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Cooperative WebLab in chemical engineering between

France and Brazil: Validation of the methodology

Marion Alliet-Gaubert, Galo Carrillo Leroux, Charles D.F. de Jesus, Antonio

J.G. Cruz, David Rouzineau, Roberto C. Giordano, Xavier Joulia, Claudio

A.O. Nascimento

To cite this version:

Marion Alliet-Gaubert, Galo Carrillo Leroux, Charles D.F. de Jesus, Antonio J.G. Cruz, David

Rouzineau, et al.. Cooperative WebLab in chemical engineering between France and Brazil:

Vali-dation of the methodology. Education for Chemical Engineers, Elsevier, 2012, vol. 7, pp. e7-e13.

�10.1016/j.ece.2011.09.001�. �hal-00878668�

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Carrillo and De Jesus, Charles D.F. and Cruz, Antonio J.G. and

Rouzineau, David and Giordano, Roberto C. and Joulia, Xavier and

Nascimento, Claudio A.O. Cooperative WebLab in chemical

engineering between France and Brazil: Validation of the methodology.

(2012) Education for Chemical Engineers, vol. 7 (n° 1). pp. e7-e13.

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Cooperative

WebLab

in

chemical

engineering

between

France

and

Brazil:

Validation

of

the

methodology

Marion

Alliet-Gaubert

a,∗

,

Galo

Carrillo

LeRoux

b

,

Charles

D.F.

de

Jesus

c,1

,

Antonio

J.G.

Cruz

c

,

David

Rouzineau

a

,

Roberto

C.

Giordano

c

,

Xavier

Joulia

a

,

Claudio

A.O.

Nascimento

b

aUniversitédeToulouseINPT-ENSIACET,4,AlléeEmileMonso,BP44362,310030Toulouse,Cedex04,France

bDepartamentodeEngenhariaQuímica,EscolaPolitécnicadaUniversidadedeSãoPaulo,Av.Prof.LucianoGualberto,Trav.3,380,

05508-900SãoPaulo,SP,Brazil

cDepartamentodeEngenhariaQuímica,UniversidadeFederaldeSãoCarlos,RodoviaWashingtonLuis(SP310),km235,13565-905São

Carlos,SP,Brazil

a

b

s

t

r

a

c

t

AWebLabisanexperimentoperatedremotelyviaInternet.Besidesthestrictlytechnicalaspectsofsuchan experi-ment,whichmaycontributetothelearningofChemicalEngineeringfundamentals,thereisalsoimportantfeedback whenteamsofstudentsoftwodifferentcountriesareworkingtogether:theWebLabbecomesanintercultural expe-rience,enhancingthecommunicationskillsofthestudents.AWebLabbetweenUniversidadeFederaldeSãoCarlos (DEQ/UFSCar)andtheEcoleNationaleSupérieured’IngénieursenArtsChimiquesetTechnologiques(ENSIACET)is presentedinthiswork.Amasstransferexperimentinabenchscalereactor(stirredandaerated)hadtobestudiedby mixedteams,thusemulatingchallengesthatwillbecommoninfutureworkingenvironments.Inordertoperform theexperiment,studentsinBrazilandinFrancewereputintogroups.Thestudentshadtomakedecisionsaboutthe procedureforexecutingtheexperiments.Allthestudentswereabletocontroltheequipment,nomatterwherethey werephysically.Studentscommunicatedusingvideoconferencesoftware.Thestudents’andteachers’opinionsof thisexperiencewereverypositive.Thismethodologyisanimportantcontributiontotheeducationofengineersin aworldintegratedbymoderncommunicationtechnologies.

Keywords: CooperativeWebLab;Internetexperiment;Chemicalengineering;iLabs

1.

Introduction

Onlinelaboratories(“WebLabs” or“iLabs”)are experimental setupsthatcanbeaccessedthroughtheInternetfroma reg-ularwebbrowser.iLabwasborninmicroelectronicsclasses taughtbytheelectricalengineeringprofessorJesusdelAlamo ofMIT,in1998(iLabprojecthomepage,2011).Fromtimeto time,thisconceptisusedbyotherdisciplineslikechemical engineering(HenryandKnight,2003;Kleinetal.,2005;Shin etal.,2002).

Correspondingauthor.Tel.:+33534323630;fax:+33534323399.

E-mailaddresses:Marion.Alliet@ensiacet.fr(M.Alliet-Gaubert),galoroux@usp.br(G.C.LeRoux),cdfcdf2@yahoo.com, charles.jesus@bioetanol.org.br(C.D.F.deJesus),ajgcruz@ufscar.br(A.J.G.Cruz),David.Rouzineau@ensiacet.fr(D.Rouzineau), roberto@ufscar.br(R.C.Giordano),Xavier.Joulia@ensiacet.fr(X.Joulia),oller@usp.br(C.A.O.Nascimento).

Received13July2011;Receivedinrevisedform12September2011;Accepted15September2011

1 CurrentlyatCTBELaboratórioNacionaldeCiênciaeTecnologiadoBioetanol,RuaGiuseppeMáximoScolfaro,n10.000BairroGuará,

DistritodeBarãoGeraldo,Campinas,SP,Brazil.

InaworkshopaboutWebLabsinChemicalEngineeringthat tookplaceinCambridge,UK(SelmerandKraft,2011;Moros, 2005),threemainkindsofWebLabusewerefoundtobethe mostpromising:

1. Verysmallsetupsofafewcentiliters(Moros,2005;Selmer etal.,2005)thatdonotneedtobelocallysupervised.Their main advantageis more convenient access to the labs. Experimentscanbecarriedoutfromanywhereatanytime. 2. Pilot-scalesetupsfromafewliterstotensofliters,which

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Fig.1– ExperimentalsetupusedforkLadetermination.

areconductedbytwogroupsofpeople:onegroupclose totheequipment,theotheranywhereintheworld.Their mainadvantagesare,first,toenabletheplanttobe oper-atedfromfarawayasisincreasinglydoneinindustryand, second,topromoteinterculturalexchanges.

3. Specific experiments that are used few times and are expensive.Morepeoplecanaccesssuchequipment,thus contributingtoitsfinancialequilibrium.

An experimental setup for the determination of mass transfer coefficient was prepared for remote experiments attheLaboratoryforDevelopment and Automationof Bio-chemical Processes (LaDABio) of the Chemical Engineering Department of the Universidade Federal de São Carlos (DEQ/UFSCar)withthesupportoftheKyateraprogram.This programwasestablishedbytheSãoPauloStateAgencyfor Research Development (FAPESP) to study and develop the useoftechnologyandapplicationsinadvancedInternetfor research and educational purposes (KyaTera). One of the projectsthatoriginatedinKyateraisthe“ClusterofWebLabs forChemical and BiochemicalProcess Engineering”,which aimstodevelopasetofrealexperiments,availablethrough theInternet,forchemicalengineeringstudentsat undergrad-uatelevel.OtherKyaTeraprojectsandtheannualreportcan befoundathttp://www.kyatera.fapesp.br.

In order to validate the methodology, a WebLab was implementedbetweenLaDABioandtheProcessEngineering DepartmentoftheEcoleNationaleSupérieured’Ingénieursen ArtsChimiquesetTechnologiques(ENSIACET).

OneofthemainobjectivesofthisWebLabexperimentisto offerstudentsinterculturalexperiencewhileenhancingtheir communication skills.Atthe same time, atechnical prob-lemhastobesolvedbyheterogeneousteams,thusemulating challengesthatwillbecommonintheirfuturework environ-ment.And,last but notleast, eventhoughtheobjective of thisWebLabisnottoreplaceactualexperiments,ithelpsin theassimilationofconceptsconcerningChemical Engineer-ingfundamentals.Toachievethesegoals,thestudentsofboth countriesarerequiredtoworkinsynergy.

During 4differentsessions,14 students from ENSIACET and8studentsfromDEQ/UFSCarwereinvitedtostudya sys-temphysicallylocatedatLaDaBiousingremoteaccess.The WebLabconsistedofamasstransferexperimentina bench-scale reactor(stirredand aerated). Theexperimentapplied thegassing-outdynamicmethodtodeterminethevolumetric

oxygenmasstransfercoefficient(kLa)fordifferentconditions

ofstirringandaeration.

Inordertoperformtheexperiment,twostudentsinBrazil andthreeorfourinFranceworkedasagroup,supervisedby teachersofeachcountry.Thestudentshadtodecideonthe measurementsthatweretobemadeandontheexperimental protocols(whocontrolswhat).AsonlythestudentsinBrazil wereabletointeractphysicallywiththesystem,web-cameras wereinstalledinordertoallowthestudentsinFranceto fol-lowthe experimentvisually.Studentscommunicated using conventionalvideoconferencesoftware.

Each student was invited to answer a questionnaire intended to assess his/her expectations before the experi-ment,and anotheroneafterthe finalreportwasreturned. Thisworkcompilestheopinionsofthestudentsand teach-ersinordertosketchaportraitofthepedagogicalimpactof thistypeofexperiment.

2.

Determination

of

mass

transfer

coefficient

(k

L

a

):

theory

Duringtheaerobicgrowthofmicroorganismsorcellsintank bioreactors,thelevelofdissolvedoxygenmustbekepthigh enoughfortheorganismstothrive.Itisimportantforfuture (bio-)chemicalengineerstomasterthefundamentalsofmass transferinvolved,andalsotobecomeacquaintedwith tech-niques forassessingrates ofoxygen transferfrom thegas phaseintotheliquidculturemedium.

The method usedin the WebLab to determine kLa was

the unsteady statemethod (“Gassing-out Method”). In this method, the dissolved oxygen is removed from the liquid phasebyspargingnitrogenintothemedium.Whenthe dis-solvedoxygenconcentration(DO)reachesavalueofzero,the nitrogenfeedisinterruptedandtheairflowisrestarted.DO ismonitoreduntilthesolutionisnearlysaturated.Assuming idealmixingintheliquidphase,themassbalanceforDOin theliquidphaseduringthere-aerationcanbeexpressedby Eq.(1).

dC

dt =kLa·(C

−C) (1)

whereC*istheDOsaturationconcentrationandCistheDO concentration

Eq.(1)issuitablewhenfastprobesareemployed.Ifafast probeisnotavailable,thedynamicsoftheelectrodeshould

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Fig.2–Photographofthehardwareusedforimplementing theWebLabinLaDABio.

be considered.The response of modern electrodes can be describedasafirst-ordersystem,givenbyEq.(2).

dCe

dt = 1 E(C

−Ce) (2)

whereCeistheDOmeasuredbytheelectrodeandEisitstime

constant.

CombiningEqs.(1)and(2)andsolvingforCe,givesEq.(3).

Ce =Ce0·e−((t−t0)/E)+C

es·(1−e−((t−t0)/E))

+(1/E)·(Ces−C0) (1/E)−kLa

·(e−((t−t0)/E)−e−kLa·(t−t0)) (3) whereC0istheDOconcentration(attimet0),Ce0istheDO

measuredbytheelectrodeatre-aeration(attimet0),Cesisthe

DOconcentrationatsteady-state.

Theparameter kLais estimatedby fitting Eq. (3) tothe

experimental data by means of a nonlinear least-squares algorithm.Foraccurateresults,thecriterionE1/kLais rec-ommended(BadinoJr.etal.,2000).

3.

Experimental

facilities

TheWebLab systemwas implementedemploying National InstrumentshardwarefordataacquisitionandLabVIEW®as

thesupervisorysystem.AsketchoftheimplementedWebLab isshowninFig. 1anda picture ofthe experimentalsetup isshowninFig.2.InTable1,theresourcesavailableforthis WebLabarepresented.

TheuserinterfacewasdevelopedusingLabVIEW7.0and was hosted ina framed web page.This approach allowed theusertoaccessinformationabouttheexperiment(theory, recordeddata,etc.)withoutleavingtheLabVIEWinterface.

Fig.3showsascreenshotoftheprincipal webpageand Fig.4depictsthemaininterfaceoftheexperiment.Attheend ofeachexperimentalsession,thestudentssavedthecollected dataforfurtheroff-lineanalysis,inordertodeterminekLa.

4.

The

exercise

“Gas–LiquidAgitatedTank”isasecond year experimentof ChemicalEngineeringatEcoleNationaled’IngénieursenArts ChimiquesetTechnologiques.Itsaimistogivethestudents indispensable knowledge on stirred tanks. At the present time,therearenoclassesdedicatedtothisspecifictopicbut

thestudentsborrowtheconceptfromvariousothercourses (transportphenomena,masstransfer...).

Theactivitywasdividedintothreeparts:

1. Preparatory experimental work was done, in France, in ordertoenablethestudentstoidentifyandcalculate spe-cificparameters(powernumberNp,kLa)fromexperimental

dataacquiredfroma100Lstirredtank.Thisexperiment wasperformedonlyinFrancebecausethesetupdiffered fromthatinBrazil.StudentsinBrazildidnothavetodo theexperimentbeforehand.

2. AnexperimentalWebLabsession,withaccessandcontrol, inFrance,ofthesystemphysicallylocatedinBrazil. 3. Processingofthedataobtainedduringthe experiments,

analysis of the results obtained and further discussion abouttheimportanceoftheparameterscalculated. For the first part, groups of four French students spent two half-days studying the general behavior of a stirred tank located at AIGEP (Atelier Interuniversitaire de GéniedesProcédés: http://www.inp-toulouse.fr/fr/aussi-sur-le-campus/aigep.html).Partoftheirworkwasdevotedtothe determinationofthepower number(Np)ofaRushton

Tur-bine.TheystudiedtheevolutionofNpfordifferentstirring

speedsandfordifferentfluids(air,water,andwater+air).The secondobjectiveofthepracticalexercisewasthe determina-tionoftheoverallvolumetricoxygenmasstransfercoefficient (kLa)accordingtoEq.(3),forthevariousexperimental

condi-tionstested.Duringalltheseexperiments,specialattention waspaidtothegasholdup(ε),thesizeofthebubblesand thedispersionregime.Fromthedata,thestudentscritically comparedtheirexperimentalresultstoempiricalcorrelations foundinthe literature.BeforetheWebLabsession,the stu-dents received the main guidelines from the teacher and discussedthedifferencesbetweenthetwosystemsandhow tochoosenewexperimentalconditionsinordertoobtain com-parableresults.

For the second part, the French tutor logged on to the WebLab at http://ladabio.deq.ufscar.br and the use of the Graphical UserInterface (developedin LabVIEW®

) was explainedtothestudents.Inordertofacilitatethe communi-cationbetweenthegroups,Skype®chatviawebcamwasused.

First,thestudentsofeachcountryintroducedthemselvesand then,aspartoftheWebLabexperiment,theFrenchstudents statedthepreciseexperimentalconditionstheywantedtotest andexplainedwhytheyhadchosenthem.

During the French access, the Brazilian students acted asasupportinggroup,providinginformationaboutthe sys-temphysicalcharacteristics(e.g.,size,volume)andconditions (e.g.,temperaturebeforeandaftertheexperiment).Afterthe endoftheFrenchsession,theysavedthesamelogfile(for fur-theranalysis)and,whennecessary,accessedtheexperiment totestnewconditionsandtoclarifyanyremainingdoubts.

Throughout the experiments, the students exchanged information and opinions about the phenomena that took placeinthestirredtank.Theirmainconcernswereaboutthe quality ofthemixing, the sizeofthe bubbles andthe var-iousproblemsthat arise duringsuchexperiments(bubbles blockingthetipoftheprobe,highcoalescencephenomena, conditionsofinefficientmixing...).Modelingthedynamical system was part ofthe work, but it was not addressedin thecaseoftheFrenchexperiment.Whenthesystemdidnot respondastheyexpected,thestudentsdecidedcollectively whichparametertheyshouldmodifyusingtheirtheoretical

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Table1–WebLabresources.

Resource Description

Bioreactorandmotor (Bio)reactorwithjacket(ApplikonBV,Switzerland),2Lworkingvolume,motor/impeller(0–1200rpm) Moduleforstirrercontrol Usedtomanipulatethestirrerspeed,4–20mAsignal(ApplikonBV,Switzerland)

Thermostatizedbath Withrecirculation(NovaEtica,Brazil);waterispumpedthroughthebioreactorjacket Massflowcontroller Controlsandmeasuresairflowratesintothebioreactor,4–20mAsignal(Aalborg,USA) DOtransmitter AmplifiesDOprobesignal(Mettler-Toledo,Switzerland)

DOprobe MeasuresDOinthemedium(Mettler-Toledo,Switzerland) Thermoresistance/transmitter Measuresthetemperatureinthemedium(Pt-100,Exacta,Brazil)

Dataacquisition CompactFieldPoint,c-FP2020,withAI,AO,DIandDOmodules(NationalInstruments,USA)

Fig.3–Screenshotofthewebpageaccessedbythestudents. background.Oncetheyhadsetthechosenconditions,thedata

wereloadedthroughtheinterfaceandrecordedinalogfile. Duringtheactivity,itwasclearthatahighlevelof interac-tionoccurredamongthestudents,whotalkedanddiscussed throughouttheirwork.

Aftertheexperimentalsession,thestudentsprocessedthe data collected in order to calculate kLa and wrote generic

reports. Knowing the value of the time constant of the electrode and assuming that the response time could be describedusingafirst-orderequation,thestudentsestimated

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the parameter kLa by fitting a theoretical equation to the

experimentaldatausinganonlinearleastsquaresalgorithm (MS-Excelsolver). Afterthis experiment,the studentswere expectedtobeabletogiveexplanationsforthediscrepancies betweenthemodelandtheexperimentaldata,torealizethat, fortanksofdifferentsizes,relevantparametersdonothave thesameimportance,andtoexplainwhykLavaluesobtained

fromtheBrazilianandFrenchsystemsweredifferent.

5.

Practical

considerations

Theorganizationofthetimetablewasthefirstchallengeto befaced.TheWebLabexperimentcouldonlybeheldbetween themonthsofMarchandAprilduetoAIGEP’sbusy sched-ule.Asthe Brazilianacademicyear beginsinFebruary,the Brazilianstudentsdidnothavetimetobecomeasfamiliar withtheexperimentastheFrenchstudents,whoseacademic yearhadbegun7monthsearlierandwhohaddonearelated experimentafewdaysbefore.Thisdidnotseemtoimpactthe experimenttoomuchbuttheBrazilianteachersmayhavehad togivemoreexplanations.

Thetime delay betweenFrance and Brazil was another challenge.First,itforcedthegroupstoworkatdifferenttimes ofday:afternooninFranceandmorninginBrazil.Inaddition, theWebLabexperimentswerecarriedoutduringtheperiodof changefordaylightsavingtime.Thechangeintime-difference fromfivehourstothreehourscomplicatedtheorganization.

Anotherchallenge concerned the softwareadjustments. AlthoughtheinterfacedevelopedbytheBraziliangroup oper-atesextremelywell,afewproblemsrelatedtothedatatransfer rateoftheInternetconnectionoccurred.Forexample,ifthe videooftheexperimentwasenabled,itwasdifficultto visu-alizewhathappenedinthestirredtankinrealtimebecause ofthedelaybetweenframes.

Thesethreepointsshowthatsomeimprovementsneedto beimplementedandthatverygood“practical”organizationis crucialinordertorunaWebLabexperimentatsuchadistance. Therewasasecond,moresubjectivekindofchallenge.One ofthemainobjectivesofWebLabistoofferintercultural expe-riencetostudents.Itisinterestingtoobservethattherewasa highlevelofinteractionamongthemduringtheactivity:they chattedanddiscussedallthetime.However,thechatwasnot exclusivelyabouttechnicalaspectsoftheexperiment!

Theseexperimentsalsoofferedtheteachersintercultural experienceon their teaching context.Ageneraland previ-ousagreementneededtobefoundbetweenthetwoteachers inordertosupervisethestudentscorrectlyduringtheclass. Fromapedagogicalpointofview,itwasalsohighlyinstructive toseehowtheothersupervisorexplainedthesame phenom-enatohis/herstudents.ItwasnoticedthattheFrenchteachers gaverather moreimportancetothetheory whereas Brazil-ianteachersweremoreconcrete.Moreovertherelationship betweenteachersandstudentsseemedmorefamiliarinBrazil andmoreformalinFrance.

Communicationbetweenteachers,althoughpleasant,was notalwaysobvious.Forexample,thequestionnairesubmitted tothestudentscontaineddifferentquestionsforthetwosides ofthe Atlantic Ocean because culturaldifferences implied timeforadjustment,whichwas notplanned.For example, thechoicesintheanswersweredifferentforculturalreasons: Frenchteacherswantedtheirstudentstoagreeor disagree (avoidingneutralstatements)buthavetheopportunitytonot haveanyopinion,whereasBrazilianinstructorswantedtheir

Table2–QuestionspresentedtotheFrenchstudents.

Q F1 Ienjoydoingthis

QF2 Beingintouchwithstudents8000kmawayis interesting

QF3 Thislaboratoryisinteresting

QF4 Thislaboratoryiswellsituatedinmyeducation program

QF5 Thislaboratoryisrelevanttomyprogram QF6 Thislaboratorywillbedoneagainnextyear Q F7 WebLabwilldevelop

studentshavetheopportunitytopartlyagree,partlydisagree, buttoexpressanopinion.

6.

Students’

opinions

French students answered questionnaires before and after doingtheexperiment.Thesequestionnairescontained ques-tions about the previous relationships of students with foreignersandtheiropinionsabouttheWebLabexperiment. TheselastquestionsarepresentedinTable2andtherelated syntheticanswersareshowninFig.5.Asimilarquestionnaire wasansweredbytheBrazilianstudentsaftertheexperiment. Table3presentsthe questionsinthequestionnaires.Fig.6 showstheanswersoftheBrazilianstudents.

First, Frenchstudents hadalready been abroad,86%for shortperiodsand14%forlongstays.71%thoughtthatthey spoke aforeign languagecorrectlyand29%thattheydidit

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Table3–QuestionspresentedtotheBrazilianstudents.

Q B1 Theactivityhelpedmetoconsolidatetheconcepts exposedintheclassroom

QB2 Theinterfaceusedtocontroltheexperimentwas appropriate

QB3 TheuseofEnglishfacilitatedtheexchangeof informationbetweenthegroups

QB4 Thiskindofactivityhadapositiveimpactonmy academiceducation

QB5 Theuseofremoteexperimentsincreasesstudents’ motivation

Q B6 Theparticipationoftheprofessor/tutorduringthe experimentisimportant

poorly.64%hadhadnoworkingexperiencewithforeigners, 29%hadhadafewmeetingsand7%longtrainingperiods.

FortheiropinionabouttheWebLabexperiment,although thequestionswerenotaskedinthisorder,wehavegrouped theminthree sets:the first concerningwhat theythought about thisnew typeofteaching (Q F1,Q F2and Q F3),the secondhowtheyconsideredthisteachingexperienceinthe context oftheirwhole education program(QF4 and QF5), andthelastwhattheythoughtaboutthefutureofWebLab (QF6andQF7).AscanbeseenonFig.5,theyconsistently likedtheconceptofWebLab.Theyweredividedaboutthe ade-quacyofWebLab totheir educationprogram(thiscould be becausethesestudentswerefromIndustrialEngineeringand theymayhavepreferredcontrolledexperimentstoatypical chemicalengineeringexperiment.Finally,theythoughtthat WebLabshouldbecontinued andwoulddevelop.Moreover, twogroupsofFrenchstudentsreportedthatthisexperience hadencouragedthemtothinkaboutalongtrainingperiodina foreigncountryandmostofthemthoughtthatithelpedthem todemystifytheconceptofworkingwithpeopleoverseas.

Theunderstandingoftechnicalandscientificconceptswas evaluatedthroughareportfortheFrenchstudents(asusual forpracticalworks).There was nosignificant difference in

Fig.6–Brazilianstudents’answers.

learningbetweenthestudentswhichperformedtheWebLab andthosewhofacedactualexperimenttwicemoretime.

AmongtheBrazilianstudents,nonechosetheoptions “Dis-agree”or“Stronglydisagree”foranyquestion.Mostofthem thoughtthatthiskindofactivityhadapositiveimpactontheir education(QB4)and,despiteEnglishnotbeingtheirmother tongue,theythoughttheywere abletocommunicate prop-erly(QB3).ItisinterestingtonotethatnoneoftheBrazilian studentschose“Stronglyagree”forQ B1.Asacomplement, they reinforcedthe importanceofateachertoguide them (QB6).TheyagreedthatthemotivationalaspectoftheWebLab is appealing, but a fewstudents did not enjoythe experi-mentthatmuch(Q B5).Despitesomeconcerns,thestudents approvedtheuserinterfaceusedtocontroltheWebLab(Q B2). Theinterpretationoftheseanswersledtotheconclusion thattheuseofWebLabsfostersinterestinstudents,butthat caremustbetakenwhenpreparingthetheoreticalcontent oftheclassandwhenimplementingtheexperimentandthe userinterfacetocontrolit.

7.

Conclusions

Theimplementation ofWebLabs isnotvery expensiveand offersinterculturalexperiencetostudents, inavarietythat couldnotbeobtainedwithoutthenewcommunication tech-nologies. It emulates challenges that will be common in students’futureworkingenvironment.Theunderstandingof technical and scientific concepts was evaluated through a reportforthe Frenchstudents(asusualforpracticalwork). Therewasnosignificantdifferenceinlearningbetweenthe students who participated in WebLab and those who did not. And, last but not least, without replacing an actual experiment,theinteractiveWebLabhelpstheassimilationof conceptsconcerningChemicalEngineeringfundamentals.As thestudentsofbothcountriesworkinsynergythis method-ology is an important contribution to the development of engineersinaworldintegratedbymodern communication technologies.Evenifitisdifficulttoevaluatethelong-term benefits(forexampleontheinternationalizationofstudent careers), the questionnairesshowed that students’ opinion onthisexperiencewasverypositive.Thisinvolvement cor-respondstoanadditionalmotivation forthe furtheruseof thistechnologyinteachingactivities.

Acknowledgment

TheauthorswouldliketoacknowledgetheKyaTeraProjectof theFundac¸ãodeAmparoàPesquisadoEstadodeSãoPaulo (FAPESP–ProcessNumber03/08155-1).

References

BadinoJr.,A.C.,Facciotti,M.C.R.,Schmidell,W.,2000.Improving

kLadeterminationinfungalfermentation,takingintoaccount

electroderesponsetime.JournalofChemicalTechnologyand Biotechnology75,469–474.

Henry,J.,Knight,C.,2003.Modernengineeringlaboratoriesata distance.IntJ.EngngEd.19(3),403–408.

iLabprojecthomepage,2011.https://confab.mit.edu/ confluence/display/ILAB2/Home(accessed21.03.11). Klein,A.,Hausmanns,C.,Wozny,G.,2005.Web-basedremote

experimentswitharealtechnicalplantinchemical

engineeringeducation.In:AIChEAnnualMeeting,October30 toNovember4,2005,Cincinnati,OH,USA.

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Moros,R.,2005.VIPRATECH,OurWaytoanOnlineLaboratoryin ChemicalEngineeringandUnitOperations,http://como. cheng.cam.ac.uk/pdfs/workshop/ralfmorosws.pdf(accessed 23.03.11).

Selmer,A.,Goodson,M.,Kraft,M.,Sen,S.,McNeill,V.F.,Johnston, B.S.,Colton,C.K.,2005.Performingprocesscontrol

experimentsacrosstheAtlantic.ChemicalEngineering Education39(3),232–237.

Selmer,A.,Kraft,M.,2011.http://como.cheng.cam.ac.uk/conf. workshop.html(accessed23.03.11).

Shin,D.,Yoon,E.S.,Lee,K.Y.,Lee,E.S.,2002.Aweb-based interactivevirtuallaboratorysystemforunitoperationsand processsystemengineeringeducation:issues,designand implementation.ComputersandChemicalEngineering26, 319–330.

Figure

Fig. 1 – Experimental setup used for k L a determination.
Fig. 2 – Photograph of the hardware used for implementing the WebLab in LaDABio.
Fig. 3 – Screenshot of the web page accessed by the students.
Table 3 presents the questions in the questionnaires. Fig. 6 shows the answers of the Brazilian students.
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3.My sister(not – to like ) doesn’t like making posters but she (like)likes talking to students.. My sister doesn’t like making posters but she likes talking

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The activity of writing on antiquities is recorded other times in his manuscripts at the third person : “Pyrrho Ligorio che ha scritta quest'opera (taur.13,f.14)” or “Pyrrho che