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Shrinking droplets in electrospray ionization and their influence on chemical equilibria

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Academic year: 2021

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Figure

Figure 1. Setup with laser-induced fluorescence and phase Doppler anemometry. The argon ion laser is used for fluorescence excitation and as a light source for the phase Doppler anemometer
Figure 2. Droplet size distribution at different spray positions: comparison of positive (a) and negative (b) spraying mode for an acetonitrile solution containing 10 ␮M DCM and oxazine 1
Figure 3. Calculation of changes in the equilibrium for the reaction A ⫹ B ↔ C in a droplet shrinking from 10 to 1 ␮m
Figure 4. Fluorescence maximum for 100 ␮M rhodamine B–sulfonylchloride at different positions within the electrospray plume
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