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Use of Life Cycle Assesment to determine the environmental impact of thermochemical conversion routes of lignocellulosic biomass: state of the art.

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(1)

Methodology:

1. Determine required land and its properties (slope, fertility, etc.)

2. Determine dLUC and iLUC (most likely changes, yield improvement, etc.

in a

regional

context)

3. Determine reference state, duration and final state. The reference state

can be different than the initial state (most likely state, state before any

human activity, etc.)

4. Quantify environmental impacts:

Bibliography

Many studies on the technological aspects of lignocellulosic

biomass, but few on the environmental aspects (LCA ), presented here:

Gasification

Use of Life Cycle Assessment to determine the

environmental impact of thermochemical conversion routes

of lignocellulosic biomass: state of the art

S. Gerbinet, A. Léonard

Laboratory of Chemical Engineering – Sustainable processes and development - University of Liège, Building

B6 – Sart-Tilman, 4000 Liège, Belgium. Saicha.Gerbinet@ulg.ac.be

Biomass

- Limited fossil fuel resources

- Too much energy dependence

First generation:

- High waste

- Low yield

Competition for land / water with

food crops

Lignocellulosic biomass (second generation technologies)

Abundant, cheap, and available in non-food plants: wood and energy

crops such as miscanthus.

Lignocellulosic

biomass

development

Conclusions and perspectives:

Promising processes for substituting fossil fuels. Their environmental impact remains uncertains

LCA methodology

LCA adapted to include land use change effect.

Allow comparison beween biomass development and fossil technologies.

Bibliography

Environmental impact ?

LCA (Life Cycle Assessment)

Introduction

Scope of the study

[2]

New methodological development for Land Use

Change

3 Aspects: Land Occupation (LO) and Direct and Indirect

Land Use Change (dLUC and iLUC).

Fuels

type

Feedstock

dLU

C

Well-

to-wheel

Environmental impact

Eco

Comp

.

fossil

Comp

biofuel

Sensi

-tivity

Unce

rtaint

y

Results

1

FT-diesel

Switchgrass

And/or coal

yes

well-to-tank

GWP

yes

no

no

no

no

GWP

2

FT-diesel

Biomass

/ coal / gas

no

yes

Energy Consumption (EC)

GWP

yes

yes

no

yes

yes

EC

GWP

3

FT-diesel

Biomass

/coal / gas

no

well-to-tank

Energy consumption

GWP

Emissions

no

yes

no

no

no

EC

GWP

Emissions

4

FT-diesel

Biomass

/coal

no

well-to-tank

Cumulative Energy Demand

CED

GWP

no

no

Green

diesel

no

no

CED

GWP

5

FT-diesel Biomass

no

well-to-tank

Energy consumption

GWP

yes

no

Green

diesel

no

no

Cost

GWP

6

Methanol Bagasse

no

well-to-tank

CML and normalization

no

no

no

no

no

7

Methanol

Wood

no

well-to-tank

CO

2

yes

yes

no

no

no

CO

2

if

co-generation but

Cost

8

Hydrogen

Methanol

Biomass

no

well-to-tank

Energy Payback Time

CO

2

yes

yes

yes

no

no

H

2

than methanol

Biofuels

than

fossils

9

FT-diesel

Ethanol

DME

Switchgrass

no

yes

Fossil Energy Consumption

Emission

no

yes

1st

generati

on

no

no

FEC

Emission

10

FT-diesel

Ethanol

Hydrogen

Biomass

/natural gas

/wind (H

2

)

yes

Energy Consumption (EC)

GWP

no

Diesel

gasoil

1st

generati

on

yes

no

EC :

diesel ethanol

GWP

11

1st and

2sd

generatio

n

Biomass

no

well-to-tank

Energy Consumption (EC)

GWP

no

yes

yes

yes

no

2d generation

than

fossil fuel

eco = economic analysis; Comp. = comparison; Result: green environmental indicator :

studied fuel better than the fuel (comparison(s) colon(s))

Studies not complete:

- all aspects never taken into account in one study

- dLUC generally not taken into account – iLUC, never

New studies are necessary  Land Use Change Impact

 Whole Life Cycle

1. Liu, G., et al., Making Fischer-Tropsch Fuels and Electricity from Coal and Biomass: Performance and Cost Analysis. Energy & Fuels, 2011. 25.

2. van Vliet, O.P.R., A.P.C. Faaij, and W.C. Turkenburg, Fischer-Tropsch diesel production in a well-to-wheel perspective: A carbon, energy flow and cost analysis. Energy Conversion and Management, 2009. 50(4): p. 855-876. 3. Gill, S.S., et al., Combustion characteristics and emissions of Fischer-Tropsch diesel fuels in IC engines. Progress in Energy and Combustion Science, 2011. 37(4): p. 503-523.

4. Kalnes, T.N., et al., A Technoeconomic and Environmental Life Cycle Comparison of Green Diesel to Biodiesel and Syndiesel. Environmental Progress & Sustainable Energy, 2009. 28(1): p. 111-120. 5. Sunde, K., A. Brekke, and B. Solberg, Environmental Impacts and Costs of Hydrotreated Vegetable Oils, Transesterified Lipids and Woody BTL-A Review. Energies, 2011. 4(6): p. 845-877.

6. Grillo Reno, M.L., et al., A LCA (life cycle assessment) of the methanol production from sugarcane bagasse. Energy, 2011. 36(6): p. 3716-3726. 7. Kumabe, K., et al., Environmental and economic analysis of methanol production process via biomass gasification. Fuel, 2008. 87(7): p. 1422-1427. 8. Komiyama, H., et al., Assessment of energy systems by using biomass plantation. Fuel, 2001. 80(5): p. 707-715.

9. Wu, M., Y. Wu, and M. Wang, Energy and emission benefits of alternative transportation liquid fuels derived from switchgrass: A fuel life cycle assessment. Biotechnology Progress, 2006. 22(4): p. 1012-1024.

10. Fleming, J.S., S. Habibi, and H.L. MacLean, Investigating the sustainability of lignocellulose-derived fuels for light-duty vehicles. Transportation Research Part D: Transport and Environment, 2006. 11(2): p. 146-159. 11. Reinhardt, G.A. and E.v. Falkenstein, Environmental assessment of biofuels for transport and the aspects of land use Competition. Biomass & Bioenergy, 2011. 35.

12. ISO, ISO 14040 : Management environnemental - Analyse du cycle de vie - Principes et cadre, ISO, Editor. 2006.

13. ISO, ISO 14044 : Management environnemental - Analyse du cycle de vie - Exigences et lignes directrices, ISO, Editor. 2006.

14. Kumar, A., D.D. Jones, and M.A. Hanna, Thermochemical Biomass Gasifiction: A Review of the Current Status of Thechnology. Energies, 2009. 2 15. Warnecke, R., Gasification of biomass: comparison of fixed bed and fluidized bed gasifier. Biomass & Bioenergy, 2000. 18.

Studied culture

Culture A

Culture B

dLUC

iLUC

Ground erosion

and compaction

LO

dLUC and

iLUC

Land avaibility

Ecosystems

Human

Health

Resources

Land avaibility

Change cycle C

(ground)

Change cycle N

(ground)

Change albedo

Eutrophisation

Ground quality

Climate

change

Change C

(biomass)

Previous methodologies

Ground

acidification

EndPoint

MidPoint

Environemental

mechanism

Upstream process

Gas cleaning

and reforming

Biomass pretreatment

-

Size

reduction

-

Drying

Biomass + Oxidizing agent

Syngaz

1. T: 600 – 1000 °C

Heat supply: allothermal or

autothermal

2. Oxidizing agent flow rate

-

Air

-

Oxygen

-

Steam

-

Nitrogen and

sulfur compounds

-

Particle removal

-

Alkali removal

-

Tar elimination

-

Reforming

Methanol

Heavy olefins

Light olefins

Ethylene

Propylene

Chemical

Industry

DME

Lubricating oil and paraffin wax

Diesel

Fuel

Downstream process

MTO: methanol to olefins

Olefins cracking

Hydrocracking

Fischer- Tropsch

synthesis

T: 220 – 250°C

Catalyst: Co or Fe

From methanol: T: 250

365 °C - Catalyst: alumina

From gas: T: 240 °C - P >30 bar - Catalyst

T: 180 – 270 °C

P: 50 -100 bar

Catalyst: Cu/Zn

P

r

o

c

e

s

s

Field 1

Field 2

Field 1

Field 2

Sustainable development

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