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Photoelectron Spectroscopy of Vinyl Bromide and Intramolecular Dynamics of the ionic B state.

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Figure

Fig.  1: (a)  Deconvoluted  He(I)-photoelectron  spectrum  of  C 2 H 3 Br  recorded  between  9.0  and  20.0  eV  and  (b)  threshold-photoelectron spectrum of C 2 H 3 Br recorded between 9.0 and 25.0 eV photon energy
Fig. 2: Expanded energy scale for the He(I)-photoelectron spectrum of (a) the  X ~ 2
Fig.  3:  Threshold-photoelectron  spectrum,  He(I)-photoelectron  spectrum  and  photoabsorption  spectrum  of  C 2 H 3 Br recorded between 9.6 and 10.8 eV photon energy
Fig.  4:  Schematic  representation  of  the  optically  active  normal  modes  of  the  X  state  of  the  C 2 H 3 Br +   ion  calculated at the UHF/6-311+G* level
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