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Investigation of the luminescence of [UO<sub>2</sub>X<sub>4</sub>]<sup>2-</sup> (X=Cl, Br) complexes in organic phase using time-resolved laser-induced fluorescence spectroscopy and quantum chemical simulations

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FIG. 1: Structures of [R 4 N] 2 [UO 2 X 4 ] complexes ([R 4 N]
FIG. 2: Recorded time-resolved luminescence spectra of [Bu 4 N] 2 [UO 2 Cl 4 ] in acetone (the maxima taken from Görller-Walrand et al
TABLE I: Ground- and Excited State Geometries of [UO 2 X 4 ] 2– (X = Cl, Br) Compared to Selected Previous Results R U−O yl , Å R U−X , Å Compound/media Method Ref.
TABLE III: Ground- and Excited-State Geometries of the [R 4 N] 2 [UO 2 Cl 4 ] Compounds Compared to Selected Experimental Results
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