballkema, Rotterdam, p. 115-l 2 1.
Johnson, K.S., 1990, Hydrogeology and karst of the Blaine gypsum-dolomite aquifer, southwestern Oklahoma: Oklahoma Geological Survey Special Publication 90-5, 3 1 p.
Johnson, K.S., 1992, Evaporite karst in the Permian Blaine Formation and associated strata in western Oklahoma, USA, in Back, W., Herman, JS., and Paloc, H. (eds.), Hydrogeology of selected karst regions: International Association Hydrogeologists, v. 13, Verlag Heinz Heisse Publishing Co.;Hannover, Germany, p. 405420.
Johnson, K.S., 1993, Dissolution of Permian Salado salt during Salado time in the Wink area, Winkler County, Texas, in Love, D.W. (ed.), Carlsbad region, New Mexico and west Texas: New- Mexico Geological Society 44th Field Conference, p. 211-218.
Johnson, K.S., 1996, Gypsum karst in the United States: International Journal of Speleology, v. 25 (334), p.
183-193.
Johnson, K.S., 1997, Evaporite karst in the United States: Carbonates and Evaporites, v. 12, no. 1, p. 2-14.
Johnson, K.S., 1998, Land subsidence above man-made salt-dissolution cavities, in Borchers, J.W. (ed.), Land subsidence case studies and current research: Proceedings of the Dr. Joseph F. Poland symposium on land subsidence: Association of Engineering Geologists Special Publication No.
8, p. 385-392.
Johnson, K.S., and Gonzales, S., 1978, Salt deposits in the United States and regional geologic characteristics important for storage of radioactive waste; Prepared for Union Carbide Corporation, Nuclear Division, Office of Waste Isolation, Y/OWI/SUB-7414/l, 188 p.
Kostick, D.S., 1994, Salt, in Carr, D. D. (ed.), Industrial minerals and rocks, 6th edition: Society for Mining, Metallurgy, and Exploration, Inc., p. 85 l-868.
Krietler, C.W., and Bassett, R.L., 1983, Origin and diagenesis of cap rock, Gyp Hill and Oakwood salt domes, Texas: Texas Bureau of Economic Geology Report of Investigations 13 1, 58 p.
Lambert, S.J., 1983, Dissolution and evaporites in and around the Delaware basin, southeastern New Mexico and west Texas: Sandia National Laboratories, Albuquerque, New Mexico, SAND82- 0461.
Lefond, S.J., 1969, Handbook of world salt resources. Plenum Press, New York, 384 p.
Maley, V.L., and Huftington, R.M., 1953, Cenozoic till and evaporite solution in the Delaware Basin, Texas and New Mexico: Geological Society of America Bull’etin, v. 64, p. 539-546.
Myers, A.J., Gibson, A.M., Glass, B.P., and Patrick, C.R., 1969, Guide to Alabaster Cavern and Woodward County, Oklahoma: Oklahoma Geological Survey Guidebook 15, 38 p.
Neal, J.T., 1995, Supai salt karst features: Holbrook basin, Arizona, in Beck, B.F. (ed.), Karst geohazards:
Proceedings of 5th multidisciplinary conference on sinkholes. Balkema, Rotterdam, p. 53-59.
Neal, J.T., Colpitts, R.M., and Johnson, K.S., 1997, Evaporite-karst features: Holbrook basin, Arizona, in Borchers, J.W. (ed)., Joseph F. Poland symposium on land subsidence: Association of Engineering Geologists.
Parker, J.M., 1967, Salt solution and subsidence structures, Wyoming, North Dakota, and Montana:
American Association of Petroleum Geologists Bulletin, v. 5 1, p. 1929-l 947.
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Powers, D.W., and Hassinger, B.W., 1985, Synsedimentary dissolution pits in halite of the Permian Salado Formation, southeastern New Mexico: Journal of Sedimentary Petrology, v. 55, p. 769-773.
Quinlan, J.F., S mith, R.A., and Johnson, K.S., 1986, Gypsum karst and salt karst of the United States of America, in Atti symposio international sul carsismo nelle evaporiti (Proceedings, international symposium on karst in evaporites): Palermo, Italy, October 27-30, 1985: Le Grotte d’Italia, Series 4, v. 13, p. 73-92.
Sando, W.J., 1988, Madison Limestone (Mississippian) paleokarst: a geologic synthesis, in James, N.P. and Choquette, P.W. (eds.), Paleokarst. Springer-Verlag, New York, p. 256-277.
Saxby, D.B., and Lamar, J.E., 1957, Gypsum and anhydrite in Illinois: Illinois State Geological Survey Circular 226, 26 p.
Simpkins, W.W., Gustavson, T.C., Alhades, A.B., and Hoadley, A.D., 1981, Impact of evaporite dissolution and collapse on highways and other cultural features in the Texas Panhandle and eastern New Mexico: Texas Bureau of Economic Geology Circular 8 1-4, 23 p.
Smith, G.I., Jones, C.L., Cuberttson, W.C., Ericksen, G.E., and Dyni, J.R., 1973, Evaporites and brines, in Brobst, D.A. and Pratt, W.D. (eds.), United States mineral resources: U.S. Geological Survey Professional Paper 820, p. 197-216.
Walters, R.F., 1978, Land subsidence in central Kansas related to salt dissolution: Kansas Geological Survey Bulletin 214, 82 p.
Walters, R.F., 1991, Gorham oil field, Russell County, Kansas: Kansas Geological Survey Bulletin 228, 111 p,
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Geological Survey Mineral Investigations Resource Map MR-33.
Witzke, B.J., Bunker, B.J. and Rogers, F.S., 1988, Eifelian through lower Frasnian stratigraphy and deposition in the Iowa area, central Midcontinent, U.S.A., in McMillan, N.J., Embry, A.F., and Glass, D.J. (eds.), Devonian of the world: Canadian Society of Petroleum Geologists, v. 1, p. 221-250.
Present State and Future Trends of Karst Studies; GDnay, Ford, Johnson&Johnson, 20014JNESCO
CHARACTERISTICS OF POROSITY AND PERMEABILITY ENHANCEMENT IN UNCONFINED CARBONATE AQUIFERS DUE TO THE DEVELOPMENT OF DISSOLUTIONAL CHANNEL SYSTEMS
Stephen R.H. Worthington, Derek C. Ford and Patricia A. Beddows,
School of Geography and Geology McMaster University, Hamilton, ON L8S 4K1, Canada
ABSTRACT
Dissolution processes in unconfined carbonate aquifers result in the creation of networks of channels. We examine four contrasting carbonate aquifers, in Paleozoic dolostone, Paleozoic limestone, Mesozoic chalk, and Cenozoic limestone, to characterize the enhancement of porosity and permeability produced by this dissolution.
In all four cases the channels are found to add little to the porosity, but enhance the permeability of the fractured rock by one to three orders of magnitude. Similar porosity and permeability changes are predicted for all unconfined carbonate aquifers, in both dolostones and limestones, in both allogenic and autogenic settings, and in carbonates of all ages.
1. INTRODUCTION
Carbonate rocks are chemical precipitates. As a consequence chemical processes can affect their permeability and porosity at all diagenetic phases, from deposition through shallow or deep burial to exposure at the surface. During burial there is typically a reduction of the original 40-70% depositional porosity (Choquette & Pray, 1970) to a few percent, or less in the case of deep burial. Porosity enhancement and cave formation can occur to a limited extent in deep settings such as those associated with the maturation of oil. However, the enhancement becomes much more important at the global scale once the carbonate rock is elevated above sea level and sufficient overlying strata are removed that the aquifer becomes unconfined. Unconfined aquifers host approximately 90% of the world’s explored caves (Ford and Williams, 1989; Palmer, 199 l), provide important water resources, and are the sites for almost all important groundwater contamination problems known in carbonate rocks.
Significant enhancement of the permeability is commonly understood to be present where major caves have been explored or where there are abundant karst landforms at the surface. However, there is no consensus among hydrogeologists concerning the proportion of carbonate aquifers that have significant amounts of dissolution-enhanced permeability. For example, Freeze & Cherry (1979, p. 27) give a porosity range of O- 20% for limestone, and 5-50% for karst limestone. Bonacci (1987, p. 47) compiled the data from 20 case studies in different karst aquifers around the world, and found that the effective porosity ranged from 0.17%
to lo%, with a median value of only 1.6%.
In this paper we report on case studies in four different carbonate aquifers in order to illustrate the range of enhancement of porosity and permeability that may occur as a consequence of their karstic dissolution. The four host rocks differ sharply from each other chemically and/or lithologically. However, they are alike in that they have suffered little tectonic deformation (folding or faulting) and, as a consequence, have similar low densities of stress and strain fracturing.
2. TERMINOLOGY
Confusing and contradictory terminology is a major barrier to communication of ideas regarding flow in carbonate aquifers. Meteoric water circulating through an unconfined carbonate aquifer will tend to produce an integrated network of dissolutionally enlarged fractures or fissures. These have been called “channels”
(Choquette & Pray, 1970) “macrofissures” (Reeves, 1979), or “secondary fissures” (Price et al., 1993) and larger examples are known as “conduits” (~1 cm diameter) or “caves” (-~1 m, enterable by people) (White, 1988; Ford & Williams, 1989). The interconnectivity of the enlarged fractures is of prime importance because it creates channel networks. In this account we will use the term “channel” to refer to all interconnected, dissolutional enlargements along joints, faults, bedding planes, etc: this definition encompasses a wide range of aperture, from much less than 1 mm up to several meters.
3. CONCEPTUAL MODELS OF CARBONATE POROSITY AND PERMEABILITY
In order to measure the porosity and permeability of a carbonate aquifer, we first need a conceptual model of it so that the different porosity and permeability components can be sampled representatively. The different modes of flow in carbonate aquifers have been classified in a number of ways. Burdon & Papakis (1963) introduced the term “diffuse circulation” to describe Darcy flow through pores and fissures in carbonates, differentiating it from a second mode of flow, “concentrated circulation.” White & Schmidt ( 1966) suggested the terms “diffuse flow” and “conduit flow.” More recently, Atkinson (1985) divided flow into “diffuse”, “fissure” and “conduit” components, while Quinlan & Ewers (1985) suggested “granular”,
“diffuse”, “fracture” and “conduit” components. Thus a plethora of terms has been used!
The term “double porosity” is becoming commonly applied in hydrogeology to refer to fractured rock aquifers, where flow in both the fractures and the rock matrix needs to be considered. If we add the third element of dissolutional channels then we can simply refer to carbonates as “triple porosity aquifers”
(Worthington, 1994; Quinlan et al., 1996).
Properties of the rock matrix should be sampled from borehole cores or in fresh quarry faces because this avoids the potential problem of near-surface porosity changes that occur during the weathering of natural outcrops of the rock. Samples can be tested with porosimeters and permeameters in the laboratory. Borehole packer tests with small separation of the packers (cl m) can also measure the permeability of the unfractured bedrock.
Fracture permeability is usually assessed by pump, packer, or slug tests in boreholes. These tests measure the aquifer response (usually the change in water level) to a stress such as pumping water or adding or withdrawing a slug of water in the borehole. Fracture porosity can then be calculated by using the Cubic Law with packer test data (Snow, 1968):
b = (12 T u / (p g))O.33
(1)
where b is fracture aperture, T is transmissivity (determined from packer tests), u is dynamic viscosity (0.0179 g/cm/s at 0 degrees C, falling to 0.0080 at 30 degrees) , p is fluid density (1 .O at 0 degrees, 0.996 at 30 degrees) and g is the acceleration due to gravity. Equation 1 assumes that all the flow is in a single, smooth-walled fracture. The roughness of fracture walls means that true width will be somewhat larger than the equation indicates. An alternative method of determining fracture porosity is to use slug or pump tests results combined with observations of fracture spacing in cores or quarry faces.
Dissolutional channel porosity (including conduits and caves) can be calculated in several ways. Atkinson (1977) estimated it from the volume of pre-storm water flushed out of a karst spring following heavy rains, Such water is usually clear, and has lower suspended sediment and higher dissolved sediment concentrations than the floodwater that succeeds it. There are also accurate survey data for many caves, which can be used to estimate cave volume. A third method is to model a channel network, calculating the effective channel aperture from an expression such as:
A=CR/v (2)
where A is the channel cross section area, C is the catchment area of the channel, R 1s the runoff (precipitation minus evapotranspiration), and v is the velocity of flow through the channel. Channel velocity may be approximated by the average from tracer tests between sinks and springs in carbonate aquifers.
Figure 1 shows the results of 2877 such tests that we have compiled from reports around the world. Global average channel flow velocity from these tests is 0.022 m/s (78 m/hr).
-f
0.001 0.01 I 0.1 1 10
Velocity (m/s)
Figure 1. Velocities of 2877 traces between sinking streams and springs in carbonate bedrock.
A critical component of channeling in carbonates is the interconnectivity of the channels. Equation 2 assumes that the channels form a tributary pattern. Recent hardware and mathematical modelling studies, (e.g. Ford et al. 2000, Dreybrodt 199‘6, Gabrovsek and Dreybrodt In Press) suggest that evolving dissolutional channel systems will be interconnected, and this is found to be the case in most known examples of extensive caves. However, their patterns of flow are often not at all clear on cave maps because such maps show both the passages with modem streams and those (usually older) ones that have been abandoned by the streams. A clearer pattern emerges if a map displays just the active flow paths. Three representative channel networks are illustrated in Figure 2, showing only the currently active cave streams in cave systems that have been explored and mapped with particular thoroughness, including much of their water-filled passages (though in each case future cave exploration and mapping may add substantially to the network). Each of these networks supplies an important regional karst spring. Note that in each case the widths of most passages have been exaggerated in order to make them visible; the smaller headwater p&sages are exaggerated in width up to 20 times because the minimum true widths are about 0.5 m.
Exaggeration of passage width to aid comprehension is common in small-scale cave maps, but it leads to the false impression that the explorable caves occupy a significant fraction of the volume of a limestone aquifer.
In each example in Figure 2 it is seen that a number of tributary streams join together in broadly dendrltic patterns. In all three caves both the discharge and (usually) the passage size increase in the downstream direction. Thus channel networks in carbonate aquifers resemble the patterns of surface rivers m many respects. Some caves also branch into distributary passages at their downstream ends, as many normal rivers do at their deltas.
Mapped flow path -- Unmapped flow path Note: the width of the headwaters channels are exaggerated by up to 20 times
N
1 km
A
Wales
Spring
9 Spring
Blue Spring Cave ‘: *If-\
Indiana \ -_-
$ Spring Kingsdale Cave System England
Figure 2. Dendritic channel flow networks in three well-mapped groundwater catchments in carbonate bedrock.
4. FOUR CASE STUDIES OF POROSITY AND PERMEABILITY ENHANCEMENT
The four examples of carbonate aquifers described below illustrate some of the different ways in which the three porosity elements of matrix, fractures and channels have been characterized. These four aquifers provide a wide range of rock type (limestone, dolostone and chalk), age and diagenetic maturity (Paleozoic, Mesozoic and Cenozoic), of type of recharge (allogenic and/or autogenic), and of type and extent of karst landform development upon them.