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Surface-induced spin state locking of the [Fe(H2B(pz)2)2(bipy)] spin crossover complex

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Academic year: 2021

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Figure 1. Scanning Tunneling Microscopy images of different [Fe(H 2 B(pz) 2 ) 2 (bipy)] film thicknesses on Au(111) (a) sub-monolayer coverage at room temperature, I t = 0.3 nA, V b = -0.5 V, (b) Bilayer islands of [Fe(H 2 B(pz) 2 ) 2 (bipy)] at 77 K, I
Figure 2. X-ray photoemission of the Fe 2p core level for increasing [Fe(H 2 B(pz) 2 ) 2 (bipy)] film thicknesses on Au(111) (a) (i)A bilayer coverage at room temperature, corresponding to figure 1d (ii) 7±3 monolayer thick film at room temperature corre
Figure 3. Temperature dependent XPS of a bilayer [Fe(H 2 B(pz) 2 ) 2 (bipy)] thin film on Au(111) (a) Fe 2p core level spectra at room temperature for as grown film (b) Fe 2p core level spectra at 100 K (c) Fe 2p core level spectra after
Figure 4. (a)The temperature dependent X-ray absorption spectra of a bilayer [Fe(H 2 B(pz) 2 ) 2 (bipy)]film on Au(111) versus temperature, (b) The temperature dependence of the relative empirical unoccupied “e g /t 2g ” state ratio extracted from XAS fo

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