L’analyse calorimétrique différentielle ne montre pas de différences de comportement entre les PUI cationomères et leurs précurseurs, témoignant donc d’une très faible séparation

de phases dans ces matériaux avant et après quaternisation. Cependant, la masse volumique

des PUI cationomères est généralement légèrement supérieure à celle des précurseurs. La

masse volumique de ces nouveaux matériaux augmente avec le nombre de sites cationiques

pour des teneurs variant entre 0,2 et 0,7 équivalent, et la masse molaire du contre-ion dans le

cas des contre-ions halogénures. En revanche, on montre que la longueur de la chaîne alkyle

latérale n’a pas d’effet sur la masse volumique de ces cationomères pour des chaînes de C

1

à

C

6

.

V- Références bibliographiques

1. Al-Salah, H. A., Synthesis and characterization of ion-containing

poly(urethane-urea-imide) block copolymers, Journal of Macromolecular Science : Pure and Applied Chemistry,

1998, A35, 763-780.

2. Jonquières, A., Roizard, D., Cuny, J., Vicherat, A. and Lochon, P., Polarity

measurements in block copolymers (polyurethaneimides) and correlation with their

pervaporation features, Journal of Applied Polymer Science, 1995, 56, 1567-1579.

3. Jonquières, A., Roizard, D., Cuny, J. and Lochon, P., Solubility and polarity

parameters for assessing pervaporation and sorption properties. A critical comparison for

ternary systems alcohol/ether/polyurethaneimide, Journal of Membrane Science, 1996, 121,

117-133.

4. Ötvös, L., Marton, J. and Meisel-Agoston, J., Investigation of the reaction between

isocyanates and acid anhydrides with

¹⁴

C, Tetrahedron Letters, 1960, 2, 15-18.

5. Meyers, R. A., The polymerization of pyromellitic dianhydride with diphenylmethane

diisocyanate, Journal of Polymer Science, Part A-1, 1969, 7, 2757-2762.

6. Takekoshi, T., Synthesis of polyimides, Plastics Engineering, 1996, 36, 7-48 (review).

7. De Abajo, J. and De la Campa, J. G., Processable aromatic polyimides, Advances in

Polymer Science, 1999, 140, 23-59 (review).

8. Barikani, M., Polyimides derived from diisocyanates, Iranian Polymer Journal, 2002,

11, 215-236 (review).

9. Sillion, B., Mercier, R. and Picq, D., Polyimides and other high-temperature polymers,

Synthetic methods in step-growth polymers, 2003, John Wiley & Sons, New York, pp

265-326.

10. De Visser, A. C., Driessen, A. A. and Wolke, J. G. C., Segmented copolyether-imides,

2, Makromolekulare Chemie, Rapid communication, 1980, 1, 177-181.

11. Jeon, J.-Y. and Tak, T. M., Synthesis and characterization of block

copoly(urethane-imide), Journal Of Applied Polymer Science, 1996, 62, 763-769.

12. Masiulanis, B. and Zielinski, R., Mechanical, thermal, and electric properties of

polyurethaneimide elastomers, Journal of Applied Polymer Science, 1985, 30, 2731-2741.

13. Jonquières, A., Roizard, D. and Lochon, P., Polymer design for pervaporation

membranes: Influence of the soft segment size of block copolymers (polyurethaneimides or

polyureaimides) on their pervaporation features, Journal of Membrane Science, 1996, 118,

73-84.

14. Koenitzer, B., Polyurethane-imide membranes and their use for the separation of

aromatics from non-aromatics, 1990, US Patent 4929358.

15. Jonquières, A., Dole, C., Clément, R. and Lochon, P., Synthesis and characterization

of new highly permeable polyamideimides from dianhydride monomers containing amide

functions. An application to the purification of a fuel octane enhancer (ETBE) by

pervaporation, Journal of Polymer Science, Part A: Polymer Chemistry, 2000, 38, 614-630.

16. Masiulanis, B. and Gostanski, K., Synthesis and properties of poly(urethaneimides)

from poly(oxytetramethylene)glycols, Polimery - Tworzywa Wielkoczasteczkowe, 1993, 38,

414-418.

17. Sendijarevic, A., Sendijarevic, V., Frisch, K. C., Koruga-Lazarevic, B. and Torlic, E.,

Synthesis and properties of urethane-modified polyimides, Journal of Polymer Science Part

A: Polymer Chemistry, 1990, 28, 3603-3615.

18. Liu, J., Ma, D. and Li, Z., FTIR studies on the compatibility of hard-soft segments for

polyurethane-imide copolymers with different soft segments, European Polymer Journal,

2002, 38, 661-665.

19. Creffier, G., Nouveaux polyuréthaneimides cationomères pour les procédés de

séparation par membranes, Rapport de stage au LCPM, Nancy, France, 2002, 28 pages.

20. Buruiana, E. C., Buruiana, T., Strat, G. and Strat, M., Synthesis and optical properties

of new polyurethane cationomers with anchored stilbene chromophores, Journal of Polymer

Science, Part A: Polymer Chemistry, 2002, 40, 1918-1928.

21. Buruiana, T., Airinei, A., Buruiana, E. C. and Bestiuc, I., Polyurethane cationomers

with nitroazoaromatic groups, Die Angewandte Makromolekulare Chemie, 1998, 258, 39-44.

22. Buruiana, E. C., Buruiana, T., Strat, G. and Strat, M., Synthesis and fluorescence of

polyurethane cationomers N-modified with a stilbene chromophore, Journal of

Photochemistry and Photobiology A: Chemistry, 2004, 162, 23-31.

23. Jonquières, A., Clément, R. and Lochon, P., Permeability of block copolymers to

vapors and liquids, Progress in Polymer Science, 2002, 27, 1803-1877 (review).

24. Jonquières, A., Influence de la structure des matériaux et permeants sur les propriétés

de sorption et de transfert dans des systèmes polymère/liquides organiques, Thèse de doctorat

de l'Institut National Polytechnique de Lorraine, Nancy, France, 1994, 296 pages.

25. Heiss, H. L., Combs, F. P., Gemeinhardt, P. G., Saunders, J. H. and Hardy, E. E.,

Influence of acids and bases on preparation of urethane polymers, Journal of Industrial and

Engineering Chemistry (Washington, D. C.), 1959, 51, 929-34.

26. Saunders, J. H. and Frisch, K. C., Chapter 4 : Kinetics and catalysis of the isocyanate

reactions, Polyurethanes chemistry and technology, 1962, New York, London, Interscience

Publishers, John Wiley & Sons edn, pp 127-217.

27. Cooper, W., Pearson, R. W. and Darke, S., Isocyanate reactions and the structure of

polyurethanes, Industrial Chemist and Chemical Manufacturer, 1960, 36, 121-6.

28. Hepburn, C., Chapter 4 : Reaction rates, catalysis and surfactants, Polyurethane

elastomers, 1992, Elsevier Applied Science, London, second edn, pp 107-121.

29. Socrates, G., Infrared characteristic group frequencies, 1980, Wiley, Chichester, 1st

edn, 153 pages.

30. Rao, C. N., Chemical applications of infrared spectroscopy, 1963, Academic Press,

New York, London, 1st edn, 683 pages.

31. Wang, S.-K. and Sung, C. S. P., Spectroscopic characterization of model urea,

urethane compound and diamine extender for polyurethane-urea, Macromolecules, 2002, 35,

877-882.

32. De Abajo, J., Babe, S. G. and Fontan, J., Copolyanhydride-imides, Angewandte

Makromolekulare Chemie, 1971, 19, 121-134.

33. Pryde, C. A., IR studies of polyimides. I. Effects of chemical and physical changes

during cure, Journal of Polymer Science Part A Polymer Chemistry Edition, 1989, 27,

711-724.

34. Snyder, R. W., Thomson, B., Bartges, B., Czerniawski, D. and Painter, P. C., FTIR

studies of polyimides: Thermal curing, Macromolecules, 1989, 22, 4166-4172.

35. Lu, X., Wang, Y. and Wu, X., Investigation of interaction of polyester-polyurethanes

and their zwitterionomers by solid-state nuclear magnetic resonance, Polymer, 1992, 33,

958-962.

36. Kricheldorf, H. R. and Hull, W. E.,

¹⁵

N NMR spectroscopy. 27. Spectroscopy

characterization of polyurethanes and related compounds, Die Makromolekulare Chemie,

1981, 182, 1177-1196.

37. Zurakowska-Orszagh, J., Chreptowicz, T., Orzeszko, A. and Kaminski, J., Thermal

degradation of polyimides - I. Investigation of the role of isoimide structure on degradation

process, European Polymer Journal, 1979, 15, 409-413.

38. White, D. M., Takekoshi, T., Williams, F. J., Relles, H. M., Donahue, P. E., Klopper,

H. J., Loucks, G. R., Manello, J. S., Matthews, R. O. and Schluenz, R. W., Polyetherimides

via nitro-displacement polymerization: Monomer synthesis and

¹³

C-NMR analysis of

monomers and polymers, Journal of Polymer Science Part A: Polymer Chemistry, 1981, 19,

1635-1658.

39. Ando, S., Matsuura, T. and Nishi, S.,

¹³

C NMR analysis of fluorinated polyimides and

poly (amic acid)s, Polymer, 1992, 33, 2934-2939.

40. Masiulanis, B., Calusinski, G., Marjanski, W., Kotschy, M., Jurkowski, P., Goralczyk,

B., Staniszewska-kus, J., Solski, L. and A.Krzemien-Dabrowska, Investigation on suitability

of poly(urethaneimides) as biomaterials, Journal of Applied Polymer Science, 1995, 58,

1441-1454.

41. Liao, D. C., Hsieh, K. H. and Kao, S. C., Synthesis and characterization of

bismaleimide-polyurethane crosslinked copolymers, Journal of Polymer Science: Part A:

Polymer Chemistry, 1995, 33, 481-491.

42. Masiulanis, B., Calusinski, G. M. and Haponiuk, J. T., Physical, chemical and

mechanical properties of novel poly(urethaneamideimide)s, Journal of Biomaterials

Applications, 1997, 11, 296-317.

43. Wang, T.-L. and Huang, F.-J., Synthesis and properties of poly(amide-imide-urethane)

thermoplastic elastomers, Polymer International, 1998, 46, 280-284.

44. Zuo, M. and Takeichi, T., Preparation and characterization of poly(urethane-imide)

films prepared from reactive polyimide and polyurethane prepolymer, Polymer

Communications, 1999, 40, 5153-5160.

45. Jonquières, A., Vicherat, A. and Lochon, P., Synthesis and characterization of new

polyamideimides with a highly flexible soft block, Journal of Polymer Science, Part A:

Polymer Chemistry, 1999, 37, 2873-2889.

46. Brandrup, J. and Immergut, E. H., Polymer handbook, 1975, Wiley, New York, 2nd

edn, pages.

47. Varma, S. C., Ahsan, M. A., George, M. H. and Barrie, J. A., Synthesis of

3-(trimethylammonium)-1,2-propanediol iodide and its incorporation in polyurethane

cationomers, Polymer Communications, 1990, 31, 11-15.

48. Buruiana, T., Buruiana, E. C. and Bestiuc, I., Synthesis and characterization of some

2,4'-dibenzyldiisocyanate ionic polymers. VIII. Effect of bifunctional quaternization on the

physical properties of polyurethane cationomers, Revue Roumaine de Chimie, 1994, 39,

213-218.

49. Wenzlaff, A., Böddeker, K. W. and Hattenbach, K., Pervaporation of water--ethanol

through ion exchange membranes, Journal of Membrane Science, 1985, 22, 333-344.

50. Cabasso, I., Liu, Z.-Z. and Makenzie, T., The permselectivity of ion-exchange

membranes for non-electrolyte liquid mixtures. II. The effect of counterions (separation of

alcohol/water mixtures with Nafion membranes), Journal of Membrane Science, 1986, 28,

109-122.

51. Yoshida, H. and Miura, Y., Behavior of water in perfluorinated ionomer membranes

containing various monovalent cations, Journal of Membrane Science, 1992, 68, 1-10.

52. Ping, Z. H., Nguyen, Q. T., Chen, S. M. and Ding, Y. D., Pervaporation of

water-ethanol mixtures with polyacrylate-grafted polyethylene acid (PE-g-AA) membranes:

Physico-chemical analysis of the transport mechanism, Journal of Membrane Science, 2002,

195, 23-34.

53. Carey, F. A. and Sundberg, R. J., Advanced organic chemistry, 1990, Plenum Press,

3rd edn, pages.

54. Howells, R. D. and Mc Cown, J. D., Trifluoromethanesulfonic acid and derivatives,

Dans le document Nouvelles membranes polyurétaneimides cationomères à hautes performances pour la séparation de mélanges organiques par pervaporation : (Page 104-107)