Ability of nitrones of various structures to control the radical polymerization of styrene mediated by in situ formed nitroxides
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Figure
![Fig. 2. Time dependence of ln ([M] 0 /[M]) for the bulk radical polymerization of styrene at 110 °C [Pre-reaction of nitrone and AIBN in toluene at 85 °C for 4 h; [nitrone 1]=0.19 M and [AIBN]=9.7×10 −2 M (nitrone 1/AIBN:](https://thumb-eu.123doks.com/thumbv2/123doknet/5461944.129218/6.892.103.452.490.746/dependence-radical-polymerization-styrene-reaction-nitrone-nitrone-nitrone.webp)
![Fig. 6. Time dependence of ln ([M] 0 /[M]) for the radical polymerization of styrene at 110 °C in toluene (styrene/toluene: 1/1; v/v) and in bulk, in the presence of PBN [Pre-reaction of nitrone and AIBN in toluene at 85 °C for 4 h; [nitrone]=0.19 M and](https://thumb-eu.123doks.com/thumbv2/123doknet/5461944.129218/10.892.117.801.101.280/dependence-radical-polymerization-toluene-presence-reaction-nitrone-toluene.webp)
![Fig. 8. SEC chromatograms for the bulk polymerization of styrene at 110 °C in the presence of PBN [Pre- [Pre-reaction of PBN and AIBN in toluene at 85 °C for 4 h; [PBN]=0.19 M and [AIBN]=9.7×10 −2 M (PBN/AIBN:](https://thumb-eu.123doks.com/thumbv2/123doknet/5461944.129218/12.892.110.581.94.585/chromatograms-polymerization-styrene-presence-reaction-aibn-toluene-aibn.webp)
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