• Aucun résultat trouvé

A note on the entropy production formula

N/A
N/A
Protected

Academic year: 2021

Partager "A note on the entropy production formula"

Copied!
8
0
0

Texte intégral

(1)

HAL Id: hal-00184182

https://hal.archives-ouvertes.fr/hal-00184182

Submitted on 30 Oct 2007

HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci-entific research documents, whether they are pub-lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers.

L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

A note on the entropy production formula

Vojkan Jaksic, Claude-Alain Pillet

To cite this version:

Vojkan Jaksic, Claude-Alain Pillet. A note on the entropy production formula. Contemporary math-ematics, American Mathematical Society, 2003, 327, pp.175-180. �hal-00184182�

(2)

Vojkan Jakˇsi´c

1

and Claude-Alain Pillet

2,3 1

Department of Mathematics and Statistics

McGill University

805 Sherbrooke Street West

Montreal, QC, H3A 2K6, Canada

2

PHYMAT, Universit´e de Toulon

B.P. 132, 83957 La Garde Cedex, France

3

FRUMAM

CPT-CNRS Luminy, Case 907

13288 Marseille Cedex 9, France

September 11, 2002

Abstract

We give an elementary derivation of the entropy production formula of [JP1]. Using this derivation we show that the entropy production of any normal, stationary state is zero.

1

Introduction

LetO be a C∗- algebra,E(O) the set of all states on O and ω ∈ E(O). We assume that there

exists a referenceC∗- dynamicsσt

ω on O such that ω is a (σω, −1)-KMS state. We denote by

δω the generator of σωt (i.e. σωt = etδ ω

) and by D(δω) its domain. Let (Hω, πω, Ωω) be the

GNS-representation of the algebraO associated to the state ω.

A stateη ∈ E(O) is called ω- normal if there exists a density matrix ρη onHωsuch that, for all

A ∈ O, η(A) = Tr(ρηπω(A)). Let Nωbe the set of allω- normal states on O.

(3)

2

For η ∈ Nω, we denote by Ent(η|ω) the relative entropy of Araki [Ar1, Ar2]. (We use the

notational convention for relative entropy of [BR, Don].) Ifη 6∈ Nω, we setEnt(η|ω) = −∞.

For unitaryU ∈ O and η ∈ E(O), we denote by ηU the stateηU(A) ≡ η(U∗AU). The main

result of this note is:

Theorem 1.1 For any unitaryU ∈ O ∩ D(δω) and any η ∈ E(O),

Ent(ηU|ω) = Ent(η|ω) − iη(U∗δω(U)). (1.1)

As we shall explain below, Theorem 1.1 is a natural generalization of the entropy production formula derived in [JP1, JP2]. The method of proof we will use in this note, however, is quite different from the one in [JP1]. We will reduce the proof of Theorem 1.1 to a fairly elementary application of some well known identities in Araki’s theory of perturbation of KMS structure. The proof in [JP1], based on Araki-Connes cocycles, was technically more involved and re-stricted to faithful statesη ∈ Nω.

We now relate Equ. (1.1) to the entropy production formula of [JP1, JP2]. Assume that there exists aC∗- dynamics τt on O and that ω is τ - invariant. Let V (t) be a time-dependent local

perturbation, that is,V (t) is norm-continuous, self-adjoint, O- valued function on R (the time-independent case of [JP1] of course follows by settingV (t) ≡ V ). The perturbed time evolution

is the strongly continuous family of∗- automorphisms of O given by the formula

τVt(A) ≡ τt(A) +X n≥1 in Z t 0 dt1 Z t1 0 dt2· · · Z tn−1 0 dtn[τtn(V (tn)), [· · · , [τt1(V (t1)), τt(A)]]].

In the interaction representation,τt

V is given by

τVt(A) = ΓtVτt(A)Γt∗V,

whereΓt

V ∈ O is a family of unitaries satisfying the differential equation

d dtΓ

t

V = iΓtVτt(V (t)), Γ0V = 1.

Theorem 1.1 then has the following immediate corollary (see also Theorem 4.8 in [JP2]):

Corollary 1.2 Assume thatω is τ - invariant and that Γt

V ∈ D(δω). Then, for any η ∈ E(O),

(4)

From now on we will consider the time-independent case V (t) ≡ V . If V ∈ D(δω), then Γt V ∈ D(δω) and d dtΓ t Vδω(Γt∗V) = −iτVt(δω(V )). (1.3)

Hence, (1.2) reduces to the entropy production formula of [JP1]:

Ent(η ◦ τVt|ω) = Ent(η|ω) − Z t

0

η ◦ τVs(δω(V )) ds. (1.4)

We emphasize that the above derivation of (1.4) allows for non-faithfulη.

The entropy production of a stateη ∈ E(O) was defined in [JP1, JP2] by EpV(η) ≡ η(δω(V )),

see also [OHI, O1, O2, Ru, Sp]. On physical grounds, it is natural to conjecture that ifη is

ω-normal andτV- invariant, then EpV(η) = 0. For faithful η this was proven in [JP1]. Here, we

establish this result in full generality.

Theorem 1.3 Assume thatω is τ - invariant, that V ∈ D(δω) and that η is τV- invariant and

ω- normal. Then,

EpV(η) = 0.

Remark. If Ent(η|ω) > −∞, then Theorem 1.3 is an immediate consequence of Equ. (1.4).

The caseEnt(η|ω) = −∞ requires a separate and somewhat delicate argument.

The results of this note were announced in the recent review [JP2] where the interested reader may find additional information and references about entropy production and its role in non-equilibrium quantum statistical mechanics.

Acknowledgment. The research of the first author was partly supported by NSERC. A part of

this work has been done during the visit of the second author to the McGill University which was supported by NSERC.

2

Proof of Theorem 1.1

We assume that the reader is familiar with basic results of Tomita-Takesaki modular theory as discussed, for example, in [BR, DJP, Don, OP].

Let Mω ≡ πω(O)′′ be the enveloping von Neumann algebra. Sinceω is (σω, −1)-KMS state,

the vectorΩωis separating for Mω, and we denote byP, J, ∆ωthe corresponding natural cone,

modular conjugation and modular operator. We recall that∆ω = eLω, whereLω is the unique

self-adjoint operator onHω such that

πω(σtω(A)) = eitL ω

(5)

4

In particular,σt

ωextends naturally to aW∗- dynamics on Mω which we again denote byσωt. In

this contextσt

ω is called modular dynamics.

Any stateη ∈ Nω has a unique normal extension to Mω which we denote by the same letter.

Obviously, η is ω- normal iff ηU is ω- normal for all unitaries U ∈ O and so, in the proof of

Theorem 1.1, we may restrict ourselves toω- normal η’s.

We will use the fact that ifγ : Mω 7→ Mωis a∗- automorphism, then

Ent(η ◦ γ|ω ◦ γ) = Ent(η|ω).

In particular,

Ent(ηU|ω) = Ent(η|ωU∗).

LetΨU∗ be the unique vector representative of the stateωU∗ in the coneP. A simple

computa-tion shows that

ΨU∗ = πω(U∗)Jπω(U∗)Ωω.

We will considerP ≡ πω(−iU∗δω(U)) as a local perturbation of the modular group σtω. Letαt

be the locally perturbedW∗- dynamics,

αt(A) ≡ eit(Lω+P )Ae−it(Lω+P )= ΘtPσωt(A)Θt∗P,

whereeit(Lω+P )

e−itLω ≡ Θt

P ∈ Mω is a family of unitaries satisfying

d dtΘ

t

P = iΘtPσωt(P ), Θ0P = 1. (2.5)

Letψ be the unique (α, −1)-KMS state on Mω. By the Araki theory,Ωω ∈ D(e(Lω+P )/2) and

the unique vector representative ofψ in the natural cone P is

Ψ = e (Lω+P )/2 Ωω ke(Lω+P )/2Ω ωk .

Another fundamental result of Araki’s theory is the relation

Ent(η|ψ) = Ent(η|ω) + η(P ) − log ke(Lω+P )/2Ωωk2, (2.6)

which holds for allω- normal states η. (For η faithful, this relation was proven in [Ar1, Ar2], see

also [BR]. Its extension to generalη was obtained in [Don], see also the next section). Hence,

to finish the proof it suffices to show thate(Lω+P )/2

ω = ΨU∗.

We setTt≡ Uσt

ω(U) and observe that

d dtT

t= iTtσt

(6)

Comparison with Equ. (2.5) immediately leads toπω(Tt) = ΘtP and therefore

eit(Lω+P )

Ωω = πω(Tt)eitLωΩω

= πω(U∗)eitLωπω(U)Ωω.

(2.7)

Since the vector-valued functionz 7→ eiz(Lω+P )Ωωis analytic inside the strip−1/2 < Im z < 0

and strongly continuous on its closure, analytic continuation of the identity (2.7) toz = −i/2,

yields

e(Lω+P )/2

Ωω = πω(U∗)∆1/2ω πω(U)Ωω

= πω(U∗)Jπω(U∗)Ωω

= ΨU∗,

which is the desired relation.

3

Proof of Theorem 1.3

LetΩη be the vector representative ofη in the natural cone P. The standard Liouvillean

associ-ated to the dynamicsτt

V isLV = L + πω(V ) − Jπω(V )J, where L is the standard Liouvillean

associated toτt. We recall thatL and L

V are uniquely specified by

πω(τt(A)) = eitLπω(A)e−itL, LΩω = 0,

and

πω(τVt(A)) = eitLVπω(A)e−itLV, LVΩη = 0.

We denote bysη the support of the stateη and set s′η = JsηJ. Obviously

sηΩη = s′ηΩη = Ωη,

and sinceη is τV- invariant

eitLVsη = sηeitLV, eitLVs′η = s′ηeitLV.

Let∆ω|η be the relative modular operator. We recall thatKer ∆ω|η = Ker s′η,

J∆1/2ω|ηAΩη = s′ηA∗Ωω,

for allA ∈ Mωand that∆ω|ηis essentially self-adjoint on MωΩη + (1 − s′η)Hω. Hence

∆ω◦τt V|η◦τ t V = e −itLV ω|ηeitLV,

(7)

6

and sinceη is τV- invariant,

eitLV

∆ω|ηe−itLV = ∆ω◦τ−t

V |η = ∆ωU∗|η,

whereU∗ ≡ Γt V.

As in the proof of Theorem 1.1, we setP ≡ πω(−iU∗δω(U)) and denote by α the perturbation

of the modular dynamicsσω byP . It follows that ωU∗ is the unique(α, −1)-KMS state. Since

also ke(Lω+P )/2

Ωωk = 1, the basic perturbation formula of Araki-Donald (see Lemma 5.7 in

[Don]) yields

s′ηlog ∆ωU∗|η = s′ηlog ∆ω|η − s′ηP.

Hence,

eitLVs′ηlog ∆ω|ηe−itLV = s′ηlog ∆ω|η− s′ηP,

and we conclude that for any real numberλ 6= 0, eitLV s′ηlog ∆ω|η + iλ

−1

e−itLV = s′ηlog ∆ω|η − s′ηP + iλ

−1 .

Sincee−itLV

η = Ωη, the second resolvent identity yields that for all realλ 6= 0,

(Ωη, (s′ηlog ∆ω|η+ iλ)−1s′ηP (s′ηlog ∆ω|η − s′ηP + iλ)−1Ωη) = 0.

Since s − lim λ→∞ iλ s ′ ηlog ∆ω|η + iλ −1 = 1, and s − lim λ→∞ iλ s ′ ηlog ∆ω|η− s′ηP + iλ −1 = 1, we derive that (Ωη, P Ωη) = (Ωη, s′ηP Ωη) = 0.

On the other hand, using Equ. (1.3), we get

P = πω(−iU∗δω(U)) = −

Z t

0

πω(τVs(δω(V ))) ds,

and sinceη is τV- invariant we conclude that

0 = (Ωη, P Ωη) = −

Z t

0

η ◦ τVs(δω(V )) ds = −tη(δω(V )),

(8)

References

[Ar1] Araki, H.: Relative entropy of states of von Neumann algebras. Publ. Res. Inst. Math. Sci. Kyoto Univ. 11, 809 (1975/76).

[Ar2] Araki, H.: Relative entropy of states of von Neumann algebras II. Publ. Res. Inst. Math. Sci. Kyoto Univ. 13, 173 (1977/78).

[BR] Bratelli, O., Robinson, D.W.: Operator Algebras and Quantum Statistical Mechanics

2. Springer-Verlag, Berlin (1987).

[DJP] Derezinski, J., Jakˇsi´c, V., Pillet, C.-A.: Perturbation theory ofW∗- dynamics,

Liouvil-leans and KMS-states. Submitted, mp-arc 01-440.

[Don] Donald, M.J.: Relative Hamiltonians which are not bounded from above. J. Func. Anal.

91, 143 (1990).

[JP1] Jakˇsi´c, V., Pillet, C.-A.: On entropy production in quantum statistical mechanics. Com-mun. Math. Phys. 217, 285 (2001).

[JP2] Jakˇsi´c, V., Pillet, C.-A.: Mathematical theory of non-equilibrium quantum statistical mechanics. J. Stat. Phys. 108, 787 (2002).

[OHI] Ojima, I., Hasegawa, H., Ichiyanagi, M.: Entropy production and its positivity in non-linear response theory of quantum dynamical systems. J. Stat. Phys. 50, 633 (1988). [O1] Ojima, I.: Entropy production and non-equilibrium stationarity in quantum dynamical

systems: physical meaning of Van Hove limit. J. Stat. Phys. 56, 203 (1989).

[O2] Ojima, I.: Entropy production and non-equilibrium stationarity in quantum dynami-cal systems, in Proceedings of international workshop on quantum aspects of optidynami-cal

communications. Lecture Notes in Physics 378, 164, Springer-Verlag, Berlin (1991).

[OP] Ohya, M., Petz, D.: Quantum Entropy and its Use. Springer-Verlag, Berlin (1993). [Ru] Ruelle, D.: Entropy production in quantum spin systems. Commun. Math. Phys. 224,

3 (2001).

[Sp] Spohn, H.: Entropy production for quantum dynamical semigroups. J. Math. Phys. 19, 227 (1978).

Références

Documents relatifs

13: Configurational entropy for PVAc as a function of temperature for the experiment 3 with 60 h of aging such as described in table I, obtained by integration over temperature

An entropy estimate based on a kernel density estimation, In Limit theorems in probability and Kernel-type estimators of Shannon’s entropy statistics (P´ ecs, 1989), volume 57

Notably, this note clearly exhibits that the non-smoothness of the fundamental diagram does not change the properties of the LWR solutions: (i) existence of a unique entropy

As a starting point of analysis, a segmentation is often used; in [27], automatic segmentations, based on pulse-coupled neural network (PCNN) for medical images have been

The summary is as follows: so far as the static hys- teresis is concerned, it has been shown, in some sim- plified cases, that, though eddy currents or heat flow

We show that the entropy production in small open systems coupled to environments made of extended baths is predominantly caused by the displacement of the environment from

In an essential and quite general setup, based on networks, we identify Schnakenberg’s observables as the constraints that prevent a system from relaxing to equilibrium, showing

If the domain of every world is the same, it may well happen that one of the objects of the actual world satisfi es fortuitously some given character- izing properties intended